WO2011125557A1 - Copper foil for lithium-ion battery collector body - Google Patents
Copper foil for lithium-ion battery collector body Download PDFInfo
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- WO2011125557A1 WO2011125557A1 PCT/JP2011/057440 JP2011057440W WO2011125557A1 WO 2011125557 A1 WO2011125557 A1 WO 2011125557A1 JP 2011057440 W JP2011057440 W JP 2011057440W WO 2011125557 A1 WO2011125557 A1 WO 2011125557A1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/661—Metal or alloys, e.g. alloy coatings
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/70—Carriers or collectors characterised by shape or form
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- An important issue of the copper foil used as the negative electrode current collector is its adhesion to the negative electrode active material.
- a copper foil for a current collector has been made focusing on improving the adhesion.
- a surface treatment for forming irregularities on the surface of the copper foil which is called a roughening treatment
- methods such as blasting, rolling with a rough surface roll, mechanical polishing, electrolytic polishing, chemical polishing and plating of electrodeposited grains are known, and among these, electrodeposited grain plating is particularly preferred. It is used a lot.
- an object of the present invention is to provide a copper foil for a lithium ion battery current collector with high plate thickness accuracy. Moreover, this invention makes it another subject to provide the manufacturing method of such a copper foil.
- the ratio of ⁇ RSm RSm max ⁇ RSm min to the average (RSm avg ) of the surface roughness RSm in the rolling parallel direction ( ⁇ RSm / RSm avg ) Is 0.5 or less.
- the copper foil for a lithium ion battery current collector is for a lithium ion secondary battery negative electrode current collector.
- the surface roughness Ra of the work roll used for the final pass is 0.03 ⁇ m or more in the final cold rolling step, and the surface of the work roll used for one pass immediately before the final pass.
- Roughness Ra is less than 0.03 micrometer
- the copper foil according to the present invention is excellent in plate thickness accuracy, it is possible to suppress an error in the coating amount of the negative electrode active material, so that it is possible to stabilize the battery capacity of a mass-produced lithium ion battery. .
- the thickness of the copper foil is not particularly limited and may be appropriately selected depending on the required characteristics. Generally, the thickness is 1 to 100 ⁇ m, but when used as a current collector for a negative electrode of a lithium ion secondary battery, a battery having a higher capacity can be obtained by thinning the copper foil. From such a viewpoint, it is typically 2 to 50 ⁇ m, more typically about 5 to 20 ⁇ m.
- Ra is a value obtained by folding the roughness curve from the center line and dividing the area obtained by the roughness curve and the center line by the reference length L, and is measured according to JIS B0601: 2001.
- the average (Ra avg ) of the surface roughness Ra is an average of arbitrary 10 points.
- ⁇ Ra is the maximum value Ra max and the minimum value among the measured 10 points Ra. is the difference of the Ra min is.
- the arbitrary 10 points here do not mean 10 points in the vicinity of each measurement point.
- the rolling direction depends on the obtained length.
- 10 points are selected at intervals of at least 150 mm, preferably at intervals of 400 mm, more preferably at intervals of 1 m.
- Ra at each measurement point is given by an average value obtained by measuring the vicinity of the measurement point three times. Each measurement point is Ra in the center in the width direction.
- the measurement interval of 150 mm or more can be secured, the surface roughness of the sheet can be measured. .
- the copper foil according to the present invention is characterized in that the average (Ra avg ) of the surface roughness Ra in the rolling parallel direction satisfies 0.01 to 0.15 ⁇ m.
- the condition of 0.01 ⁇ m ⁇ Ra ⁇ 0.15 ⁇ m is that when Ra is less than 0.01 ⁇ m, the surface is smooth and sufficient adhesion to the negative electrode active material cannot be obtained, while when it exceeds 0.15 ⁇ m This is because, even if the roughness is reduced by rolling before the final pass and the variation in surface roughness is small, the rolling of the final pass varies.
