WO2011074282A1 - Composition d'agent de nettoyage et procédé de stabilisation de diméthylpolysiloxane - Google Patents

Composition d'agent de nettoyage et procédé de stabilisation de diméthylpolysiloxane Download PDF

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Publication number
WO2011074282A1
WO2011074282A1 PCT/JP2010/062370 JP2010062370W WO2011074282A1 WO 2011074282 A1 WO2011074282 A1 WO 2011074282A1 JP 2010062370 W JP2010062370 W JP 2010062370W WO 2011074282 A1 WO2011074282 A1 WO 2011074282A1
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Prior art keywords
component
mass
dimethylpolysiloxane
examples
stability
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PCT/JP2010/062370
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English (en)
Japanese (ja)
Inventor
傑 矢野
律子 宮川
利之 柏井
澄 金田
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ライオン株式会社
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Priority to JP2011545998A priority Critical patent/JP5632392B2/ja
Priority to CN201080057711.2A priority patent/CN102665662B/zh
Priority to KR1020127018842A priority patent/KR101673646B1/ko
Publication of WO2011074282A1 publication Critical patent/WO2011074282A1/fr
Priority to HK13101433.8A priority patent/HK1173981A1/xx

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55—Phosphorus compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0094—High foaming compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/361—Phosphonates, phosphinates or phosphonites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3723—Polyamines or polyalkyleneimines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones

Definitions

  • the present invention relates to a detergent composition that has good foaming and can provide smoothness when finished, and a method for stabilizing dimethylpolysiloxane that can improve the stability of dimethylpolysiloxane.
  • cationic polymers and silicone emulsions may be blended as finished components.
  • silicone since silicone is hydrophobic, it has a problem in that it does not interact with a hydrophilic preparation and it is difficult to maintain stability over time.
  • an anionic surfactant, an amphoteric surfactant, a dimethyldiallylammonium salt / acrylamide copolymer, and ammonium sulfate are added to a hair cleansing composition containing highly polymerized dimethylpolysiloxane.
  • a hair cleaning composition having a dispersion stability of dimethylpolysiloxane and a high-temperature storage stability has been proposed ( Patent Document 1).
  • liquid detergent composition in which a silicone derivative and isoprenglycol or ethanol are dispersed at a specific content ratio in a high concentration aqueous anionic surfactant solution (Patent Document 2). reference).
  • the dimethylpolysiloxane has excellent separation stability, has good foaming, and can provide smoothness when finished, and the stability of dimethylpolysiloxane can improve the stability of dimethylpolysiloxane.
  • the present invention provides a detergent composition that is excellent in separation stability of dimethylpolysiloxane, has good foaming, and can impart smoothness when finished, and dimethylpolysiloxane that can improve the stability of dimethylpolysiloxane. It aims at providing the stabilization method of polysiloxane.
  • This invention is based on the said knowledge by this inventor, and as a means for solving the said subject, it is as follows. That is, ⁇ 1> (A) at least one of a phosphate ester and a salt thereof, (B) dimethylpolysiloxane, (C) a cationic polymer, (D) an anionic surfactant other than the component (A),
  • the component (A) has an HLB of 8 to 17, the component (B) has a kinematic viscosity at 25 ° C. of at least 4 million mm 2 / s, and the content of the component (C) is
  • the cleaning composition is 0.01% by mass to 1.2% by mass, and the content of the component (D) is 1% by mass to 30% by mass.
  • ⁇ 2> The cleaning composition according to ⁇ 1>, wherein the content of the component (A) is 0.3% by mass to 3% by mass.
  • ⁇ 3> The cleaning composition according to any one of ⁇ 1> to ⁇ 2>, wherein the kinematic viscosity of the component (B) is 4 million mm 2 / s to 30 million mm 2 / s.
  • ⁇ 4> The cleaning composition according to any one of ⁇ 1> to ⁇ 3>, wherein the content of the component (B) is 0.01% by mass to 2% by mass.
  • ⁇ 6> The cleaning composition according to any one of ⁇ 1> to ⁇ 5>, wherein the component (C) is at least one of dimethyldiallylammonium chloride / acrylamide copolymer and cationized cellulose.
  • ⁇ 7> The cleaning composition according to ⁇ 6>, wherein the component (C) is a dimethyldiallylammonium chloride / acrylamide copolymer.
  • ⁇ 8> The cleaning composition according to any one of ⁇ 6> to ⁇ 7>, wherein the component (C) is a dispersion of a dimethyldiallylammonium / acrylamide copolymer and ammonium sulfate.
  • the component (C) is a dispersion of a dimethyldiallylammonium / acrylamide copolymer and ammonium sulfate.
  • the component (B) is at least 4 million mm 2 / s.
  • the content of the component (C) is 0.01% by mass to 1.2% by mass
  • the content of the component (D) is 1% by mass to 30% by mass
  • the component (B) is stable.
  • This is a method for stabilizing dimethylpolysiloxane, characterized in that ⁇ 10>
  • the component (E) is at least one of (E-1) polyoxyethylene hydrogenated castor oil and fatty acid polyoxyethylene glyceryl, and (E-2) polyoxyethylene represented by the following general formula (1)
  • R 1 CO—NH—CH 2 CH 2 O (CH 2 CH 2 O) n H:
  • R 1 represents an alkyl group having 7 to 23 carbon atoms, and n represents an integer of 1 to 20.
