WO2011161131A1 - Mélanges herbicides - Google Patents

Mélanges herbicides Download PDF

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Publication number
WO2011161131A1
WO2011161131A1 PCT/EP2011/060389 EP2011060389W WO2011161131A1 WO 2011161131 A1 WO2011161131 A1 WO 2011161131A1 EP 2011060389 W EP2011060389 W EP 2011060389W WO 2011161131 A1 WO2011161131 A1 WO 2011161131A1
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group
salts
methyl
esters
compound
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PCT/EP2011/060389
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English (en)
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Markus Gewehr
Matthias Pohlman
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Basf Se
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof

Definitions

  • the present invention relates to mixtures comprising, as active compounds
  • non ACC herbicides namely benfuresate, butylate, cycloate, dalapon, dime- piperate, EPTC, esprocarb, ethofumesate, flupropanate, molinate, orbencarb, pebulate, prosulfocarb, TCA, thiobencarb, tiocarbazil, triallate and vernolate; b2) the group of the ALS inhibitors selected from the group consisting of
  • sulfonylureas selected from the group consisting of amidosulfuron, azimsulfuron, bensulfuron, bensulfuron-methyl, chlorimuron, chlorimuron-ethyl, chlorsulfuron, cinosulfuron, cyclosulfamuron, ethametsulfuron, ethametsulfuron-methyl, ethox- ysulfuron, flazasulfuron, flucetosulfuron, flupyrsulfuron, flupyrsulfuron-methyl- sodium, foramsulfuron, halosulfuron, halosulfuron-methyl, imazosulfuron, iodo- sulfuron, iodosulfuron-methyl-sodium, mesosulfuron, metazosulfuron, metsulfu- ron, metsulfuron-methyl, nicosulfuron, orthosulfamuron,
  • imidazolinones selected from the group consisting of imazamethabenz, ima- zamethabenz-methyl, imazamox, imazapic, imazapyr, imazaquin and
  • triazolopyrimidine herbicides and sulfonamides selected from the group consisting of cloransulam, cloransulam-methyl, diclosulam, flumetsulam, florasulam, metosulam, penoxsulam, pyrimisulfan and pyroxsulam,
  • pyrimidinylbenzoates selected from the group consisting of bispyribac, bispyri- bac-sodium, pyribenzoxim, pyriftalid, pyriminobac, pyriminobac-methyl, pyrithio- bac, pyrithiobac-sodium, 4-[[[2-[(4,6-dimethoxy-2- pyrimidinyl)oxy]phenyl]methyl]amino]-benzoic acid-1 -methylethyl ester (CAS 420138-41 -6), 4-[[[[2-[(4,6-dimethoxy-2-pyrimidinyl)oxy]phenyl]methyl]amino]- benzoic acid propyl ester (CAS 420138-40-5) and N-(4-bromophenyl)-2-[(4,6- dimethoxy-2-pyrimidinyl)oxy]benzenemethanamine (CAS 420138-01 -8) and sulfonylamino
  • the group of the photosynthesis inhibitors selected from the group consisting of arnica rbazone,
  • inhibitors of the photosystem II selected from the group consisting of triazine herbicides, including chlorotriazine, triazinones, triazindiones, methylthiotriazines and pyridazinones such as ametryn, atrazine, chloridazone, cyanazine, des- metryn, dimethametryn,hexazinone, metribuzin, prometon, prometryn, propazin, simazin, simetryn, terbumeton, terbuthylazin, terbutryn and trietazin,
  • triazine herbicides including chlorotriazine, triazinones, triazindiones, methylthiotriazines and pyridazinones such as ametryn, atrazine, chloridazone, cyanazine, des- metryn, dimethametryn,hexazinone, metribuzin, prometon, prometryn, prop
  • aryl urea compounds such as chlorobromuron, chlorotoluron, chloroxuron, dime- furon, diuron, fluometuron, isoproturon, isouron, linuron, metamitron, metha- benzthiazuron, metobenzuron, metoxuron, monolinuron, neburon, siduron, te- buthiuron and thiadiazuron,
  • phenyl carbamates such as desmedipham, karbutilat, phenmedipham and phenmedipham-ethyl
  • nitrile herbicides such as bromofenoxim, bromoxynil and its salts and esters, ioxynil and its salts and esters,
  • uraciles such as bromacil, lenacil and terbacil
  • the group of the protoporphyrinogen-IX oxidase inhibitors selected from the group consisting of acifluorfen, acifluorfen-sodium, azafenidin, bencarbazone, ben- zfendizone, bifenox, butafenacil, carfentrazone, carfentrazone-ethyl, chlometh- oxyfen, cinidon-ethyl, fluazolate, flufenpyr, flufenpyr-ethyl, flumiclorac, flumi- clorac-pentyl, flumioxazin, fluoroglycofen, fluoroglycofen-ethyl, fluthiacet, flu- thiacet-methyl, fomesafen, halosafen, lactofen, oxadiargyl, oxadiazon, oxyfluor- fen, pentoxazone, profluazol,
  • PDS inhibitors selected from the group consisting of beflubutamid, diflufenican, fluridone, flurochloridone, flurtamone, norflurazon, picolinafen, and 4-(3- trifluoromethylphenoxy)-2-(4-trifluoromethylphenyl)pyrimidine (CAS 180608-33- 7),
  • HPPD inhibitors selected from the group consisting of benzobicyclon, ben- zofenap, isoxaflutole, mesotrione, pyrasulfotole, pyrazolynate, pyrazoxyfen, sul- cotrione, tefuryltrione, tembotrione, topramezone and bicyclopyrone, and bleacher, unknown target selected from the group consisting of aclonifen, ami- trole, clomazone and flumeturon;
  • the group of the glutamine synthase inhibitors selected from the group consisting of bilanaphos (bialaphos), bilanaphos-sodium, glufosinate and ist salts, in particular glufosinate-P or glufosinate-ammonium;
  • the group of the mitose inhibitors selected from the group consisting of compounds of group K1 selected from the group consisting of dinitroanilines such as benflu- ralin, butralin, dinitramine, ethalfluralin, fluchloralin, oryzalin, pendimethalin, prodiamine and trifluralin,
  • phosphoramidates such as amiprophos, amiprophos-methyl and butamiphos, benzoic acid herbicides such as chlorthal and chlorthal-dimethyl,
  • pyridines such as dithiopyr and thiazopyr
  • benzamides such as propyzamide and tebutam
  • chloroacetamides such as acetochlor, alachlor, butachlor, dimethachlor, di- methenamid, dimethenamid-P, metazachlor, metolachlor, metolachlor-S, pethox- amid, pretilachlor, propachlor, propisochlor and thenylchlor,
  • oxyacetanilides such as flufenacet and mefenacet
  • acetanilides such as diphenamid, naproanilide and napropamide
  • tetrazolinones such as fentrazamide, and other herbicides such as anilofos, cafenstrole, fenoxasulfone, ipfencarba- zone, piperophos and pyroxasulfone;
  • cellulose biosynthesis inhibitors selected from the group consisting of chlorthiamid, dichlobenil, flupoxam, isoxaben, 1 -cyclohexyl-5- pentafluorphenyloxy-14-[1 ,2,4,6]thiatriazin-3-ylamine and piperazine compounds of formula III,
  • A is phenyl or pyridyl where R a is attached in the ortho-position to the point of attachment of A to a carbon atom;
  • Ry is d-Ce-alkyl, C 3 -C 4 -alkenyl, C 3 -C 4 -alkynyl, NR A R B or Ci-C 4 -haloalkyl and q is 0, 1 or 2;
  • R A ,R B independently of one another are hydrogen, Ci-C6-alkyl, C3-C6- alkenyl and C3-C6-alkynyl; together with the nitrogen atom to which they are attached, R A , R B may also form a five- or six-membered saturated, partially or fully unsaturated ring which, in addition to carbon atoms, may contain 1 , 2 or 3 heteroatoms selected from the group consisting of O, N and S, which ring may be substituted by 1 to 3 groups R aa ;
  • D is a covalent bond or Ci-C 4 -alkylene
  • R a1 is hydrogen, OH, Ci-C 8 -Alkyl, Ci-C 4 -haloalkyl, C 3 -C 6 -cycloalkyl;
  • R b independently of one another is CN, NO2, halogen, Ci-C 4 -alkyl, Ci-C 4 - haloalkyl, C2-C 4 -alkenyl, C3-C6-alkynyl, Ci-C 4 -alkoxy, Ci-C 4 -haloalkoxy, ben-
  • R b together with the group R a or R b attached to the adjacent ring atom may also form a five- or six-membered saturated or partially or fully unsaturated ring which, in addition to carbon atoms, may contain 1 , 2 or 3 heteroatoms selected from the group consisting of O, N and S, which ring may be partially or fully substituted by R aa ;
  • p is 0 or1 ;
  • R 40 is hydrogen, Ci-C4-alkyl, Ci-C4-haloalkyl, Ci-C4-alkoxy or Ci-C4-haloalkoxy; where in groups R 30 , R a and their sub-substituents the carbon chains and/or the cyclic groups may carry 1 , 2, 3 or 4 substituents R aa and/or R a1 ;
  • R 31 is Ci-C 4 -alkyl
  • R 25 is hydrogen, Ci-C4-alkyl, Ci-C4-haloalkyl, Ci-C4-alkoxy or Ci-C4-halo-alkoxy
  • R 33 is hydrogen, or R 33 and R 34 together are a covalent bond
  • R 34 , R 35 , R 36 , R 37 independently of one another are hydrogen;
  • R 38 , R 39 independently of one another are hydrogen, halogen or OH;
  • the group of the decoupler herbicides selected from the group consisting of di- noseb, dinoterb and DNOC and its salts;
  • the group of the auxin herbicides selected from the group consisting of 2,4-D and its salts and esters, 2,4-DB and its salts and esters, aminopyralid and its salts such as aminopyralid-tris(2-hydroxypropyl)ammonium and its esters, bena- zolin, benazolin-ethyl, chloramben and its salts and esters, clomeprop, clopyralid and its salts and esters, dicamba and its salts and esters, dichlorprop and its salts and esters, dichlorprop-P and its salts and esters, fluroxypyr and its salts or esters, MCPA and its salts and esters, MCPA-thioethyl, MCPB and its salts and esters, mecoprop and its salts and esters, mecoprop-P and its salts and esters, picloram and its salts and esters, quinclorac, quinmerac, TBA (2,3,
  • auxin transport inhibitors selected from the group consisting of diflufenzopyr and its salts, naptalam and its salts;
  • the group of the other herbicides selected from the group consisting of bromobu- tide, chlorflurenol, chlorflurenol-methyl, cinmethylin, cumyluron, dalapon, dazo- met, difenzoquat, difenzoquat-metilsulfate, dimethipin, DSMA, dymron, endothal and its salts, etobenzanid, flamprop, flamprop-isopropyl, flamprop-methyl, flam- prop-M-isopropyl, flamprop-M-methyl, flurenol, flurenol-butyl, flurprimidol, fosa- mine, fosamine-ammonium, indanofan, indaziflam, maleic hydrazide, mefluidide, metam, methiozolin (CAS 403640-27-7), methyl azide, methyl bromide, methyl- dymron,
  • the mixture of the present invention generally includes the at least one compound I and the compound II in synergistically effective amounts.
