WO2012060672A2 - 표백목분, 표백목분의 제조방법, 그것을 이용한 종이 및 그 제조방법 - Google Patents
표백목분, 표백목분의 제조방법, 그것을 이용한 종이 및 그 제조방법 Download PDFInfo
- Publication number
- WO2012060672A2 WO2012060672A2 PCT/KR2011/008430 KR2011008430W WO2012060672A2 WO 2012060672 A2 WO2012060672 A2 WO 2012060672A2 KR 2011008430 W KR2011008430 W KR 2011008430W WO 2012060672 A2 WO2012060672 A2 WO 2012060672A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- wood powder
- wood
- paper
- bleached
- bleaching
- Prior art date
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21B—FIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
- D21B1/00—Fibrous raw materials or their mechanical treatment
- D21B1/04—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21B—FIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
- D21B1/00—Fibrous raw materials or their mechanical treatment
- D21B1/04—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres
- D21B1/06—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by dry methods
- D21B1/063—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by dry methods using grinding devices
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/16—Bleaching ; Apparatus therefor with per compounds
- D21C9/163—Bleaching ; Apparatus therefor with per compounds with peroxides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/16—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only modified by a particular after-treatment
- D21H11/20—Chemically or biochemically modified fibres
Definitions
- the present invention mixes bleached wood flour with natural pulp to produce paper, thereby improving dehydration while reducing the amount of pulp used to provide cheap and high-quality paper. It relates to a manufacturing method.
- the paper is produced by natural pulp or by mixing recycled pulp, the natural pulp is a variety of materials such as wood, hemp, paper mulberry, rice straw, sugar cane, papyrus.
- paper is manufactured in the form of several layers of paper lamination due to the efficiency of raw material use and the dehydration of papermaking process, and the raw materials used in paper are largely distinguished from natural pulp and recycled pulp.
- the recycled pulp has a higher content of fines and ash than natural pulp, which not only reduces dehydration but also reduces the bulk and strength of the paper.
- the decrease in bulk increases the amount of pulp used in the paper manufacturing process, thereby increasing the production cost.
- the recycled pulp increases the number of reuses, thereby increasing the ability to contain water, thereby increasing drying energy.
- Patent Registration No. 10-0898383 uses wood flour to improve the bulk of paper. By making paper, the bulk of the paper is improved to reduce the amount of pulp used.
- the wood flour used in the above-mentioned patent is to use wood selected by classifying the wood powder pulverized with a grinder, in particular, the wood flour used in the prior patent is mixed with natural pulp without using recycled pulp (paper) It is used in paper production by mixing with), and it is not widely used in white paper, and it does not reduce the amount of expensive natural pulp compared to recycled pulp, thereby increasing the paper manufacturing cost.
- the present invention does not reduce the use of natural pulp by using wood flour in recycled pulp when wood flour is used to improve the bulk of paper, and it is difficult to utilize in producing white paper due to the use of unbleached wood flour. To solve the problem.
- S10 Wood pulp drying step of performing a process of drying the wood material to a 1-2% by weight after pulverizing the wood material into a wood pulp
- S20 wood flour classification and selection step of performing the process of classifying and selecting the wood pulp dried in the woodpulp drying step to wood powder of 0.15mm or less
- S30 Mixing the wood powder classification and selection step H 2 O 2 (hydrogen peroxide) 25 ⁇ 30% aqueous solution 220 ⁇ 270 [Kg] evenly to 1 ton (Ton) of the wood powder classification and selection, and to 350 [l] of water Sodium hydroxide (NaOH) 25-30 [Kg], sodium silicate (Na2SiO3) 24-38 [Kg] and 0.2-0.6 [g] non-fluorescent brightener are added, and it is spread evenly over the wood powder and stirred for 40-70 minutes with bleaching.
- NaOH sodium hydroxide
- Na2SiO3 sodium silicate
- non-fluorescent brightener 0.2-0.6 [g] non-
- Wood bleaching step of performing the process S40: after bleaching the wood powder bleaching step, bleaching wood powder drying step of drying the bleached wood powder by supplying steam in a temperature range of 130 ⁇ 180 °C 2 hours 30 minutes to 3 hours 30 minutes; S50: the bleached wood powder classification step to classify and select the bleached wood powder dried in the bleached wood powder drying step; characterized in that comprises a.
- the paper manufacturing method using bleached wood powder characterized in that the paper is prepared by mixing 5-20% by weight of the bleached wood powder and 80-95% by weight of natural pulp into a paper machine. .
- the paper and the manufacturing method according to an embodiment of the present invention is subjected to the process of selecting and crushing the wood material after drying and sorting to a certain size or less, and bleached by adding a selected wood powder with bleach and stirring for a certain time.