  • n represents an integer of 1 to 20.
  • the dimethyl according to ⁇ 10>, wherein the mass ratio of the component (E-1) to the component (E-2) is (E-1) / (E-2) 0.1-3. This is a method for stabilizing polysiloxane.
  • the conventional problems can be solved, the object can be achieved, the dimethylpolysiloxane has excellent separation stability, good foaming, and smoothness can be imparted when finished.
  • An agent composition and a method for stabilizing dimethylpolysiloxane that can improve the stability of dimethylpolysiloxane can be provided.
  • the cleaning composition of the present invention comprises at least (A) at least one of a phosphate ester and a salt thereof, (B) dimethylpolysiloxane, (C) a cationic polymer, and (D) other than the component (A).
  • the method for stabilizing dimethylpolysiloxane of the present invention comprises at least (A) at least one of a phosphate ester and a salt thereof, (B) dimethylpolysiloxane, (C) a cationic polymer, and (D) the above (A).
  • An anionic surfactant other than the components and (E) a nonionic surfactant are mixed at least, and other components are further mixed as necessary.
  • the component (B) in the cleaning composition can be preferably stabilized by the method for stabilizing the dimethylpolysiloxane.
  • the method for stabilizing the dimethylpolysiloxane will be described together with the description of the cleaning composition.
  • ⁇ (A) component Phosphate ester and its salt> At least one of the phosphoric acid ester and salt thereof as the component (A) may be a mono-form, a di-form, a tri-form, or a mixture thereof. Also good.
  • the component (A) is not particularly limited and may be appropriately selected depending on the intended purpose.
  • Examples thereof include monoalkyl (C12-18) phosphate ester, dialkyl (C12-18) phosphate ester, trialkyl ( C12-18) phosphate ester, monoalkyl (C12-18) phosphate ester salt, dialkyl (C12-18) phosphate ester salt, trialkyl (C12-18) phosphate ester salt, monopolyoxyethylene alkyl (C12- 18) Ether phosphate ester, dipolyoxyethylene alkyl (C12-18) ether phosphate ester, tripolyoxyethylene alkyl (C12-18) ether phosphate ester, monopolyoxyethylene alkyl (C12-18) ether phosphate ester salt , Dipolyoxyethylene alkyl (C12 18) ether phosphate salt, such as tripolyphosphate polyoxyethylene alkyl (C12 ⁇ 18) ether phosphate salts. These may be used alone or in combination of two or more. Among these, the component (A) is preferably polyoxy
  • polyoxyethylene alkyl (C12-18) ether phosphate ester and the polyoxyethylene alkyl (C12-18) ether phosphate ester salt examples thereof include di-POE (10 ) Sodium lauryl ether phosphate (NIKKOL DLP-10, HLB 17.0), diPOE (8) sodium oleyl ether phosphate (NIKKOL DOP-8NV, HLB 12.5), diPOE (4) alkyl (C12-15) ) Ether phosphoric acid (NIKKOL DDP-4, HLB 9.0), di-POE (6) alkyl (C12-15) Ether phosphoric acid (NIKKOL DDP-6, HLB 9.0), di-POE (8) alkyl (C12-15) ) Ether phosphoric acid (NIKKOL DDP-8, HLB) 1.5), di-POE (10) alkyl (C12-15) ether phosphate (NIKKOL DDP-10, HLB 13.5), tri-POE (4) lauryl
  • the HLB of the component (A) is not particularly limited as long as it is 8 to 17, and can be appropriately selected according to the purpose. However, 10 to 14 is that the three-dimensional structure of the triphosphate is bulky. Therefore, it is preferable in that it is more effective in the separation stability of the component (B). If the HLB is less than 8, the separation stability and foaming of the component (B) may be reduced, and if it exceeds 17, the separation stability of the component (B) may be reduced.
  • triphosphates having an HLB of 10 to 14 can be used as the triphosphates having an HLB of 10 to 14, and specific examples thereof include tri-POE (5) cetyl ether phosphate (NIKKOL TCP-5, HLB 10.0), tri POE (8) (C12-15) alkyl ether phosphate (NIKKOL TDP-8, HLB 11.5), tri-POE (4) lauryl ether phosphate (NIKKOL TLP-4, HLB 13.0), tri-POE (10) alkyl (C12-15) Ether phosphoric acid (NIKKOL TDP-10, HLB 14.0) (all manufactured by Nikko Chemicals Co., Ltd.) and the like.
  • tri-POE (5) cetyl ether phosphate NIKKOL TCP-5, HLB 10.0
  • tri POE (8) (C12-15) alkyl ether phosphate NIKKOL TDP-8, HLB 11.5)
  • tri-POE (4) lauryl ether phosphate NIKKOL TLP-4
  • the HLB value is a value indicating the balance of strength between the hydrophilic group constituting the surfactant and the hydrophobic group. Generally, 1 to 8 is hydrophobic, and more than 8 and less than 10 is hydrophilic. It is an intermediate property to hydrophobicity, and 10 or more shows hydrophilicity, but may differ depending on the structure of the surfactant.
  • the HLB measurement method is as follows. The HLB value by the emulsification method described in “Handbook -Cosmetics / Formulation Raw Materials—Revised Edition”, Nikko Chemicals Co., Ltd., published February 1, 1977, page 854-855. It conforms to the actual measurement.
