WO2011133015A2 - Silicon nanowire based filter and method of fabricating thereof - Google Patents
Silicon nanowire based filter and method of fabricating thereof Download PDFInfo
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- WO2011133015A2 WO2011133015A2 PCT/MY2010/000264 MY2010000264W WO2011133015A2 WO 2011133015 A2 WO2011133015 A2 WO 2011133015A2 MY 2010000264 W MY2010000264 W MY 2010000264W WO 2011133015 A2 WO2011133015 A2 WO 2011133015A2
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- trench structure
- silicon nanowires
- nanowires
- silicon
- filtering
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
Definitions
- the present invention generally relates to fluidic filters, and more particularly to a fluidic filter comprising silicon nanowires with controlled attributes.
- the conventional and well-known methods which are widely implemented in regards to sensing in the electrochemical analysis of fluidic samples would comprise the use of fluidic channels incorporated with at least one sensing device.
- nanowires within said trench structure for use in controlling the flow of particles and collecting the particles of interest within said filtering device;
- silicon nanowires is provided by way of in-situ growth within said trench structure.
- a device (100) for use in filtering comprising: a substrate (20) ; at least one trench structure (60) ; at least one layer (80) for confining the trench structure; a predetermined amount of silicon nanowires (40) provided within the trench structure for controlling particles which flow through the device (100) and collect the desired particles within the device (100) ; characterized in that the silicon nanowires (40) are grown in- situ thus directly within the trench structure in a manner such that the nanowires (40) are permitted to free stand and self align therein.
- FIG 1 shows the filter device in accordance with a preferred embodiment of the present invention
- FIG 2 shows a flowchart for fabrication of the filter device in accordance with ' a preferred embodiment of the present invention
- FIG 3 shows the variety of cross sections for a trench structure in accordance with a preferred embodiment of the present invention
- FIG 4 shows the steps involved in preparing the filter in accordance with a preferred embodiment of the present invention
- FIG 5 shows the steps involved in preparing the filter in accordance with another preferred embodiment of the present invention
- FIG 6 shows the steps involved in preparing the filter in accordance with another preferred embodiment of the present invention
- FIG 7 shows the steps involved in preparing the filter in another preferred embodiment of the present invention.
- a fluidic filter device comprising silicon nanowires grown therein and method thereof.
- the silicon nanowires in accordance to the present invention are grown in-situ by an accurate and precise process which will be described herein, thus providing a filtering device with controllable pore sizes.
- the use of silicon nanowires is preferred owing to its low temperature process thereby allowing compatibility with most substrates.
- FIG 1 shows the filter device (100) embodying the present invention, whereby the essential or vital section of the filter (100) is a channel supporting free standing nanowires.
- the aim of the filter (100) of one embodiment in accordance with the present invention is to segregate the constituents of a fluid based on the pore size of the filter mesh or by means of functionalized sites. It is further described that the filtered outflow of the fluid of the constituents gathered at the filter can be analyzed with better precision.
- the filter mesh incorporated for the filter device (100) of the present invention is based on silicon nanowires which are grown therein as part of the fluidic channel fabrication.
- the filter device (100) of the present invention therefore comprises at least one channel (60) or trench structure formed within a substrate (20) for accommodating or supporting a predetermined amount of silicon nanowires (40) which are provided by means of in-situ growth within said channel (60) . These nanowires are grown in a free standing manner within the channel (60).
- An encapsulation layer (80) which functions primarily to confine the trench structure (60) is further disposed therein.
- a catalyst permits the growth of nanowires, whereby the catalyst may be deposited within the channel by means of physical vapour deposition, chemically or by means of self assembly.
- FIG 2 provides a flowchart showing the imperative steps involved for the fluidic filter fabrication in accordance with a preferred embodiment of the present invention.
- the first step is providing a suitable substrate (S200) and followed by the formation of trenches . or trench structures (S300) .
- the next step is deposition of catalyst or starting material for nanowire growth (S400) .
- This is then followed by in- situ deposition of silicon nanowire by, but not limiting to, chemical vapour deposition (S500) .
- the formed trench is encapsulated thus forming embedded channel by means of waferbonding (S600) .
- the trench structures of the present invention may be formed by means of etching and lithography. It is understood that the cross sections of the trench structures may vary, as shown, but not limiting to the types in FIG 3. The cross sections may include rectangular, triangular, V-shape and circular forms. Now referring to FIG 4 containing steps (a) to (e) accompany the description to show that the trench may be formed by means of etching into a substrate. Suitably, the trenches may be formed in the substrate by means of dry or wet etching followed by lithographic patterning. In this approach, the first step involves the deposition of suitable catalyst materials for the deposition or growth of silicon nanowires at the bottom portion of the channel.
