WO2010139716A2 - Produit cosmétique de nettoyage tensioactif contenant de la gelée royale - Google Patents

Produit cosmétique de nettoyage tensioactif contenant de la gelée royale Download PDF

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Publication number
WO2010139716A2
WO2010139716A2 PCT/EP2010/057691 EP2010057691W WO2010139716A2 WO 2010139716 A2 WO2010139716 A2 WO 2010139716A2 EP 2010057691 W EP2010057691 W EP 2010057691W WO 2010139716 A2 WO2010139716 A2 WO 2010139716A2
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WO
WIPO (PCT)
Prior art keywords
agent according
cleaning agent
alcohol
surfactant
acid
Prior art date
Application number
PCT/EP2010/057691
Other languages
German (de)
English (en)
Other versions
WO2010139716A3 (fr
Inventor
Kirsten Sartingen
Qian-Yi Li
Original Assignee
Henkel Ag & Co. Kgaa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Ag & Co. Kgaa filed Critical Henkel Ag & Co. Kgaa
Priority to EP10720305A priority Critical patent/EP2437853A2/fr
Publication of WO2010139716A2 publication Critical patent/WO2010139716A2/fr
Publication of WO2010139716A3 publication Critical patent/WO2010139716A3/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/98—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin
    • A61K8/987—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin of species other than mammals or birds
    • A61K8/988—Honey; Royal jelly, Propolis
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair

Definitions

  • Base of mild (preferably biodegradable) surfactants that are to contain natural care substances of plant or animal origin.
  • both the number of not necessarily necessary active ingredients are to be minimized, which cause an irritation potential on the skin or the scalp, as well as the necessary components strictly on
  • the aim of the present invention was therefore to find a way to develop cosmetic aqueous cleansers for the skin and hair containing lyophilized royal jelly.
  • a further aim was to stably solubilize the lyophilized royal jelly in the aqueous surfactant base over a long period of time, so that temperature fluctuations have no effect on the quality of the cleaning agent, in particular on its clarity or its viscosity.
  • the royal jelly-based cleaners should further enhance the effective cleansing and care of the skin and hair.
  • the skin should become more resistant to extreme weather conditions so that it becomes less dry and instead softer and more velvety.
  • the effects of sun exposure, which accelerates skin aging, should also be alleviated.
  • the skin should feel younger and fresher after nourishing cleansing.
  • the regular cleansing with the mild cleansing agents according to the invention led to an improved skin condition - the skin felt smoother and looked altogether fresher and full of elasticity.
  • the cleaning agents according to the invention are formulated as clear formulations, which are preferably highly viscous.
  • high viscosity is meant, in accordance with the present invention, a viscosity of the compositions in the range of 6,000 to 11,000 mPas, preferably 6,500 to 10,500, more preferably 7,000 to 10,000 mPas and most preferably 8,000 to 9,500 mPas (each measured with a Haake VT550 rotational viscometer; 0 C, measuring device MV, spindle MV II, 8 rpm) In order to achieve the requirement of clarity, it is particularly important to stably solubilize royal jelly in the cleaning formulation.
  • lyophilized royal jelly as available, for example, under the trade name "Gelee Royale, lyophilized, 3: 1" from Pfannenschmidt
  • lyophilized royal jelly as available, for example, under the trade name "Gelee Royale, lyophilized, 3: 1" from Pfannenschmidt
  • the total amount used of the lyophilized royal jelly (Gelee Royale, lyophilized 3: 1, Pfannenschmidt) in the detergents according to the invention is - based on their weight - 0.0001 to 3 wt .-%, preferably 0.0005 to 2.5 wt. -%, more preferably 0.001 to 2 wt .-% and in particular 0.005 to 1, 5 wt .-%.
  • the surfactant base is selected according to the invention from mild anionic and amphoteric / zwitterionic surfactants.
  • Suitable anionic surfactants in preparations according to the invention are all anionic surfactants suitable for use on the human body. These are characterized by a water-solubilizing, anionic group such as. Example, a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group having about 8 to 30 carbon atoms. In addition, glycol or polyglycol ether groups, ester, ether and amide groups and hydroxyl groups may be present in the molecule.
  • anionic surfactants are, in each case in the form of the sodium, potassium and ammonium and the mono-, di- and trialkanol- ammonium salts having 2 to 4 carbon atoms in the alkanol group, linear and branched fatty acids having 8 to 30 C. Atoms (soaps),
  • Ethercarbon Acid the formula RO- (CH2 "CH2 ⁇ ) ⁇ -CH2-COOH, in which R is a linear
  • Alkyl group having 8 to 30 C atoms and x 0 or 1 to 16,
  • Alpha-sulfofatty acid methyl esters of fatty acids having 8 to 30 carbon atoms, Alkyl sulfates and alkyl polyglycol ether sulfates of the formula RO (CH 2 -CH 2 O) x -OSO 3 H, in which R is a preferably linear alkyl group having 8 to 30 carbon atoms and x 0 or 1 to 12, mixtures of surface-active hydroxysulfonates, sulfated hydroxyalkylpolyethylene - and / or hydroxyalkylene glycol ethers, sulfonates of unsaturated fatty acids having 8 to 24 carbon atoms and 1 to 6 double bonds, esters of tartaric acid and citric acid with alcohols, the addition products of about 2- 15 molecules of ethylene oxide and / or propylene oxide to fatty alcohols having 8 to 22 C. Atoms, alkyl and / or alkenyl ether phosphates of the formula (T1),
  • R 29 is preferably an aliphatic hydrocarbon radical having 8 to 30 carbon atoms
  • R 30 is hydrogen, a radical (CH 2 CH 2 O) n R 29 or X
  • n is from 1 to 10