- the bleached wood powder is bleached wood powder through grinding, classification and selection process, and the bleached wood powder 5-20% by weight is mixed with 80-95% by weight of natural pulp, followed by paper making process.
- wood powder is prepared and bleached, and then bleached wood powder is mixed with natural pulp to produce paper, thereby improving dehydration and saving energy while bleaching wood flour.
- the mixed with natural pulp the amount of natural pulp is drastically reduced and widely used for the production of white paper.
- Figure 2 is a flow chart showing the steps of the method for producing bleached wood powder according to an embodiment of the present invention.
- the present invention in the production of paper, by avoiding the method of mixing and using wood powder in recycled pulp to bleach the wood powder and then mixed with natural pulp to produce paper by reducing the use of natural pulp while improving the bulk dehydration To save energy.
- the present invention describes a process of bleaching wood powder and a process of manufacturing paper using bleached wood powder.
- FIG. 2 is a flow chart showing the steps of a method for producing bleached wood powder according to an embodiment of the present invention.
- Step S10 The wood pulp is pulverized by pulverizing the wood material and dried to maintain the moisture content 1-2% by weight of the wood pulp.
- Step S20 The dried woodpulp is selected so that the fiber length is selected from wood flour of 0.15 mm or less while being classified.
- Step S30 The wood powder classification and sorting step is uniformly mixed with H 2 O 2 (hydrogen peroxide) 25-30% aqueous solution 220 ⁇ 270 [Kg] per ton of wood powder (Ton) classification and selection was made, 350 [l] of water Sodium hydroxide (NaOH) 25-30 [Kg], sodium silicate (Na2SiO3) 24-38 [Kg] and 0.2-0.6 [g] non-fluorescent brightener are added, and it is spread evenly over the wood powder and stirred for 40-70 minutes, bleaching The process of bleaching wood powder is carried out. At this time, the stirring time may be adjusted according to the amount and mixing degree of H 2 O 2 (hydrogen peroxide) aqueous solution and brine. In addition, when about 40 to 70 minutes have passed after the water is added, the moisture is sufficiently penetrated into the wood powder, it is judged that about 50 minutes is appropriate as a result of the experiment of the present inventors.
- H 2 O 2 hydrogen peroxide
- the internal temperature of the wood powder and agitator (not shown) for stirring the wood powder is to maintain a temperature range of 60 ⁇ 80 °C.
- Step S40 after bleaching in the wood powder bleaching step, bleaching wood powder drying step of drying the bleached wood powder using high temperature steam; when the bleaching is done in the bleaching equipment to dry the bleached wood powder using steam but 1 ton of wood powder
- the drying process should be about 2 hours 30 minutes to 3 hours 30 minutes.
- the bleached wood powder is dried by supplying steam in a temperature range of 130 to 180 ° C. for 2 hours 30 minutes to 3 hours 30 minutes.
- Step S50 Bleaching wood powder classification step of classifying and selecting the bleached wood powder dried in the bleaching wood powder drying step; After grinding the bleached wood powder dried in the bleaching wood powder drying step through the classification and selection process used in the manufacture of paper The bleached wood flour is prepared.
- the bleaching wood powder by the structure of this invention can be manufactured.
- FIG. 1 illustrates a paper manufacturing flowchart according to an embodiment of the present invention.
- the bleached wood powder prepared by the composition of the present invention is dispersed and added (10) through the process of mixing the bleached wood powder 5-20% by weight and natural pulp 80-95% by weight into a paper machine in a conventional manner To manufacture.
- the present invention is used to mix a certain amount of bleached wood powder to natural pulp without making paper only with natural pulp, thereby reducing the amount of natural pulp by improving the bulk of the bleached wood powder, improving the dehydration according to paper production It is to reduce energy.
- the present invention is used after bleaching the wood powder, unlike the existing method using the wood powder as it is, it can be widely used in the production of white paper in addition to the above advantages.
- the prepared wood material is put into a grinder to be pulverized into wood pulp, the wood pulp pulverized in the grinder is a water content 1-2% by weight through the drying process Dry to maintain.
- the wood material is pulverized into wood pulp and dried to allow sufficient drying to allow the water content of the wood pulp to be 1-2% by weight.
- the wood pulp which has been pulverized and dried, is classified to have a fiber length of 0.15 mm or less and is selected to make a fiber, and to use the pulverizer to match the fiber length of the above conditions, the wood flour exceeding the conditions in the classification process is crushed again. They have to go through the grinding process to have fiber sheets that can be used to make paper.
- wood flour with a fiber length of 0.15mm or less through the classification and selection process is added to a regular bleaching facility with a certain amount of water, and then waits for 5 minutes to allow sufficient moisture to be contained in the wood flour.
