WO2010003357A1 - Novel synthetic liquefied gas fuel and preparation method thereof - Google Patents
Novel synthetic liquefied gas fuel and preparation method thereof Download PDFInfo
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- WO2010003357A1 WO2010003357A1 PCT/CN2009/072642 CN2009072642W WO2010003357A1 WO 2010003357 A1 WO2010003357 A1 WO 2010003357A1 CN 2009072642 W CN2009072642 W CN 2009072642W WO 2010003357 A1 WO2010003357 A1 WO 2010003357A1
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- liquefied gas
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/12—Liquefied petroleum gas
Definitions
- the present invention relates to a novel synthetic liquefied gas fuel, and more particularly to a novel synthetic liquefied gas fuel and a preparation method thereof.
- Liquefied gas fuel is also commonly known as liquefied gas. It is widely used in household and industrial applications. However, liquefied gas is a dangerous gas. When the combustion is not complete, the carbon monoxide content in the exhaust gas is high. If the indoor ventilation is poor, it will cause Carbon monoxide poisoning in human body, especially in winter, poses a certain threat to people's precious lives. This kind of injury case has not been reported at home and abroad; Moreover, the existing liquefied gas has a low burning rate, and the furnace is easy to use during use. Carbon deposits and peers will also lead to high energy use costs. As the world's energy sources continue to be tight, the manufacturing costs and sales prices of liquefied gases are also greatly increased, which has a certain impact on people's lives.
- the object of the present invention is to propose a novel synthetic liquefied gas fuel which has the advantages of easy raw material acquisition, sufficient combustion, high safety of use, low environmental impact and low cost of use.
- a new type of synthetic liquefied gas fuel which is composed of one of n-butyl sulfonium, butyl sulfonium, and hexamethylene hydride, or a mixture thereof as a main raw material, and is rapidly mixed with a by-product by a Gaussian strong magnetization reaction to change n-butyl hydrazine
- the auxiliary material comprises a nano metal catalyst conversion agent and a carrier thereof, and the nano metal catalyst conversion agent is a methanol metal-based nano metal catalyst combustion auxiliary additive and dimethyl ether.
- the carrier is selected from one of dimethyl ether, petroleum ether or a mixture thereof.
- a method of preparing the above synthetic liquefied gas fuel comprising the steps of:
- the invention can utilize the by-products of the general petrochemical refinery, namely, butadiene, butadiene, and hexamidine as main raw materials, not only rational use of energy, but also environmental protection.
- the primary and secondary raw materials are magnetized by the Gaussian strong magnetizer in the production, It is fully reacted with the auxiliary material catalyst conversion agent in the reaction tank to completely change the physical properties of the main raw material, and synthesize a new type of liquefied gas with high quality, low cost, environmental protection, safety, high efficiency and energy saving.
- the use of a Gaussian magnetron mainly utilizes its positive hydrogen effect:
- a hydrocarbon is affected by a strong magnetic field, where the hydrogen ion is converted into a so-called positive hydrogen by a strong magnetic field, the nucleus between the two hydrogen ions is reversed by the original , (the mutual attraction is stable, it is not easy to combine with oxygen combustion), and it turns into positive rotation, and hydrogen ions and hydrogen ions repel each other, and the contact surface with oxygen is large, showing a lively state, and it is easy to combine with oxygen to burn, effectively Improve the fuel burning rate, save fuel by 5 to 20%, and reduce HC (hydrocarbon) pollution by about 90%, and CO (-carbon oxide) by more than 80%.
- the synthetic liquefied gas fuel of the present invention has the following beneficial effects as compared with the existing liquefied gas fuel:
- the new gas fuel of the present invention has a higher burning rate and is at least 15 to 30% higher than the existing natural gas, and its thermal efficiency is also 20% higher than the existing natural gas;
- the new gas fuel of the present invention is a high-efficiency fuel and is an economical, safe and safe fuel due to complete combustion and a calorific value of about 3000 calories higher than that of natural gas.
- the novel gas fuel of the invention belongs to an environmentally friendly product and is harmless to the human body. Because it is fully fuel-efficient and has no residual liquid, it is easy to use, does not need to change usage habits and replace the stove, and is ignited by a igniter. Adding fuel is convenient, it can completely replace the existing gas, in addition to household use, it is also an excellent industrial fuel.
- Figure 1 is a flow chart showing the preparation of a synthetic liquefied gas fuel of the present invention.
- the temperature in 5 is controlled at 10 ⁇ 55 degrees Celsius; the reaction pressure is controlled at 5 ⁇ 10pa; and the reaction is continued for 8 ⁇ 15Hr.
- the daytime can be controlled at 12 ⁇ 15Hr.
