WO2012008717A3 - Apparatus for coproducting iso type reaction products and alcohols from olefins, and method for coproducting them using the apparatus - Google Patents

Apparatus for coproducting iso type reaction products and alcohols from olefins, and method for coproducting them using the apparatus Download PDF

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Publication number
WO2012008717A3
WO2012008717A3 PCT/KR2011/005046 KR2011005046W WO2012008717A3 WO 2012008717 A3 WO2012008717 A3 WO 2012008717A3 KR 2011005046 W KR2011005046 W KR 2011005046W WO 2012008717 A3 WO2012008717 A3 WO 2012008717A3
Authority
WO
WIPO (PCT)
Prior art keywords
coproducting
type reaction
alcohol
olefins
alcohols
Prior art date
Application number
PCT/KR2011/005046
Other languages
French (fr)
Other versions
WO2012008717A2 (en
Inventor
Moo-Ho Hong
Dong-Hyun Ko
Sung-Shik Eom
Yong-Jin Choe
O-Hak Kwon
Dae-Chul Kim
Jae-Hui Choi
Original Assignee
Lg Chem, Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020110032435A external-priority patent/KR101089488B1/en
Application filed by Lg Chem, Ltd. filed Critical Lg Chem, Ltd.
Priority to JP2013518283A priority Critical patent/JP5422853B2/en
Priority to CN201180032502.7A priority patent/CN103025695B/en
Priority to US13/809,565 priority patent/US8791304B2/en
Publication of WO2012008717A2 publication Critical patent/WO2012008717A2/en
Publication of WO2012008717A3 publication Critical patent/WO2012008717A3/en
Priority to US14/275,723 priority patent/US9029608B2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/175—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of an oxo group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

The present invention relates to an apparatus for coproducting iso-type reaction product and alcohol from olefin, and a method for coproducting using the apparatus, in which the hydroformylation reactor provides a sufficient reaction area due to the broad contact surface area between the olefin and the synthesis gases that are the raw materials by a distributor plate installed in the reactor, and the raw materials can be sufficiently mixed with the reaction mixture due to the circulation of the reaction mixture so that the efficiency of the production of the aldehyde is excellent; and also the hydrogenation reactor suppresses the side reaction so that the efficiency for producing aldehyde and alcohol are all increased, and also iso-type reaction product and alcohol can be efficiently co-produced.
PCT/KR2011/005046 2010-07-14 2011-07-11 Apparatus for coproducting iso type reaction products and alcohols from olefins, and method for coproducting them using the apparatus WO2012008717A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2013518283A JP5422853B2 (en) 2010-07-14 2011-07-11 Co-production of isotype aldehyde and alcohol from olefins
CN201180032502.7A CN103025695B (en) 2010-07-14 2011-07-11 An apparatus for coproduction of iso type aldehydes and alcohols from olefins, and a method for coproduction using the apparatus
US13/809,565 US8791304B2 (en) 2010-07-14 2011-07-11 Apparatus for coproducting iso type reaction products and alcohols from olefins, and method for coproducting them using the apparatus
US14/275,723 US9029608B2 (en) 2010-07-14 2014-05-12 Apparatus for coproducting ISO type reaction products and alcohols from olefins, and method for coproducting them using the apparatus

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR10-2010-0067688 2010-07-14
KR20100067688 2010-07-14
KR10-2011-0032435 2011-04-08
KR1020110032435A KR101089488B1 (en) 2010-07-14 2011-04-08 An apparatus for coproduction of iso type aldehydes and alcohols from olefins, and a method for coproduction using the apparatus

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US13/809,565 A-371-Of-International US8791304B2 (en) 2010-07-14 2011-07-11 Apparatus for coproducting iso type reaction products and alcohols from olefins, and method for coproducting them using the apparatus
US14/275,723 Continuation US9029608B2 (en) 2010-07-14 2014-05-12 Apparatus for coproducting ISO type reaction products and alcohols from olefins, and method for coproducting them using the apparatus

Publications (2)