  • the mixtures of the present invention will have herbicide action due to the presence of the compound I as well as insecticide, acaricide or nematicide action due to the presence of the compound II.
  • the mixture of the present invention generally leads to a synergism between the at least one compound I and the compound II.
  • Synergism in terms of the present invention means that the use of the inventive mixture leads to an effect which surpasses the additive effect (in mathematical terms) of the compounds I and II, when applied indi- vually.
  • the term "in synergistically effective amounts” refers to the fact that the purely additive effect (in mathematical terms) of the application of the individual compounds is surpassed by the application of the inventive mixture.
  • the health of a plant is increased synergistically.
  • in synergistically effective amounts refers to the fact that the purely additive effect (in mathematical terms) of the application of the individual compounds is surpassed by the application of the inventive mixture.
  • the synergistic increase of the health of a plant is more than surprising, since it can be assumed that nematicidal compounds and herbicides have completely different mode of actions.
  • effective amount denotes an amount of the inventive mixtures, which is sufficient for achieving the synergistic plant health effects, in particular the plant health effects as defined herein, especially the yield effects as defined herein. More exemplary information about amounts, ways of application and suitable ratios to be used is given below.
  • the present invention also relates to a method for increasing the health of a plant, in particular in a synergistic manner, in particular the yield of a plant, wherein the plant, the locus where the plant is growing or is expected to grow or plant propagation material from which the plant grows is treated with a effective amount, in particular with a synergistically effective amount, of a mixture as defined above.
  • the respective compounds I can also be used as in their form as agriculturally acceptable salts and esters.
  • suitable salts include those salts, where the counterion is an agri- culturally acceptable cation or anion.
  • suitable agriculturally acceptable cations are in particular the ions of the alkali metals, preferably lithium, sodium and potassium, of the alkaline earth metals, preferably calcium, magnesium and barium, and of the transition metals, preferably manganese, copper, zinc and iron, and also ammonium (NhV) and substituted ammonium substituted ammonium (hereinafter also termed as organoam- monium) in which one to four hydrogen atoms are replaced by Ci-C4-alkyl, hydroxy-Ci- C4-alkyl, Ci-C4-alkoxy-Ci-C4-alkyl, hydroxy-Ci-C4-alkoxy-Ci-C4-alkyl, phenyl or benzyl, preferably ammonium, methylammonium, isopropylammonium, dimethylammonium, diiso
  • Suitable agriculturally acceptable anions are in particular the halogenides, especially the chlorides, the nitrates, sulfates, hydrogensulfates, phosphates, hydrogenphos- phates, ammoniumhydrogenphosphates, borates including orthoborates and metabo- rates such as diborates and pentaborates, formiates, acetates, propionates etc.
  • Suitable ester include the methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, n- pentyl, n-hexyl, isooctyl, 2-methoxylethyl, 2-ethoxyethyl, 1 -methyl-2-butoxyethyl (bu- tometyl), 2-butoxyethyl (butotyl), 3-butoxypropyl, 2-butoxypropyl, 2-ethylhexyl and mexyl (1 -methylhexyl) esters.
  • suitable salts of dicamba are dicamba-sodium, dicamba-potassium, dicamba-methylammonium, dicamba-dimethylammonium, dicamba- isopropylammonium, dicamba-diglycolamine, dicamba-olamine, dicamba-diolamine and dicamba-trolamine.
  • suitable ester are dicamba-methyl and dicamba-butoyl.
  • Suitable salts of 2,4-D are 2,4-D dimethylammonium, 2,4-D diethanolammonium, 2,4-D triethanolammonium, 2,4-D triisopropanolammonium, 2,4-D sodium; 2,4-D isopropylammonium.
  • Examples of a suitable ester of 2,4-D are 2,4-D-butotyl, 2,4-D-butyl, 2,4- D-ethyl, 2,4-D-ethylhexyl, 2,4-D-isobutyl, 2,4-D-isoctyl, 2,4-D-isopropyl.
  • Suitable salts of 2,4-DB are for example 2,4-DB sodium, 2,4-DB potassium and 2,4-DB dimethylammonium.
  • Suitable salts of dichlorprop are for example dichlorprop potassium and dichlorprop dimethylammonium.
  • Examples of a suitable ester of dichlorprop are dichlorprop-butotyl and dichlorprop-isoctyl.
  • Suitable salts and esters of MCPA include MCPA-butotyl, MCPA-butyl, MCPA- dimethylammonium, MCPA-diolamine, MCPA-ethyl, MCPA-thioethyl, MCPA-2- ethylhexyl, MCPA-isobutyl, MCPA-isoctyl, MCPA-isopropyl, MCPA-methyl, MCPA- olamine, MCPA-potassium, MCPA-sodium and MCPA-trolamine.
  • MCPB is MCPB sodium.
  • a suitable ester of MCPB is MCPB-ethyl.
  • Suitable salts of clopyralid are clopyralid potassium, clopyralid olamine and clopyralid triisopropanolammonium.
  • Examples of a suitable ester of fluroxypyr are fluroxypyr-meptyl and fluroxypyr-2- butoxy-1 -methylethyl, wherein fluroxypyr-meptyl is preferred.
  • Suitable salts of picloram are picloram dimethylammonium, picloram potassium, piclo- ram triisopropanolammonium, picloram triisopropylammonium and picloram trolamine.
  • a suitable ester of picloram is picloram-isoctyl.
  • a suitable salt of triclopyr is triclopyr triethalammonium.
  • a suitable ester of triclopyr is triclopyr-butotyl.
  • Suitable salts and esters of chloramben include chloramben-ammonium, chloramben- diolamine, chloramben-methyl, chloramben-methylammonium and chloramben-sodium.
  • Suitable salts and esters of 2,3,6-TBA include 2,3,6-TBA-dimethylammonium, 2,3,6- TBA-lithium, 2,3,6-TBA-potassium and 2,3,6-TBA-sodium.
  • Suitable salts and esters of aminopyralid include aminopyralid-potassium and amino- pyralid-tris(2-hydroxypropyl)ammonium.
  • Suitable salts of glyphosate are for example glyphosate-ammonium, glyphosate- diammonium, glyphoste-dimethylammonium, glyphosate-isopropylammonium, gly- phosate-potassium, glyphosate-sodium, glyphosate-trimesium as well as the etha- nolamine and diethanolamine salts, preferably glyphosate-diammonium, glyphosate- isopropylammonium and glyphosate-trimesium (sulfosate).
  • Suitable salts of glufosinate are for example glufosinate-ammonium and glufosinate-P.
  • Suitable salts and esters of bromoxynil are for example bromoxynil butyrate, bro- moxynil heptanoate, bromoxynil octanoate, bromoxynil potassium and bromoxynil sodium;
  • Suitable salts of ioxonil are for example ioxonil-octanoate, ioxonil-potassium and ioxo- nil-sodium.
  • Suitable salts and esters of mecoprop include mecoprop-butotyl, mecoprop- dimethylammonium, mecoprop-diolamine, mecoprop-ethadyl, mecoprop-2-ethylhexyl, mecoprop-isoctyl, mecoprop-methyl, mecoprop-potassium, mecoprop-sodium and me- coprop-trolamine.
  • Suitable salts of mecoprop-P are for example butotyl, dimethylammonium, ethylhexyl, potassium and sodium
  • Suitable salts of diflufenzopyr is diflufenzopyr-sodium.
  • Suitable salts of naptalam is naptalam -sodium.
  • Suitable salts of DNOC are for example DNOC-ammonium, DNOC-potassium and DNOC-sodium
  • Suitable salts and esters of 2,4-DB are for example 2,4-DB-butylester, 2,4-DB- dimethylammonium, 2,4-DB-triisopropanolammonium, 2,4-DB-isoctyl, 2,4-DB- potassium and 2, 4-DB-sodium
  • Suitable salts of aminocyclopyrachlor are for example aminocyclopyrachlor dimethyl- ammonium, aminocyclopyrachlor triisopropanolammonium, aminocyclopyrachlor sodium and aminocyclopyrachlor potassium
  • the compound II of formula II which has the IPAC name [(3S,4R,4aR,6S,6aS,12R,
  • Healthier plants are desirable since they result among others in better yields and/or a better quality of the plants or crops. Healthier plants also better resist to biotic and/or abiotic stress. A high resistance against biotic stresses in turn allows the person skilled in the art to reduce the quantity of pesticides applied and consequently to slow down the development of resistances against the respective pesticides.
  • these objects are in part or in whole achieved by using the mixtures as defined in the outset.
  • Preferred mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from b1 ) the group of the lipid biosynthesis inhibitors, wherein in this group, preference is given to compounds selected from the group consisting of clethodim, clodinafop-propargyl, cycloxydim, cyhalofop-butyl, diclofop-methyl, fenoxaprop, fenoxaprop-ethyl, fenoxaprop-P, fenoxaprop-P-ethyl, fluazifop, fluazifop-butyl, fluazifop-P, fluazifop-P- butyl, haloxyfop-P-methyl, metamifop, pinoxaden, profoxydim, propaquizafop, quizalo- fop-P-ethyl, quizalofop-P-
  • Preferred mixtures of the invention are also mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from b2) the group of the ALS inhibitors, wherein in this group, preference is given to the compounds selected from the group consisting of
  • sulfonylureas in particular those selected from the group consisting of amidosul- furon, azimsulfuron, bensulfuron-methyl, chlorimuron-ethyl, chlorsulfuron, cyclo- sulfamuron, ethametsulfuron-methyl, ethoxysulfuron, flazasulfuron, flucetosulfu- ron, flupyrsulfuron-methyl-sodium, foramsulfuron, halosulfuron-methyl, imazosul- furon, iodosulfuron, iodosulfuron-methyl-sodium, mesosulfuron, metazosulfuron, metsulfuron-methyl, nicosulfuron, orthosulfamuron, oxasulfuron, primisulfuron, primisulfuron-methyl, prosulfuron, pyrazosulfuron-ethyl,
  • Preferred mixtures of the invention are also mixtures comprising at least one com- pound I and the compound II, wherein the at least one compound (I) is selected from b2) the group of the ALS inhibitors, selected from the group consisting of
  • imidazolinones selected from the group consisting of imazamethabenz, ima- zamethabenz-methyl, imazamox, imazapic, imazapyr, imazaquin and
  • Preferred mixtures of the invention are also mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from b2) the group of the ALS inhibitors, selected from the group consisting of
  • the triazolopyrimidine herbicides and sulfonamides selected from the group con- sisting of diclosulam, flumetsulam, florasulam, metosulam, penoxsulam, pyrimisulfan and pyroxsulam and Preferred mixtures of the invention are also mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from b2) the group of the ALS inhibitors selected from the group consisting of
  • pyrimidinylbenzoates selected from the group consisting of bispyribac- sodium, pyribenzoxim, pyriftalid, pyriminobac-methyl, pyrithiobac-sodium, flucar- apelone-sodium, propoxycarbazon- sodium and thiencarbazone-methyl.
