WO2011071997A1 - Produit pour lave-vaisselle automatique et utilisation de celui-ci - Google Patents

Produit pour lave-vaisselle automatique et utilisation de celui-ci Download PDF

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Publication number
WO2011071997A1
WO2011071997A1 PCT/US2010/059429 US2010059429W WO2011071997A1 WO 2011071997 A1 WO2011071997 A1 WO 2011071997A1 US 2010059429 W US2010059429 W US 2010059429W WO 2011071997 A1 WO2011071997 A1 WO 2011071997A1
Authority
WO
WIPO (PCT)
Prior art keywords
ionic surfactant
surfactant
dishwasher
acid
obscuration
Prior art date
Application number
PCT/US2010/059429
Other languages
English (en)
Inventor
Paul Lapham
Eric San Jose Robles
Gillian Margaret Hardy
Mark Stewart Slassor
Original Assignee
The Procter & Gamble Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=41800741&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2011071997(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Priority to JP2012543238A priority Critical patent/JP2013513700A/ja
Publication of WO2011071997A1 publication Critical patent/WO2011071997A1/fr

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/722Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/825Mixtures of compounds all of which are non-ionic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/825Mixtures of compounds all of which are non-ionic
    • C11D1/8255Mixtures of compounds all of which are non-ionic containing a combination of compounds differently alcoxylised or with differently alkylated chains
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047Detergents in the form of bars or tablets
    • C11D17/0065Solid detergents containing builders
    • C11D17/0073Tablets
    • C11D17/0078Multilayered tablets
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047Detergents in the form of bars or tablets
    • C11D17/0065Solid detergents containing builders
    • C11D17/0073Tablets
    • C11D17/0091Dishwashing tablets
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/042Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/042Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
    • C11D17/045Multi-compartment
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/378(Co)polymerised monomers containing sulfur, e.g. sulfonate
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • C11D3/3902Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905Bleach activators or bleach catalysts
    • C11D3/3932Inorganic compounds or complexes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/14Hard surfaces
    • C11D2111/20Industrial or commercial equipment, e.g. reactors, tubes or engines

Definitions

  • the present invention provides excellent cleaning and finishing of the dishwashing load and at the same time the main body and most surprisingly, the internal parts of the dishwasher.
  • the use of the invention contributes to the maintenance and good appearance of the dishwasher. It also extends the life of the machine and keeps the efficiency of the machine higher for longer.
  • Suitable surfactants of formula I are Olin Corporation's POLY-TERGENT® SLF-18B nonionic surfactants, as described, for example, in WO 94/22800, published October 13, 1994 by Olin Corporation.
  • a non-ionic surfactant suitable for use herein has a Draves wetting time of less than 360 seconds, preferably less than 200 seconds, more preferably less than 100 seconds and especially less than 60 seconds as measured by the Draves wetting method (standard method ISO 8022 using the following conditions; 3-g hook, 5-g cotton skein, 0.1% by weight aqueous solution at a temperature of 25°C).
  • Builders for use herein include phosphate builders and phosphate free builders. If present, builders are used in a level of from 5 to 60%, preferably from 10 to 50%, more preferably from 20 to 50% by weight of the composition. In some embodiments the product comprises a mixture of phosphate and non-phosphate builders. Phosphate builders
  • Inorganic and organic bleaches are suitable cleaning actives for use herein.
  • Inorganic bleaches include perhydrate salts such as perborate, percarbonate, perphosphate, persulfate and persilicate salts.
  • the inorganic perhydrate salts are normally the alkali metal salts.
  • the inorganic perhydrate salt may be included as the crystalline solid without additional protection. Alternatively, the salt can be coated.
  • organic bleaches include the peroxy acids, particular examples being the alkylperoxy acids and the arylperoxy acids.
  • Preferred representatives are (a) peroxybenzoic acid and its ring-substituted derivatives, such as alkylperoxybenzoic acids, but also peroxy-a- naphthoic acid and magnesium monoperphthalate, (b) the aliphatic or substituted aliphatic peroxy acids, such as peroxylauric acid, peroxystearic acid, ⁇ -phthalimidoperoxycaproic acid[phthaloiminoperoxyhexanoic acid (PAP)], o-carboxybenzamidoperoxycaproic acid, N- nonenylamidoperadipic acid and N-nonenylamidopersuccinates, and (c) aliphatic and araliphatic peroxydicarboxylic acids, such as 1,12-diperoxycarboxylic acid, 1 ,9-diperoxyazelaic acid, diperoxys
  • the relatedness between two amino acid sequences is described by the parameter "identity".
  • the alignment of two amino acid sequences is determined by using the Needle program from the EMBOSS package (http://emboss.org) version 2.8.0.
  • the Needle program implements the global alignment algorithm described in Needleman, S. B. and Wunsch, C. D. (1970) J. Mol. Biol. 48, 443-453.
  • the substitution matrix used is BLOSUM62, gap opening penalty is 10, and gap extension penalty is 0.5.
  • Preferred enzyme for use herein includes a protease.
  • Suitable proteases include metalloproteases and serine proteases, including neutral or alkaline microbial serine proteases, such as subtilisins (EC 3.4.21.62).
  • Suitable proteases include those of animal, vegetable or microbial origin. In one aspect, such suitable protease may be of microbial origin.
  • the suitable proteases include chemically or genetically modified mutants of the aforementioned suitable proteases.
  • the suitable protease may be a serine protease, such as an alkaline microbial protease or/and a trypsin-type protease.
  • suitable neutral or alkaline proteases include:
  • compositions tabulated below are introduced into a dual-compartment water-soluble pack having a first compartment comprising the solid composition (in powder form) and a liquid compartment comprising the liquid compositions.
  • the water-soluble film used is Monosol M8630 film as supplied by Monosol.
  • the weight of the solid composition is 17 grams and the weight of liquid compositions is 2.6 gram.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