- the supplementary carrier in the propidium, the auxiliary material tank 3, and the auxiliary material tank 4 in the main raw material tank 1 is magnetized by the Gaussian strong magnetizers 8, 9, 10, and then sent by the metering and conveying devices 14, 12, and 13 Into the mixed reaction tank 5, the jet vortex is rapidly mixed, and under the strict control of the microcomputer process controller 7, the volume ratio of the propidium, the catalyst conversion agent and the supplementary carrier is 7:2:1;
- the reaction tank 5 is controlled by the temperature and pressure sensors on the reaction tank and the microcomputer process controller 7.
- the temperature is controlled at 20 ⁇ 40 degrees Celsius; the reaction pressure is controlled at 6 ⁇ 8pa; and the reaction is continued for 8 ⁇ 15Hr.
- the daytime can be controlled at 2 ⁇ 15Hr;
- the product obtained after the reaction is controlled to a pressure of 8 Pa by the microcomputer process controller 7, and then continuously allowed to stand for 10 to 15 Hr, preferably 12 Hr, in the sampling valve (A) 16 of the mixing reaction tank 5, sampling The valve (B) 17 and the sampling valve (C) 18 are identical in inspection of the finished product, that is, the novel synthetic liquefied gas fuel of the present invention is obtained; and the obtained synthetic liquefied gas fuel is sent to the finished product storage tank by the metering and conveying device 15. 6 storage, which is the finished product of the invention.
- a methanol-based nano metal catalyst combustion-supporting additive is added to the catalyst-supporting additive tank 2, and is sent to the auxiliary material storage tank 3 filled with the quantitative carrier dimethyl ether according to the dosage metering and conveying device 11, and mixed.
- the positive-sintering in the main raw material tank 1, the catalytic converter in the auxiliary raw material tank 3, and the supplementary carrier in the auxiliary raw material tank 4 are magnetized by a Gaussian-strength magnetizer, and then introduced into the mixing reaction tank 5 to rapidly eject the vortex.
- the volume ratio of the positive enthalpy, the catalyst conversion agent and the supplementary carrier is 7:2:1; the temperature and pressure sensor and the microcomputer process controller passing through the reaction tank 7 control, the temperature in the reaction tank 5 is controlled at 25 ⁇ 45 degrees Celsius; the reaction pressure is controlled at 6 ⁇ 8pa; and the reaction is continued for 8 ⁇ 15Hr, in order to obtain better results, the daytime can be controlled at 12 ⁇ 15Hr , the pressure of the reaction tank is controlled to 8 Pa by the microcomputer process controller 7, and then the static standing is 10 to 15 Hr, preferably 12 Hr, and the sampling valve (A) 16 and the sampling valve (B) 17 in the mixing reaction tank 5 are The sampling valve (C) 18 extracts the finished product to be consistent, that is, obtains the novel liquefied gas fuel according to the present invention; and the prepared synthetic liquefied gas fuel is transferred to the finished product storage tank 6 by the metering and conveying device 15, which is the present invention.
- the nano metal catalyst conversion agent is a methanol-based nano metal gold catalyst combustion additive and dimethyl ether, similarly, the nano metal, It may be a nano metal platinum, a nano metal gold or a nano metal magnesium, etc., and the purpose of using the above nano metal is to make the combustion value of the produced fuel higher.
- the main raw material and the auxiliary raw material are mixed by the jet vortex in the mixing reaction tank 5. Not only the mixing speed is fast, but also the mixing of the same is more sufficient, which greatly accelerates the preparation process of combustion and improves production efficiency.
- the use of the auxiliary material tank 4 as a container for replenishing the petroleum ether of the carrier makes it more convenient to control the addition of the carrier petroleum ether, and by adjusting the amount of petroleum ether added, the specific gravity of the produced fuel is made lighter. The fuel is more easily vaporized after use, thus avoiding the risk of explosion.
Abstract
A novel synthetic liquefied gas fuel comprises one or a mixture of normal butane, propane and butane and normal hexane as main raw material, which is prepared by changing physical properties of normal butane, propane and butane and normal hexane through rapid reaction of the main raw material with a secondary raw material after gauss strong magnetization of the main raw material. The secondary raw material comprises a nanometer metal catalyst converting agent and a supporting agent thereof. The nanometer metal catalyst converting agent is obtained by mixing a nanometer metal combustion-supporting catalyst which uses methanol as a base agent with dimethyl ether. The supporting agent is one or a mixture of dimethyl ether and petroleum ether. A preparation method of the synthetic liquefied gas fuel is provided too. The synthetic liquefied gas fuel has the characteristics of complete burning, high security, low cost, energy saving and environment-friendly etc.
Description
说明书 一种新型合成液化气体燃料及其制备方法 Novel synthetic liquefied gas fuel and preparation method thereof
[I] 技术领域 [I] Technical field
[2] 本发明涉及一种新型合成液化气体燃料， 特别涉及一种新型合成液化气体燃 料及其制备方法。 [2] The present invention relates to a novel synthetic liquefied gas fuel, and more particularly to a novel synthetic liquefied gas fuel and a preparation method thereof.