  • Preferred mixtures of the invention are also mixtures comprising at least one compound I and the compound II, wherein compound (I) is selected from the group b3), i.e. the group of the photosynthesis inhibitors (group b4), wherein in this group, preference is given to the compounds selected from the group consisting of amicarbazone, ametryn, atrazine, chloridazone, cyanazine, hexazinone, metribuzin, simazin, terbuthy- lazin and terbutryn, and wherein in this group is likewise preference is given to the compounds selected from the group consisting of the aryl ureas such as chlorotoluron, diuron, fluometuron, isoproturon, isouron, linuron, metamitron, methabenzthiazuron and thiadiazuron, the phenyl carbamates desmedipham, karbutilat or phenmedipham, bromoxynil and its salts and esters,
  • Preferred mixtures of the invention are also mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group of the protoporphyrinogen-IX oxidase inhibitors (group b4), wherein in this group, preference is given acifluorfen, acifluorfen-sodium, bencarbazone, ben- zfendizone, bifenox, butafenacil, carfentrazone, carfentrazone-ethyl, cinidon-ethyl, flufenpyr-ethyl, flumiclorac-pentyl, flumioxazin, fluoroglycofen-ethyl, fomesafen, lacto- fen, oxadiargyl, oxadiazon, oxyfluorfen, pentoxazone, pyraflufen-ethyl, saflufenacil, sulfentra
  • Preferred mixturesof the invention are also mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group of the bleacher herbicides (group b5), wherein in this group, preference is given to the PDS inhibitors diflufenican, flurochloridone and picolinafen, to the HPPD inhibi- tors benzobicyclon, isoxaflutole, mesotrione, sulcotrione, tefuryltrione, tembotrione, topramezone and bicyclopyrone and to the bleachers aclonifen, amitrole, clomazone and flumeturon.
  • group b5 group of the bleacher herbicides
  • Preferred mixtures of the invention are also mixtures comprising at least one compound I and the compound II, wherein compound (I) is selected from the group b6), i.e. the group of the EPSP synthase inhibitors, wherein in this group, preference is given to glyphosate and its salts.
  • Preferred mixtures are mixtures comprising compound I and compound II, wherein compound (I) is selected from b7) the group of the glutamine synthase inhibitors, wherein in this group, preference is given to glufosinate, and its salts.
  • Preferred mixtures of the invention are also mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group b9), i.e. the group of the mitose inhibitors, wherein in this group, preference is given to thedinitroanilines, in particular benfluralin, ethalfluralin, oryzalin, pendi- methalin and trifluralin, and the pyridines, in particular dithiopyr and thiazopyr.
  • Preferred mixtures of the invention are also mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group b10), i.e. the group of the VLCFA inhibitors, wherein in this group, preference is given to the chloroacetamides, which are in particular selected from the group con- sisting of acetochlor, alachlor, butachlor, dimethenamid, dimethenamid-P, metazachlor, metolachlor, metolachlor-S, pretilachlor and thenylchlor, to the the oxyacetanilides which are in particular selected from the group consisting of flufenacet and mefenacet, to the tetrazolinone fentrazamide, and to the compounds selected from the group consisting of cafenstrole, fenoxasulfone, ipfencarbazone andpyroxasulfone.
  • the group b10 i.e. the group of the
  • Preferred mixtures of the invention are also mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group b1 1 ), i.e. the group of the cellulose biosynthesis inhibitors, wherein in this group, preference is given to isoxaben and 1 -cyclohexyl-5-pentafluorphenyloxy-14- [1 ,2,4,6]thiatriazin-3-ylamine.
  • Preferred mixtures of the invention are also mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group of the compounds of the general formula III.
  • Preferred mixtures of the invention are also mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group b13), i.e. the group of the auxin herbicides, wherein in this group, preference is given to 2,4-D and its salts and esters, aminopyralid, clopyralid and its salts and es- ters, dicamba and its salts and esters, fluroxypyr and its salts or esters, MCPA and its salts and esters, MCPB and its salts and esters, mecoprop and its salts and esters, mecoprop-P and its salts and esters, picloram and its salts and esters, quinclorac, quinmerac, triclopyr and its salts and esters and aminocyclopyrachlor and its salts and esters.
  • the group b13 i.e. the group of the auxin herbicides, wherein in this group, preference is given to 2,4-D and its
  • Preferred mixtures of the invention are also mixtures comprising at least one com- pound I and the compound II, wherein the at least one compound (I) is selected from the group b14), i.e. the group of the auxin transport inhibitors, wherein in this group, preference is given to diflufenzopyr, and its salts.
  • Preferred mixtures of the invention are also mixtures comprising at least one com- pound I and the compound II, wherein the at least one compound (I) is selected from group b15), wherein in this group, preference is given to cinmethylin, dymron, indano- fan, indaziflam, oxaziclomefone and triaziflam.
  • More preferred mixtures of the invention are mixtures comprising at least one com- pound I and the compound II, wherein the at least one compound (I) is selected from the group b1 ), i.e. the group of the lipid biosynthesis inhibitors selected from the group consisting of clethodim, clodinafop-propargyl, cycloxydim, cyhalofop-butyl, fenoxaprop- P-ethyl, fluazifop-P-butyl, haloxyfop-P-methyl, pinoxaden, profoxydim, sethoxydim, te- praloxydim and tralkoxydim, esprocarb, prosulfocarb, thiobencarb and triallate.
  • the group lipid biosynthesis inhibitors selected from the group consisting of clethodim, clodinafop-propargyl, cycloxydim, cyhalofop-but
  • mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group b2), i.e. the group of the ALS inhibitors, where the ALS inhibitors are selected from the group consisting of the sulfonylureas bensulfuron-methyl, chlori- muron-ethyl, cyclosulfamuron, flupyrsulfuron-methyl-sodium, foramsulfuron, iodosulfu- ron, iodosulfuron-methyl-sodium, mesosulfuron, metazosulfuron, nicosulfuron, pyrazo- sulfuron-ethyl, rimsulfuron, sulfosulfuron, and tritosulfuron,
  • mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group b2), i.e. the group of the ALS inhibitors, where the the ALS inhibitors are selected from the group of the imidazolinones imazamethabenz, imazamethabenz- methyl, imazamox, imazapic, imazapyr, imazaquin and imazethapyr and their salts.
  • the group of the ALS inhibitors where the the ALS inhibitors are selected from the group of the triazolopyrimidine herbicides and sulfonamides, which are selected from the group consisting of diclosulam, flumetsulam, florasulam, penox- sulam and pyroxsulam.
  • the ALS inhibitors are selected from the group of the triazolopyrimidine herbicides and sulfonamides, which are selected from the group consisting of diclosulam, flumetsulam, florasulam, penox- sulam and pyroxsulam.
  • mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group b2), i.e.
  • the group of the ALS inhibitors where the ALS inhibitors are selected from the group of the pyrimidinylbenzoates bispyribac-sodium, pyribenzoxim, pyriftalid, propoxycarbazon- sodium and thiencarbazone-methyl.
  • mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from group b3), i.e. the group of the photosynthesis inhibitors selected from the group consisting of ametryn, atrazine, cyanazine, hexazinone, metribuzin, simazin, terbuthy- lazin and terbutryn.
  • group b3 i.e. the group of the photosynthesis inhibitors selected from the group consisting of ametryn, atrazine, cyanazine, hexazinone, metribuzin, simazin, terbuthy- lazin and terbutryn.
  • mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group of the b4) protoporphyrinogen-IX oxidase inhibitors selected from the group consisting of acifluorfen, acifluorfen-sodium, flumioxazin, fomesafen, lactofen, oxyfluorfen, saflufenacil, sulfentrazone, ethyl [3-[2-chloro-4-fluoro-5-(1 -methyl-6- trifluoromethyl-2,4-dioxo-1 ,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2- pyridyloxy]acetate, 2-(2,2,7-trifluoro-3-oxo-4-prop-2-ynyl-3,4-dihydro-2H- benzo[1 ,4]oxazin-6-yl
  • mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group of the b5) bleacher herbicides, which are selected from the group consisting of diflufenican, flurochloridone and picolinafen,
  • mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group of the b5) bleacher herbicides, which are selected from the group of the HPPD inhibitors: benzobicyclon, isoxaflutole, mesotrione, sulcotrione, tefuryltrione, tembotrione, topramezone and bicyclopyrone.
  • mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group b6) of the EPSP synthase inhibitors selected from the group consisting of glyphosate and its salts.
  • mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group b7) of the glutamine synthase inhibitors selected from the group consisting of glufosinate and its salts.
  • mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group b9) of the mitose inhibitors selected from the group consisting of the dinitroanilines, in particular from the group consisting of pendimethalin and trifluralin.
  • mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group b10) of the VLCFA inhibitors consisting of the chloroacetamides ace- tochlor, dimethenamid-P, metazachlor, metolachlor, metolachlor-S and pretilachlor and the oxyacetanilides flufenacet and mefenacet and the tetrazolinone fentrazamide.
  • VLCFA inhibitors consisting of the chloroacetamides ace- tochlor, dimethenamid-P, metazachlor, metolachlor, metolachlor-S and pretilachlor and the oxyacetanilides flufenacet and mefenacet and the tetrazolinone fentrazamide.
  • mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group b 1 1 ) of the cellulose biosynthesis inhibitors selected from the group consisting of isoxaben and 1 -cyclohexyl-5-pentafluorphenyloxy-14-[1 ,2,4,6]thiatriazin-3- ylamine.
  • mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group b 1 1 ) of the cellulose biosynthesis inhibitors selected from the group of the compounds of the formula III.
  • mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group b13) of the auxin herbicides selected from the group consisting of 2,4-D and its salts and esters, aminopyralid and its salts, clopyralid and its salts and esters, dicamba and its salts and esters, fluroxypyr-meptyl, MCPA, MCPB and its salts and esters, mecoprop and its salts and esters, quinclorac and quinmerac.
  • the auxin herbicides selected from the group consisting of 2,4-D and its salts and esters, aminopyralid and its salts, clopyralid and its salts and esters, dicamba and its salts and esters, fluroxypyr-meptyl, MCPA, MCPB and its salts and esters, mecoprop and its salts and esters, quinclorac and quinmerac.
  • mixtures of the invention are mixtures comprising a compound I and the compound II, wherein the compound (I) is the b14) the auxin transport inhibitor diflufenzopyr. Also more preferred mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from group b15) consisting of cinmethylin, dymron, indanofan, indaziflam, oxaziclome- fone and triaziflam.
  • Most preferred mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group b1 ) of the lipid biosynthesis inhibitors selected from the group consisting of clethodim, clodinafop-propargyl, cycloxydim, pinoxaden, profoxydim, sethoxydim, te- praloxydim and tralkoxydim.
  • mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group of the ALS inhibitors b2) selected from the group consisting of the sul- fonylureas chlorimuron-ethyl, foramsulfuron, nicosulfuron, rimsulfuron and tritosulfuron,
  • mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group of the ALS inhibitors b2) selected from the group consisting of the imi- dazolinones imazamox, imazapic, imazapyr, imazaquin and imazethapyr and their salts.
  • mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group of the ALS inhibitors b2) selected from the group consisting of the pyrimidinylbenzoates pyribenzoxim and pyriftalid.
  • mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group b3) of the photosynthesis inhibitors selected from the group consisting of ametryn, atrazine, cyanazine, simazin and terbuthylazin.
  • mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group b4) of the protoporphyrinogen-IX oxidase inhibitors selected from the group consisting of acifluorfen, flumioxazin, fomesafen, saflufenacil and sulfentrazone.
  • mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group b5) of the bleacher herbicides, selected from the group consisting of the PDS diflufenican, flurochloridone and picolinafen, Also most preferred mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group b5) of the bleacher herbicides, selected from the group consisting ofthe HPPD inhibitors: benzobicyclon, isoxaflutole, mesotrione, sulcotrione, tembotrione and topramezone.
  • mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the bleacher clomazone.
  • mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group b6) of the EPSP synthase inhibitors selected from the group consisting of glyphosate and its salts.
  • mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is the the mi- tose inhibitor pendimethalin. Also most preferred mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group b10) of the VLCFA inhibitors selected from the group consisting of the chloroacetamides acetochlor, dimethenamid-P, metazachlor, metolachlor, metolachlor- S and pretilachlor.
  • mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group b10) of the VLCFA inhibitors selected from the group consisting of the oxyacetanilide flufenacet and the tetrazolinone fentrazamide.
  • mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is selected from the group b13) of the auxin herbicides selected from the group consisting of 2,4-D and its salts and esters, clopyralid and its salts and esters, dicamba and its salts and esters, MCPA, quinclorac and quinmerac.
  • the auxin herbicides selected from the group consisting of 2,4-D and its salts and esters, clopyralid and its salts and esters, dicamba and its salts and esters, MCPA, quinclorac and quinmerac.
  • mixtures of the invention are mixtures comprising at least one compound I and the compound II, wherein the at least one compound (I) is indaziflam.
  • M-1 compound II and clethodim
  • M-2 compound II and clodinafop-propargyl
  • M-3 compound II and cycloxydim
  • M-4 compound II and pinoxaden
  • M-5 compound II and nicosulfuron
  • M-6 compound II and tritosulfuron
  • M-7 compound II and ima- zamox
  • M-8 compound II and imazapic
  • M-9 compound II and imazaquin
  • M-10 compound II and imazethapyr
  • M-1 1 compound II and pyribenzoxim
  • M-12 compound II and pyriftalid
  • M-13 compound II and atrazine
  • M-14 compound II and si- mazin
  • M-15 compound II and terbuthylazin
  • M-16 compound II and diuron
  • M-17 compound II and isoproturon
  • M-18 compound II and bro
  • the ratios by weight for the respective mixtures, in particular the binary mixtures, comprising the at least one compound I and the compound II are from from 1 :200 to 200:1 , in particular from 1 :100 to 100:1 or from 1 :50 to 50:1 , wherein the weight ratio of com- pound I is calculated as the free acid.
  • the mixtures of the invention may be binary mixtures comprising one compound I and the compound II.
  • the mixtures of the invention may also be mixtures comprising more than one compound I, e.g. 2, 3 or 4 compounds I, and the compound II.
  • the inventive mixtures can further contain one or more insecticides, fungicides, herbi- cides and plant growth regulators.
  • the present invention relates to a method for increasing the health of plants, wherein the plant, the locus where the plant is growing or is expected to grow or plant propagation material from which the plant grows is treated with an effective amount of an inven- tive mixture.
  • the present invention relates to a method for increasing the yield of a plant, wherein the plant, the locus where the plant is growing or is expected to grow or plant propagation material from which the plant grows is treated with an effective amount of an inventive mixture.
  • the present invention relates to a method of increasing the health of a plant by treating plants, parts of such plants or at their locus of growth with an effective amount of inventive mixture. In a further more preferred embodiment, the present invention relates to a method of increasing the yield of a plant by treating plants, parts of such plants or at their locus of growth with an effective amount of inventive mixture.
  • the compounds contained in the mixtures as defined above can be applied simultane- ously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
  • applying the compound I and compound II is to be understood to denote, that at least the compound I and compound II occur simultaneously at the site of action (i.e. plant, plant propagation material (preferably seed), soil, area, material or environment in which a plant is growing or may grow) in an effective amount.
  • site of action i.e. plant, plant propagation material (preferably seed), soil, area, material or environment in which a plant is growing or may grow
  • the weight ratio of the compounds generally depends from the properties of the compounds of the inventive mixtures.
  • the compounds of the inventive mixtures can be used individually or already partially or completely mixed with one another to prepare the composition according to the invention. It is also possible for them to be packaged and used further as combination composition such as a kit of parts.
  • kits may include one or more, including all, components that may be used to prepare a subject agrochemical composition.
  • kits may include the compound I and compound II and/or an adjuvant component and/or a further pesticidal compound (e.g. insecticide, fungicide or herbicide) and/or a growth regulator component).
  • a further pesticidal compound e.g. insecticide, fungicide or herbicide
  • One or more of the components may already be combined together or p re-formulated. In those embodiments where more than two components are provided in a kit, the components may already be combined together and as such are packaged in a single container such as a vial, bottle, can, pouch, bag or can- ister. In other embodiments, two or more components of a kit may be packaged separately, i.
  • kits may include one or more separate containers such as vials, cans, bottles, pouches, bags or canisters, each container containing a separate component for an agrochemical composition.
  • a component of the kit may be applied separately from or together with the further components or as a component of a combination composition according to the invention for preparing the composition according to the invention.
  • the user applies the composition according to the invention usually from a predosage device, a knapsack sprayer, a spray tank or a spray plane.
  • the agrochemical composition is made up with water and/or buffer to the desired application concentration, it being possible, if appropriate, to add further auxiliaries, and the ready-to-use spray liquid or the agrochemical composition according to the invention is thus obtained.
  • 50 to 500 liters of the ready-to-use spray liquid are applied per hectare of agricultural useful area, preferably 50 to 400 liters.
  • individual compounds of the inventive mixtures formulated as composition (or formulation) such as parts of a kit or parts of the inventive mixture may be mixed by the user himself in a spray tank and further auxiliaries may be added, if appropriate (tank mix).
  • either individual compounds of the inventive mixtures formulated as composition or partially premixed components e.g. components comprising the compound I and compound II may be mixed by the user in a spray tank and further auxiliaries and additives may be added, if appropriate (tank mix).
  • either individual components of the composition according to the invention or partially premixed components, e. g. components comprising the compound I and compound II , can be applied jointly (e. .g. after tankmix) or consecutively.
  • the term yield refers to fruits in the proper sense, vegetables, nuts, grains and seeds.
  • plants generally comprises all plants of economic importance and/or men- grown plants. They are preferably selected from agricultural, silvicultural and ornamen- tal plants, more preferably agricultural plants and silvicultural plants, utmost preferably agricultural plants.
  • plant (or plants) is a synonym of the term “crop” which is to be understood as a plant of economic importance and/or a men-grown plant.
  • plant as used herein includes all parts of a plant such as germinating seeds, emerging seedlings, herbaceous vegetation as well as established woody plants including all belowground portions (such as the roots) and aboveground portions.
  • the plants to be treated according to the invention are selected from the group consisting of agricultural, silvicultural, ornamental and horticultural plants more preferably from agricultural plants.
  • the plant to be treated according to the method of the invention is a horticultural plant.
  • the term "horticultural plants” are to be understood as plants which are commonly used in horticulture - e.g. the cultivation of ornamentals and/or fruits.
  • ornamentals are turf, geranium, pelargonia, petunia, begonia and fuchsia.
  • vegetables are potatoes, tomatoes, peppers, cucurbits, cucumbers, melons, watermelons, garlic, onions, carrots, cabbage, beans, peas and lettuce and more preferably from tomatoes, onions, peas and lettuce.
  • fruits are apples, pears, cherries, strawberry, citrus, peaches, apricots and blueberries.
  • the plant to be treated according to the method of the invention is an ornamental plant.
  • Ornamental plants are plants which are commonly used in gar- dening, e.g. in parks, gardens and on balconies. Examples are turf, geranium, pelargonia, petunia, begonia and fuchsia.
  • the plant to be treated according to the method of the invention is a silvicultural plants.
  • the term "silvicultural plant” is to be understood as trees, more specifically trees used in reforestation or industrial plantations.
  • Industrial plantations generally serve for the commercial production of forest products, such as wood, pulp, paper, rubber tree, Christmas trees, or young trees for gardening purposes.
  • Examples for silvicultural plants are conifers, like pines, in particular Pinus spec, fir and spruce, eucalyptus, tropical trees like teak, rubber tree, oil palm, willow (Salix), in particular Salix spec, poplar (cottonwood), in particular Populus spec, beech, in particular Fagus spec, birch, oil palm and oak.
  • the plant to be treated according to the method of the invention is an agricultural plant.
  • Agricultural plants are plants of which a part or all is harvested or cultivated on a commercial scale or which serve as an important source of feed, food, fibres (e.g. cotton, linen), combustibles (e.g. wood, bioethanol, biodiesel, biomass) or other chemical compounds.
  • Agricultural plants also include the horticultural plants fruits and vegetables.
  • the term agricultural plants include cereals, e.g. wheat, rye, barley, triticale, oats, sorghum or rice; beet, e.g. sugar beet or fodder beet; fruits, such as pomes, stone fruits or soft fruits, e.g.
  • the plants to be treated in accordance with the method of the present invention are agricultural plants. All of the above-mentioned plants may be also modified plants, which have been modified by breeding, mutagenesis or genetic engineering (transgenic and non-transgenic plants). Genetically modified plants are plants, which genetic material has been modified by the use of recombinant DNA techniques in a way that it cannot readily be obtained by cross breeding under natural circumstances, mutations or natural recombina- tion.
  • Plants as well as the propagation material of said plants, which can be treated with the inventive mixtures include all modified non-transgenic plants or transgenic plants, e.g. crops which tolerate the action of herbicides or fungicides or insecticides owing to breeding, including genetic engineering methods, or plants which have modified characteristics in comparison with existing plants, which can be generated for example by traditional breeding methods and/or the generation of mutants, or by recombinant procedures.
  • mixtures according to the present invention can be applied (as seed treatment, foliar spray treatment, in-furrow application or by any other means) also to plants which have been modified by breeding, mutagenesis or genetic engineering including but not limiting to agricultural biotech products on the market or in development (cf.
  • Genetically modified plants are plants, which genetic material has been so modified by the use of recombinant DNA techniques that under natural circumstances cannot readily be obtained by cross breeding, mutations or natural recombination. Typically, one or more genes have been integrated into the genetic material of a genetically modified plant in order to improve certain properties of the plant.
  • Such genetic modifications also include but are not limited to targeted post-transtional modification of protein(s), oligo- or polypeptides e.g. by glycosylation or polymer additions such as prenylated, acetylated or farnesy- lated moieties or PEG moieties.
  • Plants that have been modified by breeding, mutagenesis or genetic engineering, e.g. have been rendered tolerant to applications of specific classes of herbicides can be obtained by creating insensitivity at the site of action of the herbi- cide by expression of a target enzyme which is resistant to herbicide; rapid metabolism (conjugation or degradation) of the herbicide by expression of enzymes which inactivate herbicide; or poor uptake and translocation of the herbicide.
