WO2009077000A1 - Power capacitor - Google Patents
Power capacitor Download PDFInfo
- Publication number
- WO2009077000A1 WO2009077000A1 PCT/EP2007/064054 EP2007064054W WO2009077000A1 WO 2009077000 A1 WO2009077000 A1 WO 2009077000A1 EP 2007064054 W EP2007064054 W EP 2007064054W WO 2009077000 A1 WO2009077000 A1 WO 2009077000A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- power capacitor
- gel
- chamber
- winding
- electrical contact
- Prior art date
Links
- 239000003990 capacitor Substances 0.000 title claims description 27
- 238000004804 winding Methods 0.000 claims abstract description 34
- 239000012528 membrane Substances 0.000 claims abstract description 15
- 239000004020 conductor Substances 0.000 claims abstract description 10
- 239000000945 filler Substances 0.000 claims abstract description 10
- 235000011470 Adenanthera pavonina Nutrition 0.000 claims description 4
- 240000001606 Adenanthera pavonina Species 0.000 claims description 4
- 239000004014 plasticizer Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 239000004848 polyfunctional curative Substances 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 239000012948 isocyanate Substances 0.000 claims description 2
- 150000002513 isocyanates Chemical class 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 229920005862 polyol Polymers 0.000 claims description 2
- 150000003077 polyols Chemical class 0.000 claims description 2
- 238000009413 insulation Methods 0.000 claims 1
- 238000010943 off-gassing Methods 0.000 abstract description 4
- 239000000499 gel Substances 0.000 description 17
- 239000007788 liquid Substances 0.000 description 8
- -1 e.g Substances 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 229920005830 Polyurethane Foam Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 230000035876 healing Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 238000004382 potting Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G2/00—Details of capacitors not covered by a single one of groups H01G4/00-H01G11/00
- H01G2/14—Protection against electric or thermal overload
Definitions
- the invention concerns a power capacitor according to the generic part of claim 1.
- Such capacitors which usually contain windings of the self-healing type consisting essentially of metallized plastic films, are used, e.g., for phase correction in power distribution grids.
- a power capacitor according to the generic part of claim 1 is known from US 6 313 978 Bl.
- the winding is accommodated in a chamber within a plastic casing closed by a pressure sensitive bistable cover carrying first and second electrical contacts which are connected to the winding by conductor bands with weak points.
- the chamber is filled up with an insulating filler liquid.
- When the winding begins to fail the consequent out-gassing causes gas bubbles to form and rise through the filler liquid to the top of the chamber and increase the pressure acting on the cover. If the said pressure reaches a threshold the cover snaps into a convex shape and breaks the conductor bands at the weak points.
- the housing further contains an air volume which is compressed in case of a sudden pressure build-up which might otherwise damage the casing. Due to the filler liquid, e.g, oil, even a minor rupture of the casing may result in liquid spill with the risk of fire and damage to the environment.
- a similar power capacitor is known from US 4 580 189 A where a casing surrounds a chamber containing a winding and filled in part by a soft potting material like plasticized urethane and in part by gas. Low rates of out-gassing as occur when the failing of the winding causes the same to melt may, due to the compressibility of the gas, fail to cause a rise of the pressure large enough to ensure a timely response of the disconnector .
- a power capacitor comprising a winding or several windings in a chamber filled up with a gel as an insulating filler, in particular, oil mixed with a gelling component, is known from US 2003/0 133 255 Al.
- the capacitor however, lacks a disconnector .
- a further power capacitor is disclosed in EP 0 256 348 Al. It comprises a winding which, apart form an upper face, is surrounded by resin as an insulator. The upper face is covered by a deformable membrane separating the winding from a gas-filled compartment. The small volume between the membrane and the winding is filled with an insulating paste. If, due to out-gassing of the winding, sufficient pressure builds up under the membrane it assumes a convex shape and breaks a lead connecting the winding with an electrical contact. As the winding is surrounded mostly by a solid insulating filler, gas forming away from the upper face may be trapped and have no effect on the membrane. In this case the disconnector remains inactive and the capacitor may fail catastrophically .
- Fig. 1 schematically shows an axial section through a power capacitor according to the invention.
- the power capacitor comprises a rigid casing comprising a cylindrical container 1 consisting of plastic or metal, e.g., polyethylene, aluminium or steel, and a round cover 2 consisting of hard plastic, e.g., PU.