- Ra 0.03 ⁇ m or more is desirable, and 0.03 ⁇ m ⁇ Ra ⁇ 0.1 ⁇ m is a more preferable range from the viewpoint of stably producing appearance quality with few surface defects such as surface scratches.
- ⁇ Ra Ra max ⁇ Ra min satisfies 0.025 ⁇ m or less.
- ⁇ Ra exceeds 0.025 ⁇ m
- ⁇ Ra before the final pass of the final rolling often exceeds 0.25 ⁇ m.
- the surface roughness is large between the surface roughness and the surface roughness is small.
- ⁇ Ra is preferably 0.025 ⁇ m or less, and more preferably 0.020 ⁇ m or less.
- the oil pit is a depression generated when the rolling oil is pushed into the material to be rolled, and the density of the oil pit on the surface varies depending on the thickness of the oil film of the rolling oil. If the density of the oil pits on the surface is different, the thickness of the copper foil required by the gravimetric method is also affected, which causes variation. Therefore, it is desirable that the oil pits are uniformly distributed on the copper foil surface.
- the amount of oil pits generated can be determined using the surface roughness RSm in the rolling parallel direction as an index.
- RSm surface roughness
- RSm max the number of oil pits on the surface
- a smaller ⁇ RSm / RSm avg indicates that the oil pits are uniformly distributed on the copper foil surface.
- the reason for dividing by RSm avg is that the variation in distribution is not necessarily large because ⁇ RSm is large. That is, even with the same ⁇ RSm, if RSm avg is large, the variation in distribution is not large and the influence is small. If RSm avg is small, the distribution is large and the influence is large.
- RSm is an average value of the interval between the peaks and valleys obtained from the intersection where the roughness curve intersects the average line, and is measured in accordance with JIS B0601: 2001.
- the average surface roughness RSm (RSm avg ) is an average of 10 arbitrary points
- ⁇ RSm is the difference between RSm max which is the maximum value and RSm min which is the minimum value among 10 measured Ras. It is.
- the arbitrary 10 points here do not mean 10 points in the vicinity of each measurement point.
- the rolling direction depends on the obtained length. 10 points are selected at intervals of at least 150 mm, preferably at intervals of 400 mm, more preferably at intervals of 1 m.
- RSm at each measurement point is given as an average value obtained by measuring the vicinity of the measurement point three times.
- Each measurement point is RSm at the center in the width direction.
- the proportion of the average value of the larger one of the values of the difference between (t avg), to the average value of the plate thickness (t avg) can be 1.3% or less. This ratio can be preferably 1.2% or less, more preferably 1.1% or less.
- the surface roughness Ra can be controlled by adjusting the surface roughness of the work roll. For example, if a work roll having a large Ra is used, Ra of the rolled copper foil is increased, and conversely, a work having a small Ra is performed. If a roll is used, Ra of the rolled copper foil obtained will also become small.
- the variation value itself increases as the average value increases. The same applies to the variation value of the surface roughness Ra. The larger the average value of the surface roughness Ra, the larger the variation value. Therefore, the average value of the surface roughness Ra is reduced in order to reduce the variation value of the surface roughness Ra. Should be reduced.
- the oil pit distribution uniform In order to reduce the variation in the surface roughness RSm, it is important to make the oil pit distribution uniform. In order to make the oil pit distribution uniform, among other factors, it is important to keep the viscosity of the rolling oil constant during rolling.
- the viscosity of the rolling oil is basically determined by the type of the rolling oil, but the viscosity is lowered by gradually increasing the rolling oil by the processing heat during rolling. As the viscosity of the rolling oil changes, if the degree to which the rolling oil is pushed into the copper foil surface changes, it leads to variations in the oil pit distribution. For example, when the rolling oil is kept at around 25 ° C.
- the viscosity of the rolling oil used was 7.0 cSt (40 ° C.), and in the inventive examples, the temperature of the rolling oil during the final cold rolling was adjusted to be around 40 ° C.
