WO2010056463A3 - Waste to energy process comprising biological water shift reaction using carbon monoxide produced via gasification to produce hydrogen - Google Patents

Waste to energy process comprising biological water shift reaction using carbon monoxide produced via gasification to produce hydrogen Download PDF

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Publication number
WO2010056463A3
WO2010056463A3 PCT/US2009/060813 US2009060813W WO2010056463A3 WO 2010056463 A3 WO2010056463 A3 WO 2010056463A3 US 2009060813 W US2009060813 W US 2009060813W WO 2010056463 A3 WO2010056463 A3 WO 2010056463A3
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WO
WIPO (PCT)
Prior art keywords
waste
carbon monoxide
gas
shift reaction
fermentation
Prior art date
Application number
PCT/US2009/060813
Other languages
French (fr)
Other versions
WO2010056463A2 (en
Inventor
Jens Wiik Jensen
Eric Dickman
Original Assignee
Uni-Control, Llc
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Publication date
Application filed by Uni-Control, Llc filed Critical Uni-Control, Llc
Publication of WO2010056463A2 publication Critical patent/WO2010056463A2/en
Publication of WO2010056463A3 publication Critical patent/WO2010056463A3/en

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    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P3/00Preparation of elements or inorganic compounds except carbon dioxide
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M21/00Bioreactors or fermenters specially adapted for specific uses
    • C12M21/02Photobioreactors
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M21/00Bioreactors or fermenters specially adapted for specific uses
    • C12M21/04Bioreactors or fermenters specially adapted for specific uses for producing gas, e.g. biogas
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M29/00Means for introduction, extraction or recirculation of materials, e.g. pumps
    • C12M29/18External loop; Means for reintroduction of fermented biomass or liquid percolate
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M33/00Means for introduction, transport, positioning, extraction, harvesting, peeling or sampling of biological material in or from the apparatus
    • C12M33/10Means for introduction, transport, positioning, extraction, harvesting, peeling or sampling of biological material in or from the apparatus by centrifugation ; Cyclones
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M33/00Means for introduction, transport, positioning, extraction, harvesting, peeling or sampling of biological material in or from the apparatus
    • C12M33/14Means for introduction, transport, positioning, extraction, harvesting, peeling or sampling of biological material in or from the apparatus with filters, sieves or membranes
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M39/00Means for cleaning the apparatus or avoiding unwanted deposits of microorganisms
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M43/00Combinations of bioreactors or fermenters with other apparatus
    • C12M43/06Photobioreactors combined with devices or plants for gas production different from a bioreactor of fermenter
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M43/00Combinations of bioreactors or fermenters with other apparatus
    • C12M43/08Bioreactors or fermenters combined with devices or plants for production of electricity
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0903Feed preparation
    • C10J2300/0909Drying
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/0946Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656Conversion of synthesis gas to chemicals
    • C10J2300/1665Conversion of synthesis gas to chemicals to alcohols, e.g. methanol or ethanol
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1681Integration of gasification processes with another plant or parts within the plant with biological plants, e.g. involving bacteria, algae, fungi
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

Abstract

A waste to energy method comprising: gasifying a feed material comprising waste, to produce gasifier gaseous product comprising synthesis gas and a gasifier non-gaseous product; biologically converting carbon monoxide in a fermentation feed gas to produce a fermentation product gas comprising hydrogen, wherein at least a portion of the carbon monoxide is obtained from the gasifier gaseous product; and utilizing at least a portion of the fermentation product gas comprising hydrogen as fuel. Biologically converting may comprise introducing a fermentation feed gas into a deep shaft reactor, wherein the deep shaft reactor contains a suspension comprising a liquid nutrient medium lacking a carbon source and photoactivated microorganisms capable of carrying out the water-gas shift reaction; has a vertical depth and a shaft width; comprises a downcomer and a riser separated by a divider; and comprises a headspace above a normal operating suspension fill line.
PCT/US2009/060813 2008-11-12 2009-10-15 Waste to energy process comprising biological water shift reaction using carbon monoxide produced via gasification to produce hydrogen WO2010056463A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11384808P 2008-11-12 2008-11-12
US61/113,848 2008-11-12

Publications (2)

Publication Number Publication Date
WO2010056463A2 WO2010056463A2 (en) 2010-05-20
WO2010056463A3 true WO2010056463A3 (en) 2010-07-15

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Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102154034B (en) * 2011-03-20 2013-08-14 中国烟草总公司郑州烟草研究院 Co-transformation catalytic gasification method for tobacco straw waste and coal
US8895274B2 (en) * 2011-11-28 2014-11-25 Coskata, Inc. Processes for the conversion of biomass to oxygenated organic compound, apparatus therefor and compositions produced thereby
FR3012446B1 (en) * 2013-10-24 2017-05-26 Commissariat Energie Atomique PROCESS FOR THE PRODUCTION OF AN ORGANIC PRODUCT FROM A CHARGE OF CARBON MATERIAL IMPLEMENTING GASIFICATION FOLLOWED BY FERMENTATION OF THE SYNTHESIS GAS.
CN104990306A (en) * 2015-07-13 2015-10-21 中国能源建设集团广东省电力设计研究院有限公司 Cogeneration system for generating power through biomass
CN105603002A (en) * 2016-02-18 2016-05-25 武汉锦星科技有限公司 Discharging plasma co-disposal method for sludge and kitchen waste
CN108751294B (en) * 2018-09-07 2021-08-03 滨州学院 Sewage treatment agent
CN109250883B (en) * 2018-11-27 2021-09-14 内蒙古济世源环保生物科技有限公司 Sludge treatment method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6084139A (en) * 1997-12-05 2000-07-04 Gibros Pec B.V. Method for processing waste or biomass material
US20010020044A1 (en) * 1999-06-07 2001-09-06 Whitney John P. Process for recycling heterogeneous waste
US6410283B1 (en) * 2001-06-07 2002-06-25 Endesco Clean Harbors, L.L.C. Conversion of sewage sludge into electric power
US20080014126A1 (en) * 2006-07-11 2008-01-17 Linde Aktiengesellschaft Process and apparatus for generating hydrogen and hydrogen-containing gas mixtures
US20080182298A1 (en) * 2007-01-26 2008-07-31 Andrew Eric Day Method And System For The Transformation Of Molecules,To Transform Waste Into Useful Substances And Energy

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6084139A (en) * 1997-12-05 2000-07-04 Gibros Pec B.V. Method for processing waste or biomass material
US20010020044A1 (en) * 1999-06-07 2001-09-06 Whitney John P. Process for recycling heterogeneous waste
US6410283B1 (en) * 2001-06-07 2002-06-25 Endesco Clean Harbors, L.L.C. Conversion of sewage sludge into electric power
US20080014126A1 (en) * 2006-07-11 2008-01-17 Linde Aktiengesellschaft Process and apparatus for generating hydrogen and hydrogen-containing gas mixtures
US20080182298A1 (en) * 2007-01-26 2008-07-31 Andrew Eric Day Method And System For The Transformation Of Molecules,To Transform Waste Into Useful Substances And Energy

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
KANG, W. ET AL.: "The Study on Efficient Biological Hydrogen Production Scheme from Coal Synthetic Gas", KOREAN J. BIOTECHNOL. BIOENG., vol. 15, no. 3, 2000, pages 268 - 273 *
UFFEN, R. L.: "Anaerobic growth of a Rhodopseudomonas species in the Dark wit h Carbon Monoxide as Sole Carbon and Energy Substrate", PROC. NATL. ACAD. SCI., vol. 73, no. 9, 1976, pages 3298 - 3302 *

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