[3] 背景技术 [3] Background Art
[4] 液化气体燃料也俗称液化气， 广泛应用于家庭及工业用途， 但液化气属于危 险气体， 当燃烧不完全吋， 废气中的一氧化碳含量较高， 如果室内通风不良的 情况下， 会导致人体一氧化碳中毒， 尤其冬天更常发生， 给人们宝贵的生命带 来一定威胁， 这种伤害案例在国内外不吋有报道； 而且， 现有液化气的燃烧率 低， 在使用过程中炉具容易积炭， 同吋也会导致能源的利用成本高； 在世界能 源持续紧张的同吋， 液化气的制造成本、 销售价格也大幅度提高， 给人们的生 活带来一定影响。 [4] Liquefied gas fuel is also commonly known as liquefied gas. It is widely used in household and industrial applications. However, liquefied gas is a dangerous gas. When the combustion is not complete, the carbon monoxide content in the exhaust gas is high. If the indoor ventilation is poor, it will cause Carbon monoxide poisoning in human body, especially in winter, poses a certain threat to people's precious lives. This kind of injury case has not been reported at home and abroad; Moreover, the existing liquefied gas has a low burning rate, and the furnace is easy to use during use. Carbon deposits and peers will also lead to high energy use costs. As the world's energy sources continue to be tight, the manufacturing costs and sales prices of liquefied gases are also greatly increased, which has a certain impact on people's lives.
[5] 发明内容 [5] Summary of the invention
[6] 为了克服现有技术的不足， 本发明的目的在于提出一种新型的合成液化气体 燃料， 具有原料取得容易及燃烧充分、 使用安全性高、 对环境影响小及使用成 本低等特点。 [6] In order to overcome the deficiencies of the prior art, the object of the present invention is to propose a novel synthetic liquefied gas fuel which has the advantages of easy raw material acquisition, sufficient combustion, high safety of use, low environmental impact and low cost of use.
[7] 本发明所釆用的技术方案是： [7] The technical solution adopted by the present invention is:
[8] —种新型合成液化气体燃料， 它是由正丁垸、 丙丁垸、 正己垸中的一种或者 其混合物作为主原料， 经高斯强力磁化后与副原料快速混合反应变更正丁垸、 丙丁垸、 正己垸物性制备而成， 所述副原料包括纳米金属触媒转换剂及其载剂 ， 纳米金属触媒转换剂是以甲醇为基剂的纳米金属触媒助燃添加剂与二甲醚调 配而成， 所述载剂选自二甲醚、 石油醚中的一种或其混合物。 [8] A new type of synthetic liquefied gas fuel, which is composed of one of n-butyl sulfonium, butyl sulfonium, and hexamethylene hydride, or a mixture thereof as a main raw material, and is rapidly mixed with a by-product by a Gaussian strong magnetization reaction to change n-butyl hydrazine, The auxiliary material comprises a nano metal catalyst conversion agent and a carrier thereof, and the nano metal catalyst conversion agent is a methanol metal-based nano metal catalyst combustion auxiliary additive and dimethyl ether. The carrier is selected from one of dimethyl ether, petroleum ether or a mixture thereof.
[9] 一种制备上述合成液化气体燃料的方法， 它包括以下步骤： [9] A method of preparing the above synthetic liquefied gas fuel, comprising the steps of:
[10] 1)将主原料加入主原料槽； 将触媒助燃添加剂加入触媒助燃添加剂槽中； [10] 1) adding the main raw material to the main raw material tank; adding the catalytic combustion additive to the catalytic combustion additive tank;
[I I] 2)触媒助燃添加剂与载剂在副原料槽混合组成触媒转换剂； [I I] 2) the catalyst auxiliary additive and the carrier are mixed in the auxiliary material tank to form a catalyst conversion agent;
[12] 3)将上述主原料与触媒转换剂分别经过高斯强力磁化后加入反应器中， 在反应
器中以喷射涡流方式快速搅拌均匀， 使主原料与纳米金属金触媒转换剂快速充 分反应， 所述反应温度控制在 10~55°C; 反应压力控制在 5~10pa; 反应吋间控制 在 8~15 Hr; [12] 3) The above main raw material and the catalytic converter are respectively magnetized by Gaussian magnetization and then added to the reactor. The device is rapidly stirred and evenly sprayed by the vortex method to rapidly and fully react the main raw material with the nano metal gold catalyst converter. The reaction temperature is controlled at 10 to 55 ° C; the reaction pressure is controlled at 5 to 10 Pa; ~15 Hr;
[13] 4)将上述反应得到的产物在反应器中静置 10~15Hr， 反应器的压力控制在为 8~1 Opa, 所述经静置稳定产出新型合成液化气体燃料。 [13] 4) The product obtained by the above reaction is allowed to stand in the reactor for 10 to 15 Hr, and the pressure of the reactor is controlled to be 8 to 1 Opa, which is statically stabilized to produce a novel synthetic liquefied gas fuel.