  • the component (A) is combined with sorbitan monostearate (NIKKOL SS-10, HLB 4.7) as a standard substance for an emulsifier.
  • NIKKOL SS-10, HLB 4.7 sorbitan monostearate
  • the total amount of seed emulsifier is constant, and only the ratio is changed to emulsify liquid paraffin (HLB10.1) to be emulsified, and after standing overnight, it is stable in terms of creaming amount, white turbidity, lower layer water separation, etc.
  • the ratio of the optimal emulsifier is calculated
  • y (x ⁇ used amount (mass%) + z ⁇ used amount (mass%)) / 100
  • x represents the HLB value of the component (A)
  • y represents the HLB value of liquid paraffin
  • z represents sorbitan monostearate (NIKKOL SS). This shows the HLB value of -10).
  • the HLB value of the liquid paraffin was determined in the same manner by combining sorbitan monostearate (NIKKOL SS-10, HLB4.7) and POE sorbitan monostearate (NIKKOL TS-10, HLB14.9). Can be sought.
  • the content of the component (A) in the cleaning composition is not particularly limited and may be appropriately selected depending on the intended purpose, but is preferably 0.3% by mass to 3% by mass, and is suitable for foaming and finishing. From the viewpoint of smoothness and separation stability of the component (B), 0.5% by mass to 2% by mass is more preferable.
  • 0.3% by mass the effect of improving the separation stability of the component (B) may be insufficient, and foaming and smoothness at the finish may be reduced.
  • foaming and smoothness at the time of finishing may decrease.
  • ⁇ (B) component dimethylpolysiloxane>
  • the dimethylpolysiloxane as the component (B) is used for the purpose of imparting smoothness when finished.
  • the component (B) has a kinematic viscosity at 25 ° C. of at least 4 million mm 2 / s, but is preferably 10 million mm 2 / s or more in terms of smoothness at the finish.
  • the smoothness at the finish may be lowered.
  • the component (B) component may be an oil or an emulsion.
  • the emulsifier and the emulsification method in emulsification are not particularly limited and may be appropriately selected depending on the purpose.
  • the method for measuring the kinematic viscosity of the component (B) is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include a method obtained by the following formulas (2) to (5). That is, a toluene solution of the component (B) having a concentration of 1 g / 100 mL is prepared, and the specific viscosity ⁇ sp (25 ° C.) is obtained by the following formula (2). Next, the intrinsic viscosity [ ⁇ ] is obtained by substituting it into the Huggins relational expression shown in the following formula (3). As the Huggins constant, the one described in Nakamuta, Nikka, 77, 588, [1956] is used. Next, [ ⁇ ] is represented by A.
  • the molecular weight M is determined.
  • M is an A.I. J. et al.
  • the kinematic viscosity ⁇ of dimethylpolysiloxane can be determined.
  • ⁇ 0 represents the viscosity of toluene
  • ⁇ represents the viscosity of the solution
  • K ′ represents the Huggins constant
  • M represents the molecular weight.
  • the “ ⁇ 0” and the “ ⁇ ” are measured in accordance with the cosmetic raw material standard general test method viscosity measurement method No. 1.
  • the content of the component (B) in the cleaning composition is not particularly limited and may be appropriately selected depending on the intended purpose, but is preferably 0.01% by mass to 2% by mass, and 0.05% by mass. % To 1.5% by mass is more preferable.
  • the content of the component (B) is less than 0.01% by mass, the effect of improving the smoothness at the finish may be insufficient.
  • the content exceeds 2% by mass foaming or the (B ) Separation stability of components may be reduced.
  • the component (B) may be used in combination with other silicone compounds.
  • other silicone compounds There is no restriction
  • the content of the other silicone compound is not particularly limited as long as the effects of the present invention are not impaired, and can be appropriately selected according to the purpose.
  • the cationic polymer as the component (C) may be a homopolymer or a copolymer.
  • the cationic polymer as the component (C) component may be a homopolymer or a copolymer.
  • the cationized cellulose which added the cationic functional group to the cellulose Guar gum derivative which added the cationic functional group to the guar gum
  • a copolymer composed of repeating units having a cationic functional group-containing dimethyldiallylammonium chloride salt and acrylamide or methacrylamide as monomers hereinafter sometimes referred to as “dimethyldiallylammonium salt / acrylamide copolymer”).
  • dimethyldiallylammonium salt / acrylamide copolymer a copolymer composed of repeating units having a cationic functional group-containing dimethyldiallylammonium chloride salt and acrylamide or methacrylamide as monomers (hereinafter sometimes referred to as “dimethyldiallylammoni
  • the cationic polymer is preferably cationized cellulose, cationized guar gum, dimethyldiallylammonium chloride-acrylamide copolymer (CTFA), and dimethyldiallylammonium chloride-acrylamide copolymer is separated. More preferable from the viewpoint of stability.
  • the cationic polymer is cationized cellulose
  • the cationized cellulose is polyquaternium-10, which is O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride. From this point, it is more preferable.
  • the cationic polymer is the dimethyldiallylammonium chloride / acrylamide copolymer
  • a binary copolymer of dimethyldiallylammonium chloride and acrylamide or methacrylamide is more preferable, but dimethyldiallylammonium chloride and acrylamide or As long as the methacrylamide monomer is contained in an amount of 70% by mass or more based on the total monomer amount, another monomer may be included in the structural unit.