- Various characteristics were evaluated in the same manner as in Example 1. The test results are shown in Table 2.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Cell Electrode Carriers And Collectors (AREA)
- Metal Rolling (AREA)
Abstract
Description
そして、このような表面形態は、電解銅箔(段落0044)、圧延銅箔の表面に電解法により銅を析出させて表面を粗面化すること(段落0045)、及びエメリー紙で研磨処理すること(段落0205)で得られることが記載されている。 In Japanese Patent No. 3733065, a preferable surface property is specifically specified by a roughness parameter, and a current collector and an active material are obtained by using a copper foil having a large surface roughness Ra as a current collector. It is described that the adhesiveness to the surface is improved (paragraph 0209). The surface roughness Ra of the current collector is preferably 0.01 μm or more, more preferably 0.01 to 1 μm, and further preferably 0.05 to 0.5 μm (paragraph 0021 and the like). ). The surface roughness Ra of the current collector and the average interval S between the local peaks are preferably 100Ra ≧ S (paragraph 0022 and the like). The shape of the convex and concave portions on the surface of the current collector is preferably a cone (paragraph 0023 and the like).
Such surface morphology is obtained by electrolytic copper foil (paragraph 0044), precipitation of copper on the surface of the rolled copper foil by an electrolytic method to roughen the surface (paragraph 0045), and polishing with emery paper. (Paragraph 0205).
そこで、例えば、最終冷間圧延の最終パス直前の1パスについてのみ表面粗さの小さいワークロールを用いて表面粗さの小さな、すなわち表面が平滑な銅箔を作り込み、最終パスで表面粗さの大きなワークロールを用いて所望の表面粗さRaを作り込む。
これにより、高い厚み精度を得ながら所望の表面粗さを有し、活物質との密着性の良好な銅箔を得ることができる。すなわち、最終パスの2パス前までは表面粗さRaの粗いロールでよく、最終パス直前の1パスのみ、前パス及び最終パスより小さい粗さのロールを用いる。 However, in each product, since there is a demand for surface roughness required from the viewpoint of adhesion to the negative electrode active material, it is necessary to finally make it to the required value. In cold rolling, the surface roughness should be rough to some extent from the viewpoint of rolling efficiency that the rolling speed can be set high.
Therefore, for example, a copper foil having a small surface roughness, that is, a smooth surface is formed by using a work roll having a small surface roughness for only one pass immediately before the final pass of the final cold rolling, and the surface roughness is obtained in the final pass. The desired surface roughness Ra is made using a large work roll.
Thereby, it is possible to obtain a copper foil having a desired surface roughness and good adhesion to the active material while obtaining high thickness accuracy. That is, a roll having a surface roughness Ra may be used up to two passes before the final pass, and a roll having a smaller roughness than the previous pass and the final pass is used for only one pass immediately before the final pass.
しかしながら、表面粗さRaが0.01μm以下で表面傷等の外観上の問題ないロールを安定的に作製することは、高い技術を要し、コスト的にも割高となる。
したがって、より好ましい範囲は、最終パスにおいて使用するワークロールは表面粗さRaが0.03μm以上であるのが好ましく、ゆえに最終パス直前の1パスに用いられるワークロールの表面粗さRaは、0.03μm未満とすることが望ましい。 In the final pass, a work roll having a surface roughness Ra exceeding 0.01 μm is used so that an average (Ra avg ) of Ra in the rolling parallel direction of the copper foil is 0.01 to 0.15 μm. Therefore, in order to reduce the variation value of the surface roughness, the surface roughness Ra of the work roll used for one pass immediately before the final pass must be smaller than the work roll used for the final pass. Therefore, the surface roughness Ra of the work roll used in one pass immediately before the final pass is desirably 0.01 μm or less.
However, stably producing a roll having a surface roughness Ra of 0.01 μm or less and having no appearance problems such as surface scratches requires high technology and is expensive.
Accordingly, a more preferable range is that the work roll used in the final pass preferably has a surface roughness Ra of 0.03 μm or more. Therefore, the surface roughness Ra of the work roll used in one pass immediately before the final pass is 0. It is desirable to be less than 0.03 μm.