- the casing surrounds a chamber 3 containing a winding 4 with a first electrode and a second electrode electrically conductively connected by leads 5, 6 to a first electrical contact 7 and a second electrical contact 8, respectively, which are arranged on top of the cover 2.
- the winding 4 is preferably of the self- healing type and may consist, e.g., of two plastic foils wound together, each covered by a metal film forming one of the electrodes as described, e.g., in EP 1 341 195 Al.
- the chamber 3 also contains a compressible cushion 9 consisting, e.g., of PU foam and is otherwise filled up essentially completely with an insulating gel 10 as a filler.
- the cushion 9 serves to compensate differences in the thermal expansions of the casing on the one hand and the winding 4 and the gel 10 on the other hand. If the said thermal expansions match, i.e., if the thermal expansion of the gel is gauged so as to compensate a difference between the thermal expansion of the container 1 and the thermal expansion of the winding 4 - the former being usually somewhat larger - the cushion 9 is not required.
- a gas-filled compartment 11 which is separated from the chamber 3 by a flexible membrane 12 and a rigid wall 13.
- a blade-like separator 14 Fixed to the centre of the membrane 12 is a blade-like separator 14 with a cutting edge directed against a conductor band 15 which forms a part of the lead 5 accommodated inside the compartment 11.
- the separator 14 forms, together with the conductor band 15, a switch which can be actuated by the membrane 12. The latter is in contact with the gel 10 so as to monitor the pressure in the chamber 3. If the pressure reaches a predetermined threshold the membrane 12 will cause the switch to disconnect the winding 4 from the first electrical contact 7 as will be described in more detail below.
- the winding 4 reaches a condition where it is likely to fail in the near future, e.g., if it approaches the end of its life span or has otherwise been damaged, it will usually release gas which accumulates around the winding 4 and increases the pressure there. Due to the plasticity of the gel 10 this pressure increase is transmitted to the boundary of the chamber 3 and, due to the rigidity of the remaining parts of the same causes a marked deformation of the flexible membrane 12 which protrudes into the compartment 11 and causes the cutting edge of the separator 14 to disrupt the conductor band 15 and disconnect the winding 4 from the first electrical contact 7 when the pressure reaches the threshold. As the activation of the disconnector as described above has no effect on the shape or size of the casing it can not be obstructed by external mechanical constraints, e.g., the way the capacitor is built into a larger assembly.
- the above switch can be modified to directly connect the first electrical contact 7 to the second electrical contact 8.
- the cushion 9 can delay the action of the disconnector to some small extent which is, however, acceptable.
- the compressibility of the cushion 9 must, of course, be gauged so as to ensure that thermal expansion during normal operation does not cause the pressure to reach the threshold.
- the gel 10 has a storage modulus of between lOPa and 10'000Pa and also a loss modulus of between lOPa and 10'000Pa. Preferably, both storage modulus and loss modulus are between lOOPa and l'OOOPa.
- the gel may be a mixture of a silicone gel as a gelling component and silicone oil as a plasticizer as described in US 2003/0 133 255 Al, p.
- a lower cost alternative is a self-extinguishing polyurethane gel formed by mixing two components which react to form the gel, namely a mixture of long-chain polyols with an average molecular mass of at least 1000, preferably between 2000 and 4'000, e.g., polyether and/or polyester polyols and up to 5% (mass) of plasticizer consisting of, e.g., mineral oil and/or hydrocarbon polymers as a first component, and an isocyanate hardener, e.g., technical diphenyl methane-diisocyanate, as a second component. Both are available from ABB Sau GmbH, Micafil as resin X1321 Rl and hardener P980, respectively.
- the switch can short-circuit the winding in order to activate an over-current protection device, e.g., a fuse or interruptor in series with the capacitor.
- an over-current protection device e.g., a fuse or interruptor in series with the capacitor.
- the membrane can be of the bistable type.
- the chamber may contain several windings connected in series or in parallel etc..
