WO2011014451A3 - Fluorinated arylboron oxalate as anion receptors and additives for non-aqueous battery electrolytes - Google Patents

Fluorinated arylboron oxalate as anion receptors and additives for non-aqueous battery electrolytes Download PDF

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Publication number
WO2011014451A3
WO2011014451A3 PCT/US2010/043221 US2010043221W WO2011014451A3 WO 2011014451 A3 WO2011014451 A3 WO 2011014451A3 US 2010043221 W US2010043221 W US 2010043221W WO 2011014451 A3 WO2011014451 A3 WO 2011014451A3
Authority
WO
WIPO (PCT)
Prior art keywords
oxalate
additives
battery electrolytes
aqueous
aqueous battery
Prior art date
Application number
PCT/US2010/043221
Other languages
French (fr)
Other versions
WO2011014451A2 (en
Inventor
Hung Sui Lee
Xiao-qing YANG
Kyung-Wan Nam
Xiaojian Wang
Original Assignee
Brookhaven Science Associates Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Brookhaven Science Associates Llc filed Critical Brookhaven Science Associates Llc
Priority to US13/388,017 priority Critical patent/US20120183866A1/en
Publication of WO2011014451A2 publication Critical patent/WO2011014451A2/en
Publication of WO2011014451A3 publication Critical patent/WO2011014451A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
    • C07F5/02—Boron compounds
    • C07F5/025—Boronic and borinic acid compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0567—Liquid materials characterised by the additives
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0569—Liquid materials characterised by the solvents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1393—Processes of manufacture of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Abstract

The present invention relates to electrochemical storage devices containing a non-aqueous lithium based electrolyte with high ionic conductivity, low impedance, and high thermal stability. More particularly, this invention relates to the design, synthesis and application of novel fluorinated arylboron oxalate based compounds which act as anion receptors and/or additives for non-aqueous batteries. When used as an anion receptor for non-aqueous battery electrolytes, the fluorinated arylboron oxalate enhances conductivity, lithium ion transference number and Solid Electrolyte Interface (SEI) formation capability during the formation cycling.
PCT/US2010/043221 2009-07-29 2010-07-26 Fluorinated arylboron oxalate as anion receptors and additives for non-aqueous battery electrolytes WO2011014451A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US13/388,017 US20120183866A1 (en) 2009-07-29 2010-07-26 Fluorinated Arylboron Oxalate as Anion Receptors and Additives for Non-Aqueous Battery Electrolytes

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US22939009P 2009-07-29 2009-07-29
US61/229,390 2009-07-29

Publications (2)

Publication Number Publication Date
WO2011014451A2 WO2011014451A2 (en) 2011-02-03
WO2011014451A3 true WO2011014451A3 (en) 2011-06-16

Family

ID=43529921

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2010/043221 WO2011014451A2 (en) 2009-07-29 2010-07-26 Fluorinated arylboron oxalate as anion receptors and additives for non-aqueous battery electrolytes

Country Status (2)

Country Link
US (1) US20120183866A1 (en)
WO (1) WO2011014451A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
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CN105849967A (en) * 2013-12-26 2016-08-10 国立大学法人京都大学 Secondary battery

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CN102807578B (en) * 2011-05-30 2015-12-02 比亚迪股份有限公司 A kind of preparation method of lithium salts
WO2016160703A1 (en) 2015-03-27 2016-10-06 Harrup Mason K All-inorganic solvents for electrolytes
US9887434B2 (en) 2015-06-22 2018-02-06 Wildcat Discovery Technologies, Inc Electrolyte formulations for lithium ion batteries
US10862163B2 (en) * 2016-01-20 2020-12-08 National Technology & Engineering Solutions Of Sandia, Llc Organosilicon-based electrolytes for long-life lithium primary batteries
US10249449B2 (en) 2016-03-01 2019-04-02 Maxwell Technologies, Inc. Electrolyte formulations for energy storage devices
US20170365855A1 (en) * 2016-06-21 2017-12-21 Samsung Electronics Co., Ltd. Lithium battery
KR20230107388A (en) * 2016-09-21 2023-07-14 바스프 에스이 Electrochemical cells comprising bifunctional phosphonic acid silylesters
US10707531B1 (en) 2016-09-27 2020-07-07 New Dominion Enterprises Inc. All-inorganic solvents for electrolytes
DE112017006921T5 (en) 2017-01-25 2019-10-02 Robert Bosch Gmbh Lithium-ion cell and process for the production thereof
US10777811B2 (en) 2018-03-02 2020-09-15 Uchicago Argonne, Llc Lithium-sulfur battery with lithium polysulfide catholyte
CN110970656A (en) * 2018-09-28 2020-04-07 张家港市国泰华荣化工新材料有限公司 Additive and electrolyte capable of improving performance of lithium ion battery
US11916198B2 (en) * 2019-12-26 2024-02-27 StoreDot Ltd. Fast-charging lithium ion batteries with electrolytes that do not react on the anodes
US20220131148A1 (en) * 2020-10-28 2022-04-28 Enevate Corporation Boron-containing chemicals as cathode additives, si anode additives, electrolyte additives or separator modifiers for li-ion batteries
CN113793990B (en) * 2021-09-15 2023-07-04 中国科学院长春应用化学研究所 Method for improving multiplying power performance of lithium ion battery by artificially synthesizing specific solid electrolyte interface film

Citations (3)

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US20070292766A1 (en) * 2006-06-14 2007-12-20 Sony Corporation Organic semiconductor material and semiconductor device
US20080138715A1 (en) * 2006-12-07 2008-06-12 Sony Corporation Electrolytic solution and battery
US20080226989A1 (en) * 2000-06-16 2008-09-18 Arizona Board Of Regents Electrolytic salts for lithium batteries

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080226989A1 (en) * 2000-06-16 2008-09-18 Arizona Board Of Regents Electrolytic salts for lithium batteries
US20070292766A1 (en) * 2006-06-14 2007-12-20 Sony Corporation Organic semiconductor material and semiconductor device
US20080138715A1 (en) * 2006-12-07 2008-06-12 Sony Corporation Electrolytic solution and battery

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105849967A (en) * 2013-12-26 2016-08-10 国立大学法人京都大学 Secondary battery
CN105849967B (en) * 2013-12-26 2019-06-07 国立大学法人京都大学 Secondary cell

Also Published As

Publication number Publication date
WO2011014451A2 (en) 2011-02-03
US20120183866A1 (en) 2012-07-19

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