WO2011106277A3 - Procédé d'hydrotraitement - Google Patents

Procédé d'hydrotraitement Download PDF

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Publication number
WO2011106277A3
WO2011106277A3 PCT/US2011/025597 US2011025597W WO2011106277A3 WO 2011106277 A3 WO2011106277 A3 WO 2011106277A3 US 2011025597 W US2011025597 W US 2011025597W WO 2011106277 A3 WO2011106277 A3 WO 2011106277A3
Authority
WO
WIPO (PCT)
Prior art keywords
starting
hydrotreating process
hydrotreating
fresh
feed
Prior art date
Application number
PCT/US2011/025597
Other languages
English (en)
Other versions
WO2011106277A2 (fr
Inventor
Gabor Kiss
Iulian Nistor
John Zengel
Sabato Miseo
Roman Krycak
Teh C. Ho
Original Assignee
Exxonmobil Research And Engineering Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Research And Engineering Company filed Critical Exxonmobil Research And Engineering Company
Priority to AU2011221206A priority Critical patent/AU2011221206A1/en
Priority to SG2012058509A priority patent/SG183214A1/en
Priority to EP11706433A priority patent/EP2539421A2/fr
Priority to CA2790621A priority patent/CA2790621A1/fr
Priority to US13/575,849 priority patent/US8864980B2/en
Publication of WO2011106277A2 publication Critical patent/WO2011106277A2/fr
Publication of WO2011106277A3 publication Critical patent/WO2011106277A3/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/24—Starting-up hydrotreatment operations
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/50—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
    • B01J38/56—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1048—Middle distillates
    • C10G2300/1055—Diesel having a boiling range of about 230 - 330 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1096—Aromatics or polyaromatics
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006—Temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4012—Pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

L'invention porte sur un procédé pour l'hydrotraitement d'une première charge d'hydrocarbures contenant des composés aromatiques et du soufre à l'aide d'un catalyseur à base de CoMo supporté frais, consistant à traiter le catalyseur frais dans des premières conditions d'hydrotraitement avec une seconde charge d'hydrocarbures ayant une plus faible teneur en composés aromatiques que la première charge.
PCT/US2011/025597 2010-02-23 2011-02-21 Procédé d'hydrotraitement WO2011106277A2 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
AU2011221206A AU2011221206A1 (en) 2010-02-23 2011-02-21 Hydrotreating process
SG2012058509A SG183214A1 (en) 2010-02-23 2011-02-21 Hydrotreating process
EP11706433A EP2539421A2 (fr) 2010-02-23 2011-02-21 Procédé d'hydrotraitement
CA2790621A CA2790621A1 (fr) 2010-02-23 2011-02-21 Procede d'hydrotraitement
US13/575,849 US8864980B2 (en) 2010-02-23 2011-02-21 Hydrotreating process

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/660,249 2010-02-23
US12/660,249 US8747659B2 (en) 2010-02-23 2010-02-23 Hydrotreating process

Publications (2)

Publication Number Publication Date
WO2011106277A2 WO2011106277A2 (fr) 2011-09-01
WO2011106277A3 true WO2011106277A3 (fr) 2013-04-11

Family

ID=44317640

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2011/025597 WO2011106277A2 (fr) 2010-02-23 2011-02-21 Procédé d'hydrotraitement

Country Status (6)

Country Link
US (2) US8747659B2 (fr)
EP (2) EP2539421A2 (fr)
AU (1) AU2011221206A1 (fr)
CA (1) CA2790621A1 (fr)
SG (1) SG183214A1 (fr)
WO (1) WO2011106277A2 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11788017B2 (en) 2017-02-12 2023-10-17 Magëmã Technology LLC Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil
US12025435B2 (en) 2017-02-12 2024-07-02 Magēmã Technology LLC Multi-stage device and process for production of a low sulfur heavy marine fuel oil
US10655074B2 (en) 2017-02-12 2020-05-19 Mag{hacek over (e)}m{hacek over (a)} Technology LLC Multi-stage process and device for reducing environmental contaminates in heavy marine fuel oil
US10604709B2 (en) 2017-02-12 2020-03-31 Magēmā Technology LLC Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials
CN107999148B (zh) * 2017-10-10 2020-11-06 浙江海洋大学 一种水溶液体系脱硫催化剂的复活方法
US11590485B2 (en) 2021-01-13 2023-02-28 Saudi Arabian Oil Company Process for modifying a hydroprocessing catalyst