例えば、圧延油は、圧延前の温度調整においては25℃前後に保たれる時、圧延油を圧延中のワークロールに噴射すると加工熱によって上昇したワークロール等からの熱が伝わり、圧延油は40℃くらいまで上昇する。この状態で維持できれば、オイルピットの分布のばらつきは少なく、銅箔形状には問題ない。しかしながら、圧延油の温度制御が十分でなく、圧延油温度が40℃を超えてばらつく場合には、銅箔の表面性状がばらつきやすくなるだけでなく、板形状にも影響を与える。従って、圧延中の圧延油の温度を40℃程度に調整するためには、ロール噴射前の圧延油温度、圧延速度、加工度等を総合的に調整する必要がある。 In order to reduce the variation in the surface roughness RSm, it is important to make the oil pit distribution uniform. In order to make the oil pit distribution uniform, among other factors, it is important to keep the viscosity of the rolling oil constant during rolling. The viscosity of the rolling oil is basically determined by the type of the rolling oil, but the viscosity is lowered by gradually increasing the rolling oil by the processing heat during rolling. As the viscosity of the rolling oil changes, if the degree to which the rolling oil is pushed into the copper foil surface changes, it leads to variations in the oil pit distribution.
For example, when the rolling oil is kept at around 25 ° C. in the temperature adjustment before rolling, when the rolling oil is sprayed onto the work roll being rolled, heat from the work roll and the like that has risen due to the processing heat is transmitted, It rises to about 40 ° C. If maintained in this state, there is little variation in oil pit distribution and there is no problem with the copper foil shape. However, when the temperature control of the rolling oil is not sufficient and the rolling oil temperature varies beyond 40 ° C., not only the surface properties of the copper foil are likely to vary but also the plate shape is affected. Therefore, in order to adjust the temperature of the rolling oil during rolling to about 40 ° C., it is necessary to comprehensively adjust the rolling oil temperature, the rolling speed, the working degree, etc. before roll injection.
[圧延銅箔の製造]
タフピッチ銅のインゴットを熱間圧延した後、焼鈍と冷間圧延を繰り返し、最後に冷間圧延を行って圧延方向長さが10m以上で設定厚み10μmの圧延銅箔(No.1~6)を得た。最終冷間圧延において、最終パス直前の1パスにのみ用いたワークロールの表面粗さ、及び最終パスに用いたワークロール表面粗さを表1に示す。用いた圧延油の粘度は7.0cSt(40℃)であり、最終冷間圧延における圧延油の温度は40℃前後に制御した。ワークロールの表面粗さは、JIS B0601:2001に従い、接触式の表面粗さ計にて測定した。 <Example 1 (effect of variation in surface roughness Ra)>
[Manufacture of rolled copper foil]
After hot rolling a tough pitch copper ingot, annealing and cold rolling are repeated, and finally cold rolling is performed to obtain a rolled copper foil (No. 1 to 6) having a rolling direction length of 10 m or more and a set thickness of 10 μm. Obtained. Table 1 shows the surface roughness of the work roll used for only one pass immediately before the final pass and the work roll surface roughness used for the final pass in the final cold rolling. The viscosity of the rolling oil used was 7.0 cSt (40 ° C.), and the temperature of the rolling oil in the final cold rolling was controlled around 40 ° C. The surface roughness of the work roll was measured with a contact-type surface roughness meter according to JIS B0601: 2001.