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Fixed Capacitors And Capacitor Manufacturing Machines (AREA)
Abstract
A chamber (3) in a rigid casing contains a winding (4) and is filled up with a gel (10) with a storage modulus and a loss modulus each between 1OPa and 10'000Pa, preferably between 1OOPa and 1'OOOPa. In a separate compartment (11) a separator (14) is arranged which will disrupt a conductor band (15) connecting the winding (4) with a first electrical contact (7) actuated by a membrane (12) if the pressure in the chamber (3) reaches a threshold. Due to the use of the gel (10) as a filler a crack in the casing will not lead to spill while any increase in pressure caused by damage to the winding (4) and out-gassing of the same is, due to the plasticity of the gel (10), reliably transmitted to the membrane (12), causing the same to actuate the separator (14) to disconnect the winding (4) if the pressure reaches the threshold. A cushion (9) inside the chamber (3) compensates thermal expansion of the winding (4) and the gel (10).
Description
D E S C R I P T I O N
POWER CAPACITOR
Field of the invention
The invention concerns a power capacitor according to the generic part of claim 1. Such capacitors which usually contain windings of the self-healing type consisting essentially of metallized plastic films, are used, e.g., for phase correction in power distribution grids.
Prior art
A power capacitor according to the generic part of claim 1 is known from US 6 313 978 Bl. The winding is accommodated in a chamber within a plastic casing closed by a pressure sensitive bistable cover carrying first and second electrical contacts which are connected to the winding by conductor bands with weak points. The chamber is filled up with an insulating filler liquid. When the winding begins to fail the consequent out-gassing causes gas bubbles to form and rise through the filler liquid to the top of the chamber and increase the pressure acting on the cover. If the said pressure reaches a threshold the cover snaps into a convex shape and breaks the conductor bands at the weak points. The housing further contains an air volume which is compressed in case of a sudden pressure build-up which might otherwise damage the casing. Due to the filler liquid, e.g, oil, even a minor rupture of the casing may result in liquid spill with the risk of fire and damage to the environment.
A similar power capacitor is known from US 4 580 189 A where a casing surrounds a chamber containing a winding and filled
in part by a soft potting material like plasticized urethane and in part by gas. Low rates of out-gassing as occur when the failing of the winding causes the same to melt may, due to the compressibility of the gas, fail to cause a rise of the pressure large enough to ensure a timely response of the disconnector .
A power capacitor comprising a winding or several windings in a chamber filled up with a gel as an insulating filler, in particular, oil mixed with a gelling component, is known from US 2003/0 133 255 Al. The capacitor, however, lacks a disconnector .
A further power capacitor is disclosed in EP 0 256 348 Al. It comprises a winding which, apart form an upper face, is surrounded by resin as an insulator. The upper face is covered by a deformable membrane separating the winding from a gas-filled compartment. The small volume between the membrane and the winding is filled with an insulating paste. If, due to out-gassing of the winding, sufficient pressure builds up under the membrane it assumes a convex shape and breaks a lead connecting the winding with an electrical contact. As the winding is surrounded mostly by a solid insulating filler, gas forming away from the upper face may be trapped and have no effect on the membrane. In this case the disconnector remains inactive and the capacitor may fail catastrophically .
Summary of the invention
It is the object of the invention to provide a power capacitor according to the generic part of claim 1 which is a dry capacitor with no risk of liquid spill. This object is
attained by the feature in the characterizing part of claim 1.
As a gel is used as an insulating filler in the chamber containing the winding even a relatively large crack in the casing will not lead to spill as the deformation of the gel under the impact of mechanical forces and pressures is limited. On the other hand, it has been found that gels are sufficiently deformable to transmit pressure building up due to gas formation anywhere within the chamber to the pressure sensitive actuator although gas cannot permeate the gel in bubbles as in the case of a liquid but only by diffusion which is too slow to be relevant here. As gels are also, like liquids, virtually incompressible, even a failure of the winding where relatively small amounts of gas are produced, e.g., a failure due to melting of the plastic film, will cause the disconnector to be activated.
Brief description of the drawings
In the following, the invention will be explained in more detail with reference to the following figure which shows an embodiment.
Fig. 1 schematically shows an axial section through a power capacitor according to the invention.