La présente invention concerne l'utilisation d'un produit pour lave-vaisselle automatique dans un lave-vaisselle automatique pour nettoyer les composants internes d'un lave-vaisselle pendant une opération de lavage automatique de la vaisselle où l'opération met en œuvre la libération d'au moins 250 ppm d'un tensioactif non ionique.
PCT/US2010/059429 2009-12-10 2010-12-08 Produit pour lave-vaisselle automatique et utilisation de celui-ci WO2011071997A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2012543238A JP2013513700A (ja) 2009-12-10 2010-12-08 自動食器洗浄用製品及びその使用

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09178726.7A EP2333042B1 (fr) 2009-12-10 2009-12-10 Utilisation de détergent
EP09178726.7 2009-12-10

Publications (1)

Publication Number Publication Date
WO2011071997A1 true WO2011071997A1 (fr) 2011-06-16

Family

ID=41800741

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2010/059429 WO2011071997A1 (fr) 2009-12-10 2010-12-08 Produit pour lave-vaisselle automatique et utilisation de celui-ci

Country Status (6)

Country Link
US (1) US20110139182A1 (fr)
EP (1) EP2333042B1 (fr)
JP (3) JP2013513700A (fr)
ES (1) ES2548772T3 (fr)
PL (1) PL2333042T3 (fr)
WO (1) WO2011071997A1 (fr)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2336750B1 (fr) * 2009-12-10 2016-04-13 The Procter & Gamble Company Procédé de mesure de la capacité d'enlèvement de taches d'un produit de nettoyage
WO2015094791A1 (fr) * 2013-12-16 2015-06-25 3M Innovative Properties Company Compositions et procédés à base de détergents et produits de rinçage
DE102014205641A1 (de) * 2014-03-26 2015-10-01 Henkel Ag & Co. Kgaa Pflegemittel für automatische Geschirrspülmaschinen mit optimierter Tensidkombination
BR112017020157A2 (pt) * 2015-03-24 2018-06-05 Rohm & Haas controle de incrustação em aplicações para lavagem de louças
DE102015218475A1 (de) * 2015-09-25 2017-03-30 Henkel Ag & Co. Kgaa Verfahren zur Pflege und Reinigung einer automatischen Geschirrspülmaschine
EP3228686B1 (fr) * 2016-04-08 2021-10-27 The Procter & Gamble Company Lave-vaisselle automatique
EP3257929B1 (fr) * 2016-06-17 2022-03-09 The Procter & Gamble Company Composition de détergent de lave-vaisselle automatique
CN110013205B (zh) * 2019-02-22 2023-04-25 宁波欧琳科技股份有限公司 一种拼接式喷淋臂及洗碗机
DE102020216106A1 (de) * 2020-12-17 2022-06-23 Henkel Ag & Co. Kgaa Verfahren zur Reinigung und Pflege einer automatischen Geschirrspülmaschine
IT202100002048A1 (it) * 2021-02-01 2022-08-01 Deco Ind S Coop P A Prodotto per lavatrici

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