- the reason for containing moisture is to make the bleaching process smooth.
- the mixture of H 2 O 2 (hydrogen peroxide) 25-30% aqueous solution 220 ⁇ 270 [Kg] per 1 ton of wood powder classified and selected is evenly mixed and hydrated in 350 [l] of water.
- Sodium Silicate (Na2SiO3) 24 ⁇ 38 [Kg] and 0.2 ⁇ 0.6 [g] of Fluorescent Whitening Agent are added. Do this.
- the stirring time may be adjusted according to the amount and mixing degree of H 2 O 2 (hydrogen peroxide) aqueous solution and brine.
- the moisture is sufficiently penetrated into the wood powder, it is judged that about 50 minutes is appropriate as a result of the experiment of the present inventors.
- the internal temperature of the wood powder and agitator (not shown) for stirring the wood powder is to maintain a temperature range of 60 ⁇ 80 °C. By doing in this way, a homogeneous stirring effect is acquired.
- the steam is moved from the bleaching equipment to the steam equipment to dry the bleached wood powder with steam, but the drying process is performed for 2 to 30 minutes to 3 hours and 30 minutes per ton of wood powder. Take it through.
- the bleached wood flour dried by steam while the above-described drying process is subjected to the polishing process again to produce the bleached wood powder used for the manufacture of paper through the above-described classification and selection process.
- bleached wood flour When bleached wood flour is produced in the same manner as above, it is used to manufacture paper.
- the present invention is to prepare a paper by a conventional method using natural pulp, by mixing bleached wood powder with natural pulp to produce a paper, the amount of natural pulp required for the production of white paper by the amount of bleached wood powder It will dramatically reduce usage.
- the present invention mixes a certain amount of bleached wood powder with natural pulp, thereby reducing the amount of natural pulp used by improving the bulk of the bleached wood powder, and improving the dehydration property, thereby reducing the energy of paper manufacturing. .
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- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Paper (AREA)
Abstract
Description
Claims (4)
- S10: 목재료를 분쇄기로 분쇄하여 우드펄프로 만든 후 수분함량 1-2중량%로 건조시키는 과정을 수행하는 우드펄프 건조단계;S20: 상기 우드펄프 건조단계에서 건조된 우드펄프를 섬유장이 0.15mm 이하의 목분으로 분급하고 정선하는 과정을 수행하는 목분 분급정선단계;S30: 상기 목분 분급정선단계를 통해 분급 및 정선이 이루어진 목분 1톤(Ton)당 H2O2(과산화수소) 25~30% 수용액 220~270[Kg]을 골고루 혼합하고, 물 350[ℓ]에 수산화나트륨(NaOH) 25~30[Kg]과 규산나트륨(Na2SiO3) 24~38[Kg]과 무형광 증백제 0.2~0.6[g]을 첨가한 후, 목분에 골고루 뿌려서 40~70분간 교반하며 표백하는 과정을 수행하는 목분 표백단계;S40: 상기 목분 표백단계에서 표백을 행한 후, 130~180℃ 온도범위의 스팀을 2시간 30분 내지 3시간 30분정도 공급하여 표백목분을 건조시키는 표백목분 건조단계;S50: 상기 표백목분 건조단계에서 건조된 표백목분을 분급 및 정선하는 표백목분 분급정선단계;를 구비하여 이루어지는 것을 특징으로 하는 표백목분의 제조방법.
- 제1항에 기재된 방법에 의하여 제조되는 표백목분을 이용하여 제조한 종이.
- 제1항에 있어서,상기 제조된 표백목분 5-20중량%와 천연펄프 80-95중량%를 혼합하여 초지기에 투입하여 종이를 제조하는 것을 특징으로 하는 표백목분을 이용한 종이 제조방법.
