WO2010052437A3 - Integrated air-separating and water-heating apparatus intended for a boiler - Google Patents
Integrated air-separating and water-heating apparatus intended for a boiler Download PDFInfo
- Publication number
- WO2010052437A3 WO2010052437A3 PCT/FR2009/052145 FR2009052145W WO2010052437A3 WO 2010052437 A3 WO2010052437 A3 WO 2010052437A3 FR 2009052145 W FR2009052145 W FR 2009052145W WO 2010052437 A3 WO2010052437 A3 WO 2010052437A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- exchanger
- boiler
- water
- air
- separating
- Prior art date
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04151—Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
- F25J3/04163—Hot end purification of the feed air
- F25J3/04169—Hot end purification of the feed air by adsorption of the impurities
- F25J3/04181—Regenerating the adsorbents
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K13/00—General layout or general methods of operation of complete plants
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K27/00—Plants for converting heat or fluid energy into mechanical energy, not otherwise provided for
- F01K27/02—Plants modified to use their waste heat, other than that of exhaust, e.g. engine-friction heat
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04D—NON-POSITIVE-DISPLACEMENT PUMPS
- F04D25/00—Pumping installations or systems
- F04D25/02—Units comprising pumps and their driving means
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04D—NON-POSITIVE-DISPLACEMENT PUMPS
- F04D29/00—Details, component parts, or accessories
- F04D29/58—Cooling; Heating; Diminishing heat transfer
- F04D29/582—Cooling; Heating; Diminishing heat transfer specially adapted for elastic fluid pumps
- F04D29/5826—Cooling at least part of the working fluid in a heat exchanger
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
- F22B1/00—Methods of steam generation characterised by form of heating method
- F22B1/02—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
- F22B1/18—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04012—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling
- F25J3/04018—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling of main feed air
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04109—Arrangements of compressors and /or their drivers
- F25J3/04115—Arrangements of compressors and /or their drivers characterised by the type of prime driver, e.g. hot gas expander
- F25J3/04121—Steam turbine as the prime mechanical driver
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04151—Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
- F25J3/04157—Afterstage cooling and so-called "pre-cooling" of the feed air upstream the air purification unit and main heat exchange line
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04521—Coupling of the air fractionation unit to an air gas-consuming unit, so-called integrated processes
- F25J3/04612—Heat exchange integration with process streams, e.g. from the air gas consuming unit
- F25J3/04618—Heat exchange integration with process streams, e.g. from the air gas consuming unit for cooling an air stream fed to the air fractionation unit
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04763—Start-up or control of the process; Details of the apparatus used
- F25J3/04769—Operation, control and regulation of the process; Instrumentation within the process
- F25J3/04812—Different modes, i.e. "runs" of operation
- F25J3/04824—Stopping of the process, e.g. defrosting or deriming; Back-up procedures
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2205/00—Processes or apparatus using other separation and/or other processing means
- F25J2205/60—Processes or apparatus using other separation and/or other processing means using adsorption on solid adsorbents, e.g. by temperature-swing adsorption [TSA] at the hot or cold end
- F25J2205/66—Regenerating the adsorption vessel, e.g. kind of reactivation gas
- F25J2205/70—Heating the adsorption vessel
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
- F25J2230/06—Adiabatic compressor, i.e. without interstage cooling
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2240/00—Processes or apparatus involving steps for expanding of process streams
- F25J2240/70—Steam turbine, e.g. used in a Rankine cycle
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Combustion & Propulsion (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Separation By Low-Temperature Treatments (AREA)
- Physical Water Treatments (AREA)
- Air Supply (AREA)
Abstract
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200980144751.8A CN102209873B (en) | 2008-11-10 | 2009-11-06 | Integrated air-separating and water-heating apparatus intended for a boiler |
US13/128,173 US20110214452A1 (en) | 2008-11-10 | 2009-11-06 | Integrated Air-Separating And Water-Heating Apparatus Intended For A Boiler |
EP09768157A EP2344822A2 (en) | 2008-11-10 | 2009-11-06 | Integrated air-separating and water-heating apparatus intended for a boiler |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0857631 | 2008-11-10 | ||
FR0857631A FR2938320B1 (en) | 2008-11-10 | 2008-11-10 | INTEGRATED AIR SEPARATION AND WATER HEATING SYSTEM FOR A BOILER |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2010052437A2 WO2010052437A2 (en) | 2010-05-14 |
WO2010052437A3 true WO2010052437A3 (en) | 2011-06-03 |
Family
ID=40842757