圧延銅箔の板厚は、重量法(IPC-TM-650)に準拠して測定した。得られた銅箔から任意の10mの圧延方向長さを選択し、これについて1mおきに板厚を10点測定した。各測定点の板厚Tは3回測定した平均値を取った。10点のTの平均値をTavg、10点のTの最大値をTmax、10点のTの最小値をTminとした。表1には(Tavg-Tmin)/Tavg及び(Tmax-Tavg)/Tavgの大きい方を「板厚ばらつき(%)」として記載した。 [Thickness accuracy evaluation]
The plate thickness of the rolled copper foil was measured according to the weight method (IPC-TM-650). An arbitrary length of 10 m in the rolling direction was selected from the obtained copper foil, and the thickness was measured at 10 points every 1 m. The plate thickness T at each measurement point was an average value measured three times. The average value of T at 10 points was T avg , the maximum value of T at 10 points was T max , and the minimum value of T at 10 points was T min . In Table 1, the larger of (T avg −T min ) / T avg and (T max −T avg ) / T avg is described as “plate thickness variation (%)”.
No.5は最終パス直前の1パスの表面粗さが大きかったため、ΔRaが十分に制御できなかった。No.6は最終パス直前の1パスのワークロールの表面粗さを大きくするかわりに、最終パスのワークロールの表面粗を小さくしたが、依然としてΔRaが十分に制御できなかった。 No. 1-No. No. 4 is an invention example, and the variation of the plate thickness could be suppressed to 1.3% or less.
No. In No. 5, since the surface roughness of one pass immediately before the final pass was large, ΔRa could not be controlled sufficiently. No. In Example 6, instead of increasing the surface roughness of the work roll of one pass immediately before the final pass, the surface roughness of the work roll of the final pass was reduced, but ΔRa could not be sufficiently controlled.
[圧延銅箔の製造]
タフピッチ銅のインゴットを熱間圧延した後、焼鈍と冷間圧延を繰り返し、最後に冷間圧延を行って圧延方向長さが10m以上で設定厚み10μmの圧延銅箔(No.7~12)を得た。最終冷間圧延において、最終パス前まで用いたワークロールの表面粗さRaを0.010μm、及び最終パスに用いたワークロール表面粗さRaを0.050μmとした。用いた圧延油の粘度は7.0cSt(40℃)であり、発明例は、最終冷間圧延中の圧延油の温度を40℃前後となるように調整した。各種特性評価は例1と同様の方法で行った。試験結果を表2に示す。 <Example 2 (effect of oil pit distribution)>
[Manufacture of rolled copper foil]
After hot rolling a tough pitch copper ingot, annealing and cold rolling were repeated, and finally, cold rolling was performed to obtain a rolled copper foil (No. 7 to 12) having a set thickness of 10 μm or more in a rolling direction length of 10 m or more. Obtained. In the final cold rolling, the surface roughness Ra of the work roll used before the final pass was 0.010 μm, and the work roll surface roughness Ra used for the final pass was 0.050 μm. The viscosity of the rolling oil used was 7.0 cSt (40 ° C.), and in the inventive examples, the temperature of the rolling oil during the final cold rolling was adjusted to be around 40 ° C. Various characteristics were evaluated in the same manner as in Example 1. The test results are shown in Table 2.
発明例No.10~12は、最終冷間圧延機中の圧延油の温度の管理以外は発明例No.7~9と同じ条件で実施した。ここでは最終冷間圧延機中の圧延油の温度の管理を十分には行なわなかったため、40℃を超えて45℃程度にまで上昇した。測定では確認できないが局部的には50℃を超える部分もあったと想定される。その結果、オイルピットの分布は均一化することができず、板厚のばらつきが1.2%を超えるケースが見られた。 Invention Example No. In Nos. 7 to 9, since the temperature control of the rolling oil of the final rolling mill was controlled at 40 ° C., the oil pit distribution was uniform, there was little variation, and the plate thickness variation was as small as less than 1.2%.
Invention Example No. Nos. 10 to 12 are invention example Nos. Except for controlling the temperature of the rolling oil in the final cold rolling mill. The test was carried out under the same conditions as in 7-9. Here, since the temperature of the rolling oil in the final cold rolling mill was not sufficiently controlled, the temperature rose from 40 ° C. to about 45 ° C. Although it cannot be confirmed by measurement, it is assumed that there was a part that exceeded 50 ° C locally. As a result, the distribution of oil pits could not be made uniform, and there was a case where the variation in thickness exceeded 1.2%.
