WO2011132674A1 - 熱硬化性組成物 - Google Patents
熱硬化性組成物 Download PDFInfo
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- WO2011132674A1 WO2011132674A1 PCT/JP2011/059627 JP2011059627W WO2011132674A1 WO 2011132674 A1 WO2011132674 A1 WO 2011132674A1 JP 2011059627 W JP2011059627 W JP 2011059627W WO 2011132674 A1 WO2011132674 A1 WO 2011132674A1
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- Prior art keywords
- resin
- group
- resin composition
- compound
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- 229920001665 Poly-4-vinylphenol Polymers 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004695 Polyether sulfone Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 229920006397 acrylic thermoplastic Polymers 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 description 1
- 229910002113 barium titanate Inorganic materials 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
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- 239000003795 chemical substances by application Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- UQLDLKMNUJERMK-UHFFFAOYSA-L di(octadecanoyloxy)lead Chemical compound [Pb+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O UQLDLKMNUJERMK-UHFFFAOYSA-L 0.000 description 1
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 1
- LQRUPWUPINJLMU-UHFFFAOYSA-N dioctyl(oxo)tin Chemical compound CCCCCCCC[Sn](=O)CCCCCCCC LQRUPWUPINJLMU-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000006735 epoxidation reaction Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 239000005350 fused silica glass Substances 0.000 description 1
- JMANVNJQNLATNU-UHFFFAOYSA-N glycolonitrile Natural products N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- DLAPQHBZCAAVPQ-UHFFFAOYSA-N iron;pentane-2,4-dione Chemical compound [Fe].CC(=O)CC(C)=O DLAPQHBZCAAVPQ-UHFFFAOYSA-N 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 229920003049 isoprene rubber Polymers 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- GIWKOZXJDKMGQC-UHFFFAOYSA-L lead(2+);naphthalene-2-carboxylate Chemical compound [Pb+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 GIWKOZXJDKMGQC-UHFFFAOYSA-L 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 125000005439 maleimidyl group Chemical group C1(C=CC(N1*)=O)=O 0.000 description 1
- SGGOJYZMTYGPCH-UHFFFAOYSA-L manganese(2+);naphthalene-2-carboxylate Chemical compound [Mn+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 SGGOJYZMTYGPCH-UHFFFAOYSA-L 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- JDEJGVSZUIJWBM-UHFFFAOYSA-N n,n,2-trimethylaniline Chemical compound CN(C)C1=CC=CC=C1C JDEJGVSZUIJWBM-UHFFFAOYSA-N 0.000 description 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- AFEQENGXSMURHA-UHFFFAOYSA-N oxiran-2-ylmethanamine Chemical compound NCC1CO1 AFEQENGXSMURHA-UHFFFAOYSA-N 0.000 description 1
- 229920009441 perflouroethylene propylene Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000013034 phenoxy resin Substances 0.000 description 1
- 229920006287 phenoxy resin Polymers 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 239000003504 photosensitizing agent Substances 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920003055 poly(ester-imide) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920001955 polyphenylene ether Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229920002102 polyvinyl toluene Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 1
- 229960001755 resorcinol Drugs 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 125000002256 xylenyl group Chemical class C1(C(C=CC=C1)C)(C)* 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- BNEMLSQAJOPTGK-UHFFFAOYSA-N zinc;dioxido(oxo)tin Chemical compound [Zn+2].[O-][Sn]([O-])=O BNEMLSQAJOPTGK-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/04—Epoxynovolacs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/14—Layered products comprising a layer of metal next to a fibrous or filamentary layer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
- C08G59/5046—Amines heterocyclic
- C08G59/5053—Amines heterocyclic containing only nitrogen as a heteroatom
- C08G59/5073—Amines heterocyclic containing only nitrogen as a heteroatom having two nitrogen atoms in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
- C08G59/56—Amines together with other curing agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
- C08G59/681—Metal alcoholates, phenolates or carboxylates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
- C08G59/686—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
- C08J5/244—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using glass fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/02—Composition of the impregnated, bonded or embedded layer
- B32B2260/021—Fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/04—Impregnation, embedding, or binder material
- B32B2260/046—Synthetic resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
- B32B2457/08—PCBs, i.e. printed circuit boards
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/32—Epoxy compounds containing three or more epoxy groups
- C08G59/38—Epoxy compounds containing three or more epoxy groups together with di-epoxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
- C08L63/04—Epoxynovolacs
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
Definitions
- the present invention relates to a resin composition. More specifically, the present invention relates to a resin composition used as a printed wiring board material for forming an electric circuit, a prepreg impregnated or coated on a base material, and the prepreg is cured. It is related with the laminated board obtained.