[14] 本发明可以利用一般石化炼油厂的副产品一丁烧、 丙丁烧、 正己垸为主要原 料， 不仅合理利用能源， 而且环保， 在生产吋首先将主副原料经过高斯强力磁 化器磁化后， 在反应槽中与副原料触媒转换剂充分反应合成， 彻底改变了主原 料的物理性质， 合成一种新型的质优、 价廉、 环保、 安全、 高效节能的液化燃 气。 使用高斯强力磁化器主要利用其正氢效应： 当碳氢化合物受到强力磁场影 响吋， 其中氢离子受强大磁场转化成所谓的正氢， 此吋两个氢离子之间的原子 核由原本的逆向旋转， （相互吸引呈现安定状态， 不易与氧结合燃烧)， 转为正向 旋转， 而氢离子与氢离子间相互排斥， 与氧接触面変大， 呈现活泼状态， 极易 与氧结合燃烧， 有效的改善燃料的燃烧率， 可节省燃料 5~20%， 更可使废气 HC( 碳氢化合物)污染降低约 90%， 而 CO(—氧化碳)降低 80%以上。 [14] The invention can utilize the by-products of the general petrochemical refinery, namely, butadiene, butadiene, and hexamidine as main raw materials, not only rational use of energy, but also environmental protection. After the primary and secondary raw materials are magnetized by the Gaussian strong magnetizer in the production, It is fully reacted with the auxiliary material catalyst conversion agent in the reaction tank to completely change the physical properties of the main raw material, and synthesize a new type of liquefied gas with high quality, low cost, environmental protection, safety, high efficiency and energy saving. The use of a Gaussian magnetron mainly utilizes its positive hydrogen effect: When a hydrocarbon is affected by a strong magnetic field, where the hydrogen ion is converted into a so-called positive hydrogen by a strong magnetic field, the nucleus between the two hydrogen ions is reversed by the original , (the mutual attraction is stable, it is not easy to combine with oxygen combustion), and it turns into positive rotation, and hydrogen ions and hydrogen ions repel each other, and the contact surface with oxygen is large, showing a lively state, and it is easy to combine with oxygen to burn, effectively Improve the fuel burning rate, save fuel by 5 to 20%, and reduce HC (hydrocarbon) pollution by about 90%, and CO (-carbon oxide) by more than 80%.
[15] 本发明合成液化气体燃料与现有液化气燃料相比， 具有以下有益效果： [15] The synthetic liquefied gas fuel of the present invention has the following beneficial effects as compared with the existing liquefied gas fuel:
[16] 1.本发明这种新燃气燃料， 燃烧率较高， 比现有天然气至少高出 15~30%， 而同 吋它的热效也比现有天然气高 20%以上； [16] 1. The new gas fuel of the present invention has a higher burning rate and is at least 15 to 30% higher than the existing natural gas, and its thermal efficiency is also 20% higher than the existing natural gas;
[17] 2.本发明这种新燃气燃料由于燃烧完全， 热值较一般天然气高约 3000大卡， 是 一种高效能燃料， 是一种经济、 安心、 安全燃料 [17] 2. The new gas fuel of the present invention is a high-efficiency fuel and is an economical, safe and safe fuel due to complete combustion and a calorific value of about 3000 calories higher than that of natural gas.
[18] 3.本发明这种新燃气燃料属于环保产品， 对人体无害， 因燃烧充分较节省燃料 且无残液， 其使用简便， 不用改变使用习惯及更换炉具， 用点火枪点火， 添加 燃料方便， 可完全取代现有的燃气， 除了供家庭使用外， 亦是优良的工业用燃 料 [18] 3. The novel gas fuel of the invention belongs to an environmentally friendly product and is harmless to the human body. Because it is fully fuel-efficient and has no residual liquid, it is easy to use, does not need to change usage habits and replace the stove, and is ignited by a igniter. Adding fuel is convenient, it can completely replace the existing gas, in addition to household use, it is also an excellent industrial fuel.
[19] 附图说明 [19] BRIEF DESCRIPTION OF THE DRAWINGS
[20] 下面结合附图和实施例对本发明进一步说明。 The invention will now be further described with reference to the drawings and embodiments.
[21] 图 1是本发明合成液化气体燃料的制备流程图。 BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a flow chart showing the preparation of a synthetic liquefied gas fuel of the present invention.