  • Examples are the expression of enzymes which are tolerant to the herbicide in comparison to wild type enzymes, such as the expression of 5-enolpyruvylshikimate-3-phosphate synthase (EPSPS), which is tolerant to glyphosate (see e.g.
  • EPSPS 5-enolpyruvylshikimate-3-phosphate synthase
  • Zea mays with chimeric gene sequences coging for HDDP see e.g. W01996/38567, WO 2004/55191 ); Arabidopsis thaliana which is resistant to protox inhibitors (see e.g. US2002/0073443).
  • CB/LL/RW® (Syngenta) with tolerance to glufosinate; the soybean varieties “Roundup Ready® Soybean” (Monsanto) and “Optimum GAT®” (DuPont, Pioneer) with tolerance to glyphosate; the cotton varieties “Roundup Ready® Cotton” and “Roundup Ready Flex®” (Monsanto) with tolerance to glyphosate; the cotton variety "FiberMax Liberty Link®” (Bayer) with tolerance to glufosinate; the cotton variety “BXN®” (Calgene) with tolerance to bromoxynil; the canola varieties ..Navigator® “ und ..Compass® " (Rhone- Poulenc) with bromoxynil tolerance; the canola varierty"Roundup Ready® Canola” (Monsanto) with glyphosate tolerance; the canola variety "InVigor®” (Bayer) with glu- fosinate
  • plants are also covered that are by the use of recombinant DNA techniques capable to synthesize one or more insecticidal proteins, especially those known from the bacterial genus Bacillus, particularly from Bacillus thuringiensis, such as ⁇ - endotoxins, e.g. CrylA(b), CrylA(c), CrylF, CrylF(a2), CryllA(b), CrylllA, CrylllB(bl ) or Cry9c; vegetative insecticidal proteins (VIP), e.g. VIP1 , VIP2, VIP3 or VIP3A; insecticidal proteins of bacteria colonizing nematodes, e.g. Photorhabdus spp.
  • VIP vegetative insecticidal proteins
  • toxins produced by animals such as scorpion toxins, arachnid toxins, wasp toxins, or other insect-specific neurotoxins
  • toxins produced by fungi such Streptomy- cetes toxins, plant lectins, such as pea or barley lectins; agglutinins
  • proteinase inhibitors such as trypsin inhibitors, serine protease inhibitors, patatin, cystatin or papain inhibitors
  • ribosome-inactivating proteins (RIP) such as ricin, maize-RIP, abrin, luffin, saporin or bryodin
  • steroid metabolism enzymes such as 3-hydroxysteroid oxidase, ecdysteroid-IDP-glycosyl-transferase, cholesterol oxidases, ecdysone inhibitors or HMG-CoA-reductase
  • ion channel blockers such as blockers of sodium
  • these insecticidal proteins or toxins are to be understood expressly also as pre-toxins, hybrid proteins, truncated or otherwise modified proteins.
  • Hybrid proteins are characterized by a new combination of protein domains, (see, e. g. WO 02/015701 ).
  • Further examples of such toxins or genetically modified plants capa- ble of synthesizing such toxins are disclosed, e.g., in EP-A 374 753, WO 93/007278, WO 95/34656, EP-A 427 529, EP-A 451 878, WO 03/18810 und WO 03/52073.
  • the methods for producing such genetically modified plants are generally known to the person skilled in the art and are described, e. g.
  • insecticidal proteins contained in the genetically modified plants impart to the plants producing these proteins tolerance to harmful pests from all taxonomic groups of athropods, especially to beetles (Coeloptera), two-winged insects (Diptera), and moths (Lepidoptera) and to nematodes (Nematoda).
  • WO 03/018810 MON 863 from Monsanto Europe S.A., Belgium (corn cultivars producing the Cry3Bb1 toxin), IPC 531 from Monsanto Europe S.A., Belgium (cotton cultivars producing a modified version of the CrylAc toxin) and 1507 from Pioneer Overseas Corporation, Belgium (corn cultivars producing the Cry1 F toxin and PAT enzyme).
  • plants are also covered that are by the use of recombinant DNA techniques capable to synthesize one or more proteins to increase the resistance or tolerance of those plants to bacterial, viral or fungal pathogens.
  • proteins are the so-called "pathogenesis-related proteins" (PR proteins, see, e.g. EP-A 392225), plant disease resistance genes (e. g. potato cultivars, which express resistance genes acting against Phytophthora infestans derived from the mexican wild potato Solanum bulbocastanum) or T4-lysozym (e.g. potato cultivars capable of synthesizing these proteins with increased resistance against bacteria such as Erwinia amylvora).
  • PR proteins pathogenesis-related proteins
  • plant disease resistance genes e. g. potato cultivars, which express resistance genes acting against Phytophthora infestans derived from the mexican wild potato Solanum bulbocastanum
  • T4-lysozym e.g. potato cultivars capable of
  • plants are generally known to the person skilled in the art and are described, e.g. in the publications mentioned above. Furthermore, plants are also covered that are by the use of recombinant DNA techniques capable to synthesize one or more proteins to increase the productivity (e.g. bio mass production, grain yield, starch content, oil content or protein content), tolerance to drought, salinity or other growth-limiting environmental factors or tolerance to pests and fungal, bacterial or viral pathogens of those plants.
  • productivity e.g. bio mass production, grain yield, starch content, oil content or protein content
  • plants are also covered that contain by the use of recombinant DNA techniques a modified amount of substances of content or new substances of content, specifically to improve human or animal nutrition, e.g. oil crops that produce health- promoting long-chain omega-3 fatty acids or unsaturated omega-9 fatty acids (e.g. Nexera® rape, DOW Agro Sciences, Canada).
  • a modified amount of substances of content or new substances of content specifically to improve human or animal nutrition, e.g. oil crops that produce health- promoting long-chain omega-3 fatty acids or unsaturated omega-9 fatty acids (e.g. Nexera® rape, DOW Agro Sciences, Canada).
  • plants are also covered that contain by the use of recombinant DNA techniques a modified amount of substances of content or new substances of content, specifically to improve raw material production, e.g. potatoes that produce increased amounts of amylopectin (e.g. Amflora® potato, BASF SE, Germany).
  • a modified amount of substances of content or new substances of content specifically to improve raw material production, e.g. potatoes that produce increased amounts of amylopectin (e.g. Amflora® potato, BASF SE, Germany).
  • Preferred modified plants suitable to be used in the methods of the present invention are those, which are rendered tolerant to the herbicide, which is compound II (includ- ing, but not limited to the above-referred plants) in accordance with the preferences within the inventive mixtures as set forth above.
  • preferred plants are those, which are resistant to glyphosate, glyphosinate, dicamba and imidazolinones.
  • Preferred agricultural plants are field crops, sugar beets, cereals such as wheat, rye, barley, triticale, oats, sorghum, rice, corn, cotton, rape, sunflowers, oilseed rape, juncea and canola, vine, legumes such as soybeans, peas and beans (fieldbeans), lentil, sugar cane, turf; ornamentals; vegetables, such as vegetables, such as cucumbers, leeks, paprika spinach, lettuce, asparagus, cabbages, carrots, onions, tomatoes, potatoes, cucurbits (squashes, cucumber or melons ); alfalfa, clover and fruits, such as pomes, stone fruits or soft fruits, e.g.
  • More preferred agricultural plants are selected from soybean, wheat, sunflower, canola, oilseed rape, corn, cotton, sugar cane, juncea, peas, lentils, alfalfa, vine, and fruits (as defined above) and vegetables as defined above). Most preferred agricultural plants are selected from wheat, barley, corn, soybean, rice, canola, sunflower and fruits (as defined above) and vegetables as defined above). The utmost preferred plants are soybean, vine, and fruits (as defined above) and vegetables as defined above).
  • locus is to be understood as any type of environment, soil, area or material where the plant is growing or intended to grow as well as the environmental conditions (such as temperature, water availability, radiation) that have an influence on the growth and development of the plant and/or its propagules.
  • mixture means a combination of at least two active ingredients (compounds).
  • a mixture used for increasing the health of a plant comprises one compound (I) and one compound (II) or one compound (I) and one compound (II).
  • plant propagation material is to be understood to denote all the generative parts of the plant such as seeds and vegetative plant material such as cuttings and tubers (e.g. potatoes), which can be used for the multiplication of the plant. This in- eludes seeds, grains, roots, fruits, tubers, bulbs, rhizomes, cuttings, spores, offshoots, shoots, sprouts and other parts of plants, including seedlings and young plants, which are to be transplanted after germination or after emergence from soil, meristem tissues, single and multiple plant cells and any other plant tissue from which a complete plant can be obtained.
  • vegetative plant material such as cuttings and tubers (e.g. potatoes)
  • propagules or "plant propagules” is to be understood to denote any structure with the capacity to give rise to a new plant, e.g. a seed, a spore, or a part of the vegetative body capable of independent growth if detached from the parent.
  • the term “propagules” or “plant propagules” denotes for seed.
  • health of a plant or "plant health” is defined as a condition of the plant and/or its products which is determined by several aspects alone or in combination with each other such as increased yield, plant vigor, quality and tolerance to abiotic and/or biotic stress. It has to be emphasized that the above mentioned effects of the inventive mixtures, i.e. enhanced health of the plant, are also present when the plant is not under biotic stress and in particular when the plant is not under pest pressure.
  • "increased yield" of a plant, in particular of an agricultural, silvicultural and/or horticultural plant means that the yield of a product of the respective plant is increased by a measurable amount over the yield of the same product of the plant produced under the same conditions, but without the application of the inventive mixture.
  • Increased yield can be characterized, among others, by the following improved properties of the plant: increased plant weight; and/or increased plant height; and/or increased biomass such as higher overall fresh weight (FW); and/or increased number of flowers per plant; and/or higher grain and/or fruit yield ; and/or more tillers or side shoots (branches); and/or larger leaves; and/or increased shoot growth; and/or increased protein content; and/or increased oil content; and/or increased starch content; and/or increased pigment content; and/or increased chlorophyll content (chlorophyll content has a positive correlation with the plant's photosynthesis rate and accordingly, the higher the chlorophyll content the higher the yield of a plant)
  • Gram and “fruit” are to be understood as any plant product which is further utilized after harvesting, e.g. fruits in the proper sense, vegetables, nuts, grains, seeds, wood (e.g. in the case of silviculture plants), flowers (e.g. in the case of gardening plants, ornamentals) etc., that is anything of economic value that is produced by the plant.
  • the yield is increased by at least 4 %, preferable by 5 to 10 %, more preferable by 10 to 20 %, or even 20 to 30 %. In general, the yield increase may even be higher.
  • the plant vigor becomes manifest in several aspects such as the general visual appearance.
  • Improved plant vigor can be characterized, among others, by the following improved properties of the plant: improved vitality of the plant; and/or improved plant growth; and/or improved plant development; and/or improved visual appearance; and/or improved plant stand (less plant verse/lodging); and/or improved emergence; and/or en- hanced root growth and/or more developed root system; and/or enhanced nodulation, in particular rhizobial nodulation; and/or bigger leaf blade; and/or bigger size; and/or increased plant height; and/or increased tiller number; and/or increased number of side shoots; and/or increased number of flowers per plant; and/or increased shoot growth; and/or enhanced photosynthetic activity (e.g.