- a cyanate resin containing a cyanate compound and a bismaleimide triazine resin (BT resin) containing a compound obtained by reacting a cyanate compound and a bismaleimide compound have long been known as a thermosetting resin excellent in high heat resistance and dielectric properties. ing. In recent years, these resins have been widely used for high-performance printed wiring board materials such as for semiconductor plastic packages (for example, Patent Documents 1 and 2).
- the inventors of the present invention now perform a drying process or a laminated press molding after impregnation coating of a prepreg in a low temperature and in a short time by adding an epoxy resin and a specific imidazole compound to a cyanate resin or a BT resin. And a knowledge that a resin composition capable of maintaining the storage stability of the prepreg can be realized. The present invention is based on this finding.
- an object of the present invention is to provide a resin composition capable of performing a drying process and lamination press molding after impregnation coating of a prepreg at a low temperature and in a short time and maintaining the storage stability of the prepreg. .
- the resin composition by this invention is An imidazole compound (A) represented by the following formula (I); An epoxy compound (B), A cyanate compound (C1) or a BT resin (C2); Is included.
- R 1 and R 2 are each independently an alkyl group having 3 to 18 carbon atoms, an alkenyl group having 3 to 18 carbon atoms, an alkoxyl group having 3 to 18 carbon atoms, or a substituted or unsubstituted group having 6 to 14 carbon atoms.
- Represents an aromatic substituent of R 3 is hydrogen, an alkyl group having 1 to 18 carbon atoms, an alkenyl group having 2 to 18 carbon atoms, an alkoxyl group having 1 to 18 carbon atoms, a substituted or unsubstituted aromatic substituent having 6 to 14 carbon atoms, or Represents a halogen group.
- the present invention it is possible to realize a resin composition that can perform a drying process and laminate press molding after impregnation coating of a prepreg in a low temperature and in a short time and can also maintain the storage stability of the prepreg. Therefore, both the productivity and the storage stability of the cyanate compound-containing resin and the BT resin having excellent heat resistance and moisture absorption heat resistance can be achieved.
- the resin composition according to the present invention contains a specific imidazole compound (A), an epoxy compound (B), and a cyanate compound (C1) or a BT resin (C2) as essential components.
- A specific imidazole compound
- B epoxy compound
- C1 cyanate compound
- C2 a BT resin
- the resin composition according to the present invention contains an imidazole compound (A) represented by the following formula (I).
- R 1 and R 2 are each independently an alkyl group having 3 to 18 carbon atoms, an alkenyl group having 3 to 18 carbon atoms, an alkoxyl group having 3 to 18 carbon atoms, or a carbon number of 6 Represents -14 substituted or unsubstituted aromatic substituents.
- examples of such a substituent include an alkyl group having 1 to 18 carbon atoms, an alkenyl group having 2 to 18 carbon atoms, and a carbon number Examples include 1 to 18 alkoxyl groups and halogen groups.
- R 1 and R 2 are each independently isopropyl group, t-butyl group, isopropylalkoxyl group, t-butylalkoxyl group, phenyl group, or naphthyl. It is preferable that each of R 1 and R 2 is a phenyl group.
- R 3 represents hydrogen, an alkyl group having 1 to 18 carbon atoms, an alkenyl group having 2 to 18 carbon atoms, an alkoxyl group having 1 to 18 carbon atoms, a substitution having 6 to 14 carbon atoms, It represents an unsubstituted aromatic substituent or a halogen group.
- examples of such a substituent include an alkyl group having 1 to 18 carbon atoms, an alkenyl group having 2 to 18 carbon atoms, and a carbon number Examples include 1 to 18 alkoxyl groups and halogen groups.
- the productivity and storage stability of the cyanate compound-containing resin and BT resin having the properties can be made compatible.
- the reason for this is not clear, but can be considered as follows. That is, the specific imidazole compound (A) having a bulky substituent in the vicinity of the secondary amine, which is the reaction active site in the imidazole compound, has high molecular kinetic energy at high temperatures and exhibits catalytic activity due to the secondary amine. However, since the molecular kinetic energy is low at low temperatures and the catalytic activity of the secondary amine is suppressed, it is considered that both productivity (curing rate) and storage stability can be achieved.
- the imidazole compound (A) is preferably contained in an amount of 0.1 to 10% by mass, more preferably 0.2%, based on the total amount of the resin, from the viewpoint of curing acceleration effect, storage stability and moldability. ⁇ 5% by mass.
- the total amount of resin refers to the total mass of the imidazole compound (A), the epoxy compound (B), and the cyanate compound (C1) or BT resin (C2).
- the resin composition according to the present invention may contain other known curing accelerators in addition to the imidazole compound (A).
- curing accelerators include organic peroxides exemplified by benzoyl peroxide, lauroyl peroxide, acetyl peroxide, parachlorobenzoyl peroxide, di-tert-butyl-di-perphthalate, and the like.