  • the molar ratio of the dimethyldiallylammonium salt to acrylamide or methacrylamide in the dimethyldiallylammonium salt / acrylamide copolymer is not particularly limited and may be appropriately selected depending on the intended purpose. 40:60 is preferable, and 15:85 to 35:65 is more preferable.
  • the weight average molecular weight of the cationic polymer is not particularly limited and may be appropriately selected depending on the intended purpose, but is preferably 100,000 to 3,000,000, more preferably 300,000 to 2,000,000.
  • the weight average molecular weight of the cationic polymer is less than 100,000, the smoothness at the time of finishing may decrease, or the separation stability of the component (B) may decrease. While the separation stability of the component (B) is lowered, it may be difficult to dissolve in the cleaning composition.
  • the weight average molecular weight can be measured using a gel permeation chromatograph / multi-angle laser light scattering detector (GPC-MALLS), and the conditions are as follows. -Measurement condition- Mobile phase: 0.3 M NaClO 4 , NaN 3 aqueous solution Column: TSKgel ⁇ -M 2 pieces, Precolumn: TSK guard column ⁇ Reference material: Polyethylene glycol
  • the component (C) may be used in the form of a powder, may be used by dissolving in a solvent such as water, alcohol, polyhydric alcohol, etc., and an aqueous solution of a water-soluble inorganic salt such as sodium sulfate, sodium chloride, or ammonium sulfate. They may be used in a dispersed manner.
  • a solvent such as water, alcohol, polyhydric alcohol, etc.
  • an aqueous solution of a water-soluble inorganic salt such as sodium sulfate, sodium chloride, or ammonium sulfate. They may be used in a dispersed manner.
  • the component (C) is a dimethyldiallylammonium chloride-acrylamide copolymer
  • the dimethyldiallylammonium chloride-acrylamide copolymer may be a dispersion liquid dispersed in the water-soluble inorganic salt.
  • a component having high separation stability is preferred, and an ammonium sulfate-
  • the content of the water-soluble inorganic salt in the water-soluble inorganic salt dispersion of the dimethyldiallylammonium chloride / acrylamide copolymer is not particularly limited and may be appropriately selected depending on the intended purpose. 35 mass% is preferable, 10 mass% to 30 mass% is more preferable, and 15 mass% to 25 mass% is still more preferable.
  • the content of the water-soluble inorganic salt is less than 5% by mass, it may be difficult to form a dispersion, and when it exceeds 35% by mass, the salt may precipitate at a low temperature.
  • the content of the dimethyldiallylammonium chloride / acrylamide copolymer in the water-soluble inorganic salt dispersion of the dimethyldiallylammonium chloride / acrylamide copolymer is not particularly limited and may be appropriately selected depending on the purpose. Is preferably 10% by mass to 40% by mass, and more preferably 15% by mass to 35% by mass. When the content of the dimethyldiallylammonium chloride-acrylamide copolymer is less than 10% by mass, it may be difficult to form a dispersion, and when it exceeds 40% by mass, the viscosity may be high and handling may be difficult.
  • the content of the component (C) in the cleaning composition is 0.01% by mass to 1.2% by mass, but 0.05% by mass to 0% in terms of foaming and smoothness at the finish. .8% by mass is preferred.
  • the component (C) is less than 0.01% by mass, the separation stability and foaming of the component (B) may be reduced, and when it exceeds 1.2% by mass, the smoothness at the finish may be obtained. May decrease.
  • the mass ratio of the component (A) to the component (C) ((A) / (C)) is not particularly limited and may be appropriately selected depending on the intended purpose. From the viewpoint of smoothness and separation stability of the component (B), the mass ratio is preferably 0.3 to 100, and more preferably 1.3 to 20. When (A) / (C) is less than 0.3, the separation stability of the component (B) may be reduced, and when it exceeds 100, bubbling or separation stability of the component (B) may occur. May decrease.
  • component (A) and the component (C) have the preferred mass ratio, a hydrophobic anion-cation complex can be formed, and the separation stability of the hydrophobic component (B) can be improved. It is advantageous in that it can be improved and foaming can be improved.
  • anionic surfactant other than the component (A) that is the component (D) is not particularly limited and may be appropriately selected depending on the intended purpose.
  • the anionic surfactant other than the component (A) that is the component (D) is not particularly limited and may be appropriately selected depending on the intended purpose.
  • polyoxyethylene alkyl ether sulfate, fatty acid soap , Alkyl ether carboxylates, acyl alaninates, acyl taurates amino acid anionic surfactants represented by N-alkyliminodicarboxylates or salts thereof, alkylbenzene sulfonates, alkylnaphthalene sulfonates, ⁇ -sulfos
  • Examples include fatty acid salts, alkyl sulfonates, alkyl sulfosuccinates and ⁇ -olefin sulfonates. These may be used alone or in combination of two or more.
  • the average added mole number of ethylene oxide is not particularly limited and may be appropriately selected depending on the intended purpose, but is preferably 1 to 10, 1 to 3 is more preferable, and 2 to 3 is still more preferable.
  • the alkyl chain length of the component (D) is not particularly limited and may be appropriately selected depending on the intended purpose, but is preferably 12 to 14, and more preferably 12 from the viewpoint of foaming.