- 제1항에 기재된 방법에 의하여 제조되는 표백목분.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/883,598 US20130292071A1 (en) | 2010-11-05 | 2011-11-07 | Method for manufacturing bleached wood powder and papers |
CN2011800535063A CN103348061A (zh) | 2010-11-05 | 2011-11-07 | 漂白木粉、漂白木粉的制造方法及利用该漂白木粉的纸及其制造方法 |
JP2013537619A JP5938837B2 (ja) | 2010-11-05 | 2011-11-07 | 漂白木粉、漂白木粉の製造方法、それを用いた紙及びその製紙方法 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020100109662A KR101207845B1 (ko) | 2010-11-05 | 2010-11-05 | 표백목분, 표백목분의 제조방법, 그것을 이용한 종이 및 그 제조방법 |
KR10-2010-0109662 | 2010-11-05 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2012060672A2 true WO2012060672A2 (ko) | 2012-05-10 |
WO2012060672A3 WO2012060672A3 (ko) | 2012-09-13 |
Family
ID=46024983
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/KR2011/008430 WO2012060672A2 (ko) | 2010-11-05 | 2011-11-07 | 표백목분, 표백목분의 제조방법, 그것을 이용한 종이 및 그 제조방법 |
Country Status (5)
Country | Link |
---|---|
US (1) | US20130292071A1 (ko) |
JP (1) | JP5938837B2 (ko) |
KR (1) | KR101207845B1 (ko) |
CN (1) | CN103348061A (ko) |
WO (1) | WO2012060672A2 (ko) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105906820B (zh) * | 2016-04-14 | 2019-03-01 | 封开县嘉诚纸业有限公司 | 一种改性木粉材料及其制备方法和应用 |
EP3994306A1 (en) * | 2019-07-05 | 2022-05-11 | UPM Plywood Oy | A wood based powder, a composite material comprising the wood based powder, and a method for manufacturing the wood based powder |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2004204274A (ja) * | 2002-12-25 | 2004-07-22 | Jfe Steel Kk | 高炉原料装入方法 |
JP2004204270A (ja) * | 2002-12-24 | 2004-07-22 | Nippon Steel Corp | 超音波式連続酸洗方法 |
KR100750875B1 (ko) * | 2006-03-09 | 2007-08-22 | 충남대학교산학협력단 | 개질된 목질섬유분을 이용한 벌크 및 휨강도가 증가된종이판지의 제조방법 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
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GB438434A (en) * | 1934-05-16 | 1935-11-18 | Henry Dreyfus | Improvements in the manufacture of cellulose |
FI61215B (fi) * | 1976-11-23 | 1982-02-26 | Defibrator Ab | Saett och anordning att kontinuerligt framstaella lignocellulosahaltiga fibermaterial |
JPS59222305A (ja) * | 1983-06-01 | 1984-12-14 | 永大化工株式会社 | 木粉の漂白方法 |
JP3125489B2 (ja) * | 1992-12-11 | 2001-01-15 | 王子製紙株式会社 | 微細リグノセルロース繊維およびその繊維を用いた紙製品 |
JPH06228898A (ja) * | 1993-01-29 | 1994-08-16 | New Oji Paper Co Ltd | 印刷用塗被紙 |
US6605350B1 (en) * | 1996-08-23 | 2003-08-12 | Weyerhaeuser Company | Sawdust alkaline pulp having low average degree of polymerization values and method of producing the same |
ID27230A (id) * | 1998-06-17 | 2001-03-08 | Alex Alt Biomass Inc Cs | Produk-produk pulp, kertas, arundo donax dan papan partikel |
BRPI0810574B1 (pt) * | 2007-04-24 | 2018-10-23 | Basf Se | processos para a produção de partículas de madeira branqueada, e para a produção de materiais baseados em madeira clara a branca |
KR100898383B1 (ko) * | 2008-07-11 | 2009-05-21 | 한솔제지주식회사 | 제지용 목분의 제조방법 및 이를 이용한 벌크가 증가된제지의 제조방법 |
CN101665624A (zh) * | 2009-09-28 | 2010-03-10 | 林远才 | 超细木质纤维粉及其制备方法及其应用 |
-
2010
- 2010-11-05 KR KR1020100109662A patent/KR101207845B1/ko active IP Right Grant
-
2011
- 2011-11-07 CN CN2011800535063A patent/CN103348061A/zh active Pending
- 2011-11-07 US US13/883,598 patent/US20130292071A1/en not_active Abandoned
- 2011-11-07 JP JP2013537619A patent/JP5938837B2/ja not_active Expired - Fee Related
- 2011-11-07 WO PCT/KR2011/008430 patent/WO2012060672A2/ko active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004204270A (ja) * | 2002-12-24 | 2004-07-22 | Nippon Steel Corp | 超音波式連続酸洗方法 |
JP2004204274A (ja) * | 2002-12-25 | 2004-07-22 | Jfe Steel Kk | 高炉原料装入方法 |
KR100750875B1 (ko) * | 2006-03-09 | 2007-08-22 | 충남대학교산학협력단 | 개질된 목질섬유분을 이용한 벌크 및 휨강도가 증가된종이판지의 제조방법 |
Also Published As
Publication number | Publication date |
---|---|
US20130292071A1 (en) | 2013-11-07 |
KR101207845B1 (ko) | 2012-12-04 |
WO2012060672A3 (ko) | 2012-09-13 |
JP2014506961A (ja) | 2014-03-20 |
CN103348061A (zh) | 2013-10-09 |
JP5938837B2 (ja) | 2016-06-22 |
KR20120048175A (ko) | 2012-05-15 |
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