- Bisnitrile azo compounds N, N-dimethylbenzylamine, N, N-dimethylaniline, N, N-dimethyltoluidine, 2-N-ethylanilinoethanol, tri-n-butylamine, pyridine, quinoline, N- Tertiary amines such as methylmorpholine, triethanolamine, triethylenediamine, tetramethylbutanediamine, N-methylpiperidine, phenols such as phenol, xylenol, cresol, resorcin, catechol, lead naphthenate, lead stearate, naphthene Zinc acid Organic metal salts such as zinc octylate, tin oleate, dibutyltin malate, manganese naphthenate, cobalt naphthenate, iron acetylacetone, etc., and those organic metal salts dissolved in hydroxyl-containing compounds such as phenol and bisphenol, tin chloride, chlor
- the epoxy compound (B) used in the present invention is not particularly limited as long as it is a compound having two or more epoxy groups in one molecule, and known compounds can be used.
- preferred epoxy compounds (B) include those having a structure in which a hydrogen atom of a hydroxyl group of a compound having two or more hydroxyl groups in one molecule is substituted with a glycidyl group.
- the epoxy compound (B) preferably has an aromatic group, and an epoxy compound having a structure in which a glycidyl group is directly connected to the aromatic group can be suitably used.
- epoxy compounds include bisphenol A, bisphenol F, bisphenol M, bisphenol P, bisphenol E, phenol novolac resin, cresol novolac resin, dicyclopentadiene novolac resin, tetramethylbisphenol F, bisphenol A novolak resin, bromine.
- Bisphenol A brominated phenol novolak resin, trifunctional phenol, tetrafunctional phenol, naphthalene type phenol, biphenyl type phenol, phenol aralkyl resin, biphenyl aralkyl resin, naphthol aralkyl resin, dicyclopentadiene aralkyl resin, alicyclic phenol, phosphorus A compound having a structure in which a hydrogen atom of a hydroxyl group such as phenol is substituted with a glycidyl group, or glycidylamine, glycidyl ester Ether, compounds obtained by epoxidation of a double bond such as butadiene, compounds obtained by the reaction of hydroxyl-containing silicone resins and epichlorohydrin, and the like.
- These epoxy compounds (B) may be used alone or in combination of two or more.
- the above-described epoxy compound (B) may be in any form of a monomer, an oligomer and a
- the epoxy compound (B) is preferably contained in an amount of 25 to 95% by mass, more preferably 30 to 90% by mass with respect to the total amount of the resin, from the viewpoints of moisture absorption heat resistance and heat resistance.
- the cyanate compound (C1) used in the present invention is not particularly limited as long as it is a compound having two or more cyanate groups in one molecule, and a known one can be used.
- preferred cyanate compounds (C1) include those having a structure in which the hydroxyl group of a compound having two or more hydroxyl groups in one molecule is substituted with a cyanate group.
- what has an aromatic group is preferable as a cyanate compound (C1), and the thing of the structure where the cyanate group was directly connected to the aromatic group can be used conveniently.
- cyanate compounds include bisphenol A, bisphenol F, bisphenol M, bisphenol P, bisphenol E, phenol novolac resin, cresol novolac resin, dicyclopentadiene novolac resin, tetramethylbisphenol F, bisphenol A novolac resin, bromine.
- Bisphenol A brominated phenol novolak resin, trifunctional phenol, tetrafunctional phenol, naphthalene type phenol, biphenyl type phenol, phenol aralkyl resin, biphenyl aralkyl resin, naphthol aralkyl resin, dicyclopentadiene aralkyl resin, alicyclic phenol, phosphorus
- cyanate compounds (C1) may be used alone or in combination of two or more. Further, the cyanate compound (C1) described above may be in any form of a monomer, an oligomer and a resin.
- the above-described cyanate compound (C1) can be produced by a conventionally known method, and can be obtained, for example, by a reaction between a compound having two or more hydroxyl groups in one molecule and cyanogen halide.
- the cyanate compound (C1) is preferably contained in an amount of 5 to 75% by mass, more preferably 10 to 70% by mass, based on the total amount of the resin.
- the BT resin (C2) used in the present invention is a polymer in which the cyanate compound (C1) and the maleimide compound described above are heated and melt-mixed without solvent, or dissolved in a suitable organic solvent and heated and mixed. It means what has become.
- the organic solvent used for mixing the cyanate compound (C1) and the maleimide compound include methyl ethyl ketone, N methyl pyrodoline, dimethylformamide, dimethylacetamide, toluene, xylene and the like.
- any compound having one or more maleimide groups in one molecule can be used without any particular limitation.
- These maleimide compounds may be used alone or in appropriate combination of two or more.
- the BT resin (C2) is preferably contained in an amount of 5 to 75% by mass, more preferably 10 to 70% by mass with respect to the total amount of the resin, from the viewpoints of moisture absorption heat resistance and heat resistance.