- Such deposition may be carried out by means of physical vapour deposition including sputtering and evaporation.
- a lift off is preferably used to remove the excess catalyst material, after which the silicon nanowires is then suitably deposited in -situ within the formed channel.
- the channel is accordingly encapsulated by mean of waferbonding.
- FIG 5 accompanies the description in the event that the trench is formed by means of lithography.
- a polymer is involved. Similar to that of the previously discussed etching method, the starting or catalyst material may be deposited within the channel by means of physical vapour deposition. However for the removal of excess catalyst, physical polishing is preferred. Then the silicon nanowires are deposited within the channel and encapsulated by means of waferbonding.
- FIG 6 accompanies the description in the event that the trench structure is formed comprising deliberately underdeveloped polymer. This embodiment involves forming of trenches by means of lithography, whereby the channel is deliberately underdosed in order to ensure that the depth is not developed straight to the supporting substrate.
- the catalyst for the growth of the silicon nanowires may be suitably deposited within the formed channel by means of physical vapour deposition.
- the excess catalyst is then removed by means of physical polishing prior to deposition of silicon nanowires within the channel.
- the channel is then suitably encapsulated by means of waferbonding .
- the polymer containing the channel is removed from the supporting substrate.
- the silicon nanowires is deposited at desired sites with the aid of a chemical affinity to the silicon nanowires catalyst precursor.
- the trenches are defined by lithography whereby the filter region or channel is provided with a thin layer of material with chemical affinity to the catalyst material.
- the channel containing this material is suitably encapsulated by means of waferbonding, after which a solution containing the catalyst material is then channeled through the trench.
- the silicon nanowires are then deposited in-situ within the formed channel or trench by means of process gas.
- the filter device (100) comprising silicon nanowires which is preferably grown at a temperature of 350 to 500 °C in accordance to the present invention allows controllable pore size based on the spacing between the silicon nanowires and thereby the capacity to make the filter application specific and selective by way of functionalizing the silicon nanowires .
- the growth of silicon nanowires are preferably done in-situ, specifically within the formed channel of the device (100) .
- Such deposition thereby results to self-aligning process, as well as ordered morphology and thus reducing the number of required steps of the prior art methods .
- the formation of the silicon nanowires within the channel is based on a clean and controlled process which therefore does not necessitate further purification step.
- the pore size of the filter channel can vary from 50nm to 5 ⁇ , subject to its application, which may include biomedical purposes such as, but not limiting to, insolating bacteria and virus for analysis. It is further observed that the filter as described may aid in the separation of materials that may impede the operation of other devices within the fluidic cell such as sensors and filtering materials to be channeled independently to different areas of the fluidic cell.
Description
SILICON NANOWIRE BASED FILTER AND METHOD OF FABRICATING THEREOF
FIELD OF INVENTION
The present invention generally relates to fluidic filters, and more particularly to a fluidic filter comprising silicon nanowires with controlled attributes.
BACKGROUND
The conventional and well-known methods which are widely implemented in regards to sensing in the electrochemical analysis of fluidic samples would comprise the use of fluidic channels incorporated with at least one sensing device.
Generally, for an attempt of sensing chemical elements or molecules for fluidic samples using a device as briefly described above, the common challenges in producing an accurate result based on the sensing are prominently influenced by external factors such as, but not limiting to, temperature, humidity, light, motion and pressure. In order to partially resolve this increasingly unsettling drawback, users have started to incorporate filters or filtering apparatus within the apparatus in effort to reduce disruptions to obtain better sensing outcome.
The number of studies conducted in order to further develop the efficiency and enhance the capability of fluidic sensing with the aid of filtering apparatus has tremendously increased over the past few years. Such studies may become solutions for complications or undesirable characteristics as discussed previously and may further include such sensing capabilities being time drift and temperature dependence, and thus reduce the precision of sensing which is quite significant- in relation to producing an accurate output.
Another significant drawback which relates to fluidic sensing is in regards to the presence of superfluous constituents which would in many occasions result to creation of noises thus interrupting the measured signals.
Whilst many prior art and technology substitutions may be expedient and considerably enhanced in regards to the utilization of fluidic filters, the current condition or challenge of filtering unwanted materials to obtain better sensing clarity has yet to be thoroughly resolved. A great majority of devices or methods which may be able to provide at least half of the clarity in sensing are more often prohibitively expensive.
