WO2011124189A3 - Method for the production of hydrogen and other products and device for carrying out this method - Google Patents

Method for the production of hydrogen and other products and device for carrying out this method Download PDF

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Publication number
WO2011124189A3
WO2011124189A3 PCT/CZ2011/000030 CZ2011000030W WO2011124189A3 WO 2011124189 A3 WO2011124189 A3 WO 2011124189A3 CZ 2011000030 W CZ2011000030 W CZ 2011000030W WO 2011124189 A3 WO2011124189 A3 WO 2011124189A3
Authority
WO
WIPO (PCT)
Prior art keywords
hydrogen
reactor
reaction
production
products
Prior art date
Application number
PCT/CZ2011/000030
Other languages
French (fr)
Other versions
WO2011124189A2 (en
WO2011124189A4 (en
Inventor
Lukáš MOUREK
Ivan TRÁVNÍČEK
Ladislav BÍLÝ
Original Assignee
Mourek Lukas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mourek Lukas filed Critical Mourek Lukas
Priority to EP11728765A priority Critical patent/EP2556017A2/en
Publication of WO2011124189A2 publication Critical patent/WO2011124189A2/en
Publication of WO2011124189A3 publication Critical patent/WO2011124189A3/en
Publication of WO2011124189A4 publication Critical patent/WO2011124189A4/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/08—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents with metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B01J19/002—Avoiding undesirable reactions or side-effects, e.g. avoiding explosions, or improving the yield by suppressing side-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053—Details of the reactor
    • B01J19/0066—Stirrers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J7/00—Apparatus for generating gases
    • B01J7/02—Apparatus for generating gases by wet methods
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D3/00—Halides of sodium, potassium or alkali metals in general
    • C01D3/04—Chlorides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D3/00—Halides of sodium, potassium or alkali metals in general
    • C01D3/14—Purification
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D3/00—Halides of sodium, potassium or alkali metals in general
    • C01D3/14—Purification
    • C01D3/16—Purification by precipitation or adsorption
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
    • C01F7/42—Preparation of aluminium oxide or hydroxide from metallic aluminium, e.g. by oxidation
    • C01F7/428—Preparation of aluminium oxide or hydroxide from metallic aluminium, e.g. by oxidation by oxidation in an aqueous solution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00004—Scale aspects
    • B01J2219/00006—Large-scale industrial plants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094—Jackets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00162—Controlling or regulating processes controlling the pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00245—Avoiding undesirable reactions or side-effects
    • B01J2219/00259—Preventing runaway of the chemical reaction
    • B01J2219/00263—Preventing explosion of the chemical mixture
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00245—Avoiding undesirable reactions or side-effects
    • B01J2219/0027—Pressure relief
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

Hydrogen is produced from waste aluminium by its reaction with water in the presence of sodium hydroxide as a catalyst. In addition to hydrogen, products of the reaction are also aluminium hydroxide, sodium chloride, heat and potentially electric energy. The reaction occurs in the reactor (1), and hydrogen is collected in a low-pressure hydrogen tank (3). The substance of hydrogen production, according to the invention, is that gas is successively removed from the reactor (1) and/or other accessory devices with the use of a vacuum pump (4) at a minimum pressure of 0.5 kPa before the reaction, then the reactor is filled with hydrogen of a minimum purity of 99.5%, the gas is pumped away again with a subsequent filling with hydrogen of a minimum purity of 99.5% again to a positive pressure of at least 0.1 MPa. Gas removed from the reactor and/or accessory equipment with the use of the vacuum pump (4) is exhausted to a chimney (5) and dispersed into the atmosphere. The subject of the invention is a method and device for 'the safe production of hydrogen at an industrial level and' other products as well as their purification for suitable industrial application as raw materials for other industrial production.
PCT/CZ2011/000030 2010-04-07 2011-04-06 Method for the production of hydrogen and other products and device for carrying out this method WO2011124189A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP11728765A EP2556017A2 (en) 2010-04-07 2011-04-06 Method for the production of hydrogen and other products and device for carrying out this method

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CZ20100268A CZ302453B6 (en) 2010-04-07 2010-04-07 Process for preparing hydrogen and other products and apparatus for making the same
CZPV2010-268 2010-04-07

Publications (3)

Publication Number Publication Date
WO2011124189A2 WO2011124189A2 (en) 2011-10-13
WO2011124189A3 true WO2011124189A3 (en) 2012-02-23
WO2011124189A4 WO2011124189A4 (en) 2012-04-19

Family

ID=44041778

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CZ2011/000030 WO2011124189A2 (en) 2010-04-07 2011-04-06 Method for the production of hydrogen and other products and device for carrying out this method

Country Status (3)

Country Link
EP (1) EP2556017A2 (en)
CZ (1) CZ302453B6 (en)
WO (1) WO2011124189A2 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013150527A1 (en) * 2012-04-05 2013-10-10 H Force Ltd A system and method for efficient production of hydrogen
WO2014062833A1 (en) * 2012-10-16 2014-04-24 Helton Bill W Hydrogen production catalysts and associated systems and methods
CZ305018B6 (en) 2013-09-30 2015-03-25 Mourek Lukáš Waste aluminium recycling process and apparatus for making the same
WO2015089778A1 (en) * 2013-12-19 2015-06-25 Honeywell International Inc. Heat dissipation material and method of making the same
CN104192796B (en) * 2014-09-04 2016-01-27 桂林浩新科技服务有限公司 A kind of from stirring device for producing hydrogen
RU173853U1 (en) * 2016-10-28 2017-09-14 Общество с ограниченной ответственностью "Технологии алюмоэнергетики" (ООО "Технологии алюмоэнергетики") HIGH PURITY ALUMINUM OXIDES PLANT
JP7056372B2 (en) * 2018-05-22 2022-04-19 Ｊｆｅエンジニアリング株式会社 Hydrogen production method and hydrogen production equipment
FR3103482B1 (en) * 2019-11-25 2022-07-22 Nebula Tech Process and installation for producing aluminum hydroxide
CN115259187B (en) * 2022-07-25 2024-01-16 河津市炬华铝业有限公司 High specific surface area macroporous pseudo-boehmite powder and preparation method thereof
GB202213860D0 (en) * 2022-09-22 2022-11-09 Net Zero Scient Ltd Hydrogen production process