[22] 具体实施方式
[23] 实施例 1 : [22] Specific implementation [23] Example 1:
[24] 在主原料槽 1中加入丁垸， 该丁垸来自炼油厂的副产品； [24] Adding Ding in the main feed tank 1, which is a by-product of the refinery;
[25] 在触媒助燃添加剂槽 2中加入以甲醇为基剂的纳米金属触媒助燃添加剂， 根 据剂量用计量输送装置 11传送至已填加入定量载剂二甲醚之副原料储存槽 3， 混 合组成触媒转换剂， 将上述主原料槽 1中的丁垸和副原料槽 3中的触媒转换剂分 别经高斯强力磁化器 8、 9磁化后利用计量输送装置 14、 12送入混合反应槽 5中以 喷射涡流快速混合， 并在微电脑过程控制器 7的控制下， 使丁垸比触媒转换剂的 体积比为 3~6:1。 [25] Adding a methanol-based nano metal catalyst combustion-supporting additive to the catalyst-supporting additive tank 2, and transferring it to the auxiliary material storage tank 3 filled with the quantitative carrier dimethyl ether according to the dosage metering and conveying device 11, mixed composition The catalyst conversion agent, the catalyst conversion agent in the main raw material tank 1 and the auxiliary material conversion tank 3 are magnetized by the Gaussian strong magnetizers 8, 9 respectively, and then sent to the mixing reaction tank 5 by the metering and conveying devices 14, 12 to The jet vortex is rapidly mixed, and under the control of the microcomputer process controller 7, the volume ratio of the butadiene to the catalyst converter is 3-6:1.
[26] 经过反应槽 5上的温度和压力传感器和微电脑过程控制器 7的控制， 使反应槽 [26] After the temperature and pressure sensors on the reaction tank 5 and the microcomputer process controller 7 are controlled, the reaction tank is made
5中的温度控制在 10~55摄氏度； 反应压力控制在 5~10pa; 并使反应持续 8~15Hr ， 为获得更好的效果， 可将吋间控制在 12~15Hr。 The temperature in 5 is controlled at 10~55 degrees Celsius; the reaction pressure is controlled at 5~10pa; and the reaction is continued for 8~15Hr. For better results, the daytime can be controlled at 12~15Hr.
[27] 将反应后得到的产物稳定静置， 通过微电脑过程控制器 7将压力控制在 8~10p a, 再持续 10~15Hr， 最好静置 12Hr， 在混合反应槽 5的取样阀 (A)16、 取样阀 (B)l 7、 取样阀 (C)18提取成品检验一致， 即得到本发明所述的新型合成液化气体燃料 ； 将制得的合成液化气体燃料用计量输送装置 15传送至制成品储存槽 6储存， 即 为本发明的成品。 [27] The product obtained after the reaction is stably allowed to stand, and the pressure is controlled by the microcomputer process controller 7 at 8 to 10 p a, and then for 10 to 15 Hr, preferably at 12 Hr, in the sampling valve of the mixing reaction tank 5 (A) 16、Sampling valve (B)7, sampling valve (C)18 extracting the finished product is consistent, that is, obtaining the novel synthetic liquefied gas fuel according to the present invention; and the obtained synthetic liquefied gas fuel is sent to the metering conveying device 15 to The finished product storage tank 6 is stored, which is the finished product of the present invention.
[28] 实施例 2: [28] Example 2:
[29] 在主原料槽 1中加入丙丁垸， 该丙丁垸来自炼油厂的副产品； [29] adding propanthene to the main feed tank 1, the by-product from the refinery;
[30] 在触媒助燃添加剂槽 2中加入以甲醇为基剂的纳米金属触媒助燃添加剂， 根 据剂量用计量输送装置 11传送至已填加入定量载剂二甲醚之副原料储存槽 3， 混 合组成触媒转换剂， 其中载剂二甲醚比石油醚的体积比为 4~10:1， 进一步可将其 体积比控制在 4:1 ; [30] Adding a methanol-based nano metal catalyst combustion-supporting additive to the catalyst-assisted combustion additive tank 2, and transferring it to the auxiliary material storage tank 3 filled with the quantitative carrier dimethyl ether according to the dosage metering and conveying device 11, mixed composition The catalyst conversion agent, wherein the volume ratio of the carrier dimethyl ether to petroleum ether is 4 to 10:1, and the volume ratio thereof can be further controlled to 4:1;
[31] 在副原料槽 4中加入补充载剂石油醚； [31] adding a supplementary carrier petroleum ether to the auxiliary feed tank 4;
[32] 将上述主原料槽 1中的丙丁垸、 副原料槽 3和副原料槽 4中的补充载剂经高斯 强力磁化器 8、 9、 10磁化后利用计量输送装置 14、 12和 13送入混合反应槽 5中以 喷射涡流快速混合， 并在微电脑过程控制器 7的严格控制下， 使其中丙丁垸、 触 媒转换剂、 补充载剂的体积比为 7:2:1 ; [32] The supplementary carrier in the propidium, the auxiliary material tank 3, and the auxiliary material tank 4 in the main raw material tank 1 is magnetized by the Gaussian strong magnetizers 8, 9, 10, and then sent by the metering and conveying devices 14, 12, and 13 Into the mixed reaction tank 5, the jet vortex is rapidly mixed, and under the strict control of the microcomputer process controller 7, the volume ratio of the propidium, the catalyst conversion agent and the supplementary carrier is 7:2:1;
[33] 经过反应槽上的温度和压力传感器和微电脑过程控制器 7的控制， 使反应槽 5
中的温度控制在 20~40摄氏度； 反应压力控制在 6~8pa; 并使反应持续 8~15Hr， 为获得更好的效果， 可将吋间控制在 2~15Hr; [33] The reaction tank 5 is controlled by the temperature and pressure sensors on the reaction tank and the microcomputer process controller 7. The temperature is controlled at 20~40 degrees Celsius; the reaction pressure is controlled at 6~8pa; and the reaction is continued for 8~15Hr. For better effect, the daytime can be controlled at 2~15Hr;
[34] 将反应后得到的产物， 通过微电脑过程控制器 7将压力控制在 8pa， 再持续稳 定静置 10~15Hr， 最好是 12Hr， 在混合反应槽 5的取样阀 (A)16、 取样阀 (B)17、 取 样阀 (C)18提取成品检验一致， 即得到本发明所述的新型合成液化气体燃料； 将 制得的合成液化气体燃料用计量输送装置 15传送至制成品储存槽 6储存， 即为本 发明的成品。 [34] The product obtained after the reaction is controlled to a pressure of 8 Pa by the microcomputer process controller 7, and then continuously allowed to stand for 10 to 15 Hr, preferably 12 Hr, in the sampling valve (A) 16 of the mixing reaction tank 5, sampling The valve (B) 17 and the sampling valve (C) 18 are identical in inspection of the finished product, that is, the novel synthetic liquefied gas fuel of the present invention is obtained; and the obtained synthetic liquefied gas fuel is sent to the finished product storage tank by the metering and conveying device 15. 6 storage, which is the finished product of the invention.