Proceeding from the above, there is a need to provide a device and method that is able to resolve the abovementioned drawbacks in regards to the utilization of fluidic filter technology. The present invention is particularly developed to overcome the aforementioned complications.
It is therefore a primary object of the present invention to provide a device and method thereof for use in fluid or fluidic filter devices, said device and method provides the capability of selective filtering thereby producing an enhanced sensing clarity .
It is further an object of the present invention to provide a device and method thereof for use in fluid or fluidic filter devices, said device and method allows the circumvention of a purification step in filtering signals during use.
It is yet another object of the present invention to provide a device and method thereof for use in fluid or fluidic filter devices, said device comprising silicon nanowires grown therein.
Further objects and advantages of the present invention may become apparent upon referring to the preferred embodiments of the present invention as shown in the accompanying drawings and as described in the following description.
SUMMARY OF INVENTION
There is disclosed a method for use in fabricating a filtering device, said method comprising the steps of:
i) forming a trench structure on a support material; ii) providing a predetermined amount of silicon
nanowires within said trench structure for use in controlling the flow of particles and collecting the particles of interest within said filtering device;
iii) confining the trench structure;
wherein said silicon nanowires is provided by way of in-situ growth within said trench structure.
In another aspect of the present invention there is disclosed a device (100) for use in filtering, said device comprising: a substrate (20) ; at least one trench structure (60) ; at least one layer (80) for confining the trench structure; a predetermined amount of silicon nanowires (40) provided within the trench structure for controlling particles which flow through the device (100) and collect the desired particles within the device (100) ; characterized in that the silicon nanowires (40) are grown in- situ thus directly within the trench structure in a manner such that the nanowires (40) are permitted to free stand and self align therein.
BRIEF DESCRIPTION OF THE ACCOMPANYING DRAWINGS In order to provide a comprehensive understanding of the nature of the invention, reference should be made to the accompanying drawings and the subsequent description. Briefly, the drawings are : FIG 1 shows the filter device in accordance with a preferred embodiment of the present invention;
FIG 2 shows a flowchart for fabrication of the filter device in accordance with' a preferred embodiment of the present invention;
FIG 3 shows the variety of cross sections for a trench structure in accordance with a preferred embodiment of the present invention; FIG 4 shows the steps involved in preparing the filter in accordance with a preferred embodiment of the present invention;
FIG 5 shows the steps involved in preparing the filter in accordance with another preferred embodiment of the present invention;
FIG 6 shows the steps involved in preparing the filter in accordance with another preferred embodiment of the present invention; FIG 7 shows the steps involved in preparing the filter in another preferred embodiment of the present invention.
DETAILED DESCRIPTION In addition to the drawings, further understanding of the object, construction, characteristics and functions of the invention, a detailed description with reference to the embodiments is given in the following. It should be noted that the preferred embodiments which will be described in detail herein are provided to assist in further understanding of the invention. The steps involved in attaining the outcome based on the scope of the appended claims are described in their best mode and sequential order, said sequential order may vary and thus the best mode which will be described herein should not be construed as restricting the scope of the invention.
In accordance with one aspect of the present invention for achieving the above discussed objects, there is provided a fluidic filter device comprising silicon nanowires grown therein
and method thereof. The silicon nanowires in accordance to the present invention are grown in-situ by an accurate and precise process which will be described herein, thus providing a filtering device with controllable pore sizes. The use of silicon nanowires is preferred owing to its low temperature process thereby allowing compatibility with most substrates.
FIG 1 shows the filter device (100) embodying the present invention, whereby the essential or vital section of the filter (100) is a channel supporting free standing nanowires.
The aim of the filter (100) of one embodiment in accordance with the present invention is to segregate the constituents of a fluid based on the pore size of the filter mesh or by means of functionalized sites. It is further described that the filtered outflow of the fluid of the constituents gathered at the filter can be analyzed with better precision. As previously mentioned, the filter mesh incorporated for the filter device (100) of the present invention is based on silicon nanowires which are grown therein as part of the fluidic channel fabrication.
The filter device (100) of the present invention therefore comprises at least one channel (60) or trench structure formed within a substrate (20) for accommodating or supporting a predetermined amount of silicon nanowires (40) which are provided
by means of in-situ growth within said channel (60) . These nanowires are grown in a free standing manner within the channel (60). An encapsulation layer (80) which functions primarily to confine the trench structure (60) is further disposed therein. A catalyst permits the growth of nanowires, whereby the catalyst may be deposited within the channel by means of physical vapour deposition, chemically or by means of self assembly.