  • the content of the component (D) in the cleaning composition is 1% by mass to 30% by mass, and is preferably 10% by mass to 20% by mass in terms of foaming and smoothness at the finish.
  • foaming may be reduced, and when it exceeds 30% by mass, the separation stability of the component (B) and smoothness at the finish may be reduced. is there.
  • the component (E) is used for the purpose of stabilizing the viscosity and stabilizing the component (B).
  • the component (E) is not particularly limited as long as it is a nonionic surfactant and can be appropriately selected according to the purpose.
  • Polyoxyethylene (POE) hydrogenated castor oil and fatty acid polyoxyethylene glyceryl And / or polyoxyethylene (POE) fatty acid monoethanolamide hereinafter referred to as “(E-2) component”). Is preferred).
  • the component (E-1) is not particularly limited and may be appropriately selected depending on the intended purpose. From the viewpoints of viscosity stabilization and component (B) stabilization, polyoxyethylene (POE) curing is possible. Castor oil is more preferable, and the average added mole number of ethylene oxide (EO) is more preferably 5 to 100, particularly preferably 10 to 40.
  • Specific examples of the component (E-1) include trade names of NIKKOL HCO-5 (EO: 5), NIKKOL HCO-10 (EO: 10), NIKKOL HCO-20 (EO: 20), and NIKKOL HCO-.
  • NIKKOL HCO-40 EO: 40
  • NIKKOL HCO-50 EO: 50
  • NIKKOL HCO-60 EO: 60
  • NIKKOL HCO-100 EO: 100
  • EMALEX GWS-204 EO: 4
  • GWS-304 EO: 4
  • GWS-305 EO: 5
  • GWS-306 EO: 6
  • GWS-310 EO: 10.
  • GWS-320 EO: 20
  • GWIS-110 EO: 10
  • GWIS-320 Rujon Co., Ltd.
  • the amount of the component (E-1) used is not particularly limited and may be appropriately selected depending on the intended purpose, but is preferably 1% by mass to 5% by mass. From the viewpoint of separation stability, 2% by mass to 3% by mass is more preferable.
  • the component (E-2) is not particularly limited and may be appropriately selected depending on the intended purpose.
  • polyoxyethylene fatty acid monoethanolamide represented by the following general formula (1) is preferable.
  • R 1 represents an alkyl group having 7 to 23 carbon atoms, preferably 11 to 17 carbon atoms, and n represents an integer of 1 to 20, preferably 2 to 10.
  • component (E-2) examples include POE (2) coconut oil fatty acid monoethanolamide (PEG-3 cocamide), POE (5) coconut oil fatty acid monoethanolamide (PEG-6 cocamide), POE (10 ) Palm oil fatty acid monoethanolamide (PEG-11 cocamide), POE (20) Palm oil fatty acid monoethanolamide (PEG-20 coconut fatty acid amide MEA), POE (2) Lauric acid monoethanolamide (PEG-3 cocamide), POE (5) lauric acid monoethanolamide (PEG-6 cocamide), POE (10) lauric acid monoethanolamide (PEG-10 lauric acid amide MEA) and the like. These may be used alone or in combination of two or more.
  • the amount of the component (E-2) used is not particularly limited and may be appropriately selected depending on the intended purpose, but is preferably 1% by mass to 3% by mass, stabilizing the viscosity and the component (B). From the viewpoint of stabilization, 1.5 mass% to 2.5 mass% is more preferable.
  • the component (E) may be used alone or in combination of two or more, but the component (E-1) and the component (E-2) may be used in combination. From the viewpoints of viscosity stabilization and separation stability of the component (B).
  • the total amount of component (E) used is not particularly limited and may be appropriately selected depending on the intended purpose. It is preferably 2% by mass to 7% by mass, and 3.5% by mass to 5% by mass. It is more preferable from the viewpoint of stabilization and stabilization of the component (B).
  • the mass ratio between the component (E-1) and the component (E-2) is not particularly limited and may be appropriately selected depending on the intended purpose. However, it is possible to stabilize the viscosity and separate the component (B).
  • (E-1) / (E-2) is preferably from 0.1 to 3, more preferably from 1 to 1.7.
  • mass ratio is less than 0.1 or exceeds 3, viscosity stability and separation stability of the component (B) may be deteriorated.
  • the other components are not particularly limited and can be appropriately selected according to the purpose within a range not impairing the effects of the present invention.
  • flavor composition, etc. are mentioned.
  • the additive component is not particularly limited and may be appropriately selected depending on the intended purpose.
  • examples thereof include: a semipolar surfactant; an anionic polymer such as an acrylic acid polymer; a nonionic polymer such as a vinylpyrrolidone polymer Polyols; organic salts; humectants; tonic agents; solubilizers; antioxidants such as BHT and ⁇ -tocopherol; bactericides such as triclosan, trichlorocarban, isopropylmethylphenol; fatty acid monoethanolamide, fatty acid diethanolamide, etc.
  • UV absorbers ; protein derivatives; animal and plant extracts; antidandruff agents such as piroctone olamine and zinc pyrithione; anti-inflammatory agents such as pyrrolidone carboxylic acids and salts, herbal medicines, vitamins, glycyrrhetinic acid, dipotassium glycyrrhizinate; Benzoic acid and its salts, parabens, ke Preservatives such as Son CG; pH adjusters such as citric acid and triethanolamine; Pearling agents such as ethylene glycol difatty acid esters; Emulsifiers; Hydrotropes; Vitamins; Gallic acid derivatives, glycine, serine, arginine, etc.
