WO2009035234A3 - Process for the chlorine by oxidation of hydrogen chloride - Google Patents
Process for the chlorine by oxidation of hydrogen chloride Download PDFInfo
- Publication number
- WO2009035234A3 WO2009035234A3 PCT/KR2008/005241 KR2008005241W WO2009035234A3 WO 2009035234 A3 WO2009035234 A3 WO 2009035234A3 KR 2008005241 W KR2008005241 W KR 2008005241W WO 2009035234 A3 WO2009035234 A3 WO 2009035234A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- hydrogen chloride
- chlorine
- based catalyst
- oxidation
- present
- Prior art date
Links
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title abstract 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 title abstract 4
- 239000000460 chlorine Substances 0.000 title abstract 4
- 229910052801 chlorine Inorganic materials 0.000 title abstract 4
- 229910000041 hydrogen chloride Inorganic materials 0.000 title abstract 4
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 4
- 230000003647 oxidation Effects 0.000 title 1
- 238000007254 oxidation reaction Methods 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 3
- 229910052684 Cerium Inorganic materials 0.000 abstract 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 238000006864 oxidative decomposition reaction Methods 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/01—Chlorine; Hydrogen chloride
- C01B7/03—Preparation from chlorides
- C01B7/04—Preparation of chlorine from hydrogen chloride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
-
- B01J35/40—
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
Abstract
The present invention relates to a method for preparing chlorine by decomposing hydrogen chloride, in which hydrogen chloride is reacted with oxygen containing gas in the presence of a cerium based catalyst at comparatively low temperature of up to 400°C to produce chlorine. The cerium based catalyst of the present invention maintains its catalytic activity for a long time, compared with other catalysts prepared by the conventional processes, has excellent stability at high temperature, and has high economical efficiency, so that it paves the way to the development of an economically excellent oxidative decomposition process to produce chlorine from hydrogen chloride.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020070091300A KR20090026381A (en) | 2007-09-10 | 2007-09-10 | Process for the chlorine by oxidation of hydrogen chloride |
KR10-2007-0091300 | 2007-09-10 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2009035234A2 WO2009035234A2 (en) | 2009-03-19 |
WO2009035234A3 true WO2009035234A3 (en) | 2009-05-07 |
Family
ID=40452673
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/KR2008/005241 WO2009035234A2 (en) | 2007-09-10 | 2008-09-04 | Process for the chlorine by oxidation of hydrogen chloride |
Country Status (2)
Country | Link |
---|---|
KR (1) | KR20090026381A (en) |
WO (1) | WO2009035234A2 (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102009021675A1 (en) * | 2009-05-16 | 2010-11-18 | Bayer Technology Services Gmbh | Process for producing chlorine by gas phase oxidation of hydrogen chloride in the presence of a ceria catalyst |
WO2013004649A1 (en) | 2011-07-05 | 2013-01-10 | Bayer Intellectual Property Gmbh | Process for the production of chlorine using a cerium oxide catalyst in an adiabatic reaction cascade |
EP2729408A1 (en) | 2011-07-05 | 2014-05-14 | Bayer Intellectual Property GmbH | Process for the production of chlorine using a cerium oxide catalyst in an isothermic reactor |
IN2014CN02995A (en) * | 2011-10-24 | 2015-07-03 | Bayer Ip Gmbh | |
EP3421416A1 (en) | 2017-06-29 | 2019-01-02 | Covestro Deutschland AG | Photocatalytic oxidation of hydrogen chloride with carbon monoxide |
EP3670444A1 (en) | 2018-12-18 | 2020-06-24 | Covestro Deutschland AG | Photocatalytic oxidation of hydrogen chloride with oxygen |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR950016873A (en) * | 1993-12-01 | 1995-07-20 | 김은영 | Cerium chloride-dichromium trioxide catalyst for the production of chlorine by oxidation of hydrogen chloride and preparation method thereof |
KR970015456A (en) * | 1995-09-12 | 1997-04-28 | 랑핑거, 스타인호프 | Preparation of chlorine from hydrogen chloride |
KR20020056939A (en) * | 1999-11-22 | 2002-07-10 | 그래햄 이. 테일러 | Process for vinyl chloride manufacture from ethane and ethylene with immediate HCl recovery from reactor effluent |
-
2007
- 2007-09-10 KR KR1020070091300A patent/KR20090026381A/en not_active IP Right Cessation
-
2008
- 2008-09-04 WO PCT/KR2008/005241 patent/WO2009035234A2/en active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR950016873A (en) * | 1993-12-01 | 1995-07-20 | 김은영 | Cerium chloride-dichromium trioxide catalyst for the production of chlorine by oxidation of hydrogen chloride and preparation method thereof |
KR970015456A (en) * | 1995-09-12 | 1997-04-28 | 랑핑거, 스타인호프 | Preparation of chlorine from hydrogen chloride |
KR20020056939A (en) * | 1999-11-22 | 2002-07-10 | 그래햄 이. 테일러 | Process for vinyl chloride manufacture from ethane and ethylene with immediate HCl recovery from reactor effluent |
Non-Patent Citations (1)
Title |
---|
GRUY F. ET AL., J. AM. CERAM. SOC., vol. 77, 1994, pages 1537 - 1544 * |
Also Published As
Publication number | Publication date |
---|---|
WO2009035234A2 (en) | 2009-03-19 |
KR20090026381A (en) | 2009-03-13 |
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