- the resin composition according to the present invention may further contain a maleimide compound (D).
- a maleimide compound (D) those described above can be preferably used.
- the content of the maleimide compound (D) is preferably 50% by mass or less, more preferably 40% by mass or less, based on the total amount of the resin, from the viewpoint of moisture absorption heat resistance.
- the total amount of resin refers to the total mass of the imidazole compound (A), epoxy compound (B), cyanate compound (C1) or BT resin (C2), and maleimide compound (D).
- the resin composition may contain an inorganic filler.
- an inorganic filler By adding an inorganic filler, it is possible to impart low thermal expansion, flame retardancy and laser processability to the resin, and to control the fluidity of the resin during molding of the prepreg or laminate.
- the inorganic filler used in the present invention known ones can be used without any particular limitation.
- natural silica fused silica, amorphous silica, fumed silica, hollow silica and other silicas, aluminum hydroxide, hydroxylated Aluminum heat-treated products (heat treated with aluminum hydroxide and reduced in part of crystal water), boehmite, metal hydroxides such as magnesium hydroxide, molybdenum compounds such as molybdenum oxide and zinc molybdate, titanium oxide, Barium titanate, barium sulfate, zinc borate, zinc stannate, alumina, clay, kaolin, talc, calcined clay, calcined kaolin, calcined talc, mica, short glass fiber (glass fine powders such as E glass and D glass) And hollow glass.
- metal hydroxides such as magnesium hydroxide, molybdenum compounds such as molybdenum oxide and zinc molybdate, titanium oxide, Barium titanate, barium sulfate, zinc borate, zinc stannate, alumina, clay,
- aluminum hydroxide aluminum hydroxide heat-treated product (a product obtained by heat-treating aluminum hydroxide and reducing part of crystal water), boehmite, magnesium hydroxide, etc.
- Molybdenum compounds such as metal hydrate, molybdenum oxide, and zinc molybdate can be preferably used. These inorganic fillers may be used alone or in combination of two or more.
- the inorganic filler is preferably contained in an amount of 10 to 600% by mass, more preferably 30 to 500% by mass, based on the total amount of resin, from the viewpoint of linear expansion coefficient, flame retardancy, and moldability.
- the resin composition according to the present invention may contain other components as necessary in addition to the above-described components.
- Other thermosetting resins, thermoplastic resins, and various polymer compounds such as oligomers and elastomers, other flame retardant compounds, additives, etc. are added within the range where the desired properties are not impaired. It may be. These can be used without particular limitation as long as they are generally used.
- phosphorus compounds such as phosphate esters and melamine phosphate
- nitrogen-containing compounds such as melamine and benzoguanamine
- oxazine ring-containing compounds silicon compounds
- polyimides polyvinyl acetals
- phenoxy resins acrylic resins, acrylics having hydroxyl groups or carboxyl groups Resin, alkyd resin, thermoplastic polyurethane resin, polybutadiene, butadiene-acrylonitrile copolymer, polychloroprene, butadiene-styrene copolymer, polyisoprene, butyl rubber, fluorine rubber, natural rubber and other elastomers, styrene-isoprene rubber, acrylic Rubber, core-shell rubber, epoxidized butadiene, maleated butadiene, polyethylene, polypropylene, polyethylene-propylene copolymer, poly-4-methylpente -1, Polyvinyl chloride, polyvinylidene chloride
- Thermoplastic resins and their low molecular weight polymers (meth) acrylates, epoxy (meth) acrylates, poly (meth) acrylates such as di (meth) acryloxy-bisphenol, styrene Polymerization of polyallyl compounds such as vinyl pyrrolidone, diacryl phthalate, divinyl benzene, diallyl benzene, diallyl ether bisphenol, trialkenyl isocyanurate and prepolymers thereof, dicyclopentadiene and prepolymers thereof, phenol resin, unsaturated polyester, etc. Curable double bond-containing monomers and prepolymers thereof, and thermosetting monomers such as polyisocyanates or prepolymers thereof.
- Additives include UV absorbers, antioxidants, photopolymerization initiators, optical brighteners, photosensitizers, dyes, pigments, thickeners, lubricants, antifoaming agents, dispersants, leveling agents, brighteners A polymerization inhibitor and the like, and these additives may be used alone or in combination of two or more thereof as necessary.
- the resin composition according to the present invention is cured by heating. Curing conditions vary depending on the composition of the resin composition, the amount of imidazole compound (A) that is a curing accelerator, and the like. When the resin composition is completely cured, heating is usually performed in the range of 100 to 300 ° C. for a predetermined time. For example, the resin composition is cured under a pressure of 0.1 to 5 MPa, preferably 0.5 to 3 MPa.
- the cured product obtained as described above can be used for various applications because of its excellent physical properties and workability.