Claims (7)
- 圧延平行方向における表面粗さRaの平均(Raavg)が0.01~0.15μmであり、ΔRa=Ramax-Raminが0.025μm以下であることを特徴とするリチウムイオン電池集電体用銅箔。 Lithium ion battery current collector characterized by having an average (Ra avg ) of surface roughness Ra in the rolling parallel direction of 0.01 to 0.15 μm and ΔRa = Ra max −Ra min of 0.025 μm or less Copper foil.
- 銅箔の板厚が5~20μmであることを特徴とする請求項1に記載のリチウムイオン電池集電体用銅箔。 2. The copper foil for a lithium ion battery current collector according to claim 1, wherein the copper foil has a thickness of 5 to 20 μm.
- 銅箔の板厚の最大値(tmax)と板厚の平均値(tavg)との差、又は最小値(tmin)と板厚の平均値(tavg)との差のいずれか大きい方の値の、板厚の平均値(tavg)に対する割合が1.3%以下であることを特徴とする請求項1又は2に記載のリチウムイオン電池集電体用銅箔。 The difference between the maximum value (t max ) of the copper foil thickness and the average value (t avg ) of the plate thickness, or the difference between the minimum value (t min ) and the average value (t avg ) of the plate thickness, whichever is greater 3. The copper foil for a lithium ion battery current collector according to claim 1, wherein a ratio of the first value to the average value (t avg ) of the plate thickness is 1.3% or less.
- 圧延平行方向における表面粗さRSmの平均(RSmavg)に対するΔRSm=RSmmax-RSmminの比(ΔRSm/RSmavg)が0.5以下であることを特徴とする請求項1~3の何れか一項記載のリチウムイオン電池集電体用銅箔。 The ratio (ΔRSm / RSm avg ) of ΔRSm = RSm max -RSm min to the average (RSm avg ) of the surface roughness RSm in the rolling parallel direction is 0.5 or less, or any one of claims 1 to 3 The copper foil for lithium ion battery collectors according to one item.
- リチウムイオン二次電池負極集電体用である請求項1~4何れか一項記載のリチウムイオン電池集電体用銅箔。 The copper foil for a lithium ion battery current collector according to any one of claims 1 to 4, which is used for a negative electrode current collector of a lithium ion secondary battery.
- 請求項1~5何れか一項記載の銅箔を集電体として備えたリチウムイオン電池。 A lithium ion battery comprising the copper foil according to any one of claims 1 to 5 as a current collector.
- 最終冷間圧延工程において、最終パスに用いられるワークロールの表面粗さRaが0.03μm以上であり、最終パス直前の1パスに用いられるワークロールの表面粗さRaが0.03μm未満であることを特徴とするリチウムイオン電池集電体用銅箔の製造方法。 In the final cold rolling step, the surface roughness Ra of the work roll used for the final pass is 0.03 μm or more, and the surface roughness Ra of the work roll used for one pass immediately before the final pass is less than 0.03 μm. The manufacturing method of the copper foil for lithium ion battery collectors characterized by the above-mentioned.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
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KR1020127018875A KR101422376B1 (en) | 2010-03-31 | 2011-03-25 | Copper foil for lithium-ion battery collector body |
CN201180016720.1A CN102812585B (en) | 2010-03-31 | 2011-03-25 | Copper foil for lithium-ion battery collector body |
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JP2010083474A JP5226027B2 (en) | 2010-03-31 | 2010-03-31 | Copper foil for lithium-ion battery current collector |
JP2010-083474 | 2010-03-31 |
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WO2011125557A1 true WO2011125557A1 (en) | 2011-10-13 |
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PCT/JP2011/057440 WO2011125557A1 (en) | 2010-03-31 | 2011-03-25 | Copper foil for lithium-ion battery collector body |
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KR (1) | KR101422376B1 (en) |
CN (1) | CN102812585B (en) |
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EP2822068B1 (en) | 2012-02-28 | 2018-05-23 | UACJ Corporation | Aluminum foil for collectors and method for producing same |