  • antidandruff agents such as piroctone olamine and zinc pyrithione
  • anti-inflammatory agents such as pyrrolidone carboxylic acids and salts, herbal medicines, vitamins, glycyrrhetinic acid, dipotassium glycy
  • Amino acids hydrocarbons such as liquid paraffin and squalane; inorganic powders such as anhydrous silica and magnesia silica; organic powders such as nylon and polyethylene; volatile oils; solvents such as lower alcohols; hydrophobic solvents; It is done.
  • These additive components may be used alone or in combination of two or more. There is no restriction
  • the fragrance and the fragrance composition used in the cleaning composition of the present invention are not particularly limited and may be appropriately selected depending on the intended purpose.
  • the “perfume composition” means a mixture comprising the above-described perfume ingredients, a solvent, a perfume stabilizer and the like.
  • the content of the fragrance solvent in the fragrance composition is not particularly limited and may be appropriately selected depending on the intended purpose, but is preferably 0.1% by mass to 99% by mass, and 1% by mass to 50% by mass. % Is more preferable.
  • the fragrance stabilizer include dibutylhydroxytoluene, butylhydroxyanisole, vitamin E or a derivative thereof, a catechin compound, a flavonoid compound, a polyphenol compound, and the like. Among these, dibutylhydroxytoluene is particularly preferable.
  • the content of the fragrance stabilizer in the fragrance composition is not particularly limited and may be appropriately selected depending on the intended purpose, but is preferably 0.0001% by mass to 10% by mass, preferably 0.001% by mass. More preferable is 5% by mass.
  • the content of the fragrance composition in the cleaning composition is not particularly limited and may be appropriately selected depending on the intended purpose, but is preferably 0.005% by mass to 40% by mass, and 0.01% by mass More preferred is 10% by mass.
  • the cleaning composition of the present invention is prepared by mixing and dissolving a water-soluble component containing the component (A) in a hot water bath at 80 ° C. to form an aqueous phase.
  • the aqueous phase contains the components (B) and (C).
  • an oil phase containing the component (D) is added and mixed uniformly. Then, it can prepare by further cooling to room temperature (25 degreeC), stirring.
  • room temperature 25 degreeC
  • stirring There is no restriction
  • the pH of the cleaning composition is not particularly limited and may be appropriately selected depending on the intended purpose, but is preferably 3 to 7, and more preferably 4 to 6. If the pH of the cleaning composition is less than 3, there is concern about irritation to the background, and if it exceeds 7, the antiseptic power may be reduced and microorganisms may grow.
  • the pH is measured in accordance with a cosmetic raw material standard general test method pH measurement method.
  • the viscosity of the cleaning composition is not particularly limited and may be appropriately selected depending on the intended purpose, but the viscosity at 25 ° C. is preferably 1,000 mPa ⁇ s to 6,000 mPa ⁇ s. If the viscosity at 25 ° C. of the cleaning composition is less than 1,000 mPa ⁇ s, it may be difficult to use because it spills from the hand during use, and if it exceeds 6,000 mPa ⁇ s, it is discharged from the container. May get worse.
  • the viscosity is measured in accordance with the Cosmetic Raw Material Standard General Test Method Viscosity Measurement Method No. 2.
  • ⁇ Container> There is no restriction
  • the laminate film of the aluminum laminate tube usually has two or more layers, and the material thereof is not particularly limited and can be appropriately selected according to the purpose.
  • polyethylene, polyethylene terephthalate, polyester two Examples include axially stretched polypropylene, non-stretched polypropylene, polyacrylonitrile, synthetic resins such as ethylene vinyl acetate copolymer, paper, and aluminum-deposited plastic. These may be used alone or in combination of two or more.
  • the laminated film of the aluminum laminated tube may be used as a single layer or may be used in combination of two or more layers, but generally considering the strength, flexibility, weather resistance, etc. Five layers are preferred.
  • the material of the bottle container is not particularly limited and can be appropriately selected according to the purpose.
  • polyethylene, polypropylene, polyethylene terephthalate, polystyrene, polyvinyl chloride, ethylene-vinyl alcohol resin, acrylonitrile / styrene resin examples thereof include ABS resin, polyamide, and glass. These may be used in a single layer or in combination of two or more layers.
  • the method for mixing the component (A), the component (B), the component (D), and the component (E) is not particularly limited.
  • the water-soluble component containing the component (A) is mixed and dissolved in an 80 ° C. hot water bath to form an aqueous phase.
  • the aqueous phase contains the component (B) and the component (C).
  • the method of adding the component, the component (D), and the oil phase containing the component (E) and mixing them uniformly is preferable.
  • the method for stabilizing dimethylpolysiloxane of the present invention can improve the stability of dimethylpolysiloxane, and therefore can be suitably used for the production of a cleaning composition containing the dimethylpolysiloxane.
  • the cleaning composition of the present invention is excellent in separation stability, and can impart smoothness to hair, skin, etc. damaged by repeated coloring, perming, excessive drying, etc.
  • it can be suitably used for various washings such as hair cleansing shampoos, damage care shampoos, mild shampoos, rinse-in shampoos, and skin cleansing agents such as body soaps and hand soaps. .