- Preferable uses of the resin composition according to the present invention include materials for printed wiring boards such as prepregs and copper-clad laminates, structural materials, and casting resins.
- the prepreg is obtained by impregnating or applying the above resin composition to a base material.
- a base material the well-known inorganic or organic fibrous reinforcement used for various printed wiring board materials etc. can be used.
- the inorganic fiber reinforcing material include glass fibers such as E, NE, D, S, and T glass, quartz glass fibers, carbon fibers, alumina fibers, silicon carbide fibers, asbestos, rock wool, slag wool, and gypsum whiskers. Inorganic fibers, and their woven or non-woven fabrics, or a mixture thereof.
- organic fiber reinforcing material examples include organic fibers such as wholly aromatic polyamide fibers, polyimide fibers, liquid crystal polyesters, polyester fibers, fluorine fibers, polybenzoxazole fibers, cotton, hemp, semi-carbon fibers, and their textiles. Or a non-woven cloth, or a mixture thereof.
- inorganic or organic fibrous reinforcing materials may be used alone or in combination of two or more as necessary.
- glass fiber and wholly aromatic polyamide fiber, glass fiber and carbon fiber, glass fiber and polyamide fiber, glass fiber and liquid crystalline aromatic polyester mixed fiber, glass paper, mica paper, inorganic paper such as alumina paper, kraft paper A combination of cotton paper, paper-glass mixed paper, or a combination of two or more of these may be used.
- the above-described base material may be subjected to a surface treatment in order to improve adhesion with the resin.
- a surface treatment a conventionally known method applied in a prepreg or a laminate can be used.
- a polyimide film, a wholly aromatic polyamide film, a polybenzoxazole film, a liquid crystal polyester film, etc. can be used suitably as a base material used for a thin object use.
- the prepreg can be produced by impregnating or applying the above resin composition to a substrate.
- the resin is semi-cured by heating in a dryer at 100 to 200 ° C. for 1 to 60 minutes.
- the content of the resin composition (including the inorganic filler) relative to the substrate is preferably in the range of 20 to 90% by mass with respect to the entire prepreg.
- a laminated board can be formed by laminating and molding (curing) the above-described prepreg.
- a laminated board is manufactured by superimposing one or two or more of the above-described prepregs, placing a metal foil such as copper or aluminum on one side or both sides as desired, laminating, and molding (curing).
- the metal foil to be used any metal foil can be used without particular limitation as long as it is used for printed wiring board materials.
- the method of the normal laminated board for printed wiring boards and a multilayer board is employable for lamination molding. For example, as the conditions for lamination molding, a multistage press, a multistage vacuum press, continuous molding, an autoclave molding machine, a vacuum laminator, etc.
- the temperature is 100 to 300 ° C.
- the pressure is 2 to 100 kgf / cm 2
- the heating time is 0 A range of .05 to 5 hours is common.
- it can also be set as a multilayer board by carrying out lamination molding combining the above-mentioned prepreg and the wiring board for inner layers prepared separately.
- Example 1 25 parts by mass of 2,2-bis (4-cyanatophenyl) propane (CA200, manufactured by Mitsubishi Gas Chemical Co., Inc.), and bis (3-ethyl-5-methyl-4-maleimidophenyl) methane (BMI-70, 25 parts by mass were mixed, melted at 150 ° C., reacted for 6 hours with stirring, and then dissolved in methyl ethyl ketone to obtain a BT resin.
- CA200 2,2-bis (4-cyanatophenyl) propane
- BMI-70 bis (3-ethyl-5-methyl-4-maleimidophenyl) methane
- BT resin 50 parts by mass of the obtained BT resin (parts in terms of solid content), 25 parts by mass of a phenol novolac type epoxy (N770, manufactured by DIC), biphenylaralkyl type epoxy (NC-3000-FH, manufactured by Nippon Kayaku Co., Ltd.) 25 parts by mass, 0.02 parts by mass of zinc octylate, and 1 part by mass of 2,4,5-triphenylimidazole (manufactured by Tokyo Chemical Industry) were mixed to prepare a varnish.
- the obtained varnish was impregnated with 0.1 mm thick E glass cloth (E10T, manufactured by Unitika glass fiber) and dried at 165 ° C. until the gelation time reached 90 seconds.
- a prepreg was prepared.
- Example 2 60 parts by mass of 2,2-bis (4-cyanatophenyl) propane (CA200, manufactured by Mitsubishi Gas Chemical Co., Inc.) was melted at 150 ° C., reacted for 6 hours with stirring, and then dissolved in methyl ethyl ketone. As a result, a prepolymer was obtained.
- CA200 2,2-bis (4-cyanatophenyl) propane
- Comparative Example 1 Insulating layer thickness of 0. 1 is the same as Example 1 except that 2-phenyl, 4-methylimidazole (manufactured by Tokyo Chemical Industry Co., Ltd.) is used instead of 2,4,5-triphenylimidazole in Example 1. A 2 mm copper clad laminate was obtained.