FIG 2 provides a flowchart showing the imperative steps involved for the fluidic filter fabrication in accordance with a preferred embodiment of the present invention. As evident in the flowchart the first step is providing a suitable substrate (S200) and followed by the formation of trenches . or trench structures (S300) . The next step is deposition of catalyst or starting material for nanowire growth (S400) . This is then followed by in- situ deposition of silicon nanowire by, but not limiting to, chemical vapour deposition (S500) . Finally, the formed trench is encapsulated thus forming embedded channel by means of waferbonding (S600) .
The trench structures of the present invention may be formed by means of etching and lithography. It is understood that the cross sections of the trench structures may vary, as shown, but not limiting to the types in FIG 3. The cross sections may include rectangular, triangular, V-shape and circular forms.
Now referring to FIG 4 containing steps (a) to (e) accompany the description to show that the trench may be formed by means of etching into a substrate. Suitably, the trenches may be formed in the substrate by means of dry or wet etching followed by lithographic patterning. In this approach, the first step involves the deposition of suitable catalyst materials for the deposition or growth of silicon nanowires at the bottom portion of the channel. Such deposition may be carried out by means of physical vapour deposition including sputtering and evaporation. In the next step, a lift off is preferably used to remove the excess catalyst material, after which the silicon nanowires is then suitably deposited in -situ within the formed channel. In the final step of this process, the channel is accordingly encapsulated by mean of waferbonding.
FIG 5 accompanies the description in the event that the trench is formed by means of lithography. As seen in step 5 (a) , a polymer is involved. Similar to that of the previously discussed etching method, the starting or catalyst material may be deposited within the channel by means of physical vapour deposition. However for the removal of excess catalyst, physical polishing is preferred. Then the silicon nanowires are deposited within the channel and encapsulated by means of waferbonding. FIG 6 accompanies the description in the event that the trench structure is formed comprising deliberately underdeveloped
polymer. This embodiment involves forming of trenches by means of lithography, whereby the channel is deliberately underdosed in order to ensure that the depth is not developed straight to the supporting substrate. In step 6 (b) and similar to that of the previously discussed methods, the catalyst for the growth of the silicon nanowires may be suitably deposited within the formed channel by means of physical vapour deposition. The excess catalyst is then removed by means of physical polishing prior to deposition of silicon nanowires within the channel. The channel is then suitably encapsulated by means of waferbonding . For this method, the polymer containing the channel is removed from the supporting substrate.
In another preferred embodiment of the present invention and as shown in FIG 7 the silicon nanowires is deposited at desired sites with the aid of a chemical affinity to the silicon nanowires catalyst precursor. For this embodiment, the trenches are defined by lithography whereby the filter region or channel is provided with a thin layer of material with chemical affinity to the catalyst material. Subsequently, the channel containing this material is suitably encapsulated by means of waferbonding, after which a solution containing the catalyst material is then channeled through the trench. The silicon nanowires are then deposited in-situ within the formed channel or trench by means of process gas.
It should be noted that the filter device (100) comprising silicon nanowires which is preferably grown at a temperature of 350 to 500 °C in accordance to the present invention allows controllable pore size based on the spacing between the silicon nanowires and thereby the capacity to make the filter application specific and selective by way of functionalizing the silicon nanowires .
In accordance to a preferred embodiment of the present invention and as discussed briefly in the preceding paragraphs, the growth of silicon nanowires are preferably done in-situ, specifically within the formed channel of the device (100) . Such deposition thereby results to self-aligning process, as well as ordered morphology and thus reducing the number of required steps of the prior art methods .
In another preferred embodiment of the present invention, the formation of the silicon nanowires within the channel is based on a clean and controlled process which therefore does not necessitate further purification step.
It is noted that the pore size of the filter channel can vary from 50nm to 5μπι, subject to its application, which may include biomedical purposes such as, but not limiting to, insolating bacteria and virus for analysis. It is further observed that the filter as described may aid in the separation of materials that
may impede the operation of other devices within the fluidic cell such as sensors and filtering materials to be channeled independently to different areas of the fluidic cell. Although the present invention has been described in terms of the presently preferred embodiments, it is to be understood that such disclosure is not to be interpreted as limiting. Various alterations and modifications will no doubt become apparent to those skilled- in the art after having read the above disclosure. The appended claims should be interpreted as covering all alterations and modifications as fall within the scope of invention .