  • Examples 1 to 33 Comparative Examples 1 to 9
  • the detergent compositions of Examples and Comparative Examples shown in Tables 1 to 9 were produced according to the following production method with the compositions and blending amounts shown in Tables 1 to 9, and the resulting detergent compositions were produced by the methods shown below. Sensory evaluation and long-term storage stability (separation stability) were evaluated. However, the compounding amounts shown in Tables 1 to 9 represent mass% in the cleaning composition in terms of pure unless otherwise specified.
  • Comparative Example 1 the detergent composition of Comparative Example 1 was prepared in the same manner as Examples 1 to 33 and Comparative Examples 6 to 9 except that the component (A) was not blended. Prepared.
  • Comparative Example 2 The cleaning of Comparative Example 2 was performed in the same manner as in Examples 1 to 33 and Comparative Examples 6 to 9, except that in Example 1 to 33 and Comparative Examples 6 to 9, the component (A) was replaced with the component (A ′). An agent composition was prepared.
  • Comparative Example 4 Cleaning of Comparative Example 4 was performed in the same manner as in Examples 1 to 33 and Comparative Examples 6 to 9, except that the component (B) was replaced with the component (B ′) in Examples 1 to 33 and Comparative Examples 6 to 9.
  • An agent composition was prepared.
  • the dimethyl silicone oil as the component (B ′) is dimethyl silicone itself having a kinematic viscosity at 25 ° C. of 100,000 mm 2 / s.
  • Comparative Example 5 The cleaning of Comparative Example 5 was performed in the same manner as in Examples 1 to 33 and Comparative Examples 6 to 9, except that the component (C) was replaced with the component (C ′) in Examples 1 to 33 and Comparative Examples 6 to 9. An agent composition was prepared.
  • ⁇ Sensory evaluation> The subjects were 40 men and women in their 20s to 60s who were dissatisfied with foaming at the time of hair washing and smoothness of the hair at the finish, and the cleaning compositions of Examples 1 to 33 and Comparative Examples 1 to 9 were used as subjects. It was used continuously for days and evaluated for good foaming and smooth hair when finished, based on the following evaluation criteria. The results are shown in Tables 1-9. -Evaluation criteria- ⁇ : 30 to 40 respondents are good ⁇ : 20 to 29 respondents are good ⁇ : 10 to 19 respondents are good ⁇ : 0 to respondents are good
  • -Evaluation criteria- ⁇ : 30 to 40 respondents are good ⁇ : 20 to 29 respondents are good ⁇ : 10 to 19 respondents are good ⁇ : 0 to respondents are good Nine people In the above evaluation criteria, “good” means that foaming is good and the hair is smooth when washing the hair.
  • ⁇ Separation stability evaluation> Fill the PET (polyethylene terephthalate) vials with about 40 mL each of the cleaning compositions of Examples 1 to 33 and Comparative Examples 1 to 9, store them in a constant temperature bath at 40 ° C. for 6 months, and visually inspect the appearance. Thus, the separation stability was evaluated based on the following evaluation criteria. The results are shown in Tables 1-9. -Evaluation criteria- ⁇ : No change in appearance, no separation observed ⁇ : Slight separation is observed, but there is no problem in quality ⁇ : Separation observed ⁇ : Completely separated into two layers
  • Example 34 Body soap
  • a body soap of Example 34 was obtained in the same manner as in Examples 1 to 33 except that the composition of the cleaning composition in Examples 1 to 33 was changed to the following composition.
  • separation stability was evaluated in the same manner as in Examples 1 to 33.
  • sensory evaluation was performed by the method shown below. ⁇ Sensory evaluation> 40 men and women in their 20s and 60s who are dissatisfied with the foaming at the time of washing the skin and the smoothness of the skin at the finish, using the body soap of Example 34 for 7 days continuously, The smoothness of the skin when finished was evaluated based on the following evaluation criteria.
  • Example 35 Hand soap
  • a hand soap of Example 35 was obtained in the same manner as in Examples 1 to 33 except that the composition of the cleaning composition in Examples 1 to 33 was changed to the composition shown below.
  • the separation stability was evaluated in the same manner as in Examples 1 to 33.
  • sensory evaluation was performed in the same manner as in Example 34.
  • Examples 36 to 48, Comparative Examples 10 to 14 Next, the method for stabilizing dimethylpolysiloxane was tested.
  • the cleaning compositions of Examples and Comparative Examples shown in Tables 10 to 12 were produced according to the following production method with the compositions and blending amounts shown in Tables 10 to 12, and the resulting cleaning compositions were used in Examples 1 to Sensory evaluation was performed in the same manner as in No.33.
  • long-term storage stability (separation stability) evaluation and long-term viscosity stability evaluation were performed by the method shown below.
  • the results are shown in Tables 10-12.
  • the blending amounts shown in Tables 10 to 12 represent mass% in the cleaning composition in terms of pure unless otherwise specified.
  • Comparative Example 10 In Examples 36 to 48 and Comparative Examples 12 to 13, the cleaning composition of Comparative Example 10 was prepared in the same manner as Examples 36 to 48 and Comparative Examples 12 to 13 except that the component (A) was not blended. Prepared.
  • Comparative Example 11- Cleaning of Comparative Example 11 was carried out in the same manner as in Examples 36 to 48 and Comparative Examples 12 to 13, except that the component (C) was replaced with the component (C ′) in Examples 36 to 48 and Comparative Examples 12 to 13.
