WO2009131474A3 - Gasoline synthesis catalyst comprising copper ions on an aluminosilicate - Google Patents

Gasoline synthesis catalyst comprising copper ions on an aluminosilicate Download PDF

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Publication number
WO2009131474A3
WO2009131474A3 PCT/PL2009/000037 PL2009000037W WO2009131474A3 WO 2009131474 A3 WO2009131474 A3 WO 2009131474A3 PL 2009000037 W PL2009000037 W PL 2009000037W WO 2009131474 A3 WO2009131474 A3 WO 2009131474A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
aluminosilicate
copper ions
synthesis catalyst
gasoline synthesis
Prior art date
Application number
PCT/PL2009/000037
Other languages
French (fr)
Other versions
WO2009131474A2 (en
Inventor
Dobieslaw Nazimek
Stanislaw Jablonski
Waldemar Zaniuk
Original Assignee
Uniwersytet Marii Curie Sklodowskiej
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uniwersytet Marii Curie Sklodowskiej filed Critical Uniwersytet Marii Curie Sklodowskiej
Priority to EP09734615A priority Critical patent/EP2276565A2/en
Priority to AU2009238764A priority patent/AU2009238764A1/en
Publication of WO2009131474A2 publication Critical patent/WO2009131474A2/en
Publication of WO2009131474A3 publication Critical patent/WO2009131474A3/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/072Iron group metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B01J29/66Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively containing iron group metals, noble metals or copper
    • B01J29/68Iron group metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76Iron group metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/18After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/30Ion-exchange
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02Gasoline
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/20Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

The subject of the present invention is a catalyst for the synthesis of gasolines from methanol or its homologues, in particular its nanostructural matrix having high catalytic resistance to water, even as high as above 100 ppm and making it possible to appropriately deposit active sites onto it, which results in high and long-lasting activity of the catalyst and its selectivity towards increasing the degree of hydrocarbons isomerisation to increase the octane number of the gasoline to be obtained. Preferably the catalyst is in form of copper ions supported on an aluminosilicate matrix.
PCT/PL2009/000037 2008-04-22 2009-04-21 Gasoline synthesis catalyst WO2009131474A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP09734615A EP2276565A2 (en) 2008-04-22 2009-04-21 Gasoline synthesis catalyst
AU2009238764A AU2009238764A1 (en) 2008-04-22 2009-04-21 Gasoline synthesis catalyst comprising copper ions on an aluminosilicate

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
PLP-384999 2008-04-22
PL384999A PL207580B1 (en) 2008-04-22 2008-04-22 Petrol synthesis catalyst

Publications (2)

Publication Number Publication Date
WO2009131474A2 WO2009131474A2 (en) 2009-10-29
WO2009131474A3 true WO2009131474A3 (en) 2009-12-17

Family

ID=40940550

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/PL2009/000037 WO2009131474A2 (en) 2008-04-22 2009-04-21 Gasoline synthesis catalyst

Country Status (4)

Country Link
EP (1) EP2276565A2 (en)
AU (1) AU2009238764A1 (en)
PL (1) PL207580B1 (en)
WO (1) WO2009131474A2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111696619B (en) * 2019-03-13 2023-06-20 赣南师范大学 Method for predicting influence degree of reaction environment on reaction activation energy

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0018117A1 (en) * 1979-04-04 1980-10-29 Mobil Oil Corporation Catalytic production of hydrocarbons including catalyst regeneration
US4735927A (en) * 1985-10-22 1988-04-05 Norton Company Catalyst for the reduction of oxides of nitrogen
US5491273A (en) * 1994-11-17 1996-02-13 Mobil Oil Corporation Catalytic conversion of methanol to linear olefins
WO2007116201A1 (en) * 2006-04-12 2007-10-18 Bp Chemicals Limited Process for the preparation of carboxylic acids and/or derivatives thereof

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL135292B1 (en) 1983-12-02 1985-10-31 Inst Chemii Przemyslowej Method of manufacture of zsm-5 type high-silicon zeolite

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0018117A1 (en) * 1979-04-04 1980-10-29 Mobil Oil Corporation Catalytic production of hydrocarbons including catalyst regeneration
US4735927A (en) * 1985-10-22 1988-04-05 Norton Company Catalyst for the reduction of oxides of nitrogen
US5491273A (en) * 1994-11-17 1996-02-13 Mobil Oil Corporation Catalytic conversion of methanol to linear olefins
WO2007116201A1 (en) * 2006-04-12 2007-10-18 Bp Chemicals Limited Process for the preparation of carboxylic acids and/or derivatives thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
SAKOH HARUMI ET AL: "CATALYTIC ACTIVITY AND SELECTIVITY OF MODIFIED CLINOPTILOLITES FOR CONVERSION OF METHANOL TO LIGHT OLEFINS.", 15 May 1985, APPLIED CATALYSIS 1985 MAY 15, VOL. 16, NR. 2, PAGE(S) 249 - 253, XP002543750 *

Also Published As

Publication number Publication date
PL384999A1 (en) 2009-10-26
WO2009131474A2 (en) 2009-10-29
AU2009238764A1 (en) 2009-10-29
EP2276565A2 (en) 2011-01-26
PL207580B1 (en) 2011-01-31

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