- Comparative Example 2 A copper clad laminate having an insulating layer thickness of 0.2 mm was obtained in the same manner as in Example 1 except that 2,4,5-triphenylimidazole was not used in Example 1.
- Comparative Example 3 Insulating layer thickness of 0. 2 in the same manner as in Example 2 except that 2-phenyl, 4-methylimidazole (manufactured by Tokyo Chemical Industry Co., Ltd.) was used instead of 2,4,5-triphenylimidazole in Example 2. A 2 mm copper clad laminate was obtained.
- Comparative Example 4 A copper clad laminate having an insulating layer thickness of 0.2 mm was obtained in the same manner as in Example 2, except that 2,4,5-triphenylimidazole was not used in Example 2.
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Abstract
Description
下記式(I)で表されるイミダゾール化合物(A)と、
エポキシ化合物(B)と、
シアネート化合物(C1)またはBT樹脂(C2)と、
を含んでなるものである。
R1およびR2は、それぞれ独立して、炭素数3~18のアルキル基、炭素数3~18のアルケニル基、炭素数3~18のアルコキシル基、または炭素数6~14の置換もしくは非置換の芳香族置換基を表し、
R3は、水素、炭素数1~18のアルキル基、炭素数2~18のアルケニル基、炭素数1~18のアルコキシル基、炭素数6~14の置換もしくは非置換の芳香族置換基、またはハロゲン基を表す。)
本発明において用いられるエポキシ化合物(B)は、1分子中に2個以上のエポキシ基を有する化合物であれば特に制限なく、公知のものを使用することができる。本発明において、好ましいエポキシ化合物(B)としては、1分子中に2個以上の水酸基を有する化合物の水酸基の水素原子をグリシジル基に置換した構造のものが挙げられる。また、エポキシ化合物(B)は、芳香族基を有するものが好ましく、グリシジル基が芳香族基に直結した構造のものを好適に使用することができる。このようなエポキシ化合物としては、例えば、ビスフェノールA、ビスフェノールF、ビスフェノールM、ビスフェノールP、ビスフェノールE、フェノールノボラック樹脂、クレゾールノボラック樹脂、ジシクロペンタジエンノボラック樹脂、テトラメチルビスフェノールF、ビスフェノールAノボラック樹脂、臭素化ビスフェノールA、臭素化フェノールノボラック樹脂、3官能フェノール、4官能フェノール、ナフタレン型フェノール、ビフェニル型フェノール、フェノールアラルキル樹脂、ビフェニルアラルキル樹脂、ナフトールアラルキル樹脂、ジシクロペンタジエンアラルキル樹脂、脂環式フェノール、リン含有フェノール等の水酸基の水素原子をグリシジル基に置換した構造の化合物、またはグリシジルアミン、グリシジルエステル、ブタジエンなどの2重結合をエポキシ化した化合物、水酸基含有シリコン樹脂類とエピクロルヒドリン等との反応により得られる化合物等が挙げられる。これらのエポキシ化合物(B)は、単独でまたは2種以上を適宜組み合わせて使用してもよい。また、上記したエポキシ化合物(B)は、モノマー、オリゴマーおよび樹脂のいずれの形態であってもよい。
本発明において用いられるシアネート化合物(C1)は、1分子中に2個以上のシアネート基を有する化合物であれば特に制限なく、公知のものを使用することができる。本発明において、好ましいシアネート化合物(C1)としては、1分子中に2個以上の水酸基を有する化合物の水酸基をシアネート基に置換した構造のものが挙げられる。また、シアネート化合物(C1)は、芳香族基を有するものが好ましく、シアネート基が芳香族基に直結した構造のものを好適に使用することができる。このようなシアネート化合物としては、例えば、ビスフェノールA、ビスフェノールF、ビスフェノールM、ビスフェノールP、ビスフェノールE、フェノールノボラック樹脂、クレゾールノボラック樹脂、ジシクロペンタジエンノボラック樹脂、テトラメチルビスフェノールF、ビスフェノールAノボラック樹脂、臭素化ビスフェノールA、臭素化フェノールノボラック樹脂、3官能フェノール、4官能フェノール、ナフタレン型フェノール、ビフェニル型フェノール、フェノールアラルキル樹脂、ビフェニルアラルキル樹脂、ナフトールアラルキル樹脂、ジシクロペンタジエンアラルキル樹脂、脂環式フェノール、リン含有フェノール等の水酸基をシアネート基に置換した構造のものが挙げられる。これらのシアネート化合物(C1)は、単独でまたは2種以上を適宜組み合わせて使用してもよい。また、上記したシアネート化合物(C1)は、モノマー、オリゴマーおよび樹脂のいずれの形態であってもよい。
