WO2011142855A3 - Room temperature ionic liquids and ionic liquid epoxy adducts as initiators for epoxy systems - Google Patents

Room temperature ionic liquids and ionic liquid epoxy adducts as initiators for epoxy systems Download PDF

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Publication number
WO2011142855A3
WO2011142855A3 PCT/US2011/023739 US2011023739W WO2011142855A3 WO 2011142855 A3 WO2011142855 A3 WO 2011142855A3 US 2011023739 W US2011023739 W US 2011023739W WO 2011142855 A3 WO2011142855 A3 WO 2011142855A3
Authority
WO
WIPO (PCT)
Prior art keywords
epoxy resins
ionic liquids
curing
room temperature
thermosetting epoxy
Prior art date
Application number
PCT/US2011/023739
Other languages
French (fr)
Other versions
WO2011142855A2 (en
Inventor
Guiseppe R. Palmese
M. Aflal M. Rahmathullah
Amutha Jeyarajasingam
Original Assignee
Drexel University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Drexel University filed Critical Drexel University
Publication of WO2011142855A2 publication Critical patent/WO2011142855A2/en
Publication of WO2011142855A3 publication Critical patent/WO2011142855A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/182—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing using pre-adducts of epoxy compounds with curing agents
    • C08G59/184—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing using pre-adducts of epoxy compounds with curing agents with amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/5046—Amines heterocyclic
    • C08G59/5053—Amines heterocyclic containing only nitrogen as a heteroatom
    • C08G59/5073—Amines heterocyclic containing only nitrogen as a heteroatom having two nitrogen atoms in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
    • C08K5/3445—Five-membered rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Epoxy Resins (AREA)

Abstract

Certain room temperature ionic liquids (RTILs) are utilized to initiate cure or as additives to manage mechanical properties in thermosetting epoxy resins. Curing thermosetting epoxy resins in the presence of room temperature ionic liquids which may initiate curing and/or act as additives to manage mechanical properties of the thermosetting epoxy resins is disclosed, as well as ionic liquids useful for curing thermosetting epoxy resins and/or to act as additives to manage mechanical properties of the thermosetting epoxy resins. The ionic liquids may form part of a curing accelerator. Resin compositions comprising a compound which contains an epoxy group and at least one ionic liquid are also disclosed, as are cured products obtained by curing a resin composition in accordance with the present invention. Tunable properties of the epoxy resins of the present invention include ability to vary cross-linker ratios, the ability to vary non-reactive RTIL concentration possessing desired characteristics.
PCT/US2011/023739 2010-02-04 2011-02-04 Room temperature ionic liquids and ionic liquid epoxy adducts as initiators for epoxy systems WO2011142855A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US30149010P 2010-02-04 2010-02-04
US61/301,490 2010-02-04

Publications (2)

Publication Number Publication Date
WO2011142855A2 WO2011142855A2 (en) 2011-11-17
WO2011142855A3 true WO2011142855A3 (en) 2012-02-02

Family

ID=44914897

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2011/023739 WO2011142855A2 (en) 2010-02-04 2011-02-04 Room temperature ionic liquids and ionic liquid epoxy adducts as initiators for epoxy systems

Country Status (1)

Country Link
WO (1) WO2011142855A2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103265492B (en) * 2013-05-16 2015-04-01 西北工业大学 Chlorinated 1-vinyl-3-carboxymethyl imidazole polymerizable acidic ionic liquid and synthetic method thereof
US10975238B2 (en) 2016-10-25 2021-04-13 Arizona Board Of Regents On Behalf Of Arizona State University Solvent-less ionic liquid epoxy resin
US11976162B2 (en) 2019-02-18 2024-05-07 Arizona Board Of Regents On Behalf Of Arizona State University Solvent-less ionic liquid epoxy resin

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06211969A (en) * 1992-10-22 1994-08-02 Ajinomoto Co Inc Epoxy resin composition
WO2008152011A1 (en) * 2007-06-13 2008-12-18 Basf Se Catalyst for curing epoxides
US20090030158A1 (en) * 2007-07-26 2009-01-29 Ajinomoto Co., Inc Resin composition
US20090035580A1 (en) * 2005-08-09 2009-02-05 The Yokohama Rubber Co., Ltd. Electropeeling composition, and making use of the same, adhesive and electropeeling multilayer adhesive

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06211969A (en) * 1992-10-22 1994-08-02 Ajinomoto Co Inc Epoxy resin composition
US20090035580A1 (en) * 2005-08-09 2009-02-05 The Yokohama Rubber Co., Ltd. Electropeeling composition, and making use of the same, adhesive and electropeeling multilayer adhesive
WO2008152011A1 (en) * 2007-06-13 2008-12-18 Basf Se Catalyst for curing epoxides
US20090030158A1 (en) * 2007-07-26 2009-01-29 Ajinomoto Co., Inc Resin composition

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
RAHMATHULLAH, M.A.M. ET AL.: "Room Temperature Ionic Liquids as Thermally Latent Initiators for Polymerization of Epoxy Resins", MACROMOLECULES, vol. 42, 2009, pages 3219 - 3221, XP055029794, DOI: doi:10.1021/ma802669k *

Also Published As

Publication number Publication date
WO2011142855A2 (en) 2011-11-17

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