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2009/052145 WO2010052437A2 (en) | 2008-11-10 | 2009-11-06 | Integrated air-separating and water-heating apparatus intended for a boiler |
Country Status (6)
Country | Link |
---|---|
US (1) | US20110214452A1 (en) |
EP (1) | EP2344822A2 (en) |
KR (1) | KR20110086591A (en) |
CN (1) | CN102209873B (en) |
FR (1) | FR2938320B1 (en) |
WO (1) | WO2010052437A2 (en) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2957408B1 (en) * | 2010-03-09 | 2015-07-17 | Air Liquide | METHOD AND APPARATUS FOR HEATING AN AIR GAS FROM AN AIR SEPARATION APPARATUS |
FR2984474A1 (en) * | 2011-12-16 | 2013-06-21 | Air Liquide | Method for separation of air by cryogenic distillation, involves heating gaseous nitrogen flow, and sending part of condensed steam under specific pressure and at specific temperature to mix with air upstream of compressor stage |
DE102012001606A1 (en) | 2012-01-26 | 2013-08-01 | Linde Aktiengesellschaft | Method and device for air separation and steam generation in a combined system |
EP2620732A1 (en) | 2012-01-26 | 2013-07-31 | Linde Aktiengesellschaft | Method and device for air separation and steam generation in a combined system |
DE102012004048A1 (en) | 2012-03-02 | 2013-09-05 | Linde Ag | Method and device for air separation and steam generation in a combined system |
CN103234213B (en) * | 2013-04-27 | 2015-10-14 | 东南大学 | A kind of method of oxygen-enriched combusting Btu utilization and device |
WO2020160844A1 (en) | 2019-02-07 | 2020-08-13 | Linde Gmbh | Method and arrangement for providing a first method product and a second method product |
US20210300788A1 (en) * | 2020-03-29 | 2021-09-30 | Chaac Holdings, Inc. | Atmospheric water and power generation compression apparatus, system and method |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4461154A (en) * | 1981-06-18 | 1984-07-24 | Air Products And Chemicals, Inc. | Method and apparatus for compressing gas |
EP0532429A1 (en) * | 1991-09-13 | 1993-03-17 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Gas refrigeration process in an air gas exploitational installation and the installation itself |
JPH11182263A (en) * | 1997-10-17 | 1999-07-06 | Hitachi Ltd | Gas turbine power plant |
DE19837251C1 (en) * | 1998-08-17 | 2000-02-10 | Siemens Ag | Fossil-fuel burning gas and steam-turbine installation for power generation |
US20040069016A1 (en) * | 2000-10-30 | 2004-04-15 | Alain Guillard | Process and installation for separation of air by cryogenic distillation integrated with an associated process |
US20060137393A1 (en) * | 2004-12-27 | 2006-06-29 | Bot Patrick L | Integrated air compression, cooling, and purification unit and process |
WO2006131283A2 (en) * | 2005-06-08 | 2006-12-14 | Man Turbo Ag | Steam generation plant and method for operation and retrofitting of a steam generation plant |
WO2009010931A2 (en) * | 2007-07-19 | 2009-01-22 | L'air Liquide-Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Thermal integration of oxygen plants |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4934148A (en) * | 1989-05-12 | 1990-06-19 | Union Carbide Corporation | Dry, high purity nitrogen production process and system |
DE10161584A1 (en) * | 2001-12-14 | 2003-06-26 | Linde Ag | Device and method for generating gaseous oxygen under increased pressure |
-
2008
- 2008-11-10 FR FR0857631A patent/FR2938320B1/en not_active Expired - Fee Related
-
2009
- 2009-11-06 EP EP09768157A patent/EP2344822A2/en not_active Withdrawn
- 2009-11-06 WO PCT/FR2009/052145 patent/WO2010052437A2/en active Application Filing
- 2009-11-06 CN CN200980144751.8A patent/CN102209873B/en not_active Expired - Fee Related
- 2009-11-06 US US13/128,173 patent/US20110214452A1/en not_active Abandoned
- 2009-11-06 KR KR1020117013073A patent/KR20110086591A/en not_active Application Discontinuation
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4461154A (en) * | 1981-06-18 | 1984-07-24 | Air Products And Chemicals, Inc. | Method and apparatus for compressing gas |
EP0532429A1 (en) * | 1991-09-13 | 1993-03-17 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Gas refrigeration process in an air gas exploitational installation and the installation itself |
JPH11182263A (en) * | 1997-10-17 | 1999-07-06 | Hitachi Ltd | Gas turbine power plant |
DE19837251C1 (en) * | 1998-08-17 | 2000-02-10 | Siemens Ag | Fossil-fuel burning gas and steam-turbine installation for power generation |
US20040069016A1 (en) * | 2000-10-30 | 2004-04-15 | Alain Guillard | Process and installation for separation of air by cryogenic distillation integrated with an associated process |
US20060137393A1 (en) * | 2004-12-27 | 2006-06-29 | Bot Patrick L | Integrated air compression, cooling, and purification unit and process |
WO2006131283A2 (en) * | 2005-06-08 | 2006-12-14 | Man Turbo Ag | Steam generation plant and method for operation and retrofitting of a steam generation plant |
WO2009010931A2 (en) * | 2007-07-19 | 2009-01-22 | L'air Liquide-Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Thermal integration of oxygen plants |
Also Published As
Publication number | Publication date |
---|---|
CN102209873A (en) | 2011-10-05 |
FR2938320A1 (en) | 2010-05-14 |
EP2344822A2 (en) | 2011-07-20 |
US20110214452A1 (en) | 2011-09-08 |
FR2938320B1 (en) | 2013-03-15 |
KR20110086591A (en) | 2011-07-28 |
WO2010052437A2 (en) | 2010-05-14 |
CN102209873B (en) | 2014-02-26 |
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