  • An agent composition was prepared.
  • Comparative Example 14 In Examples 36 to 48 and Comparative Examples 12 to 13, the cleaning composition of Comparative Example 11 was prepared in the same manner as Examples 36 to 48 and Comparative Examples 12 to 13 except that the component (E) was not blended. Prepared.
  • Viscosity change rate (viscosity of detergent composition immediately after production ⁇ viscosity of detergent composition after storage for 6 months) / viscosity of detergent composition immediately after production ⁇ 100 -Evaluation criteria- ⁇ : Viscosity change rate is 0% or more and less than 5% ⁇ : Viscosity change rate is 5% or more and less than 10% ⁇ : Viscosity change rate is 10% or more and less than 20% ⁇ : Viscosity change rate is 20% or more
  • the stability of dimethylpolysiloxane of the present invention can improve the stability of dimethylpolysiloxane, it can be suitably used for a cleaning composition containing the dimethylpolysiloxane.
  • the cleaning composition of the present invention is excellent in separation stability, and can impart smoothness to hair, skin, etc. damaged by repeated coloring, perming, excessive drying, etc.
  • it can be suitably used for various washings such as hair cleansing shampoos, damage care shampoos, mild shampoos, rinse-in shampoos, and skin cleansing agents such as body soaps and hand soaps. .

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Abstract

L'invention porte sur une composition d'agent de nettoyage qui présente une excellente stabilité en ce qui concerne la séparation de diméthylpolysiloxane et une bonne aptitude au moussage, et qui permet de conférer un caractère lisse au finissage, et sur un procédé de stabilisation du diméthylpolysiloxane, qui permet d'améliorer la stabilité du diméthylpolysiloxane. La composition d'agent de nettoyage comporte au moins (A) un ester de l'acide phosphorique et/ou un sel de celui-ci, (B) du diméthylpolysiloxane, (C) un polymère cationique et (D) un tensioactif anionique qui est différent du composant (A), le composant (A) ayant une valeur de HLB comprise entre 8 et 17, le composant (B) ayant une viscosité cinématique d'au moins 4 000 000 mm2/s à 25°C, le composant (C) étant contenu à hauteur de 0,01 à 1,2 % en masse et le composant (D) étant contenu à hauteur de 1 à 30 % en masse.
PCT/JP2010/062370 2009-12-18 2010-07-22 Composition d'agent de nettoyage et procédé de stabilisation de diméthylpolysiloxane WO2011074282A1 (fr)

Priority Applications (4)

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JP2011545998A JP5632392B2 (ja) 2009-12-18 2010-07-22 洗浄剤組成物及びジメチルポリシロキサンの分離安定化方法
CN201080057711.2A CN102665662B (zh) 2009-12-18 2010-07-22 洗涤剂组合物及二甲基聚硅氧烷的稳定方法
KR1020127018842A KR101673646B1 (ko) 2009-12-18 2010-07-22 세제 조성물 및 디메틸폴리실록산의 안정화 방법
HK13101433.8A HK1173981A1 (en) 2009-12-18 2013-02-01 Cleansing agent composition, and method for stabilization of dimethylpolysiloxane

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JP2009-288075 2009-12-18
JP2009288075 2009-12-18

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WO2013089059A1 (fr) * 2011-12-12 2013-06-20 ライオン株式会社 Composition d'agent de nettoyage capillaire
US9994795B2 (en) 2013-08-13 2018-06-12 Dow Silicones Corporation Method of forming an antifoam granule comprising a silicone polyether
JP2019094287A (ja) * 2017-11-22 2019-06-20 ライオン株式会社 液体皮膚洗浄剤組成物
JP2019116473A (ja) * 2017-12-26 2019-07-18 花王株式会社 皮膚洗浄剤組成物

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KR100598863B1 (ko) * 2004-09-24 2006-07-10 한국화학연구원 캡슐화된 자기유화형 실리콘 컴파운드를 포함하는 입자형실리콘 소포제 조성물 및 이의 제조방법
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JPH04134017A (ja) * 1990-09-25 1992-05-07 Lion Corp 毛髪化粧料用高濃度シリコンエマルジョン組成物
JPH0753340A (ja) * 1993-08-20 1995-02-28 Kao Corp シャンプー組成物
JP2001010935A (ja) * 1999-06-30 2001-01-16 Lion Corp シャンプー組成物
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WO2013089059A1 (fr) * 2011-12-12 2013-06-20 ライオン株式会社 Composition d'agent de nettoyage capillaire
JPWO2013089059A1 (ja) * 2011-12-12 2015-04-27 ライオン株式会社 毛髪洗浄剤組成物
US9994795B2 (en) 2013-08-13 2018-06-12 Dow Silicones Corporation Method of forming an antifoam granule comprising a silicone polyether
US10689601B2 (en) 2013-08-13 2020-06-23 Dow Silicones Corporation Method of forming an antifoam granule containing a silicone polyether
JP2019094287A (ja) * 2017-11-22 2019-06-20 ライオン株式会社 液体皮膚洗浄剤組成物
JP2019116473A (ja) * 2017-12-26 2019-07-18 花王株式会社 皮膚洗浄剤組成物
JP7397571B2 (ja) 2017-12-26 2023-12-13 花王株式会社 皮膚洗浄剤組成物

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JP5632392B2 (ja) 2014-11-26
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