[35] 实施例 3. [35] Example 3.
[36] 在主原料槽 1中加入正己垸， 该正己垸来自炼油厂的副产品； [36] Adding hexane to the main feed tank 1, which is a by-product of the refinery;
[37] 在触媒助燃添加剂槽 2中加入以甲醇为基剂的纳米金属触媒助燃添加剂， 根 据剂量用计量输送装置 11传送至已填加入定量载剂二甲醚的副原料储存槽 3， 混 合组成触媒转换剂； [37] a methanol-based nano metal catalyst combustion-supporting additive is added to the catalyst-supporting additive tank 2, and is sent to the auxiliary material storage tank 3 filled with the quantitative carrier dimethyl ether according to the dosage metering and conveying device 11, and mixed. Catalyst conversion agent;
[38] 在副原料槽 4中加入补充载剂石油醚； [38] adding a supplementary carrier petroleum ether to the auxiliary feed tank 4;
[39] 将上述主原料槽 1中的正己烧、 副原料槽 3的触媒转换剂和副原料槽 4中的补 充载剂经高斯强力磁化器磁化后通入混合反应槽 5中以喷射涡流快速混合， 并在 微电脑过程控制器 7的控制下， 使其中的正己垸、 触媒转换剂、 补充载剂的体积 比为 7:2:1 ; 经过反应槽上的温度和压力传感器和微电脑过程控制器 7的控制， 使 反应槽 5中的温度控制在 25~45摄氏度； 反应压力控制在 6~8pa; 并使反应持续 8~ 15Hr, 为获得更好的效果， 可将吋间控制在 12~15Hr， 通过微电脑过程控制器 7 将反应槽的压力控制在 8pa， 再持续稳定静置 10~15Hr， 最好是 12Hr， 在混合反 应槽 5的取样阀 (A)16、 取样阀 (B)17、 取样阀 (C)18提取成品检验一致， 即得到本 发明所述的新型液化气体燃料； 将制得的合成液化气体燃料用计量输送装置 15 传送至制成品储存槽 6储存， 即为本发明的成品。 [39] The positive-sintering in the main raw material tank 1, the catalytic converter in the auxiliary raw material tank 3, and the supplementary carrier in the auxiliary raw material tank 4 are magnetized by a Gaussian-strength magnetizer, and then introduced into the mixing reaction tank 5 to rapidly eject the vortex. Mixing, and under the control of the microcomputer process controller 7, the volume ratio of the positive enthalpy, the catalyst conversion agent and the supplementary carrier is 7:2:1; the temperature and pressure sensor and the microcomputer process controller passing through the reaction tank 7 control, the temperature in the reaction tank 5 is controlled at 25 ~ 45 degrees Celsius; the reaction pressure is controlled at 6 ~ 8pa; and the reaction is continued for 8 ~ 15Hr, in order to obtain better results, the daytime can be controlled at 12 ~ 15Hr , the pressure of the reaction tank is controlled to 8 Pa by the microcomputer process controller 7, and then the static standing is 10 to 15 Hr, preferably 12 Hr, and the sampling valve (A) 16 and the sampling valve (B) 17 in the mixing reaction tank 5 are The sampling valve (C) 18 extracts the finished product to be consistent, that is, obtains the novel liquefied gas fuel according to the present invention; and the prepared synthetic liquefied gas fuel is transferred to the finished product storage tank 6 by the metering and conveying device 15, which is the present invention. Success .
