WO2010011924A3 - Monomers derived from alpha-or beta-amino-e-caprolactam and polymers made therefrom - Google Patents
Monomers derived from alpha-or beta-amino-e-caprolactam and polymers made therefrom Download PDFInfo
- Publication number
- WO2010011924A3 WO2010011924A3 PCT/US2009/051689 US2009051689W WO2010011924A3 WO 2010011924 A3 WO2010011924 A3 WO 2010011924A3 US 2009051689 W US2009051689 W US 2009051689W WO 2010011924 A3 WO2010011924 A3 WO 2010011924A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- caprolactam
- amino
- beta
- alpha
- made therefrom
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D223/00—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom
- C07D223/02—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings
- C07D223/06—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D223/12—Nitrogen atoms not forming part of a nitro radical
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
- C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
- C07D403/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
- C08G69/16—Preparatory processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
- C08G69/22—Beta-lactams
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/60—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Polyamides (AREA)
Abstract
The invention relates to monomers that are derived from α- and β-amino-ε-caprolactam and to polymers (e.g., homopolymers and copolymers) prepared from these monomers. In many embodiments, the α-amino-ε-caprolactam or β-amino-ε-caprolactam is manufactured from a renewable starting material, for example, biomass. In one aspect, the invention relates to polyamide polymers that are prepared by the polymerization of α-amido-ε-caprolactam monomer, β-amido-ε-caprolactam monomer, or a mixture thereof. In some embodiments, the monomers have the structures shown in Structure I and the polyamide polymers of the invention have the structure as shown in Structure II.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13583008P | 2008-07-24 | 2008-07-24 | |
US61/135,830 | 2008-07-24 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2010011924A2 WO2010011924A2 (en) | 2010-01-28 |
WO2010011924A3 true WO2010011924A3 (en) | 2010-07-01 |
Family
ID=41354002
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2009/051689 WO2010011924A2 (en) | 2008-07-24 | 2009-07-24 | Monomers derived from alpha-or beta-amino-e-caprolactam and polymers made therefrom |
Country Status (1)
Country | Link |
---|---|
WO (1) | WO2010011924A2 (en) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20130126944A (en) * | 2010-12-03 | 2013-11-21 | 바스프 에스이 | Process for crosslinking polyamides |
US20120142887A1 (en) * | 2010-12-03 | 2012-06-07 | Basf Se | Crosslinked polyamides |
CN104558588B (en) * | 2013-10-22 | 2017-09-29 | 中国石油化工股份有限公司 | A kind of nylon polymer and preparation method thereof |
CN107973878B (en) * | 2016-10-25 | 2020-06-09 | 中国石油化工股份有限公司 | Copolymer, preparation method and application thereof, and blending material |
US10513515B2 (en) | 2017-08-25 | 2019-12-24 | Biotheryx, Inc. | Ether compounds and uses thereof |
CN109721695B (en) * | 2017-10-27 | 2021-03-16 | 中国石油化工股份有限公司 | Block copolymer, preparation method and application thereof, and nylon/PPS (polyphenylene sulfide) blended material |
WO2020023782A1 (en) | 2018-07-27 | 2020-01-30 | Biotheryx, Inc. | Bifunctional compounds as cdk modulators |
EP4143329A2 (en) | 2020-04-28 | 2023-03-08 | Anwita Biosciences, Inc. | Interleukin-2 polypeptides and fusion proteins thereof, and their pharmaceutical compositions and therapeutic applications |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3651023A (en) * | 1968-07-02 | 1972-03-21 | Stamicarbon | Preparation of polyamides with special properties |
EP0013553A1 (en) * | 1979-01-05 | 1980-07-23 | Toray Industries, Inc. | Polyamides and a process for their preparation from a substituted epsilon-caprolactam |
US20070149777A1 (en) * | 2004-06-10 | 2007-06-28 | Board Of Trustees Of Michigan State University | Synthesis of caprolactam from lysine |
-
2009
- 2009-07-24 WO PCT/US2009/051689 patent/WO2010011924A2/en active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3651023A (en) * | 1968-07-02 | 1972-03-21 | Stamicarbon | Preparation of polyamides with special properties |
EP0013553A1 (en) * | 1979-01-05 | 1980-07-23 | Toray Industries, Inc. | Polyamides and a process for their preparation from a substituted epsilon-caprolactam |
US20070149777A1 (en) * | 2004-06-10 | 2007-06-28 | Board Of Trustees Of Michigan State University | Synthesis of caprolactam from lysine |
Also Published As
Publication number | Publication date |
---|---|
WO2010011924A2 (en) | 2010-01-28 |
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