WO2011153002A3 - Additives for cetane improvement in middle distillate fuels - Google Patents

Additives for cetane improvement in middle distillate fuels Download PDF

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Publication number
WO2011153002A3
WO2011153002A3 PCT/US2011/037282 US2011037282W WO2011153002A3 WO 2011153002 A3 WO2011153002 A3 WO 2011153002A3 US 2011037282 W US2011037282 W US 2011037282W WO 2011153002 A3 WO2011153002 A3 WO 2011153002A3
Authority
WO
WIPO (PCT)
Prior art keywords
polymer
additive composition
middle distillate
distillate fuels
additives
Prior art date
Application number
PCT/US2011/037282
Other languages
French (fr)
Other versions
WO2011153002A2 (en
Inventor
Jianzhong Yang
Michael J. Zetlmeisl
Paul J. Biggerstaff
Original Assignee
Baker Hughes In Corporated
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Baker Hughes In Corporated filed Critical Baker Hughes In Corporated
Publication of WO2011153002A2 publication Critical patent/WO2011153002A2/en
Publication of WO2011153002A3 publication Critical patent/WO2011153002A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/12—Use of additives to fuels or fires for particular purposes for improving the cetane number
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/02—Use of additives to fuels or fires for particular purposes for reducing smoke development
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1616—Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1625—Hydrocarbons macromolecular compounds
    • C10L1/1633—Hydrocarbons macromolecular compounds homo- or copolymers obtained by reactions only involving carbon-to carbon unsaturated bonds
    • C10L1/1641—Hydrocarbons macromolecular compounds homo- or copolymers obtained by reactions only involving carbon-to carbon unsaturated bonds from compounds containing aliphatic monomers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/1811—Organic compounds containing oxygen peroxides; ozonides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/183—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/183—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom
    • C10L1/1832—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1857—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/23—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
    • C10L1/231—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites nitro compounds; nitrates; nitrites

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

The cetane number of middle distillate fuels may be increased using an additive composition including a polymer that may be a homopolymer or copolymer of olefins, and the like, where the polymer has a weight average molecular weight ranging from about 200,000 to about 5,000,000. The additive composition also includes a free radical initiator component, which may be an alkyl nitrate such as 2-ethylhexylnitrate (2-EHN), and/or a peroxide, such as t-butyl peroxide. In one non-limiting embodiment the amount of polymer in the additive composition is greater than the free radical initiator component. A solvent is also present, which the solvent may include alcohol, an alkyl substituted phenol and/or a heavy aromatic distillate.
PCT/US2011/037282 2010-06-03 2011-05-20 Additives for cetane improvement in middle distillate fuels WO2011153002A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/793,463 2010-06-03
US12/793,463 US20100325944A1 (en) 2007-05-30 2010-06-03 Additives for Cetane Improvement in Middle Distillate Fuels

Publications (2)

Publication Number Publication Date
WO2011153002A2 WO2011153002A2 (en) 2011-12-08
WO2011153002A3 true WO2011153002A3 (en) 2012-03-08

Family

ID=45067232

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2011/037282 WO2011153002A2 (en) 2010-06-03 2011-05-20 Additives for cetane improvement in middle distillate fuels

Country Status (2)

Country Link
US (1) US20100325944A1 (en)
WO (1) WO2011153002A2 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102498088A (en) * 2009-09-15 2012-06-13 帝斯曼知识产权资产管理有限公司 Nitrooxyesters, their preparation and use
MX2013001562A (en) * 2010-08-10 2013-05-17 Best Tech Brands Llc Diesel fuel combustion enhancing additive
US20130239465A1 (en) * 2012-03-16 2013-09-19 Baker Hughes Incorporated Cold Flow Improvement of Distillate Fuels Using Alpha-Olefin Compositions
CA3100786A1 (en) * 2018-05-25 2019-11-28 Exxonmobil Research And Engineering Company Distillate blending system with online derived and/or indicated cetane number analyzer and related methods
CN112625767A (en) * 2020-12-30 2021-04-09 山东新蓝环保科技有限公司 Gasoline detergent composition
CN114686278A (en) * 2022-02-18 2022-07-01 任国辉 Use of cyclic peroxides in petroleum products

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4365973A (en) * 1980-12-18 1982-12-28 Union Oil Company Of California Middle distillate fuel additive
US4482353A (en) * 1983-08-04 1984-11-13 Ethyl Corporation Compression ignition fuel compositions
JPH05132682A (en) * 1991-11-13 1993-05-28 Mitsubishi Oil Co Ltd Diesel fuel additive composition and its usage
US20020026743A1 (en) * 2000-05-12 2002-03-07 Henry Cyrus Pershing Diesel fuel stabiliser
US20080295395A1 (en) * 2007-05-30 2008-12-04 Baker Hughes Incorporated Additives for Reduction of Exhaust Emissions From Compression Ignition Engines

Family Cites Families (14)

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Publication number Priority date Publication date Assignee Title
US3227532A (en) * 1961-08-14 1966-01-04 Exxon Research Engineering Co Polymer-containing motor fuel composition
US4060569A (en) * 1975-12-24 1977-11-29 Petrolite Corporation Hydrocarbon polymers
US4239546A (en) * 1978-07-21 1980-12-16 Petrolite Corporation Hydrocarbon polymers to improve the hardness of waxes
GB9114236D0 (en) * 1991-07-02 1991-08-21 Exxon Chemical Patents Inc Fuel oil treatment
US5482518A (en) * 1994-11-18 1996-01-09 Exxon Research And Engineering Company Synergistic cetane improver composition comprising mixture of alkyl-nitrate and hydroperoxide quinone
US5906665A (en) * 1995-09-26 1999-05-25 General Technology Applications, Inc. High molecular weight fuel additive
US6107258A (en) * 1997-10-15 2000-08-22 Ethyl Corporation Functionalized olefin copolymer additives
US6048373A (en) * 1998-11-30 2000-04-11 Ethyl Corporation Fuels compositions containing polybutenes of narrow molecular weight distribution
US6200359B1 (en) * 1998-12-23 2001-03-13 Shell Oil Company Fuel oil composition
US20060201056A1 (en) * 2000-04-14 2006-09-14 Oryxe Energy International, Inc. Biodiesel fuel additive
WO2002059236A2 (en) * 2000-12-29 2002-08-01 Ge Betz, Inc. Stabilizer blends for alcohol in hydrocarbon fuel
US6776808B2 (en) * 2002-08-29 2004-08-17 Baker Hughes Incorporated Additive to prevent oil separation in paraffin waxes
US7413583B2 (en) * 2003-08-22 2008-08-19 The Lubrizol Corporation Emulsified fuels and engine oil synergy
US7727291B2 (en) * 2005-04-27 2010-06-01 Himmelsbach Holdings, Llc Low molecular weight fuel additive

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4365973A (en) * 1980-12-18 1982-12-28 Union Oil Company Of California Middle distillate fuel additive
US4482353A (en) * 1983-08-04 1984-11-13 Ethyl Corporation Compression ignition fuel compositions
JPH05132682A (en) * 1991-11-13 1993-05-28 Mitsubishi Oil Co Ltd Diesel fuel additive composition and its usage
US20020026743A1 (en) * 2000-05-12 2002-03-07 Henry Cyrus Pershing Diesel fuel stabiliser
US20080295395A1 (en) * 2007-05-30 2008-12-04 Baker Hughes Incorporated Additives for Reduction of Exhaust Emissions From Compression Ignition Engines

Also Published As

Publication number Publication date
US20100325944A1 (en) 2010-12-30
WO2011153002A2 (en) 2011-12-08

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