Publication Number Publication Date
WO2012008717A2 WO2012008717A2 (en) 2012-01-19
WO2012008717A3 true WO2012008717A3 (en) 2012-04-26

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2011/005046 WO2012008717A2 (en) 2010-07-14 2011-07-11 Apparatus for coproducting iso type reaction products and alcohols from olefins, and method for coproducting them using the apparatus

Country Status (1)

Country Link
WO (1) WO2012008717A2 (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101411040B1 (en) * 2012-05-24 2014-06-27 주식회사 엘지화학 Catalyst compositions for hydroformylation reaction and hydroformylation process using the same
EP2991956B1 (en) 2013-05-03 2019-02-27 Saudi Basic Industries Corporation Integrated process for simultaneous production of oxo-alcohols and plasticizers
CN104513143A (en) * 2013-09-26 2015-04-15 陶氏技术投资有限责任公司 Hydroformylation process
JP2016540780A (en) 2013-12-19 2016-12-28 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー Hydroformylation process
CN104725170B (en) 2013-12-19 2019-08-23 陶氏技术投资有限责任公司 Hydroformylation process
CN109071394B (en) 2016-03-18 2022-02-08 陶氏技术投资有限责任公司 Hydroformylation process
CN107032953B (en) * 2017-05-10 2023-08-04 张家港市华昌新材料科技有限公司 Device and conversion method suitable for octanol and butanol conversion production
TWI788364B (en) 2017-06-23 2023-01-01 美商陶氏科技投資有限公司 Hydroformylation reaction processes
GB201806127D0 (en) * 2018-04-13 2018-05-30 Johnson Matthey Davy Technologies Ltd Process
BR112023017950A2 (en) 2021-03-31 2023-10-10 Dow Technology Investments Llc CONTINUOUS HYDROFORMYLATION PROCESS
CN113041962B (en) * 2021-04-01 2023-05-26 南京延长反应技术研究院有限公司 Reaction system and method for preparing butyraldehyde by propylene carbonylation

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4684750A (en) * 1985-08-29 1987-08-04 Ruhrchemie Aktiengesellschaft Process for the production of 2-ethyl-hexanol
US20020028974A1 (en) * 2000-07-14 2002-03-07 Oxeno Olefinchemie Gmbh Multistage process for the preparation of oxo aldehydes and/or alcohols
KR20080105004A (en) * 2007-05-29 2008-12-03 주식회사 엘지화학 Method for the hydroformylation of olefins and apparatus using the same
KR20100058713A (en) * 2008-11-25 2010-06-04 주식회사 엘지화학 Reactor for the hydroformylation of olefin and method for the hydroformylation using the same
WO2010082793A2 (en) * 2009-01-16 2010-07-22 (주) 엘지화학 Apparatus for producing alcohols from olefins
KR20110038324A (en) * 2009-10-08 2011-04-14 주식회사 엘지화학 Method for the hydrogenation of aldehydes and apparatus using the same

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4684750A (en) * 1985-08-29 1987-08-04 Ruhrchemie Aktiengesellschaft Process for the production of 2-ethyl-hexanol
US20020028974A1 (en) * 2000-07-14 2002-03-07 Oxeno Olefinchemie Gmbh Multistage process for the preparation of oxo aldehydes and/or alcohols
KR20080105004A (en) * 2007-05-29 2008-12-03 주식회사 엘지화학 Method for the hydroformylation of olefins and apparatus using the same
KR20100058713A (en) * 2008-11-25 2010-06-04 주식회사 엘지화학 Reactor for the hydroformylation of olefin and method for the hydroformylation using the same
WO2010082793A2 (en) * 2009-01-16 2010-07-22 (주) 엘지화학 Apparatus for producing alcohols from olefins
KR20110038324A (en) * 2009-10-08 2011-04-14 주식회사 엘지화학 Method for the hydrogenation of aldehydes and apparatus using the same

Also Published As

Publication number Publication date
WO2012008717A2 (en) 2012-01-19

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