WO2011056020A3 - 혼합 메탈로센 촉매 조성물 및 이를 이용한 폴리 올레핀의 제조방법 - Google Patents

혼합 메탈로센 촉매 조성물 및 이를 이용한 폴리 올레핀의 제조방법 Download PDF

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Publication number
WO2011056020A3
WO2011056020A3 PCT/KR2010/007803 KR2010007803W WO2011056020A3 WO 2011056020 A3 WO2011056020 A3 WO 2011056020A3 KR 2010007803 W KR2010007803 W KR 2010007803W WO 2011056020 A3 WO2011056020 A3 WO 2011056020A3
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WO
WIPO (PCT)
Prior art keywords
polyolefin
catalyst composition
metallocene catalyst
preparing
same
Prior art date
Application number
PCT/KR2010/007803
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English (en)
French (fr)
Other versions
WO2011056020A2 (ko
Inventor
하종주
이충훈
금돈호
이은정
서범두
Original Assignee
주식회사 엘지화학
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020090107033A external-priority patent/KR20110050171A/ko
Priority claimed from KR1020100091085A external-priority patent/KR101366215B1/ko
Application filed by 주식회사 엘지화학 filed Critical 주식회사 엘지화학
Priority to US13/508,297 priority Critical patent/US8716414B2/en
Priority to CN201080059633XA priority patent/CN102686616A/zh
Priority to JP2012537819A priority patent/JP2013510221A/ja
Publication of WO2011056020A2 publication Critical patent/WO2011056020A2/ko
Publication of WO2011056020A3 publication Critical patent/WO2011056020A3/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

본 발명은 제 1 메탈로센 촉매 및 제 2 메탈로센 촉매를 포함하는 혼합 메탈로센 촉매 조성물 및 상기 촉매 조성물을 이용하는 폴리 올레핀의 제조방법에 관한 것으로서, 상기 촉매 조성물 및 제조 방법에 의하면 넓은 분자량 분포를 가지며 기계적 물성 및 가공성이 우수한 폴리 올레핀을 제공될 수 있다.
PCT/KR2010/007803 2009-11-06 2010-11-05 혼합 메탈로센 촉매 조성물 및 이를 이용한 폴리 올레핀의 제조방법 WO2011056020A2 (ko)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US13/508,297 US8716414B2 (en) 2009-11-06 2010-11-05 Mixed metallocene catalyst composition and method for preparing polyolefin using the same
CN201080059633XA CN102686616A (zh) 2009-11-06 2010-11-05 混合茂金属催化剂组合物以及使用该组合物制备聚烯烃的方法
JP2012537819A JP2013510221A (ja) 2009-11-06 2010-11-05 混合メタロセン触媒組成物およびこれを用いたポリオレフィンの製造方法

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR1020090107033A KR20110050171A (ko) 2009-11-06 2009-11-06 촉매 조성물 및 이를 이용한 올레핀 공중합체의 제조방법
KR10-2009-0107033 2009-11-06
KR1020100091085A KR101366215B1 (ko) 2010-09-16 2010-09-16 폴리 올레핀의 제조방법
KR10-2010-0091085 2010-09-16

Publications (2)

Publication Number Publication Date
WO2011056020A2 WO2011056020A2 (ko) 2011-05-12
WO2011056020A3 true WO2011056020A3 (ko) 2011-10-20

Family

ID=43970569

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2010/007803 WO2011056020A2 (ko) 2009-11-06 2010-11-05 혼합 메탈로센 촉매 조성물 및 이를 이용한 폴리 올레핀의 제조방법

Country Status (4)

Country Link
US (1) US8716414B2 (ko)
JP (1) JP2013510221A (ko)
CN (1) CN102686616A (ko)
WO (1) WO2011056020A2 (ko)

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KR101391692B1 (ko) * 2012-11-14 2014-05-07 주식회사 엘지화학 3원계 탄성 공중합체 및 이의 제조 방법
US9493593B2 (en) 2013-06-28 2016-11-15 Lg Chem, Ltd. Elastic diene terpolymer and preparation method thereof
US9650460B2 (en) 2013-06-28 2017-05-16 Lg Chem, Ltd. Elastic diene terpolymer and preparation method thereof
WO2014209082A1 (ko) 2013-06-28 2014-12-31 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
KR101585204B1 (ko) 2013-06-28 2016-01-13 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
KR101657680B1 (ko) * 2013-09-30 2016-09-19 주식회사 엘지화학 폴리올레핀
KR101549209B1 (ko) * 2013-11-18 2015-09-02 주식회사 엘지화학 가공성이 우수한 올레핀계 중합체
KR101705339B1 (ko) 2014-07-18 2017-02-09 주식회사 엘지화학 에틸렌-1-헥센-1-부텐 3원 공중합체 및 이를 포함하는 필름
US9732172B2 (en) 2014-10-13 2017-08-15 Lg Chem, Ltd. Ethylene/1-hexene or ethylene/1-butene copolymer having excellent processibility and environmetal stress crack resistance
KR101973191B1 (ko) 2015-06-05 2019-04-26 주식회사 엘지화학 메탈로센 담지 촉매 및 이를 이용하는 폴리올레핀의 제조 방법
KR101850984B1 (ko) 2015-06-15 2018-04-20 주식회사 엘지화학 섬유 제조용 폴리올레핀 및 이를 포함하는 섬유
US10947329B2 (en) * 2017-05-10 2021-03-16 Univation Technologies, Llc Catalyst systems and processes for using the same

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KR20040085650A (ko) * 2003-04-01 2004-10-08 주식회사 엘지화학 혼성 담지 메탈로센 촉매 및 그의 제조방법과 이를 이용한폴리올레핀의 제조방법
KR20060087890A (ko) * 2005-01-31 2006-08-03 주식회사 엘지화학 혼합 담지 메탈로센 촉매, 그 제조방법 및 이를 이용하여제조된 폴리올레핀 및 그 제조 방법
KR20070096465A (ko) * 2006-03-24 2007-10-02 주식회사 엘지화학 전이금속 화합물, 이를 포함하는 촉매 조성물 및 이를이용한 올레핀 중합
KR20090063799A (ko) * 2007-12-14 2009-06-18 주식회사 엘지화학 혼성 담지 메탈로센 촉매, 이의 제조 방법 및 혼성 담지메탈로센 촉매를 이용한 폴리올레핀의 제조방법

Also Published As

Publication number Publication date
JP2013510221A (ja) 2013-03-21
US8716414B2 (en) 2014-05-06
CN102686616A (zh) 2012-09-19
US20120259077A1 (en) 2012-10-11
WO2011056020A2 (ko) 2011-05-12

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