WO2009116378A8 - Solid transition metal hydroxide film, method for manufacturing solid transition metal hydroxide, and apparatus for manufacturing solid transition metal hydroxide - Google Patents

Solid transition metal hydroxide film, method for manufacturing solid transition metal hydroxide, and apparatus for manufacturing solid transition metal hydroxide Download PDF

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Publication number
WO2009116378A8
WO2009116378A8 PCT/JP2009/053769 JP2009053769W WO2009116378A8 WO 2009116378 A8 WO2009116378 A8 WO 2009116378A8 JP 2009053769 W JP2009053769 W JP 2009053769W WO 2009116378 A8 WO2009116378 A8 WO 2009116378A8
Authority
WO
WIPO (PCT)
Prior art keywords
transition metal
metal hydroxide
solid transition
cobalt hydroxide
film
Prior art date
Application number
PCT/JP2009/053769
Other languages
French (fr)
Japanese (ja)
Other versions
WO2009116378A1 (en
Inventor
隆史 加藤
佑哉 緒明
西村　達也
智司 梶山
Original Assignee
国立大学法人東京大学
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 国立大学法人東京大学 filed Critical 国立大学法人東京大学
Priority to JP2010503818A priority Critical patent/JPWO2009116378A1/en
Publication of WO2009116378A1 publication Critical patent/WO2009116378A1/en
Publication of WO2009116378A8 publication Critical patent/WO2009116378A8/en

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/04—Oxides; Hydroxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/78—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by stacking-plane distances or stacking sequences
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/20—Particle morphology extending in two dimensions, e.g. plate-like
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/30—Particle morphology extending in three dimensions
    • C01P2004/32—Spheres
    • C01P2004/34—Spheres hollow
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/16—Pore diameter
    • C01P2006/17—Pore diameter distribution
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22—Electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Abstract

Provided is a transition metal hydroxide film or the like with a controlled alignment. An aspect of the invention is an α-cobalt hydroxide film formed on a substrate, wherein the α-cobalt hydroxide is characterized in that the c axis of the α-cobalt hydroxide is roughly perpendicular to the substrate surface. The configuration makes it possible to obtain an α-cobalt hydroxide film with a controlled alignment and the material obtained may be expected to have various improved characteristics. Another aspect of the invention is a manufacturing method of α-cobalt hydroxide characterized in that α-cobalt hydroxide is formed while raising pH by mixing ammonia gas into a cobalt ion solution. The configuration makes it possible to obtain α-cobalt hydroxide easily.
PCT/JP2009/053769 2008-02-29 2009-02-27 SOLID TRANSITION METAL HYDROXIDE FILM, α-COBALT HYDROXIDE FILM, MANUFACTURING METHOD FOR SOLID TRANSITION METAL HYDROXIDE, MANUFACTURING METHOD FOR α-COBALT HYDROXIDE, MANUFACTURING DEVICE FOR SOLID TRANSITION METAL HYDROXIDE, MANUFACTURING METHOD FOR TRANSITION METAL HYDROXIDE, MANUFACTURING METHOD FOR HYDRATED LITHIUM COBALT OXIDE, TRANSITION METAL OXIDE FILM, AND ELECTRODE MATERIAL WO2009116378A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2010503818A JPWO2009116378A1 (en) 2008-02-29 2009-02-27 Solid transition metal hydroxide film, solid transition metal hydroxide production method, and solid transition metal hydroxide production apparatus,

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2008-051430 2008-02-29
JP2008051430 2008-02-29

Publications (2)

Publication Number Publication Date
WO2009116378A1 WO2009116378A1 (en) 2009-09-24
WO2009116378A8 true WO2009116378A8 (en) 2009-11-12

Family

ID=41090785

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2009/053769 WO2009116378A1 (en) 2008-02-29 2009-02-27 SOLID TRANSITION METAL HYDROXIDE FILM, α-COBALT HYDROXIDE FILM, MANUFACTURING METHOD FOR SOLID TRANSITION METAL HYDROXIDE, MANUFACTURING METHOD FOR α-COBALT HYDROXIDE, MANUFACTURING DEVICE FOR SOLID TRANSITION METAL HYDROXIDE, MANUFACTURING METHOD FOR TRANSITION METAL HYDROXIDE, MANUFACTURING METHOD FOR HYDRATED LITHIUM COBALT OXIDE, TRANSITION METAL OXIDE FILM, AND ELECTRODE MATERIAL

Country Status (2)

Country Link
JP (1) JPWO2009116378A1 (en)
WO (1) WO2009116378A1 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5672754B2 (en) * 2010-04-13 2015-02-18 トヨタ自動車株式会社 Method for producing colloidal solution of cobalt hydroxide
JP6342269B2 (en) * 2014-09-05 2018-06-13 国立研究開発法人物質・材料研究機構 Method for exfoliating layered transition metal hydroxide nanocones as a single layer and method for producing transition metal oxide nanocones
JP7075717B2 (en) * 2017-03-15 2022-05-26 株式会社日本マイクロニクス Power storage device
CN113134361B (en) * 2021-03-30 2023-08-25 江苏大学 Ag/alpha-Co (OH) 2 Preparation method of oxygen evolution catalyst
CN114717590B (en) * 2022-03-10 2023-08-08 中国科学院海洋研究所 Preparation method of cobalt-based chlorine evolution catalyst electrode

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06256959A (en) * 1991-09-07 1994-09-13 Shiro Kanbe Method for synthesizing oxide film via hydroxide
JP3855156B2 (en) * 2001-12-20 2006-12-06 独立行政法人科学技術振興機構 Novel cobalt film, novel electrochromic material, and positive electrode material for alkaline ion battery

Also Published As

Publication number Publication date
JPWO2009116378A1 (en) 2011-07-21
WO2009116378A1 (en) 2009-09-24

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