CN106415903B (en) | 2014-06-06 | 2019-10-25 | 株式会社Uacj | The manufacturing method of collector metal foil, collector and collector metal foil |
JP2016036829A (en) * | 2014-08-07 | 2016-03-22 | Jx日鉱日石金属株式会社 | Rolled copper foil, and secondary battery power collector using the same |
JP2019175705A (en) * | 2018-03-28 | 2019-10-10 | Jx金属株式会社 | Rolled copper foil for lithium ion battery current collector and lithium ion battery |
JP2019175802A (en) * | 2018-03-29 | 2019-10-10 | Jx金属株式会社 | Rolled copper foil for lithium ion battery current collector and lithium ion battery |
JP7100560B2 (en) * | 2018-10-29 | 2022-07-13 | Jx金属株式会社 | Lithium-ion battery Rolled copper foil for collector and lithium-ion battery |
JP6726780B1 (en) * | 2019-03-04 | 2020-07-22 | ナミックス株式会社 | Copper foil, negative electrode current collector for lithium ion battery including the same, and method for producing the same |
Citations (4)
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JP2002373644A (en) * | 2001-04-13 | 2002-12-26 | Sanyo Electric Co Ltd | Electrode for lithium secondary battery, and manufacturing method therefor |
JP2003223899A (en) * | 2002-01-31 | 2003-08-08 | Matsushita Electric Ind Co Ltd | Manufacturing method of negative electrode plate and lithium secondary battery using the negative electrode plate |
JP2006202635A (en) * | 2005-01-21 | 2006-08-03 | Furukawa Circuit Foil Kk | Copper foil for lithium secondary battery electrode, manufacturing method of copper foil, electrode for lithium secondary battery using copper foil, and lithium secondary battery |
JP2009215604A (en) * | 2008-03-10 | 2009-09-24 | Hitachi Cable Ltd | Copper foil and manufacturing method thereof |
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US6844113B2 (en) * | 2001-04-13 | 2005-01-18 | Sanyo Electric Co., Ltd. | Electrode for lithium secondary battery and method for producing the same |
WO2008132987A1 (en) * | 2007-04-20 | 2008-11-06 | Nippon Mining & Metals Co., Ltd. | Electrolytic copper foil for lithium rechargeable battery and process for producing the copper foil |
JP5321788B2 (en) * | 2007-05-23 | 2013-10-23 | ソニー株式会社 | Secondary battery current collector, secondary battery negative electrode, secondary battery and electronic device |
JP5252342B2 (en) | 2008-03-11 | 2013-07-31 | 本田技研工業株式会社 | Vehicle inspection device |
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2002373644A (en) * | 2001-04-13 | 2002-12-26 | Sanyo Electric Co Ltd | Electrode for lithium secondary battery, and manufacturing method therefor |
JP2003223899A (en) * | 2002-01-31 | 2003-08-08 | Matsushita Electric Ind Co Ltd | Manufacturing method of negative electrode plate and lithium secondary battery using the negative electrode plate |
JP2006202635A (en) * | 2005-01-21 | 2006-08-03 | Furukawa Circuit Foil Kk | Copper foil for lithium secondary battery electrode, manufacturing method of copper foil, electrode for lithium secondary battery using copper foil, and lithium secondary battery |
JP2009215604A (en) * | 2008-03-10 | 2009-09-24 | Hitachi Cable Ltd | Copper foil and manufacturing method thereof |
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Publication number | Publication date |
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TWI455394B (en) | 2014-10-01 |
KR20120096091A (en) | 2012-08-29 |
KR101422376B1 (en) | 2014-07-22 |
TW201205931A (en) | 2012-02-01 |
JP5226027B2 (en) | 2013-07-03 |
JP2011216336A (en) | 2011-10-27 |
CN102812585A (en) | 2012-12-05 |
CN102812585B (en) | 2015-06-17 |
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