Description of the preferred embodiments
The power capacitor comprises a rigid casing comprising a cylindrical container 1 consisting of plastic or metal, e.g., polyethylene, aluminium or steel, and a round cover 2 consisting of hard plastic, e.g., PU. The casing surrounds a chamber 3 containing a winding 4 with a first electrode and
a second electrode electrically conductively connected by leads 5, 6 to a first electrical contact 7 and a second electrical contact 8, respectively, which are arranged on top of the cover 2. The winding 4 is preferably of the self- healing type and may consist, e.g., of two plastic foils wound together, each covered by a metal film forming one of the electrodes as described, e.g., in EP 1 341 195 Al. It may, however, have a different structure, e.g., containing additional electrodes not connected to electrical contacts as disclosed in WO 2007/071 097 Al. The chamber 3 also contains a compressible cushion 9 consisting, e.g., of PU foam and is otherwise filled up essentially completely with an insulating gel 10 as a filler. The cushion 9 serves to compensate differences in the thermal expansions of the casing on the one hand and the winding 4 and the gel 10 on the other hand. If the said thermal expansions match, i.e., if the thermal expansion of the gel is gauged so as to compensate a difference between the thermal expansion of the container 1 and the thermal expansion of the winding 4 - the former being usually somewhat larger - the cushion 9 is not required.
Also accommodated in the container 1 is a gas-filled compartment 11 which is separated from the chamber 3 by a flexible membrane 12 and a rigid wall 13. Fixed to the centre of the membrane 12 is a blade-like separator 14 with a cutting edge directed against a conductor band 15 which forms a part of the lead 5 accommodated inside the compartment 11. The separator 14 forms, together with the conductor band 15, a switch which can be actuated by the membrane 12. The latter is in contact with the gel 10 so as to monitor the pressure in the chamber 3. If the pressure reaches a predetermined threshold the membrane 12 will cause the switch to disconnect the winding 4 from the first
electrical contact 7 as will be described in more detail below.
If the winding 4 reaches a condition where it is likely to fail in the near future, e.g., if it approaches the end of its life span or has otherwise been damaged, it will usually release gas which accumulates around the winding 4 and increases the pressure there. Due to the plasticity of the gel 10 this pressure increase is transmitted to the boundary of the chamber 3 and, due to the rigidity of the remaining parts of the same causes a marked deformation of the flexible membrane 12 which protrudes into the compartment 11 and causes the cutting edge of the separator 14 to disrupt the conductor band 15 and disconnect the winding 4 from the first electrical contact 7 when the pressure reaches the threshold. As the activation of the disconnector as described above has no effect on the shape or size of the casing it can not be obstructed by external mechanical constraints, e.g., the way the capacitor is built into a larger assembly.
Instead of designing the above described switch for disconnecting the first electrode from the first electrical contact, the above switch can be modified to directly connect the first electrical contact 7 to the second electrical contact 8.
The cushion 9 can delay the action of the disconnector to some small extent which is, however, acceptable. The compressibility of the cushion 9 must, of course, be gauged so as to ensure that thermal expansion during normal operation does not cause the pressure to reach the threshold.
The gel 10 has a storage modulus of between lOPa and 10'000Pa and also a loss modulus of between lOPa and 10'000Pa. Preferably, both storage modulus and loss modulus are between lOOPa and l'OOOPa. The gel may be a mixture of a silicone gel as a gelling component and silicone oil as a plasticizer as described in US 2003/0 133 255 Al, p. 4, that is, Silgel® from Wacker-Chemie GmbH and "Dow Corning® Silicone Transformer Liquid" from Dow Corning, mixed with a mass ratio of 60-70% to 40-30%. A lower cost alternative is a self-extinguishing polyurethane gel formed by mixing two components which react to form the gel, namely a mixture of long-chain polyols with an average molecular mass of at least 1000, preferably between 2000 and 4'000, e.g., polyether and/or polyester polyols and up to 5% (mass) of plasticizer consisting of, e.g., mineral oil and/or hydrocarbon polymers as a first component, and an isocyanate hardener, e.g., technical diphenyl methane-diisocyanate, as a second component. Both are available from ABB Schweiz AG, Micafil as resin X1321 Rl and hardener P980, respectively.
There are many possible modifications of the embodiment described above which are well inside the compass of the invention. In particular, the switch can short-circuit the winding in order to activate an over-current protection device, e.g., a fuse or interruptor in series with the capacitor. The membrane can be of the bistable type. The chamber may contain several windings connected in series or in parallel etc..