  • Another indicator for the condition of the plant is the "quality" of a plant and/or its products.
  • enhanced quality means that certain plant characteristics such as the content or composition of certain ingredients are increased or improved by a measurable or noticeable amount over the same factor of the plant produced under the same conditions, but without the application of the mixtures of the present invention.
  • Enhanced quality can be characterized, among others, by following improved properties of the plant or its product: increased nutrient content; and/or in- creased protein content; and/or increased content of fatty acids; and/or increased metabolite content; and/or increased carotenoid content; and/or increased sugar content; and/or increased amount of essential amino acids; and/or improved nutrient composition; and/or improved protein composition; and/or improved composition of fatty acids; and/or improved metabolite composition; and/or improved carotenoid composition; and/or improved sugar composition; and/or improved amino acids composition ; and/or improved or optimal fruit color; and/or improved leaf color; and/or higher storage capacity; and/or higher processability of the harvested products.
  • Another indicator for the condition of the plant is the plant's tolerance or resistance to biotic and/or abiotic stress factors.
  • Biotic and abiotic stress can have harmful effects on plants. Biotic stress is caused by living organisms while abiotic stress is caused for example by environmental extremes.
  • "enhanced tolerance or resistance to biotic and/or abiotic stress factors” means (1 .) that certain negative factors caused by biotic and/or abiotic stress are diminished in a measurable or noticeable amount as compared to plants exposed to the same conditions, but without being treated with an inventive mixture and (2.) that the negative effects are not diminished by a direct action of the inventive mixture on the stress factors, e.g.
  • Biotic stress can be caused by living organisms, such as competing plants (for example weeds), microorganisms (such as phythopathogenic fungi and/or bacteria) and/or viruses.
  • Negative factors caused by abiotic stress are also well-known and can often be observed as reduced plant vigor (see above), for example: dotted leaves, "burned leaves", reduced growth, less flowers, less biomass, less crop yields, reduced nutritional value of the crops, later crop maturity, to give just a few examples.
  • Abiotic stress can be caused for example by: extremes in temperature such as heat or cold (heat stress / cold stress); and/or strong variations in temperature; and/or temperatures unusual for the specific season; and/or drought (drought stress); and/or extreme wetness; and/or high salinity (salt stress); and/or radiation (for example by increased UV radiation due to the decreasing ozone layer); and/or increased ozone levels (ozone stress); and/or organic pollution (for example by phythotoxic amounts of pesticides); and/or inorganic pollution (for example by heavy metal contaminants).
  • extremes in temperature such as heat or cold (heat stress / cold stress); and/or strong variations in temperature; and/or temperatures unusual for the specific season; and/or drought (drought stress); and/or extreme wetness; and/or high salinity (salt stress); and/or radiation (for example by increased UV radiation due to the decreasing ozone layer); and/or increased ozone levels (ozone stress); and/or organic pollution (for example by
  • Advantageous properties, obtained especially from treated seeds, are e.g. improved germination and field establishment, better vigor and/or a more homogen field establishment.
  • the above identified indicators for the health condition of a plant may be interdependent and may result from each other. For example, an increased resistance to biotic and/or abiotic stress may lead to a better plant vigor, e.g. to better and bigger crops, and thus to an increased yield. Inversely, a more developed root system may result in an increased resistance to biotic and/or abiotic stress.
  • these interdependencies and interactions are neither all known nor fully understood and therefore the different indicators are described separately.
  • the inventive mixtures effectuate an increased yield of a plant or its product.
  • inventive mixtures effectuate an increased vigor of a plant or its product.
  • inventive mixtures effectuate in an increased quality of a plant or its product. In yet another embodiment the inventive mixtures effectuate an increased tolerance and/or resistance of a plant or its product against biotic stress.
  • inventive mixtures effectuate an increased tolerance and/or resistance of a plant or its product against abiotic stress.
  • the inventive mixtures effect an increase in the yield.
  • the inventive mixtures the inventive mix- tures effects an increase in the yield such as the plant weight and/or the plant biomass (e.g. overall fresh weight) and/or the grain yield and/or the number of tillers.
  • the inventive mixtures effect an improvement of the plant vigor.
  • the inventive mixtures effect an increase in the yield.
  • the inventive mixtures effect an in- crease in the yield such as the plant weight and/or the plant biomass (e.g. overall fresh weight) and/or the grain yield and/or the number of tillers.
  • inventive mixtures are employed by treating the plant, plant propagation material (preferably seed), soil, area, material or environment in which a plant is growing or may grow with an effective amount of the active compounds.
  • the application can be carried out in the absense of pest pressure and/or both before and after an infection of the materials, plants or plant propagation materials (preferably seeds) by pests.
  • a mixture for increasing the health of a plant is applied at a growth stage (GS) between GS 00 and GS 65 BBCH of the treated plant.
  • a mixture for increasing the health of a plant is applied at a growth stage (GS) between GS 00 and GS 55 BBCH of the treated plant.
  • a mixture for increasing the health of a plant is applied at a growth stage (GS) between GS 00 and GS 37 BBCH of the treated plant.
  • a mixture for increasing the health of a plant is applied at a growth stage (GS) between GS 00 and GS 21 BBCH of the treated plant.
  • a mixture comprising compound (I) and (II) for increasing the health of a plant is applied at a growth stage (GS) between GS 13 and GS 37 BBCH of the treated plant.
  • a mixture comprising compound (I) and (II) for increasing the health of a plant is applied at a growth stage (GS) between GS 13 and GS 37 BBCH of the treated plant.
  • the term "growth stage” refers to the extended BBCH-scale which is a system for a uniform coding of phenologically similar growth stages of all mono- and dicotyledonous plant species in which the entire developmental cycle of the plants is subdivided into clearly recognizable and distinguishable longer-lasting developmental phases.
  • the BBCH-scale uses a decimal code system, which is divided into principal and secondary growth stages.
  • the abbreviation BBCH derives from the Federal Biological Research Centre for Agriculture and Forestry (Germany), the Bundessortenamt (Germany) and the chemical industry.
  • the plants and/or plant propagules are treated simultaneously (together or separately) or subsequently with a mixture as described above.
  • Such subsequent application can be carried out with a time interval which allows a combined action of the applied compounds.
  • the time interval for a subsequent application of compound (I) and compound (II) ranges from a few seconds up to 3 months, preferably, from a few seconds up to 1 month, more preferably from a few seconds up to 2 weeks, even more preferably from a few seconds up to 3 days and in particular from 1 second up to 24 hours.
  • the application rates of the mixtures are between 0,3 g/ha and 1500 g/ha, depending on various parameters such as the treated plant species or the mixture applied. In a preferred embodiment of the method according to the invention, the application rates of the mixtures are between 5 g/ha and 750 g/ha. In an even more preferred embodiment of the method according to the invention, the application rates of the mixtures are between 20 g/ha and 500 g/ha, in particular from 20 g/ha to 300 g/ha.
  • amounts of from 0,01 g to 3 kg, in particular amounts from 0,01 g to 1 kg of inventive mixtures are generally required per 100 kg of plant propagation material (preferably seed).
  • amounts of from 0,01 g to 250 g of inventive mixtures are required per 100 kg of plant propagation material (preferably seed).
  • amounts of from 0,01 g to 150 g of inventive mixtures are required per 100 kg of plant.
  • compounds I and II present in the inventive mixtures are used in "effective amounts". This means that they are used in a quantity which allows to obtain the desired effect which is a synergistic increase of the health of a plant but which does not give rise to any phytotoxic symptom on the treated plant.
  • compound (I) and compound (II) are employed in amounts which result in a synergistic effect.
  • the pesticial composition for increasing the health of a plant comprises a liquid or solid carrier and a mixture as described above.
  • the inventive mixtures can be converted into the customary formulations, for example solutions, emulsions, suspensions, dusts, powders, pastes and granules.
  • the use form depends on the particular intended purpose; in each case, it should ensure a fine and even distribution of the mixtures accord- ing to the present invention.
  • the formulations are prepared in a known manner (cf. US 3,060,084, EP-A 707 445 (for liquid concentrates), Browning: “Agglomeration”, Chemical Engineering, Dec. 4, 1967, 147-48, Perry's Chemical Engineer's Handbook, 4th Ed., McGraw-Hill, New York, 1963, S. 8-57 und ff. WO 91/13546, US 4,172,714, US 4,144,050, US 3,920,442, US 5,180,587, US 5,232,701 , US 5,208,030,
  • the agrochemical formulations may also comprise auxiliaries which are customary in agrochemical formulations.
  • the auxiliaries used depend on the particular application form and active substance, respectively.
  • suitable auxiliaries are solvents, solid carriers, dispersants or emulsifiers (such as further solubilizers, protective colloids, surfactants and adhesion agents), organic and anorganic thickeners, bactericides, anti-freezing agents, anti-foaming agents, if appropriate colorants and tackifiers or binders (e.g. for seed treatment formulations).
  • Suitable solvents are water, organic solvents such as mineral oil fractions of medium to high boiling point, such as kerosene or diesel oil, furthermore coal tar oils and oils of vegetable or animal origin, aliphatic, cyclic and aromatic hydrocarbons, e.g.
  • Solid carriers are mineral earths such as silicates, silica gels, talc, kaolins, limestone, lime, chalk, bole, loess, clays, dolomite, diatomaceous earth, calcium sulfate, magnesium sulfate, magnesium oxide, ground synthetic materials, fertilizers, such as, e.g. ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas, and products of vegetable origin, such as cereal meal, tree bark meal, wood meal and nutshell meal, cellulose powders and other solid carriers.
  • mineral earths such as silicates, silica gels, talc, kaolins, limestone, lime, chalk, bole, loess, clays, dolomite, diatomaceous earth, calcium sulfate, magnesium sulfate, magnesium oxide, ground synthetic materials, fertilizers, such as, e.g. ammonium sulfate, ammonium phosphate, ammoni
  • Suitable surfactants are alkali metal, alkaline earth metal and ammonium salts of aromatic sulfonic acids, such as ligninsoulfonic acid (Borresperse® types, Borregard, Norway) phenolsulfonic acid, naphthalenesulfonic acid (Morwet® types, Akzo Nobel, U.S.A.), dibutylnaphthalene- sulfonic acid (Nekal® types, BASF, Germany), and fatty acids, alkylsulfonates, alkyl- arylsulfonates, alkyl sulfates, laurylether sulfates, fatty alcohol sulfates, and sulfated hexa-, hepta- and octadecanolates, sulfated fatty alcohol glycol ethers, furthermore conden
  • methylcellulose methylcellulose
  • hydrophobically modified starches polyvinyl alcohols (Mowiol® types, Clariant, Swit- zerland), polycarboxylates (Sokolan® types, BASF, Germany), polyalkoxylates, polyvi- nylamines (Lupasol® types, BASF, Germany), polyvinylpyrrolidone and the copolymers therof.