Claims
1. A method for use in fabricating a filtering device, said method comprising the steps of:
a) forming a trench structure (S300) on a support
material ;
b) providing a predetermined amount of silicon nanowires (S500) within said trench structure for use in controlling the flow of particles and collecting the particles of interest within said filtering device;
c) confining (S600) the trench structure;
wherein said silicon nanowires is provided by way of in-situ growth within said trench structure. d) The method as claimed in Claim 1 wherein the method further comprising the step of providing a form of catalyst for the growth of silicon nanowires
(S400) . e) The method as claimed in Claim 1 wherein the step providing a predetermined amount of silicon nanowires (S400) comprises providing said nanowires directly in the trench structure and thus allowing self alignment of the silicon nanowires. The method as claimed in Claim 1 wherein the trench structure is confined in a manner such that a capping or encapsulating layer is provided on said structure .
The method as claimed in Claim 1 wherein the supporting material comprises a substrate.
The method as claimed in Claim 1 wherein the temperature for growth of silicon nanowires is between 350-500°C.
The method as claimed in Claim 1 wherein the trench structure has a cross-section generally in the form of either a rectangular, circular, V-shape or triangular shape.
The method as claimed in Claim 1 wherein the silicon nanowire has a pore size of between 50nm to 1.5 μπι, whereby the pore size can be varied subject to the desired particles to be filtered.
The method as claimed in Claim 1 wherein the trench structure may be formed by etching or lithography.
The method as claimed in Claim 3 wherein the catalyst is provided by means of physical vapour deposition, chemically or by means of self assembly. m) The method as claimed in Claim 1 wherein the silicon nanowires may be grown by means of chemical vapour deposition or flowing a process gas. n) The method as claimed in Claim 2 wherein the step providing a catalyst further comprising the step of removing excess catalyst from the trench structure. o) The method as claimed in Claim 4 wherein the encapsulation may be provided by means of anodic bonding, silicon bonding, adhesive bonding or polymer bonding.
p) The method as claimed in Claim 1 wherein the filtering device is for use in fluid and gases. q) A device (100) for use in filtering, said device comprising:
a substrate (20) ;
at least one trench structure (60) ;
at least one layer (80) for confining the trench structure;
a predetermined amount of silicon nanowires (40) provided within the trench structure for controlling particles which flow through the device (100) and collect the desired particles within the device (100); characterized in that the silicon nanowires (40) are grown in-situ thus directly within the trench structure in a manner such that the nanowires (40) are permitted to free stand and self align therein, r) The device (100) as claimed in Claim 15 wherein the device is used in series or parallel for filtering fluid at different stages,
s) The device (100) as claimed in Claim 15 for use in filtering fluid and gases.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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MYPI2010001857A MY190580A (en) | 2010-04-23 | 2010-04-23 | Silicon nanowire based filter and method of fabricating thereof |
MYPI2010001857 | 2010-04-23 |
Publications (1)
Publication Number | Publication Date |
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WO2011133015A2 true WO2011133015A2 (en) | 2011-10-27 |
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PCT/MY2010/000264 WO2011133015A2 (en) | 2010-04-23 | 2010-11-10 | Silicon nanowire based filter and method of fabricating thereof |
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MY (1) | MY190580A (en) |
WO (1) | WO2011133015A2 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10598575B2 (en) | 2015-07-17 | 2020-03-24 | The Penn State Research Foundation | Sizable tunable enrichment platform for capturing nano particles in a fluid |
CN116747615A (en) * | 2016-06-07 | 2023-09-15 | 苏州苏瑞膜纳米科技有限公司 | Fluid treatment device based on porous film and preparation process thereof |
-
2010
- 2010-04-23 MY MYPI2010001857A patent/MY190580A/en unknown
- 2010-11-10 WO PCT/MY2010/000264 patent/WO2011133015A2/en active Application Filing
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10598575B2 (en) | 2015-07-17 | 2020-03-24 | The Penn State Research Foundation | Sizable tunable enrichment platform for capturing nano particles in a fluid |
US11022529B2 (en) | 2015-07-17 | 2021-06-01 | The Penn State Research Foundation | Sizable tunable enrichment platform for capturing nano particles in a fluid |
CN116747615A (en) * | 2016-06-07 | 2023-09-15 | 苏州苏瑞膜纳米科技有限公司 | Fluid treatment device based on porous film and preparation process thereof |
Also Published As
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MY190580A (en) | 2022-04-27 |
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