WO2010002486A3 - Continuous diesel soot control with minimal back pressure penality using conventional flow substrates and active direct soot oxidation catalyst disposed thereon - Google Patents

Continuous diesel soot control with minimal back pressure penality using conventional flow substrates and active direct soot oxidation catalyst disposed thereon Download PDF

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Publication number
WO2010002486A3
WO2010002486A3 PCT/US2009/038403 US2009038403W WO2010002486A3 WO 2010002486 A3 WO2010002486 A3 WO 2010002486A3 US 2009038403 W US2009038403 W US 2009038403W WO 2010002486 A3 WO2010002486 A3 WO 2010002486A3
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WO
WIPO (PCT)
Prior art keywords
penality
back pressure
oxidation catalyst
soot
conventional flow
Prior art date
Application number
PCT/US2009/038403
Other languages
French (fr)
Other versions
WO2010002486A2 (en
Inventor
Barry W. L. Southward
John G. Nunan
Original Assignee
Umicore Ag& Co.Kg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US12/240,170 external-priority patent/US20090246109A1/en
Priority claimed from US12/363,329 external-priority patent/US20100196217A1/en
Priority claimed from US12/363,310 external-priority patent/US9403151B2/en
Application filed by Umicore Ag& Co.Kg filed Critical Umicore Ag& Co.Kg
Priority to JP2011502059A priority Critical patent/JP2011515221A/en
Priority to CN200980113778.0A priority patent/CN102006923B/en
Priority to EP09773938.7A priority patent/EP2259870A4/en
Priority to KR1020167030330A priority patent/KR20160129913A/en
Priority to BRPI0909377A priority patent/BRPI0909377A2/en
Publication of WO2010002486A2 publication Critical patent/WO2010002486A2/en
Publication of WO2010002486A3 publication Critical patent/WO2010002486A3/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9445Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
    • B01D53/945Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404Removing only nitrogen compounds
    • B01D53/9409Nitrogen oxides
    • B01D53/9413Processes characterised by a specific catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/944Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
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    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
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    • B01J37/02Impregnation, coating or precipitation
    • B01J37/024Multiple impregnation or coating
    • B01J37/0244Coatings comprising several layers
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01J37/02Impregnation, coating or precipitation
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    • B01J37/0246Coatings comprising a zeolite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01J37/03Precipitation; Co-precipitation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/033Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices
    • F01N3/035Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices with catalytic reactors, e.g. catalysed diesel particulate filters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2803Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
    • F01N3/2825Ceramics
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01D2255/102Platinum group metals
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01DSEPARATION
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    • B01D2255/102Platinum group metals
    • B01D2255/1021Platinum
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01DSEPARATION
    • B01D2255/00Catalysts
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    • B01D2255/1023Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/202Alkali metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
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    • B01D2255/207Transition metals
    • B01D2255/20761Copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01D2255/407Zr-Ce mixed oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/50Zeolites
    • B01D2255/502Beta zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/90Physical characteristics of catalysts
    • B01D2255/908O2-storage component incorporated in the catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/90Physical characteristics of catalysts
    • B01D2255/91NOx-storage component incorporated in the catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/40Nitrogen compounds
    • B01D2257/404Nitrogen oxides other than dinitrogen oxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/01Engine exhaust gases
    • B01D2258/012Diesel engines and lean burn gasoline engines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
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    • B01D2259/4566Gas separation or purification devices adapted for specific applications for use in transportation means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
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    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/894Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
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    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007Zeolite Beta
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027Powdering
    • B01J37/0036Grinding
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2330/00Structure of catalyst support or particle filter
    • F01N2330/06Ceramic, e.g. monoliths
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2570/00Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
    • F01N2570/16Oxygen
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

Abstract

There is disclosed high cell density or tortuous/turbulent flow through monolithic catalyst devices for the direct catalytic, and (semi) continuous oxidation of diesel particulate matter. The catalysts relate to OIC/OS materials having a stable cubic crystal structure, and most especially to promoted OIC/OS wherein the promotion is achieved by the post-synthetic introduction of non-precious metals via a basic (alkaline) exchange process. The catalyst may additionally be promoted by the introduction of Precious Group Metals.
PCT/US2009/038403 2008-03-27 2009-03-26 Continuous diesel soot control with minimal back pressure penality using conventional flow substrates and active direct soot oxidation catalyst disposed thereon WO2010002486A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2011502059A JP2011515221A (en) 2008-03-27 2009-03-26 Continuous diesel soot control with minimum back pressure penalty using conventional flow substrate and active direct soot oxidation catalyst placed on it
CN200980113778.0A CN102006923B (en) 2008-03-27 2009-03-26 Continuous diesel soot control with minimal back pressure penality using conventional flow substrates and active direct soot oxidation catalyst disposed thereon
EP09773938.7A EP2259870A4 (en) 2008-03-27 2009-03-26 Continuous diesel soot control with minimal back pressure penality using conventional flow substrates and active direct soot oxidation catalyst disposed thereon
KR1020167030330A KR20160129913A (en) 2008-03-27 2009-03-26 Continuous diesel soot control with minimal back pressure penality using conventional flow substrates and active direct soot oxidation catalyst disposed thereon
BRPI0909377A BRPI0909377A2 (en) 2008-03-27 2009-03-26 continuous diesel soot control with minimal back pressure loss using conventional flow substrates and active direct soot oxidation catalyst disposed on them