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0530598A1 (en) * 1991-09-04 1993-03-10 Deutsche Solvay-Werke Gesellschaft mit beschränkter Haftung Process of preparation of basic aluminium chloride and/or bromide
US5286473A (en) * 1993-02-01 1994-02-15 Nobuyasu Hasebe Process for the production of hydrogen
US6506360B1 (en) * 1999-07-28 2003-01-14 Erling Reidar Andersen Method for producing hydrogen
WO2008114951A1 (en) * 2007-03-20 2008-09-25 Jung-Tae Park Apparatus for generating hydrogen gas using composition for generating hydrogen gas and composition for generating hydrogen gas
WO2009018468A1 (en) * 2007-07-31 2009-02-05 Purdue Research Foundation Control system for an on-demand gas generator
US20100061923A1 (en) * 2008-09-05 2010-03-11 Reddy Alla V K Hydrogen production and use

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DE3401194A1 (en) 1984-01-14 1985-07-18 Werner 7433 Dettingen Schweikert Apparatus for exploiting the energy from various metal wastes in connection with sodium hydroxide
JPH01208301A (en) * 1988-02-15 1989-08-22 Mitsubishi Heavy Ind Ltd Generating method of hydrogen
JP2003226502A (en) * 2002-02-06 2003-08-12 Mitsubishi Heavy Ind Ltd Hydrogen production apparatus and method
CN100563820C (en) 2006-04-29 2009-12-02 刘欣 A kind of catalyst with aluminium displacing hydrogen from water
AT504050A1 (en) 2006-08-07 2008-02-15 Alvatec Alkali Vacuum Technolo HYDROGEN GENERATOR
RU2356830C2 (en) 2007-06-26 2009-05-27 ОАО Научно-производственное предприятие "Квант" Method of obtaining hydrogen
CN101284647B (en) * 2008-02-29 2011-05-11 邓振炎 Hydrogen preparing process by reacting surface-modified pure alminuim powder with water
CN101284646B (en) * 2008-02-29 2011-07-20 上海大学 Hydrogen preparing process by reacting pure alminuim powder with water

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0530598A1 (en) * 1991-09-04 1993-03-10 Deutsche Solvay-Werke Gesellschaft mit beschränkter Haftung Process of preparation of basic aluminium chloride and/or bromide
US5286473A (en) * 1993-02-01 1994-02-15 Nobuyasu Hasebe Process for the production of hydrogen
US6506360B1 (en) * 1999-07-28 2003-01-14 Erling Reidar Andersen Method for producing hydrogen
WO2008114951A1 (en) * 2007-03-20 2008-09-25 Jung-Tae Park Apparatus for generating hydrogen gas using composition for generating hydrogen gas and composition for generating hydrogen gas
WO2009018468A1 (en) * 2007-07-31 2009-02-05 Purdue Research Foundation Control system for an on-demand gas generator
US20100061923A1 (en) * 2008-09-05 2010-03-11 Reddy Alla V K Hydrogen production and use

Non-Patent Citations (4)

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Title
"Alumina Chemicals, Science and Technology Handbook", 1990, THE AMERICAN CERAMIC SOCIETY, INC., ISBN: 0-916094-33-2, article LARRY L. MUSSELMAN: "III Production Processes, Properties, and Applications for Aluminium-Containing Hydroxides", pages: 75 - 92, XP002666075 *
K. H. GAYER, L. C. THOMPSON, O. T. ZAJICEK: "THE SOLUBILITY OF ALUMINUM HYDROXIDE IN ACIDIC AND BASIC MEDIA AT 25 °C", CANADIAN JOURNAL OF CHEMISTRY, 1958, pages 1268 - 1271, XP002666077, Retrieved from the Internet <URL:http://www.nrcresearchpress.com/action/doSearch?sortBy=&startPage=0&pageSize=20&searchText=&title=&author=gayer&abstract=&stemming=yes&publication=40000018&startEarliestMonth=&startEarliestYear=1958&endEarliestMonth=&endEarliestYear=1958> [retrieved on 20111219], DOI: 10.1139/v58-184 *
STOCKBURGER D ET AL: "ON-LINE HYDROGEN GENERATION FROM ALUMINUM IN AN ALKALINE SOLUTION", PROCEEDINGS OF THE ELECTROCHEMICAL SOCIETY, NEW YORK,NY, US, vol. 92-5, 1 January 1991 (1991-01-01), pages 431 - 444, XP001032928 *
W. BLUM: "The Determination of Aluminium as Oxide", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, July 1916 (1916-07-01), pages 1282 - 1297, XP002666076, Retrieved from the Internet <URL:http://pubs.acs.org/doi/abs/10.1021/ja02264a006> [retrieved on 20111219], DOI: 10.1021/ja02264a006 *

Also Published As

Publication number Publication date
CZ2010268A3 (en) 2011-05-25
WO2011124189A2 (en) 2011-10-13
CZ302453B6 (en) 2011-05-25
EP2556017A2 (en) 2013-02-13
WO2011124189A4 (en) 2012-04-19

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