WO2010015331A3 - Catalyst composition for use in transesterification - Google Patents

Catalyst composition for use in transesterification Download PDF

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Publication number
WO2010015331A3
WO2010015331A3 PCT/EP2009/005334 EP2009005334W WO2010015331A3 WO 2010015331 A3 WO2010015331 A3 WO 2010015331A3 EP 2009005334 W EP2009005334 W EP 2009005334W WO 2010015331 A3 WO2010015331 A3 WO 2010015331A3
Authority
WO
WIPO (PCT)
Prior art keywords
transesterification
catalyst composition
relates
catalyst
fats
Prior art date
Application number
PCT/EP2009/005334
Other languages
German (de)
French (fr)
Other versions
WO2010015331A2 (en
Inventor
Stefan Grasser
Leslaw Mleczko
Wulf Dietrich
Ren WU
Original Assignee
Bayer Technology Services Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Technology Services Gmbh filed Critical Bayer Technology Services Gmbh
Publication of WO2010015331A2 publication Critical patent/WO2010015331A2/en
Publication of WO2010015331A3 publication Critical patent/WO2010015331A3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/003—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J35/647—
    • B01J35/66—
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Abstract

The invention relates to a catalyst and to a method for producing the same. The invention also relates to the use thereof for the transesterification of fats and oils to fatty acid alkyl esters on a commercial scale for the combustion in diesel engines.
PCT/EP2009/005334 2008-08-04 2009-07-23 Catalyst composition for use in transesterification WO2010015331A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102008036295A DE102008036295A1 (en) 2008-08-04 2008-08-04 Catalyst composition for transesterification
DE102008036295.6 2008-08-04

Publications (2)

Publication Number Publication Date
WO2010015331A2 WO2010015331A2 (en) 2010-02-11
WO2010015331A3 true WO2010015331A3 (en) 2010-06-10

Family

ID=41213244

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2009/005334 WO2010015331A2 (en) 2008-08-04 2009-07-23 Catalyst composition for use in transesterification

Country Status (2)

Country Link
DE (1) DE102008036295A1 (en)
WO (1) WO2010015331A2 (en)

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4413064A (en) * 1981-10-13 1983-11-01 Gulf Research & Development Company Fluid bed catalyst for synthesis gas conversion and utilization thereof for preparation of diesel fuel
DE3319171A1 (en) * 1982-05-27 1983-12-01 Snamprogetti S.p.A., 20121 Milano METHOD FOR ISOMERIZING OLEFINS
US5116800A (en) * 1990-12-11 1992-05-26 Allied-Signal Inc. High durability and exhuast catalyst with low hydrogen sulfide emissions
EP0599287A1 (en) * 1992-11-25 1994-06-01 Nippon Shokubai Co., Ltd. A process for preparing dialkyl carbonates
US5350879A (en) * 1993-11-17 1994-09-27 Uop Transesterification using metal oxide solid solutions as the basic catalyst
US6537945B2 (en) * 2000-03-17 2003-03-25 Energy International Corporation Highly active fischer-tropsch catalyst having increased thermal stability
WO2006088254A2 (en) * 2005-02-21 2006-08-24 Nippon Shokubai Co., Ltd. Method for producing fatty acid alkyl esters and/or glycerin
CN1836772A (en) * 2005-03-23 2006-09-27 中国石油化工股份有限公司 Load type calcium oxide catalyst, its preparation method and uses
CN1966142A (en) * 2006-11-20 2007-05-23 华中科技大学 Catalyst for synthesizing bio diesel oil and its preparation method
WO2009077161A2 (en) * 2007-12-19 2009-06-25 Bayer Technology Services Gmbh Method for producing fatty acid alkyl esters

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2752242B1 (en) 1996-08-08 1998-10-16 Inst Francais Du Petrole PROCESS FOR THE MANUFACTURE OF ESTERS FROM VEGETABLE OR ANIMAL OILS AND ALCOHOLS
WO1998056747A1 (en) 1997-06-10 1998-12-17 Universidad Politecnica De Valencia Process and catalysts for the selective production of esters of fatty acids
FR2811984B1 (en) 2000-07-19 2004-02-06 Pharmascience Lab PROCESS FOR THE PREPARATION OF A FATTY BODY ESTER AND ITS USE IN THE PHARMACEUTICAL, COSMETIC OR FOOD FIELDS
ITMI20042163A1 (en) 2004-11-11 2005-02-11 Aser S R L PROCESS FOR THE PRODUCTION OF ESTERS FROM VEGETABLE OILS OR ANIMAL FATS WITH THE USE OF HETEROGENEOUS CATALYSTS
WO2006127839A2 (en) 2005-05-25 2006-11-30 Long Island Technical Associates, Llc Process for production of esters from olefin-containing hydrocarbon streams and vegetable or animal oils
BRPI0504759A (en) 2005-09-01 2007-06-12 Univ Rio De Janeiro catalytic process for transesterification of vegetable oils and fats using basic solid catalysts
DE102007061872A1 (en) 2007-12-19 2009-06-25 Bayer Technology Services Gmbh Producing fatty acid alkyl esters useful as diesel fuel comprises esterifying free fatty acids, transesterifying triglycerides and separating glycerol using a hydrophobic membrane

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4413064A (en) * 1981-10-13 1983-11-01 Gulf Research & Development Company Fluid bed catalyst for synthesis gas conversion and utilization thereof for preparation of diesel fuel
DE3319171A1 (en) * 1982-05-27 1983-12-01 Snamprogetti S.p.A., 20121 Milano METHOD FOR ISOMERIZING OLEFINS
US5116800A (en) * 1990-12-11 1992-05-26 Allied-Signal Inc. High durability and exhuast catalyst with low hydrogen sulfide emissions
EP0599287A1 (en) * 1992-11-25 1994-06-01 Nippon Shokubai Co., Ltd. A process for preparing dialkyl carbonates
US5350879A (en) * 1993-11-17 1994-09-27 Uop Transesterification using metal oxide solid solutions as the basic catalyst
US6537945B2 (en) * 2000-03-17 2003-03-25 Energy International Corporation Highly active fischer-tropsch catalyst having increased thermal stability
WO2006088254A2 (en) * 2005-02-21 2006-08-24 Nippon Shokubai Co., Ltd. Method for producing fatty acid alkyl esters and/or glycerin
CN1836772A (en) * 2005-03-23 2006-09-27 中国石油化工股份有限公司 Load type calcium oxide catalyst, its preparation method and uses
CN1966142A (en) * 2006-11-20 2007-05-23 华中科技大学 Catalyst for synthesizing bio diesel oil and its preparation method
WO2009077161A2 (en) * 2007-12-19 2009-06-25 Bayer Technology Services Gmbh Method for producing fatty acid alkyl esters

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
BABU N S ET AL: "Room-temperature transesterification of edible and nonedible oils using a heterogeneous strong basic Mg/La catalyst", ENERGY AND FUELS MAY/JUNE 2008 AMERICAN CHEMICAL SOCIETY US, vol. 22, no. 3, May 2008 (2008-05-01), pages 1965 - 1971, XP002565059 *

Also Published As

Publication number Publication date
WO2010015331A2 (en) 2010-02-11
DE102008036295A1 (en) 2010-02-11

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