  • thickeners i.e. compounds that impart a modified flowability to formulations, i.e.
  • Xanthan gum Kel- zan®, CP Kelco, U.S.A.
  • Rhodopol® 23 Rhodia, France
  • Veegum® R.T. Vanderbilt, U.S.A.
  • Attaclay® Engelhard Corp., NJ, USA
  • Bactericides may be added for preservation and stabilization of the formulation.
  • suitable bactericides are those based on dichlorophene and benzylalcohol hemi formal (Proxel® from ICI or Acticide® RS from Thor Chemie and Kathon® MK from Rohm & Haas) and isothiazolinone derivatives such as alkylisothiazolinones and benzisothiazolinones (Acticide® MBS from Thor Chemie).
  • suitable anti- freezing agents are ethylene glycol, propylene glycol, urea and glycerin.
  • anti-foaming agents are silicone emulsions (such as e.g. Silikon® SRE, Wacker, Ger- many or Rhodorsil®, Rhodia, France), long chain alcohols, fatty acids, salts of fatty acids, fluoroorganic compounds and mixtures thereof.
  • Suitable colorants are pigments of low water solubility and water-soluble dyes. Examples to be mentioned und the designations rhodamin B, C. I. pigment red 1 12, C. I. solvent red 1 , pigment blue 15:4, pigment blue 15:3, pigment blue 15:2, pigment blue 15:1 , pigment blue 80, pigment yellow 1 , pigment yellow 13, pigment red 1 12, pigment red 48:2, pigment red 48:1 , pigment red 57:1 , pigment red 53:1 , pigment orange 43, pigment orange 34, pigment orange 5, pigment green 36, pigment green 7, pigment white 6, pigment brown 25, basic violet 10, basic violet 49, acid red 51 , acid red 52, acid red 14, acid blue 9, acid yellow 23, basic red 10, basic red 108.
  • tackifiers or binders examples include polyvinylpyrrolidone, polyvinylacetates, polyvinyl alcohols and cellulose ethers (Tylose®, Shin-Etsu, Japan).
  • Powders, materials for spreading and dusts can be prepared by mixing or concomi- tantly grinding the compounds (I) and/or (ll)and, if appropriate, further active substances, with at least one solid carrier.
  • Granules e.g. coated granules, impregnated granules and homogeneous granules, can be prepared by binding the active substances to solid carriers.
  • solid carriers are mineral earths such as silica gels, silicates, talc, kaolin, attaclay, limestone, lime, chalk, bole, loess, clay, dolomite, diatomaceous earth, calcium sulfate, magnesium sulfate, magnesium oxide, ground synthetic materials, fertilizers, such as, e.g., ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas, and products of vegetable origin, such as cereal meal, tree bark meal, wood meal and nutshell meal, cellulose powders and other solid carriers.
  • formulation types are:
  • compositions 15 parts by weight of compounds of the inventive mixtures are dissolved in 75 parts by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil eth- oxylate (in each case 5 parts by weight). Dilution with water gives an emulsion.
  • the composition has an active substance content of 15% by weight.
  • Emulsions (EW, EO, ES)
  • 25 parts by weight of compounds of the inventive mixtures are dissolved in 35 parts by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil eth- oxylate (in each case 5 parts by weight).
  • This mixture is introduced into 30 parts by weight of water by means of an emulsifying machine (Ultraturrax) and made into a homogeneous emulsion. Dilution with water gives an emulsion.
  • the composition has an active substance content of 25% by weight.
  • compositions 50 parts by weight of compounds of the inventive mixtures are ground finely with addition of 50 parts by weight of dispersants and wetting agents and prepared as water- dispersible or water-soluble granules by means of technical appliances (e. g. extrusion, spray tower, fluidized bed). Dilution with water gives a stable dispersion or solution of the active substance.
  • the composition has an active substance content of 50% by weight.
  • Water-dispersible powders and water-soluble powders 75 parts by weight of compounds of the inventive mixtures are ground in a rotor-stator mill with addition of 25 parts by weight of dispersants, wetting agents and silica gel. Dilution with water gives a stable dispersion or solution of the active substance.
  • the active substance content of the composition is 75% by weight.
  • Dustable powders (DP, DS)
  • the agrochemical formulations generally comprise between 0.01 and 95%, preferably between 0.1 and 90%, most preferably between 0.5 and 90%, by weight of active substances.
  • the compounds of the inventive mixtures are employed in a purity of from 90% to 100%, preferably from 95% to 100% (according to NMR spectrum).
  • the compounds of the inventive mixtures can be used as such or in the form of their compositions, e.g. in the form of directly sprayable solutions, powders, suspensions, dispersions, emulsions, oil dispersions, pastes, dustable products, materials for spreading, or granules, by means of spraying, atomizing, dusting, spreading, brushing, immersing or pouring.
  • the application forms depend entirely on the intended purposes; it is intended to ensure in each case the finest possible distribution of the compounds present in the inventive mixtures.
  • Aqueous application forms can be prepared from emulsion concentrates, pastes or wettable powders (sprayable powders, oil dispersions) by adding water.
  • the substances can be homogenized in water by means of a wetter, tackifier, dispersant or emulsifier.
  • a wetter, tackifier, dispersant or emulsifier it is possible to prepare concentrates composed of active substance, wetter, tackifier, dispersant or emulsifier and, if appropriate, solvent or oil, and such concentrates are suitable for dilution with water.
  • the active substance concentrations in the ready-to-use preparations can be varied within relatively wide ranges. In general, they are from 0.0001 to 10%, preferably from 0.001 to 1 % by weight of compounds of the inventive mixtures .
  • the compounds of the inventive mixtures may also be used successfully in the ultra- low-volume process (ULV), it being possible to apply compositions comprising over 95% by weight of active substance, or even to apply the active substance without additives.
  • UUV ultra- low-volume process
  • Various types of oils, wetters, adjuvants, herbicides, fungicides, other pesticides, or bactericides may be added to the active compounds, if appropriate not until
  • compositions of this invention may also contain fertilizers such as ammonium nitrate, urea, potash, and superphosphate, phytotoxicants and plant growth regulators and safeners. These may be used sequentially or in combination with the above-described compositions, if appropriate also added only immediately prior to use (tank mix). For example, the plant(s) may be sprayed with a composition of this invention either before or after being treated with the fertilizers.
  • fertilizers such as ammonium nitrate, urea, potash, and superphosphate, phytotoxicants and plant growth regulators and safeners.
  • the compounds contained in the mixtures as defined above can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
  • applying the compound (I) and compound (II) is to be understood to denote, that at least the compound (I) and compound (II) occur simultaneously at the site of action (i.e. plant, plant propagation material (preferably seed), soil, area, material or environment in which a plant is growing or may grow) in a effective amount.
  • site of action i.e. plant, plant propagation material (preferably seed), soil, area, material or environment in which a plant is growing or may grow
  • the compound (I) and compound (II) can be obtained by applying the compound (I) and compound (II) simultaneously, either jointly (e.g. as tank-mix) or seperately, or in succession, wherein the time interval between the individual applications is selected to ensure that the active substance ap- plied first still occurs at the site of action in a sufficient amount at the time of application of the further active substance(s).
  • the order of application is not essential for working of the present invention.
  • the weight ratio of the compounds generally depends from the properties of the compounds of the inventive mixtures.
  • the compounds of the inventive mixtures can be used individually or already partially or completely mixed with one another to prepare the composition according to the invention. It is also possible for them to be packaged and used further as combination composition such as a kit of parts.
  • kits may include one or more, including all, components that may be used to prepare a subject agrochemical composition.
  • kits may include the compound (I) and compound (II) and/or an adjuvant component and/or a further pesticidal compound (e.g. insecticide, fungicide or herbicide) and/or a growth regulator component).
  • a further pesticidal compound e.g. insecticide, fungicide or herbicide
  • One or more of the components may already be com- bined together or p re-formulated. In those embodiments where more than two components are provided in a kit, the components may already be combined together and as such are packaged in a single container such as a vial, bottle, can, pouch, bag or canister.
  • kits may include one or more separate con- tainers such as vials, cans, bottles, pouches, bags or canisters, each container containing a separate component for an agrochemical composition.
  • a component of the kit may be applied separately from or together with the further components or as a component of a combination composition according to the invention for preparing the composition according to the invention.
  • the user applies the composition according to the invention usually from a predosage device, a knapsack sprayer, a spray tank or a spray plane.
  • the agrochemical composition is made up with water and/or buffer to the desired application concentration, it being possible, if appropriate, to add further auxiliaries, and the ready-to-use spray liquid or the agrochemical composition according to the invention is thus obtained.
  • 50 to 500 liters of the ready-to-use spray liquid are applied per hectare of agricultural useful area, preferably 50 to 400 liters.
  • compositions such as parts of a kit or parts of the inventive mixture may be mixed by the user himself in a spray tank and further auxiliaries may be added, if appropriate (tank mix).
  • either individual compounds of the inventive mixtures formu- lated as composition or partially premixed components e.g. components comprising the compound (I) and compound (II) may be mixed by the user in a spray tank and further auxiliaries and additives may be added, if appropriate (tank mix).
  • either individual components of the composition according to the invention or partially premixed components e.g. components comprising the compound (I) and compound (II) can be applied jointly (e.g. after tankmix) or consecutively.
  • inventive mixtures are employed by treating the plant, plant propagation material (preferably seed), soil, area, material or environment in which a plant is growing or may grow with an effective amount of the active compounds.
  • the application rates of the inventive mixtures are from 0,3 g/ha to 2000 g/ha, preferably 5 g/ha to 2000 g/ha, more preferably from 50 to 900 g/ha, in particular from 50 to 900 g/ha.
  • the application rates are in the range of from 0,1 to 6,0 kg of active ingredient (acid equivalent) per hectare, depending on various parameters such as the weather conditions and the plant species.
  • a variant of the present invention also comprises seed treatment with compound (II) followed by foliar spraying with compound (I).
  • Seed treatment can be made into the seedbox before planting into the field.
  • the weight ratio in the binary or ternary mixtures of the present invention generally depends on the properties of the compounds of the inven- tive mixtures.
  • compositions which are especially useful for seed treatment are e.g.:
  • a Soluble concentrates (SL, LS)
  • I Dustable powders (DP, DS) These compositions can be applied to plant propagation materials, particularly seeds, diluted or undiluted.
  • the compositions in question give, after two-to-tenfold dilution, active substance concentrations of from 0.01 to 60% by weight, preferably from 0.1 to 40% by weight, in the ready-to-use preparations. Application can be carried out before or during sowing.
  • Methods for applying or treating agrochemical compounds and compositions thereof, respectively, on to plant propagation material, especially seeds are known in the art, and include dressing, coating, pelleting, dusting and soaking application methods of the propagation material (and also in furrow treatment).
  • the compounds or the compositions thereof, respectively are applied on to the plant propagation material by a method such that germination is not induced, e. g. by seed dressing, pelleting, coating and dusting.
  • the application rates of the inventive mixture are generally for the formulated product (which usually comprises from 10 to 750 g/l of the active(s)).