  • X is hydrogen, an alkali metal radical or alkaline earth metal or NR 31 R 32 R 33 R 34 , with R 31 to R 34 independently of one another represents a C 1 to C 4 hydrocarbon radical, sulfated fatty acid alkylene glycol esters of the formula (TII) R 35 CO (AlkO) n SO 3 M (TII) in the R 35 CO- for a linear or branched, aliphatic, saturated and / or unsaturated acyl radical having 6 to 22 C atoms, Alk for CH 2 CH 2 , CHCH 3 CH 2 and / or CH 2 CHCH 3 , n is from 0.5 to 5 and M is a cation, monoglyceride sulfates and monoglyceride ether sulfates of
  • Ampholytic surfactants are understood as meaning those surface-active compounds which, apart from a C 8 -C 2 ⁇ -alkyl or acyl group in the molecule, contain at least one free amino group and at least one -COOH or -SO 3 H group and which are capable of forming internal salts .
  • suitable ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids each having about 8 to 24 C atoms in the alkyl group.
  • Particularly preferred ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylaminopropionate and the
  • Particularly preferred zwitterionic / amphoteric surfactants are C 8 _i 8 -alkyl betaines, C 8 _i 8 - and / or C 8 _i 8 -Alkylamphomono- or diacetates.
  • the ampholytic / zwitterionic surfactant (s) is (are) in the cleaning agents according to the invention - based on their weight - in a total amount of 0.05 to 20% by weight, preferably from 0 , 1 to 15 wt .-%, more preferably from 0.25 to 10 wt .-% and in particular in an amount of 0.5 to 7.5 wt .-%.
  • the cleaning agents for increasing the skin-milding properties and for improving the foam quality additionally comprise at least one nonionic surfactant in an amount such that the ratio of anionic surfactant (s): amphoteric / zwitterionic (n ) Surfactant (s): nonionic surfactant (s) (8-15): (2-4): 1.
  • the alkyl or alkenyl radical R 1 can also be derived from primary alcohols having 12 to 22, preferably 12 to 14 carbon atoms.
  • the cleaning compositions of the invention based on the aforementioned surfactant combination and the lyophilized royal jelly, which is pre-solubilized in the described manner to give the surfactant mixture, imparts elasticity to the skin treated therewith.
  • the Royal Jelly also revitalizes deeper skin layers during cleansing, making the skin look younger and fresher.
  • polyalkyl siloxanes polyaryl siloxanes, polyalkylaryl siloxanes which are volatile or nonvolatile, straight chain, branched or cyclic, crosslinked or uncrosslinked;
  • Decanols, octanols, dodecadienol, decadienol, oleyl alcohol, eruca alcohol, ricinoleic alcohol, stearyl alcohol, isostearyl alcohol, cetyl alcohol, lauryl alcohol, myristyl alcohol, arachidyl alcohol, caprylic alcohol, capric alcohol, linoleyl alcohol, linolenyl alcohol and behenyl alcohol are, for example, decanol, octanolol, dodecadienol, decadienol , as well as their Guerbet alcohols, this list should have exemplary and non-limiting character.
  • wool wax alcohols such as are commercially available under the names Corona®, White Swan®, Coronet® or Fluilan®
  • the natural or synthetic waxes used according to the invention are solid paraffins or isoparaffins, carnauba waxes, beeswaxes, candelilla waxes, ozokerites, ceresin, spermaceti, sunflower wax, fruit waxes such as apple wax or citrus wax, microwaxes of PE or PP.
  • Such waxes are available, for example, from Kahl & Co., Trittau.
  • the natural and synthetic cosmetic oil bodies include, for example: liquid paraffin oils, isoparaffin oils and synthetic hydrocarbons and di-n-alkyl ethers having a total of from 12 to 36 carbon atoms, in particular 12 to 24 carbon atoms, such as di-n-octyl ether , Di-n-decyl ether, di-n-nonyl ether, di-n-undecyl ether, di-n-dodecyl ether, n-hexyl n-octyl ether, n-octyl n-decyl ether, n-decyl n-undecyl ether, n Undecyln-dodecyl ether and n-hexyl n-undecyl ether and di-tert-butyl ether, di-iso-pentyl ether, di-3-ethyldecyl ether, tert
  • fatty alcohol components in the ester oils are isopropyl alcohol, caproic alcohol, capryl alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, linolyl alcohol, linolenyl alcohol, elaeostearyl alcohol, arachyl alcohol, Gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol and their technical mixtures, for example, in the high-pressure hydrogenation of technical methyl esters based on fats and oils or aldehydes from the Roelen oxo synthesis and as a monomer fraction in the dimerization of unsaturated fatty alcohols.
  • isopropyl myristate IPM Rilanit®
  • isononanoic acid C 16-i 8 alkyl ester Cetiol SN
  • 2-ethylhexyl palmitate Cegesoft® 24
  • stearic acid 2-ethylhexyl ester Cetiol 868