List of reference symbols
1 container 2 cover 3 chamber
4 winding
5, 6 leads
7, 8 electrical contacts
9 cushion 10 gel
11 compartment
12 membrane
13 wall
14 separator 15 conductor band
Claims
1. A power capacitor comprising a casing with, on its outside, a first electrical contact (7) and a second electrical contact (8), the casing containing a chamber (3) where at least one winding (4) is accommodated with a first electrode which is electrically conductively connected to the first electrical contact (7) and a second electrode which is electrically conductiveley connected to the second electrical contact (8) the chamber (3) further containing a disconnector with a switch for disconnecting the first electrode from the first electrical contact (7) or directly connecting the first electrical contact (7) with the second electrical contact (8), and a pressure-sensitive actuator configured to monitor the pressure in the chamber (3) and actuate the switch if the said pressure reaches a predetermined threshold, the chamber (3) being filled up with an incompressible insulating filler, characterized in that the filler is a gel (10) .
2. The power capacitor of claim 1, characterized in that the electrodes are formed by a electrically conductive layer on a self-healing insulation layer.
3. The power capacitor of claim 1 or 2, characterized in that the gel (10) has a storage modulus of between lOPa and 10'000Pa and a loss modulus of between lOPa and
10'000Pa and in particular a storage modulus of between lOOPa and l'OOOPa and a loss modulus of between lOOPa and 1' 000Pa.
4. The power capacitor according to one of claims 1 to 3, characterized in that the gel (10) is a product of mixing at least one long-chain polyol and a plasticizer with an isocyanate hardener.
5. The power capacitor according to one of claims 1 to 3, characterized in that the gel (10) is a mixture of a silicone gel and a plasticizer.
6. The power capacitor according to one of claims 1 to 5, characterized in that the chamber (3) , apart from the pressure-sensitive actuator, is bounded by a rigid boundary .
7. The power capacitor according to one of claims 1 to 6, characterized in that the chamber (3) contains a cushion (9) consisting of compressible material for compensating thermal expansion of the winding (4) and gel (10) .
8. The power capacitor according to one of claims 1 to 7, characterized in that the pressure-sensitive actuator is a flexible membrane (12) which is in contact with the gel (10) and separates the chamber (3) from a gas- filled compartment (11) accommodated within the casing.
9. The power capacitor of claim 8, characterized in that the switch comprises a conductor, preferably a conductor band (15), and a separator (14) configured to cut through the conductor when actuated by the membrane (12) .
10. The power capacitor according to claim 8 or 9, characterized in that the switch is accommodated in the compartment (11) .
11. The power capacitor according to one of claims 1 to 10, characterized in that the casing is rigid.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/EP2007/064054 WO2009077000A1 (en) | 2007-12-17 | 2007-12-17 | Power capacitor |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/EP2007/064054 WO2009077000A1 (en) | 2007-12-17 | 2007-12-17 | Power capacitor |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2009077000A1 true WO2009077000A1 (en) | 2009-06-25 |
Family
ID=39731787
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2007/064054 WO2009077000A1 (en) | 2007-12-17 | 2007-12-17 | Power capacitor |
Country Status (1)
Country | Link |
---|---|
WO (1) | WO2009077000A1 (en) |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0693758A1 (en) * | 1994-07-20 | 1996-01-24 | ALPES TECHNOLOGIES (société anonyme) | Capacitor with overpressure protection |
US5708558A (en) * | 1995-07-13 | 1998-01-13 | Commonwealth Sprague Capacitor Inc. | Capacitor having dielectric material containing calcium oxide |
JPH10326721A (en) * | 1997-05-26 | 1998-12-08 | Nitsuko Corp | Film capacitor contained in case |
-
2007
- 2007-12-17 WO PCT/EP2007/064054 patent/WO2009077000A1/en active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0693758A1 (en) * | 1994-07-20 | 1996-01-24 | ALPES TECHNOLOGIES (société anonyme) | Capacitor with overpressure protection |
US5708558A (en) * | 1995-07-13 | 1998-01-13 | Commonwealth Sprague Capacitor Inc. | Capacitor having dielectric material containing calcium oxide |
JPH10326721A (en) * | 1997-05-26 | 1998-12-08 | Nitsuko Corp | Film capacitor contained in case |
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