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3308054A (en) * 1964-04-06 1967-03-07 Union Oil Co Hydrocracking process startup
US3368965A (en) * 1965-08-04 1968-02-13 Hydrocarbon Research Inc Two stage slurrying
US3423307A (en) * 1965-11-12 1969-01-21 Gulf Research Development Co Start-up of a hydrodesulfurization reaction
US3654138A (en) * 1970-06-17 1972-04-04 Standard Oil Co Method of starting up a hydrocracking process
US4098721A (en) * 1974-12-27 1978-07-04 Texaco Inc. Treatment of desulfurization catalyst and its use
US4149965A (en) * 1978-06-27 1979-04-17 Exxon Research & Engineering Co. Method for starting-up a naphtha hydrorefining process
EP0189632A1 (fr) * 1984-12-28 1986-08-06 Exxon Research And Engineering Company Catalyseurs de sulfure de molybdène ou de tungstène sur support avec promoteur de sulfure de métal de transition et leur utilisation pour un procédé d'hydrotraitement
WO1998038265A1 (fr) * 1997-02-28 1998-09-03 Exxon Research And Engineering Company Procede de desulfuration permettant d'eliminer des heterocycles d'organosulfures refractaires de flux de petrole

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3436338A (en) * 1965-12-23 1969-04-01 Texaco Inc Hydroconversion of hydrocarbons
US4663023A (en) 1984-04-02 1987-05-05 Exxon Research And Engineering Company Hydrotreating with self-promoted molybdenum and tungsten sulfide catalyst
US4973397A (en) * 1988-07-05 1990-11-27 Exxon Research And Engineering Company Hydrotreating process with mixed catalysts
US5034116A (en) * 1990-08-15 1991-07-23 Conoco Inc. Process for reducing the coarse-grain CTE of premium coke
US5212128A (en) * 1991-11-29 1993-05-18 Exxon Research & Engineering Company Method for recovering or maintaining the activity of hydroisomerization catalysts

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3308054A (en) * 1964-04-06 1967-03-07 Union Oil Co Hydrocracking process startup
US3368965A (en) * 1965-08-04 1968-02-13 Hydrocarbon Research Inc Two stage slurrying
US3423307A (en) * 1965-11-12 1969-01-21 Gulf Research Development Co Start-up of a hydrodesulfurization reaction
US3654138A (en) * 1970-06-17 1972-04-04 Standard Oil Co Method of starting up a hydrocracking process
US4098721A (en) * 1974-12-27 1978-07-04 Texaco Inc. Treatment of desulfurization catalyst and its use
US4149965A (en) * 1978-06-27 1979-04-17 Exxon Research & Engineering Co. Method for starting-up a naphtha hydrorefining process
EP0189632A1 (fr) * 1984-12-28 1986-08-06 Exxon Research And Engineering Company Catalyseurs de sulfure de molybdène ou de tungstène sur support avec promoteur de sulfure de métal de transition et leur utilisation pour un procédé d'hydrotraitement
WO1998038265A1 (fr) * 1997-02-28 1998-09-03 Exxon Research And Engineering Company Procede de desulfuration permettant d'eliminer des heterocycles d'organosulfures refractaires de flux de petrole

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2539421A2 *

Also Published As

Publication number Publication date
EP2835412A1 (fr) 2015-02-11
US8747659B2 (en) 2014-06-10
EP2539421A2 (fr) 2013-01-02
WO2011106277A2 (fr) 2011-09-01
AU2011221206A1 (en) 2012-09-13
US20130006029A1 (en) 2013-01-03
US20110203971A1 (en) 2011-08-25
US8864980B2 (en) 2014-10-21
CA2790621A1 (fr) 2011-09-01
SG183214A1 (en) 2012-09-27

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