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
US3987908P 2008-03-27 2008-03-27
US61/039,879 2008-03-27
US12/240,170 2008-09-29
US12/240,170 US20090246109A1 (en) 2008-03-27 2008-09-29 Solid solutions and methods of making the same
US12/363,310 2009-01-30
US12/363,329 US20100196217A1 (en) 2009-01-30 2009-01-30 Application of basic exchange os materials for lower temperature catalytic oxidation of particulates
US12/363,329 2009-01-30
US12/363,310 US9403151B2 (en) 2009-01-30 2009-01-30 Basic exchange for enhanced redox OS materials for emission control applications

Publications (2)

Publication Number Publication Date
WO2010002486A2 WO2010002486A2 (en) 2010-01-07
WO2010002486A3 true WO2010002486A3 (en) 2010-03-25

Family

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Family Applications (4)

Application Number Title Priority Date Filing Date
PCT/US2009/038403 WO2010002486A2 (en) 2008-03-27 2009-03-26 Continuous diesel soot control with minimal back pressure penality using conventional flow substrates and active direct soot oxidation catalyst disposed thereon
PCT/EP2009/002263 WO2009118190A2 (en) 2008-03-27 2009-03-27 Application of basic exchange os materials for lower temperature catalytic oxidation of particulates
PCT/EP2009/002261 WO2009118188A1 (en) 2008-03-27 2009-03-27 Solid solutions and methods of making the same
PCT/EP2009/002262 WO2009118189A1 (en) 2008-03-27 2009-03-27 Basic exchange for enhanced redox os materials for emission control applications

Family Applications After (3)

Application Number Title Priority Date Filing Date
PCT/EP2009/002263 WO2009118190A2 (en) 2008-03-27 2009-03-27 Application of basic exchange os materials for lower temperature catalytic oxidation of particulates
PCT/EP2009/002261 WO2009118188A1 (en) 2008-03-27 2009-03-27 Solid solutions and methods of making the same
PCT/EP2009/002262 WO2009118189A1 (en) 2008-03-27 2009-03-27 Basic exchange for enhanced redox os materials for emission control applications

Country Status (6)

Country Link
EP (3) EP2259870A4 (en)
JP (3) JP2011515221A (en)
KR (3) KR20160129913A (en)
CN (3) CN102006923B (en)
BR (3) BRPI0909377A2 (en)
WO (4) WO2010002486A2 (en)

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US9403151B2 (en) 2009-01-30 2016-08-02 Umicore Ag & Co. Kg Basic exchange for enhanced redox OS materials for emission control applications
EP2276701A4 (en) * 2008-03-27 2017-11-08 Umicore AG & Co. KG Base metal and base metal modified diesel oxidation catalysts
EP2259870A4 (en) * 2008-03-27 2017-11-15 Umicore AG & Co. KG Continuous diesel soot control with minimal back pressure penality using conventional flow substrates and active direct soot oxidation catalyst disposed thereon
EP2335808B1 (en) 2009-12-21 2015-06-03 Bernhard Kahlert NO2 Slip catalyst
US8529853B2 (en) 2010-03-26 2013-09-10 Umicore Ag & Co. Kg ZrOx, Ce-ZrOx, Ce-Zr-REOx as host matrices for redox active cations for low temperature, hydrothermally durable and poison resistant SCR catalysts
US8017097B1 (en) * 2010-03-26 2011-09-13 Umicore Ag & Co. Kg ZrOx, Ce-ZrOx, Ce-Zr-REOx as host matrices for redox active cations for low temperature, hydrothermally durable and poison resistant SCR catalysts
US9239019B2 (en) * 2012-01-26 2016-01-19 Ford Global Technologies, Llc Particulate matter retaining system
CN102854207A (en) * 2012-09-21 2013-01-02 兰州大学 Method for determining content of palygorskite in attapulgite clay
RU2502561C1 (en) * 2012-11-28 2013-12-27 Федеральное государственное бюджетное учреждение науки Институт металлургии и материаловедения им. А.А. Байкова Российской академии наук (ИМЕТ РАН) Method of preparing catalyst for purification of exhaust gases of combustion engines and catalyst obtained thereof
US9321042B2 (en) 2012-12-12 2016-04-26 Basf Corporation Catalyst compositions, catalytic articles, systems and processes using large particle molecular sieves
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