本発明において用いられるBT樹脂(C2)とは、上記したシアネート化合物(C1)とマレイミド化合物とを、無溶剤で加熱溶融混合するか、または、適当な有機溶剤に溶解させて加熱混合し、ポリマー化したものを意味する。シアネート化合物(C1)とマレイミド化合物とを混合するのに用いられる有機溶剤としては、メチルエチルケトン、Nメチルピロドリン、ジメチルホルムアミド、ジメチルアセトアミド、トルエン、キシレン等が挙げられる。
本発明による樹脂組成物は、さらにマレイミド化合物(D)を含んでいてもよい。マレイミド化合物(D)としては、上記したものを好適に使用することができる。マレイミド化合物(D)の含有量は、吸湿耐熱性の観点から、樹脂の総量に対して、50質量%以下であることが好ましく、より好ましくは40質量%以下である。なお、ここでの樹脂の総量とは、イミダゾール化合物(A)と、エポキシ化合物(B)と、シアネート化合物(C1)またはBT樹脂(C2)と、マレイミド化合物(D)との合計質量をいうものとする。
本発明による樹脂組成物は、加熱することにより硬化する。硬化条件は、樹脂組成物の組成や硬化促進剤であるイミダゾール化合物(A)の配合量などによって変化する。樹脂組成物を完全に硬化させる場合は、通常、100~300℃の範囲で、所定時間の加熱を行う。加圧環境下で加熱してもよく、例えば、0.1~5MPa、好ましくは0.5~3MPaの加圧下で、樹脂組成物を硬化させる。
プリプレグは、上記した樹脂組成物を、基材に含浸または塗布したものである。基材としては、各種プリント配線板材料等に用いられている公知の無機または有機の繊維質補強材を使用することができる。無機繊維質補強材としては、例えば、E、NE、D、S、Tガラス等のガラス繊維、石英ガラス繊維、カーボン繊維、アルミナファイバー、炭化珪素ファイバー、アスベスト、ロックウール、スラグウール、石膏ウィスカーなどの無機繊維や、その繊布もしくは不繊布、またはこれらの混合物が挙げられる。また、有機繊維質補強材としては、例えば、全芳香族ポリアミド繊維、ポリイミド繊維、液晶ポリエステル、ポリエステル繊維、フッ素繊維、ポリベンゾオキサゾール繊維、綿、麻、セミカーボン繊維などの有機繊維や、その繊布もしくは不繊布、またはこれらの混合物が挙げられる。
2,2-ビス(4-シアナトフェニル)プロパン(CA200、三菱ガス化学(株)製)25質量部、およびビス(3-エチル-5-メチル-4-マレイミドフェニル)メタン(BMI-70、ケイアイ化成製)25質量部を混合し、150℃で溶融させて攪拌しながら6時間反応させた後、これをメチルエチルケトンに溶解させることによりBT樹脂を得た。
加熱条件1:製品温度220℃で20分間保持
加熱条件2:製品温度200℃で60分間保持
加熱条件3:製品温度200℃で60分間保持
2,2-ビス(4-シアナトフェニル)プロパン(CA200、三菱ガス化学(株)製)60質量部を150℃で溶融させて攪拌しながら6時間反応させた後、これをメチルエチルケトンに溶解させることによりプレポリマー得た。
実施例1において2,4,5-トリフェニルイミダゾールに代えて2-フェニル,4-メチルイミダゾール(東京化成工業製)を使用した以外は、実施例1と同様にして、絶縁層厚さ0.2mmの銅張積層板を得た。
実施例1において2,4,5-トリフェニルイミダゾールを使用しなかった以外は、実施例1と同様にして、絶縁層厚さ0.2mmの銅張積層板を得た。
実施例2において2,4,5-トリフェニルイミダゾールに代えて2-フェニル,4-メチルイミダゾール(東京化成工業製)を使用した以外は、実施例2と同様にして、絶縁層厚さ0.2mmの銅張積層板を得た。
実施例2において2,4,5-トリフェニルイミダゾールを使用しなかった以外は、実施例2と同様にして、絶縁層厚さ0.2mmの銅張積層板を得た。
上記のようにして得られた各プリプレグおよび積層板について、下記のようにして、プリプレグゲル化時間測定、ガラス転移温度測定、および吸湿耐熱性評価を行った。
(1)プリプレグゲル化時間
プリプレグを40℃の恒温環境下に0,5,10,15および30日放置し、各ゲル化時間を測定した。ゲル化時間の測定は、JIS C6521(多層プリント配線板用プリプレグ試験法)の硬化時間測定に準拠して行った(JIS C6521の5.7参照)。
サイズ10mm×60mmのサンプルを作製し、DMA装置(TA Instrumen2980型)を用いて、昇温10℃/minの条件下でガラス転移温度の測定を行った。測定は、JIS C6481(プリント配線板用銅張積層板試験方法)のDMA法B法に準拠して行った(JIS C6481の5.17.2参照)。
Claims (12)
- 前記式(I)のR1およびR2が、それぞれ独立して、イソプロピル基、t-ブチル基、イソプロピルアルコキシル基、t-ブチルアルコキシル基、フェニル基、またはナフチル基を表す、請求項1に記載の樹脂組成物。
- 前記式(I)のR1およびR2が、いずれもフェニル基である、請求項2に記載の樹脂組成物。
- 前記イミダゾール化合物(A)が、樹脂の総量に対して、0.1~10質量%含まれてなる、請求項1~3のいずれか一項に記載の樹脂組成物。
- 前記エポキシ化合物(B)が、樹脂の総量に対して、25~95質量%含まれてなる、請求項1~4のいずれか一項に記載の樹脂組成物。
- 前記シアネート化合物(C1)が、樹脂の総量に対して、5~75質量%含まれてなる、請求項1~5のいずれか一項に記載の樹脂組成物。
- 前記BT樹脂(C2)が、樹脂の総量に対して、5~75質量%含まれてなる、請求項1~6のいずれか一項に記載の樹脂組成物。