  • the invention also relates to the propagation products of plants, and especially the seed comprising, that is, coated with and/or containing, a mixture as defined above or a composition containing the mixture of two or more active ingredients or a mixture of two or more compositions each providing one of the active ingredients.
  • the plant propagation material (preferably seed) comprises the inventive mixtures in an amount of from 0.01 g to 10 kg per 100 kg of plant propagation material (preferably seed).
  • the separate or joint application of the compounds of the inventive mixtures is carried out by spraying or dusting the seeds, the seedlings, the plants or the soils before or after sowing of the plants or before or after emergence of the plants.
  • the mixture of the invention is also suitable for combating animal pests, preferably invertebrate pests.
  • invertebrate pest encompasses animal populations, such as insects, arachnids and nematodes, which may attack plants, thereby causing substantial damage to the plants attacked, as well as ectoparasites which may infest animals, in particular warm blooded animals such as e.g. mammals or birds, or other higher animals such as reptiles, amphibians or fish, thereby causing substantial damage to the animals infested.
  • Invertebrate pests controlled by the mixture of the invention include for example: Insects from the order of the lepidopterans (Lepidoptera), for example Agrotis ypsilon, Agrotis segetum, Alabama argillacea, Anticarsia gemmatalis, Argyresthia conjugella, Autographa gamma, Bupalus piniarius, Cacoecia murinana, Capua reticulana, Cheima- tobia brumata, Choristoneura fumiferana, Choristoneura occidentalis, Cirphis unipuncta, Cydia pomonella, Dendrolimus pini, Diaphania nitidalis, Diatraea grandi- osella, Earias insulana, Elasmopalpus lignosellus, Eupoecilia ambiguella, Evetria bou- liana, Feltia subterranea, Galleria mellonella,
  • beetles Coldeoptera
  • Agrilus sinuatus for example Agrilus sinuatus, Agriotes lineatus, Agriotes obscu- rus, Amphimallus solstitialis, Anisandrus dispar, Anthonomus grandis, Anthonomus pomorum, Atomaria linearis, Blastophagus piniperda, Blitophaga undata, Bruchus rufi- manus, Bruchus pisorum, Bruchus lentis, Byctiscus betulae, Cassida nebulosa, Cero- toma trifurcata, Ceuthorrhynchus assimilis, Ceuthorrhynchus napi, Chaetocnema tibialis, Conoderus vespertinus, Crioceris asparagi, Diabrotica longicornis, Diabrotica 12 punctata, Diabrotica virgifera, Epilachna varivestis, Epitrix hirtip
  • dipterans dipterans
  • Aedes aegypti Aedes vexans, Anastrepha ludens, Anopheles maculipennis, Ceratitis capitata, Chrysomya bezziana, Chrysomya homi- nivorax, Chrysomya macellaria, Contarinia sorghicola, Cordylobia anthropophaga, Culex pipiens, Dacus cucurbitae, Dacus oleae, Dasineura brassicae, Fannia canicu- laris, Gasterophilus intestinalis, Glossina morsitans, Haematobia irritans, Haplodiplosis equestris, Hylemyia platura, Hypoderma lineata, Liriomyza sativae, Liriomyza trifolii, Lucilia caprina, Lucilia cuprina, Lucilia sericata, Lycor
  • thrips (Thysanoptera), e.g. Dichromothrips corbetti, Frankliniella fusca, Frankliniella occidentalis, Frankliniella tritici, Scirtothrips citri, Thrips oryzae, Thrips palmi and Thrips tabaci; hymenopterans (Hymenoptera), e.g. Athalia rosae, Atta cephalotes, Atta sexdens, Atta texana, Hoplocampa minuta, Hoplocampa testudinea, Monomorium pharaonis, So- lenopsis geminata and Solenopsis invicta;
  • Heteroptera e.g. Acrosternum hilare, Blissus leucopterus, Cyrtopeltis notatus, Dysdercus cingulatus, Dysdercus intermedius, Eurygaster integriceps,
  • homopterans e.g. Acyrthosiphon onobrychis, Adelges laricis, Aphidula nasturtii, Aphis fabae, Aphis forbesi, Aphis pomi, Aphis gossypii, Aphis grossulariae, Aphis schneideri, Aphis spiraecola, Aphis sambuci, Acyrthosiphon pisum, Aulacorthum solani, Bemisia argentifolii, Brachycaudus cardui, Brachycaudus helichrysi, Brachy- caudus persicae, Brachycaudus prunicola, Brevicoryne brassicae, Capitophorus horni, Cerosipha gossypii, Chaetosiphon fragaefolii, Cryptomyzus ribis, Dreyfusia nordman- nianae,
  • Isoptera e.g. Calotermes flavicollis, Leucotermes flavipes, Reticulitermes flavipes, Reticulitermes lucifugus und Termes natalensis;
  • orthopterans e.g. Acheta domestica, Blatta orientalis, Blattella germanica, Forficula auricularia, Gryllotalpa gryllotalpa, Locusta migratoria, Melanoplus bivittatus, Melanoplus femur-rubrum, Melanoplus mexicanus, Melanoplus sanguinipes, Melanoplus spretus, Nomadacris septemfasciata, Periplaneta americana, Schistocerca ameri- cana, Schistocerca peregrina, Stauronotus maroccanus and Tachycines asynamorus; Arachnoidea, such as arachnids (Acarina), e.g.
  • Argasidae such as Amblyomma americanum, Amblyomma variegatum, Argas persi- cus, Boophilus annulatus, Boophilus decoloratus, Boophilus microplus, Dermacentor silvarum, Hyalomma truncatum, Ixodes ricinus, Ixodes rubicundus, Ornithodorus mou- bata, Otobius megnini, Dermanyssus gallinae, Psoroptes ovis, Rhipicephalus appendi- culatus, Rhipicephalus evertsi, Sarcoptes scabiei, and Eriophyidae spp.
  • Tetranychidae spp. such as Tetranychus cinnabarinus, Tetranychus kanzawai, Tetranychus pacificus, Tetranychus telarius and Tetranychus urticae, Panonychus ulmi, Panonychus citri, and oligonychus pratensis;
  • Siphonatera e.g. Xenopsylla cheopsis, Ceratophyllus spp.
  • the mixture of the invention is useful for the control of nematodes, especially plant parasitic nematodes such as root knot nematodes, Meloidogyne hapla, Meloidogyne incognita, Meloidogyne javanica, and other Meloidogyne species;
  • cyst-forming nematodes Globodera rostochiensis and other Globodera species
  • Het- erodera avenae Heterodera glycines, Heterodera schachtii, Heterodera trifolii, and other Heterodera species
  • Seed gall nematodes Anguina species
  • Stem and foliar nematodes Aphelenchoides species
  • Sting nematodes Belonolaimus longicaudatus and other Belonolaimus species
  • Pine nematodes Bursaphelenchus xylophilus and other Bursaphelenchus species
  • Ring nematodes Criconema species, Criconemella species, Criconemoides species, Mesocriconema species
  • Stem and bulb nematodes Ditylenchus destructor, Ditylenchus dipsaci and other Ditylenchus species
  • Awl nematodes Dolichodorus
  • the mixture of the invention is used for controlling insects or arachnids, in particular insects of the orders Lepidoptera, Coleop- tera, Thysanoptera and Homoptera and arachnids of the order Acarina.
  • the mixture of the invention is particularly useful for controlling insects of the order Thysanoptera and Homoptera.
  • the mixtures of the present invention preferably show synergistic action with regard to the pests to be controlled or with regard to the plant-health effects.
  • Synergism can be described as an interaction where the combined effect of a mixture of two or more compounds is greater than the sum of the individual effects of each of the compounds.
  • X and Y are the % control or the % effect observed for the individual compounds at a given concentration.
  • E is the expected combined control/effect, which would be expected in the absence of synergism, if the compounds were applied together at the same concentrations of solo application.
  • the control/effect observed for the mixture i.e. the observed combined control/effect
  • E the expected combined control/effect

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

La présente invention, comprenant le cyclopropanecarboxylate de [(3S,4R,4aR,6S,6aS,12R,12aS,12bS)-3- (cyclopropanecarbonyloxy)-6,12-dihydroxy-4,6a,12b-triméthyl-11 -oxo-9-(pyridin-3-yl)- 1,2,3,4,4a,5,6,6a,12a,12b-décahydro-11 H,12H-benzo[f]pyranno[4,3-b]chromén-4-yl]méthyle de formule II et un herbicide, préférentiellement à des teneurs synergiquement actives.
PCT/EP2011/060389 2010-06-25 2011-06-22 Mélanges herbicides WO2011161131A1 (fr)

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WO2013134310A1 (fr) * 2012-03-05 2013-09-12 Syngenta Participations Ag Compositions herbicides
CN103300014A (zh) * 2013-06-20 2013-09-18 安徽丰乐农化有限责任公司 一种除草水悬浮剂
WO2014100525A2 (fr) 2012-12-21 2014-06-26 Pioneer Hi-Bred International, Inc. Compositions et procédés pour la conjugaison d'analogues d'auxine
CN104054720A (zh) * 2014-07-10 2014-09-24 安徽科技学院 一种金银花除草剂组合物及使用方法
WO2014153242A1 (fr) 2013-03-14 2014-09-25 Pioneer Hi-Bred International, Inc. Compositions ayant une activité de décarboxylase de dicamba et leurs procédés d'utilisation
WO2014153234A1 (fr) 2013-03-14 2014-09-25 Pioneer Hi-Bred International, Inc. Compositions ayant une activité de dicamba décarboxylase et procédés d'utilisation
CN104334549A (zh) * 2012-05-25 2015-02-04 巴斯夫欧洲公司 1,5-二甲基-6-硫代-3-(2,2,7-三氟-3-氧代-4-(丙-2-炔基)-3,4-二氢-2H-苯并[b][1,4]噁嗪-6-基)-1,3,5-三嗪烷-2,4-二酮的晶型A
CN104334550A (zh) * 2012-05-25 2015-02-04 巴斯夫欧洲公司 1,5-二甲基-6-硫代-3-(2,2,7-三氟-3-氧代-4-(丙-2-炔基)-3,4-二氢-2H-苯并[b][1,4]噁嗪-6-基)-1,3,5-三嗪烷-2,4-二酮的晶型B
KR20170139133A (ko) * 2015-04-27 2017-12-18 바이엘 크롭사이언스 악티엔게젤샤프트 글루포시네이트 및 인다지플람을 포함하는 제초제 조합물
KR20180005230A (ko) * 2015-05-11 2018-01-15 바이엘 크롭사이언스 악티엔게젤샤프트 L-글루포시네이트 및 인다지플람을 포함하는 제초제 조합물
CN109287675A (zh) * 2018-10-23 2019-02-01 安徽绿亿种业有限公司 一种水稻苗前专用除草剂及其制备方法
EP3245873B1 (fr) 2013-07-12 2019-05-15 Bayer CropScience Aktiengesellschaft Combinaison d'herbicide contenant de l'acide pélargonique et flazasulfuron
KR20190113797A (ko) * 2017-01-31 2019-10-08 유피엘 리미티드 제초성 배합물
CN110583680B (zh) * 2018-06-12 2021-07-09 孟州传奇生物科技有限公司 一种玉米田复配除草组合物

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