  • cetyl oleate Glycerol tricaprylate
  • coconut fatty alcohol caprinate / caprylate (Cetiol® LC)
  • n-butyl stearate oleyl erucate
  • isopropyl palmitate Rosanit® IPP
  • oleyl oleate Cetiol®
  • hexyl laurate Cetiol® A
  • di-n -butyl adipate Cetiol® B
  • myristyl myristate Cetio
  • Purification preparations could be royal jelly in addition to one or more of the aforementioned
  • Component B is according to the invention ethoxylated hydrogenated castor oil with a
  • the humectants are in the inventive compositions - based on the total composition - in amounts of 0.01 to 10 wt .-%, preferably in amounts of 0.05 to 5 wt .-% and in particular in amounts of 0.1 to 3 % By weight used.
  • the clear or cloudy cleaning agent according to the invention is formulated as a hair shampoo, shower gel, shower bath, wash gel, facial cleanser, hand wash and / or bubble bath. As such, it may contain, in addition to the aforementioned mandatory and preferred optional components, other active ingredients, auxiliaries and additives which will be described below.
  • Such a polymer is contained in the commercial product Sepigel ® 305 from SEPPIC.
  • the use of this compound, which in addition to the polymer component contains a hydrocarbon mixture (C 13 -C 14 isoparaffin) and a nonionic emulsifier (laureth-7), has proved to be particularly advantageous within the scope of the teaching according to the invention.
  • Methylhydroxypropylcellulose as used for example under the trademarks Culminal ® and
  • protein hydrolysates and / or derivatives thereof can be used to increase the activity of the composition according to the invention.
  • Protein hydrolysates are product mixtures obtained by acid, alkaline or enzymatically catalyzed degradation of proteins (proteins).
  • protein hydrolysates of both vegetable and animal origin can be used.
  • Preferred according to the invention are protein hydrolysates of plant origin, eg. Soybean, almond, rice, pea, potato and wheat protein hydrolysates.
  • Such products are for example under the trademarks Gluadin ® (Cognis), diamine ® (Diamalt) ® (Inolex) and Crotein ® (Croda) available.
  • protein hydrolysates amino acid mixtures or individual amino acids obtained otherwise, such as, for example, arginine, lysine, histidine or pyrroglutamic acid, may also be used in their place.
  • derivatives of protein hydrolysates for example in the form of their fatty acid condensation products. Such products are marketed for example under the names Lamepon ® (Cognis), Gluadin ® (Cognis), Lexein ® (Inolex), Crolastin ® (Croda) or Crotein ® (Croda).
  • Vitamin B 6 pyridoxine and pyridoxamine and pyridoxal
  • Vitamin C ascorbic acid
  • the usual amount used of vitamin C is 0.1 to 3 wt .-%, based on the total agent.
  • Use in the form of palmitic acid ester, glucosides or phosphates may be preferred.
  • the use in combination with tocopherols may also be preferred.
  • Vitamin H is the compound (3aS, 4S, 6aR) -2-oxohexahydrothienol [3,4-d] - imidazole-4-valeric acid, for which, however, meanwhile, the trivial name biotin has prevailed.
  • Biotin is preferably used in amounts of from 0.0001 to 1.0% by weight, in particular in amounts of from 0.001 to 0.01% by weight.
  • Structurants such as maleic acid and lactic acid
  • Solvents and mediators such as ethanol, isopropanol, ethylene glycol, propylene glycol, glycerol and diethylene glycol, fiber-structure-improving active substances, in particular mono-, di- and oligosaccharides such as, for example, glucose, galactose, fructose, fructose and lactose,
  • Antidandruff active ingredients such as Piroctone Olamine, Zinc Omadine and Climbazole, other substances for adjusting the pH, such as ⁇ - and ⁇ -
  • Pearlescing agents such as ethylene glycol mono- and distearate and PEG-3-distearate,
  • Propellants such as propane-butane mixtures, N 2 O, dimethyl ether, CO 2 and air,
  • Viscosity regulators such as salts (NaCl).
  • a third aspect of the invention is a process for the solubilization and stabilization of lyophilized royal jelly in a surfactant cleaning formulation in which the lyophilized royal jelly is first dissolved in a mixture of water / betaine, and then added to the surfactant mixture as a homogeneous solution.
  • CAPB INCI name: Cocamidopropyl Betaine; about 40% AS; Cognis
  • compositions 2, 3 and 5 are highly viscous and clear.
  • Compositions 1 and 4 are cloudy. The cleansing of the skin with the compositions resulted in clean and well-groomed skin that felt soft and velvety.

