WO2010011924A3 - Monomers derived from alpha-or beta-amino-e-caprolactam and polymers made therefrom - Google Patents

Monomers derived from alpha-or beta-amino-e-caprolactam and polymers made therefrom Download PDF

Info

Publication number
WO2010011924A3
WO2010011924A3 PCT/US2009/051689 US2009051689W WO2010011924A3 WO 2010011924 A3 WO2010011924 A3 WO 2010011924A3 US 2009051689 W US2009051689 W US 2009051689W WO 2010011924 A3 WO2010011924 A3 WO 2010011924A3
Authority
WO
WIPO (PCT)
Prior art keywords
caprolactam
amino
beta
alpha
made therefrom
Prior art date
Application number
PCT/US2009/051689
Other languages
French (fr)
Other versions
WO2010011924A2 (en
Inventor
Douglas A. Wicks
Original Assignee
Draths Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Draths Corporation filed Critical Draths Corporation
Publication of WO2010011924A2 publication Critical patent/WO2010011924A2/en
Publication of WO2010011924A3 publication Critical patent/WO2010011924A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
    • C08G69/14—Lactams
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D223/00—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom
    • C07D223/02—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D223/06—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D223/12—Nitrogen atoms not forming part of a nitro radical
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
    • C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
    • C07D403/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
    • C08G69/14—Lactams
    • C08G69/16—Preparatory processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
    • C08G69/14—Lactams
    • C08G69/22—Beta-lactams
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/60—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Polyamides (AREA)

Abstract

The invention relates to monomers that are derived from α- and β-amino-ε-caprolactam and to polymers (e.g., homopolymers and copolymers) prepared from these monomers. In many embodiments, the α-amino-ε-caprolactam or β-amino-ε-caprolactam is manufactured from a renewable starting material, for example, biomass. In one aspect, the invention relates to polyamide polymers that are prepared by the polymerization of α-amido-ε-caprolactam monomer, β-amido-ε-caprolactam monomer, or a mixture thereof. In some embodiments, the monomers have the structures shown in Structure I and the polyamide polymers of the invention have the structure as shown in Structure II.
PCT/US2009/051689 2008-07-24 2009-07-24 Monomers derived from alpha-or beta-amino-e-caprolactam and polymers made therefrom WO2010011924A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13583008P 2008-07-24 2008-07-24
US61/135,830 2008-07-24

Publications (2)

Publication Number Publication Date
WO2010011924A2 WO2010011924A2 (en) 2010-01-28
WO2010011924A3 true WO2010011924A3 (en) 2010-07-01

Family

ID=41354002

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2009/051689 WO2010011924A2 (en) 2008-07-24 2009-07-24 Monomers derived from alpha-or beta-amino-e-caprolactam and polymers made therefrom

Country Status (1)

Country Link
WO (1) WO2010011924A2 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20130126944A (en) * 2010-12-03 2013-11-21 바스프 에스이 Process for crosslinking polyamides
US20120142887A1 (en) * 2010-12-03 2012-06-07 Basf Se Crosslinked polyamides
CN104558588B (en) * 2013-10-22 2017-09-29 中国石油化工股份有限公司 A kind of nylon polymer and preparation method thereof
CN107973878B (en) * 2016-10-25 2020-06-09 中国石油化工股份有限公司 Copolymer, preparation method and application thereof, and blending material
US10513515B2 (en) 2017-08-25 2019-12-24 Biotheryx, Inc. Ether compounds and uses thereof
CN109721695B (en) * 2017-10-27 2021-03-16 中国石油化工股份有限公司 Block copolymer, preparation method and application thereof, and nylon/PPS (polyphenylene sulfide) blended material
WO2020023782A1 (en) 2018-07-27 2020-01-30 Biotheryx, Inc. Bifunctional compounds as cdk modulators
EP4143329A2 (en) 2020-04-28 2023-03-08 Anwita Biosciences, Inc. Interleukin-2 polypeptides and fusion proteins thereof, and their pharmaceutical compositions and therapeutic applications

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3651023A (en) * 1968-07-02 1972-03-21 Stamicarbon Preparation of polyamides with special properties
EP0013553A1 (en) * 1979-01-05 1980-07-23 Toray Industries, Inc. Polyamides and a process for their preparation from a substituted epsilon-caprolactam
US20070149777A1 (en) * 2004-06-10 2007-06-28 Board Of Trustees Of Michigan State University Synthesis of caprolactam from lysine

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3651023A (en) * 1968-07-02 1972-03-21 Stamicarbon Preparation of polyamides with special properties
EP0013553A1 (en) * 1979-01-05 1980-07-23 Toray Industries, Inc. Polyamides and a process for their preparation from a substituted epsilon-caprolactam
US20070149777A1 (en) * 2004-06-10 2007-06-28 Board Of Trustees Of Michigan State University Synthesis of caprolactam from lysine

Also Published As

Publication number Publication date
WO2010011924A2 (en) 2010-01-28

Similar Documents

Publication Publication Date Title
WO2010011924A3 (en) Monomers derived from alpha-or beta-amino-e-caprolactam and polymers made therefrom
WO2007143054A3 (en) Preparation of polyamide block copolymers
WO2009086490A3 (en) Hydroxyaryl functionalized polymers
GB201015397D0 (en) Polymerisation method
WO2010040944A3 (en) Block copolymer derived from renewable materials and method for making such a block copolymer
WO2008019217A3 (en) Stereoregular romp polymers
WO2008045534A3 (en) Novel curcumin and tetrahydrocurcumin derivatives
TW200704649A (en) Water-absorbing polymer structures based upon renewable raw materials and process for their production
WO2011148177A3 (en) Membrane enhanced polymer synthesis
WO2011014022A3 (en) Metallocene compound, catalyst composition comprising the same, and olefinic polymers produced using the same
WO2009137715A3 (en) Versatile blodegradable elastic polymers featured with dual crosslinking mechanism for biomedical applications
WO2013043796A3 (en) Modified polyethylene compositions
IN2012DN02219A (en)
WO2011019474A3 (en) Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom
WO2011002830A3 (en) Polymers functionalized with hydroxyl group-containing diphenylethylene
WO2011002994A3 (en) Method of making hydroxyaryl-functionalized interpolymer by free radical initiated polymerization
WO2009118538A3 (en) Carbohydrate lactone polymers
WO2008042289A3 (en) Polymer synthetic technique
WO2008006912A3 (en) Polymer
WO2011153109A3 (en) Hydroxyl group-containing methylstyrene and polymers incorporating same
WO2013043573A3 (en) Highly functionalized resin blends
WO2007045634A3 (en) Biocidal polymers
MX350299B (en) Polymer made from maleic acid, allyl ether, and vinyl acetate, production of said polymer, and use of said polymer.
WO2011019142A3 (en) Binder having good adhesion for a secondary battery
WO2008027267A3 (en) Production of random blockcopolymers via high melting polymer segment metathesis

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 09790803

Country of ref document: EP

Kind code of ref document: A2

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 09790803

Country of ref document: EP

Kind code of ref document: A2