[40] 上述实施例 1、 2、 3中， 所述纳米金属触媒转换剂是以甲醇为基剂的纳米金 属金触媒助燃添加剂与二甲醚调配而成， 类似的， 所述纳米金属， 也可以是纳 米金属铂、 纳米金属金或者纳米金属镁等， 使用上述纳米金属其目的是使生产 出来的燃料的燃烧值更高。 [40] In the above embodiments 1, 2, and 3, the nano metal catalyst conversion agent is a methanol-based nano metal gold catalyst combustion additive and dimethyl ether, similarly, the nano metal, It may be a nano metal platinum, a nano metal gold or a nano metal magnesium, etc., and the purpose of using the above nano metal is to make the combustion value of the produced fuel higher.
[41] 上述实施例 1、 2、 3中， 主原料与副原料在混合反应槽 5中以喷射涡流混合，
不仅混合速度快， 同吋混合更加充分， 大大加快了燃烧的制备过程， 提高生产 效率。 [41] In the above embodiments 1, 2, and 3, the main raw material and the auxiliary raw material are mixed by the jet vortex in the mixing reaction tank 5. Not only the mixing speed is fast, but also the mixing of the same is more sufficient, which greatly accelerates the preparation process of combustion and improves production efficiency.
上述实施例 2、 3中， 利用副原料槽 4作为补充载剂石油醚的容器， 使得在添 加载剂石油醚吋控制更加方便， 通过调节石油醚的添加量， 令生产出来的燃料 比重更轻， 燃料在使用吋更容易气化， 从而避免出现燃爆的危险。
In the above Examples 2 and 3, the use of the auxiliary material tank 4 as a container for replenishing the petroleum ether of the carrier makes it more convenient to control the addition of the carrier petroleum ether, and by adjusting the amount of petroleum ether added, the specific gravity of the produced fuel is made lighter. The fuel is more easily vaporized after use, thus avoiding the risk of explosion.
Claims
[1] 一种新型合成液化气体燃料， 其特征在于： 它是由正丁垸、 丙丁垸、 正己 垸中的一种或者其混合物作为主原料， 经高斯强力磁化后与副原料快速混 合反应变更正丁垸、 丙丁垸、 正己垸物性制备而成， 所述副原料包括纳米 金属触媒转换剂及其载剂， 纳米金属触媒转换剂是以甲醇为基剂的纳米金 属触媒助燃添加剂与二甲醚调配而成， 所述载剂选自二甲醚、 石油醚中的 一种或其混合物。 [1] A novel synthetic liquefied gas fuel characterized in that it is composed of one of n-butyl fluorene, butyl sulfonium, and hexamethylene hydride or a mixture thereof as a main raw material, and is rapidly mixed with a by-feed material after being highly magnetized by Gaussian. The raw materials include n-butyl hydride, butyl sulfonium, and hexamidine. The auxiliary material includes a nano metal catalyst conversion agent and a carrier thereof, and the nano metal catalyst conversion agent is a methanol-based nano metal catalyst combustion auxiliary additive and dimethyl ether. Formulated as a carrier selected from the group consisting of dimethyl ether, petroleum ether or a mixture thereof.
[2] 根据权利要求 1所述的一种新型合成液化气体燃料， 其特征在于： 所述纳米 金属触媒助燃添加剂是纳米金属金触媒助燃添加剂。 [2] A novel synthetic liquefied gas fuel according to claim 1, wherein: said nanometal catalyst combustion-supporting additive is a nano metal gold catalyst combustion-supporting additive.
[3] 根据权利要求 1所述的一种新型合成液化气体燃料， 其特征在于： 所述正丁 垸、 丙丁垸、 正己垸取材于原油分馏或石油裂解。 [3] A novel synthetic liquefied gas fuel according to claim 1, wherein: the n-butyl sulfonium, the butyl sulfonium, and the hexamethylene hydride are obtained from crude oil fractionation or petroleum cracking.
[4] 根据权利要求 1所述的一种新型合成液化气体燃料， 其特征在于： 所述载剂 为二甲醚、 石油醚的混合物， 其中二甲醚与石油醚的体积比为 4~10:1。 [4] A novel synthetic liquefied gas fuel according to claim 1, wherein: the carrier is a mixture of dimethyl ether and petroleum ether, wherein the volume ratio of dimethyl ether to petroleum ether is 4 to 10 :1.
[5] 根据权利要求 4所述的一种新型合成液化气体燃料， 其特征在于： 所述二甲 醚与石油醚的体积比为 4:1。 [5] A novel synthetic liquefied gas fuel according to claim 4, wherein the volume ratio of said dimethyl ether to petroleum ether is 4:1.
[6] 根据权利要求 1所述的一种新型合成液化气体燃料， 其特征在于： 所述主原 料和触媒转换剂的体积比为 3~6： 1。 [6] A novel synthetic liquefied gas fuel according to claim 1, wherein the volume ratio of the main raw material to the catalytic converter is from 3 to 6:1.