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Zoology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention concerne un produit cosmétique de nettoyage comprenant a) au moins un tensioactif anionique doux, b) au moins un tensioactif doux amphotère/ zwitterionique, c) de la gelée royale lyophilisée et d) au moins 70% en poids d'une base aqueuse. Ces compositions sont stables et sont particulièrement appropriées au nettoyage et aux soins de la peau et des cheveux.
PCT/EP2010/057691 2009-06-05 2010-06-02 Produit cosmétique de nettoyage tensioactif contenant de la gelée royale WO2010139716A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP10720305A EP2437853A2 (fr) 2009-06-05 2010-06-02 Produit cosmétique de nettoyage tensioactif contenant de la gelée royale

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE200910026775 DE102009026775A1 (de) 2009-06-05 2009-06-05 Tensidhaltiges kosmetisches Reinigungsmittel mit Gelee Royale
DE102009026775.1 2009-06-05

Publications (2)

Publication Number Publication Date
WO2010139716A2 true WO2010139716A2 (fr) 2010-12-09
WO2010139716A3 WO2010139716A3 (fr) 2012-05-18

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PCT/EP2010/057691 WO2010139716A2 (fr) 2009-06-05 2010-06-02 Produit cosmétique de nettoyage tensioactif contenant de la gelée royale

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EP (1) EP2437853A2 (fr)
DE (1) DE102009026775A1 (fr)
WO (1) WO2010139716A2 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2821467B1 (fr) * 2012-02-24 2018-02-14 Fain-Biomedical Inc. Utilisation d' un agent régulateur lubrifiant pour les surfaces de silicone
CA3009741A1 (fr) 2015-12-31 2017-07-06 Colgate-Palmolive Company Compositions de soins personnels
FR3090373B1 (fr) * 2018-12-21 2021-08-06 Laboratoires Lea Composition comprenant un extrait d’arganier, un extrait de camelia et de la gelee royale et ses utilisations cosmetiques

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2058494A5 (en) * 1969-09-11 1971-05-28 Bevon Marie Cosmetic composns of nat or synth lyophised - royal jelly
WO2001066079A1 (fr) * 2000-03-08 2001-09-13 Bodnar Tibor Composition cosmetique et dermatologique destinee aux peaux psoriasiques, au traitement et au soin du cuir chevelu
WO2008149838A1 (fr) * 2007-06-04 2008-12-11 Kabushiki Kaisha Hayashibara Seibutsu Kagaku Kenkyujo Nouveau produit de fractionnement de la gelée royale, son procédé de fabrication et son utilisation
WO2010102928A2 (fr) * 2009-03-11 2010-09-16 Henkel Ag & Co. Kgaa Produit de traitement capillaire contenant de la gelée royale

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3723826A1 (de) 1987-07-18 1989-01-26 Henkel Kgaa Verfahren zur herstellung von alkylglykosiden
DE3833780A1 (de) 1988-10-05 1990-04-12 Henkel Kgaa Verfahren zur direkten herstellung von alkylglykosiden
DE3929973A1 (de) 1989-09-08 1991-03-14 Henkel Kgaa Haarpflegemittel
DE19736906A1 (de) 1997-08-25 1999-03-04 Henkel Kgaa Verfahren zur Herstellung von sulfatierten Fettsäurealkylenglykolestern
DE19738866A1 (de) 1997-09-05 1999-03-11 Henkel Kgaa Schaumarme Tensidmischungen mit Hydroxymischethern
DE19756454C1 (de) 1997-12-18 1999-06-17 Henkel Kgaa Verwendung von Glycerincarbonat

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2058494A5 (en) * 1969-09-11 1971-05-28 Bevon Marie Cosmetic composns of nat or synth lyophised - royal jelly
WO2001066079A1 (fr) * 2000-03-08 2001-09-13 Bodnar Tibor Composition cosmetique et dermatologique destinee aux peaux psoriasiques, au traitement et au soin du cuir chevelu
WO2008149838A1 (fr) * 2007-06-04 2008-12-11 Kabushiki Kaisha Hayashibara Seibutsu Kagaku Kenkyujo Nouveau produit de fractionnement de la gelée royale, son procédé de fabrication et son utilisation
WO2010102928A2 (fr) * 2009-03-11 2010-09-16 Henkel Ag & Co. Kgaa Produit de traitement capillaire contenant de la gelée royale

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE GNPD [Online] Mintel; Mai 2009 (2009-05), "Caring Shampoo", XP002671358, Database accession no. 1106193 *

Also Published As

Publication number Publication date
EP2437853A2 (fr) 2012-04-11
WO2010139716A3 (fr) 2012-05-18
DE102009026775A1 (de) 2010-12-09

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