- 請求項1~7のいずれか一項に記載の樹脂組成物を、基材に含浸または塗布してなるプリプレグ。
- 請求項8に記載のプリプレグを積層成形した、積層板。
- 請求項8に記載のプリプレグと金属箔とを積層成形した、金属箔張積層板。
- 請求項1~7のいずれか一項に記載の樹脂組成物を用いた構造材料。
- 請求項1~7のいずれか一項に記載の樹脂組成物を含んでなる注型用樹脂。
Priority Applications (7)
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SG2012078093A SG184967A1 (en) | 2010-04-21 | 2011-04-19 | Heat curable composition |
CN201180020278.XA CN102939316B (zh) | 2010-04-21 | 2011-04-19 | 热固性组合物 |
US13/641,985 US20130101863A1 (en) | 2010-04-21 | 2011-04-19 | Heat curable composition |
EP11772009.4A EP2562196B1 (en) | 2010-04-21 | 2011-04-19 | Thermosetting composition |
JP2012511667A JP6085172B2 (ja) | 2010-04-21 | 2011-04-19 | 熱硬化性組成物 |
KR1020127026948A KR101840486B1 (ko) | 2010-04-21 | 2011-04-19 | 열경화성 조성물 |
HK13109097.8A HK1181796A1 (zh) | 2010-04-21 | 2013-08-05 | 熱固性組合物 |
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JP2010-097778 | 2010-04-21 | ||
JP2010097778 | 2010-04-21 |
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WO2011132674A1 true WO2011132674A1 (ja) | 2011-10-27 |
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PCT/JP2011/059627 WO2011132674A1 (ja) | 2010-04-21 | 2011-04-19 | 熱硬化性組成物 |
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US (1) | US20130101863A1 (ja) |
EP (1) | EP2562196B1 (ja) |
JP (1) | JP6085172B2 (ja) |
KR (1) | KR101840486B1 (ja) |
CN (1) | CN102939316B (ja) |
HK (1) | HK1181796A1 (ja) |
SG (2) | SG10201503091TA (ja) |
TW (1) | TWI573812B (ja) |
WO (1) | WO2011132674A1 (ja) |
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WO2016117554A1 (ja) * | 2015-01-19 | 2016-07-28 | 株式会社巴川製紙所 | 熱硬化性接着剤組成物、熱硬化性接着フィルム、および複合フィルム |
JP2017008204A (ja) * | 2015-06-22 | 2017-01-12 | 味の素株式会社 | 樹脂組成物 |
CN107253259A (zh) * | 2016-11-29 | 2017-10-17 | 上海晋运实业有限公司 | 一种再生纤维板及其制备方法、用途 |
JP2020029566A (ja) * | 2019-11-13 | 2020-02-27 | 味の素株式会社 | 樹脂組成物 |
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TWI573812B (zh) | 2017-03-11 |
CN102939316B (zh) | 2016-04-27 |
CN102939316A (zh) | 2013-02-20 |
SG184967A1 (en) | 2012-11-29 |
SG10201503091TA (en) | 2015-06-29 |
KR20130079339A (ko) | 2013-07-10 |
HK1181796A1 (zh) | 2013-11-15 |
EP2562196A1 (en) | 2013-02-27 |
EP2562196B1 (en) | 2018-02-21 |
JP6085172B2 (ja) | 2017-02-22 |
EP2562196A4 (en) | 2016-09-28 |
KR101840486B1 (ko) | 2018-03-20 |
JPWO2011132674A1 (ja) | 2013-07-18 |
US20130101863A1 (en) | 2013-04-25 |
TW201204760A (en) | 2012-02-01 |
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