[7] 一种制备权利要求 1至 6中任意一项合成液化气体燃料的方法， 其特征在于 它包括以下步骤： [7] A method of producing a synthetic liquefied gas fuel according to any one of claims 1 to 6, characterized in that it comprises the steps of:
1)将主原料加入主原料槽； 将触媒助燃添加剂加入触媒助燃添加剂槽中； 1) adding the main raw material to the main raw material tank; adding the catalytic combustion auxiliary additive to the catalytic combustion additive tank;
2)触媒助燃添加剂与载剂在副原料槽混合组成触媒转换剂；2) the catalyst auxiliary additive and the carrier are mixed in the auxiliary material tank to form a catalyst conversion agent;
3)将上述主原料与触媒转换剂分别经过高斯强力磁化后加入反应器中， 在 反应器中以喷射涡流方式快速搅拌均匀， 使主原料与纳米金属触媒转换剂 快速充分反应， 所述反应温度控制在 10~55°C; 反应压力控制在 5~10pa; 反 应吋间控制在 8~15 Hr; 3) The main raw material and the catalytic converter are respectively magnetized by Gaussian magnetization, and then added to the reactor, and rapidly stirred uniformly in the reactor by jet vortex to rapidly and fully react the main raw material with the nano metal catalyst converter. Control at 10~55 °C; reaction pressure is controlled at 5~10pa; reaction time is controlled at 8~15 Hr;
4)将上述反应得到的产物在反应器中静置 10~15Hr， 反应器的压力控制在 8~ 10pa, 经静置稳定产出新型合成液化气体燃料。 4) The product obtained by the above reaction is allowed to stand in the reactor for 10~15Hr, the pressure of the reactor is controlled at 8~10pa, and the new synthetic liquefied gas fuel is stably produced by standing.
[8] 根据权利要求 7所述的新型合成液化汽体燃料的制备方法， 其特征在于： 在
步骤 3) 中， 加入反应器中的物料除了分别经过高斯强力磁化后的主原料与 触媒转换剂外， 还有经过高斯强力磁化后直接加入的补充载剂石油醚。 [8] The method for preparing a novel synthetic liquefied vapor fuel according to claim 7, wherein: In the step 3), the materials added to the reactor are in addition to the main raw material and the catalyst conversion agent which are respectively subjected to Gaussian magnetization, and the supplementary carrier petroleum ether directly added after the Gaussian strong magnetization.
[9] 根据权利要求 7所述的新型合成液化汽体燃料的制备方法， 其特征在于： 在 步骤 3) 中， 所述反应吋间控制在 12~15Hr。 [9] The method for preparing a novel synthetic liquefied vapor fuel according to claim 7, wherein in the step 3), the reaction time is controlled at 12 to 15 Hr.
[10] 根据权利要求 7所述的新型合成液化汽体燃料的制备方法， 其特征在于： 在 步骤 4) 中， 所述静置吋间为 12Hr。
[10] The method for preparing a novel synthetic liquefied vapor fuel according to claim 7, wherein in the step 4), the stationary day is 12Hr.
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| US5059743A (en) * | 1989-04-17 | 1991-10-22 | Shinfuji Kogyo Kabushiki Kaisha | Treatment of hydrocarbon fuel |
| DE19604060A1 (en) * | 1996-02-05 | 1997-08-07 | Reika Elektronik Karin Walch | Treating liquid or gaseous media by magnetic fields |
| JP2005126653A (en) * | 2003-10-20 | 2005-05-19 | Unylec:Kk | Oil modifier and modified oil composition |
| US20070180760A1 (en) * | 2006-02-09 | 2007-08-09 | Headwaters Nanokinetix, Inc. | Crystalline nanocatalysts for improving combustion properties of fuels and fuel compositions incorporating such catalysts |
| CN101245274A (en) * | 2008-04-01 | 2008-08-20 | 萧国华 | Novel liquid gas fuel and manufacture method thereof |
| CN101319156A (en) * | 2008-07-07 | 2008-12-10 | 蔡宗榕 | Novel synthetic liquid gas fuel and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5059743A (en) * | 1989-04-17 | 1991-10-22 | Shinfuji Kogyo Kabushiki Kaisha | Treatment of hydrocarbon fuel |
| DE19604060A1 (en) * | 1996-02-05 | 1997-08-07 | Reika Elektronik Karin Walch | Treating liquid or gaseous media by magnetic fields |
| JP2005126653A (en) * | 2003-10-20 | 2005-05-19 | Unylec:Kk | Oil modifier and modified oil composition |
| US20070180760A1 (en) * | 2006-02-09 | 2007-08-09 | Headwaters Nanokinetix, Inc. | Crystalline nanocatalysts for improving combustion properties of fuels and fuel compositions incorporating such catalysts |
| CN101245274A (en) * | 2008-04-01 | 2008-08-20 | 萧国华 | Novel liquid gas fuel and manufacture method thereof |
| CN101319156A (en) * | 2008-07-07 | 2008-12-10 | 蔡宗榕 | Novel synthetic liquid gas fuel and preparation method thereof |
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