WO2009018932A3 - Integrated fluid catalytic cracking process for obtaining hydrocarbon blends having a high quality as fuel - Google Patents
Integrated fluid catalytic cracking process for obtaining hydrocarbon blends having a high quality as fuel Download PDFInfo
- Publication number
- WO2009018932A3 WO2009018932A3 PCT/EP2008/006176 EP2008006176W WO2009018932A3 WO 2009018932 A3 WO2009018932 A3 WO 2009018932A3 EP 2008006176 W EP2008006176 W EP 2008006176W WO 2009018932 A3 WO2009018932 A3 WO 2009018932A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- high quality
- catalytic cracking
- fluid catalytic
- fuel
- cracking process
- Prior art date
Links
- 239000004215 Carbon black (E152) Substances 0.000 title abstract 3
- 238000004231 fluid catalytic cracking Methods 0.000 title abstract 3
- 229930195733 hydrocarbon Natural products 0.000 title abstract 3
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 title abstract 3
- 239000000446 fuel Substances 0.000 title abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052741 iridium Inorganic materials 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 229910052702 rhenium Inorganic materials 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 229910052707 ruthenium Inorganic materials 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/74—Noble metals
- B01J29/7469—MTW-type, e.g. ZSM-12, NU-13, TPZ-12 or Theta-3
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J29/7869—MTW-type, e.g. ZSM-12, NU-13, TPZ-12 or Theta-3
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/617—500-1000 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
- C10G45/62—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing platinum group metals or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
- C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
- C10G69/04—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one step of catalytic cracking in the absence of hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/633—Pore volume less than 0.5 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/635—0.5-1.0 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/638—Pore volume more than 1.0 ml/g
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Abstract
The present invention relates to an integrated fluid catalytic cracking process (FCC) which allows hydrocarbon blends to be obtained having a high quality as fuel. In particular, it relates to an integrated process comprising a fluid catalytic cracking step wherein hydrocarbon cuts of an oil origin are converted into blends with a high content of light cycle oil (LCO) having a high quality in terms of density and nature of the aromatic products contained, which, after a separation and a hydrotreating step, is subjected to upgrading by treatment with hydrogen and a catalyst comprising one or more metals selected from Pt, Pd, Ir, Ru, Rh and Re and a silicoaluminate of an acidic nature.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP08785127A EP2175987A2 (en) | 2007-08-03 | 2008-07-21 | Integrated fluid catalytic cracking process for obtaining hydrocarbon blends having a high quality as fuel |
RU2010104993/04A RU2481388C2 (en) | 2007-08-03 | 2008-07-21 | Compound fluid catalytic cracking method for producing mixtures of hydrocarbons having high fuel quality |
US12/671,707 US20110056870A1 (en) | 2007-08-03 | 2008-07-21 | Integrated fluid catalytic cracking process for obtaining hydrocarbon blends having a high quality as fuel |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITMI2007A001610 | 2007-08-03 | ||
IT001610A ITMI20071610A1 (en) | 2007-08-03 | 2007-08-03 | INTEGRATED PROCESS OF CATALYTIC FLUID CRACKING TO OBTAIN HYDROCARBURIC MIXTURES WITH HIGH QUALITY AS FUEL |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2009018932A2 WO2009018932A2 (en) | 2009-02-12 |
WO2009018932A3 true WO2009018932A3 (en) | 2009-09-03 |
Family
ID=40299757
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2008/006176 WO2009018932A2 (en) | 2007-08-03 | 2008-07-21 | Integrated fluid catalytic cracking process for obtaining hydrocarbon blends having a high quality as fuel |
Country Status (5)
Country | Link |
---|---|
US (1) | US20110056870A1 (en) |
EP (1) | EP2175987A2 (en) |
IT (1) | ITMI20071610A1 (en) |
RU (1) | RU2481388C2 (en) |
WO (1) | WO2009018932A2 (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2527036A4 (en) | 2010-01-20 | 2014-03-05 | Jx Nippon Oil & Energy Corp | Catalyst for use in production of monocyclic aromatic hydrocarbon, and process for production of monocyclic aromatic hydrocarbon |
JP5639532B2 (en) * | 2011-05-26 | 2014-12-10 | Jx日鉱日石エネルギー株式会社 | C heavy oil composition and method for producing the same |
CN105008492A (en) | 2013-02-21 | 2015-10-28 | 吉坤日矿日石能源株式会社 | Method for producing single-ring aromatic hydrocarbons |
US10385279B2 (en) | 2014-03-25 | 2019-08-20 | Uop Llc | Process and apparatus for recycling cracked hydrocarbons |
US9181500B2 (en) | 2014-03-25 | 2015-11-10 | Uop Llc | Process and apparatus for recycling cracked hydrocarbons |
FR3043399B1 (en) * | 2015-11-09 | 2018-01-05 | Eco'ring | PROCESS FOR PRODUCING ROCK WOOL AND VALORIZABLE CAST IRON |
TWI804511B (en) | 2017-09-26 | 2023-06-11 | 大陸商中國石油化工科技開發有限公司 | A catalytic cracking method for increasing production of low-olefin and high-octane gasoline |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3617485A (en) * | 1969-02-20 | 1971-11-02 | Chevron Res | Hydrocracking catalyst comprising an amorphous aluminosilicate component, a group viii component and rhenium, and process using said catalyst |
EP0433047A1 (en) * | 1989-12-13 | 1991-06-19 | Mobil Oil Corporation | Production of gasoline and distillate fuels from light cycle oil |
FR2663946A1 (en) * | 1990-05-09 | 1992-01-03 | Inst Francais Du Petrole | PROCESS FOR CATALYTIC CRACKING IN THE PRESENCE OF A CATALYST CONTAINING A ZEOLITE ZEOLITE WITH INTERMEDIATE PORE OPENING |
WO2001060951A1 (en) * | 2000-02-16 | 2001-08-23 | Indian Oil Corporation Limited | A multi stage selective catalytic cracking process and a system for producing high yield of middle distillate products from heavy hydrocarbon feedstocks |
WO2006124175A2 (en) * | 2005-05-19 | 2006-11-23 | Uop Llc | An integrated fluid catalytic cracking process |
WO2007006473A1 (en) * | 2005-07-08 | 2007-01-18 | Eni S.P.A. | Process for improving the quality as a fuel of hydrotreated hydrocarbon blends |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1179022C (en) * | 2001-05-30 | 2004-12-08 | 中国石油化工股份有限公司 | Catalytic modification process of light petroleum hydrocarbon accompanied by low temperature regeneration of catalyst |
RU2287554C2 (en) * | 2001-10-25 | 2006-11-20 | Бп Корпорейшн Норт Америка Инк. | Method of producing product at reduced content of sulfur (versions) |
-
2007
- 2007-08-03 IT IT001610A patent/ITMI20071610A1/en unknown
-
2008
- 2008-07-21 WO PCT/EP2008/006176 patent/WO2009018932A2/en active Application Filing
- 2008-07-21 RU RU2010104993/04A patent/RU2481388C2/en not_active IP Right Cessation
- 2008-07-21 US US12/671,707 patent/US20110056870A1/en not_active Abandoned
- 2008-07-21 EP EP08785127A patent/EP2175987A2/en not_active Withdrawn
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3617485A (en) * | 1969-02-20 | 1971-11-02 | Chevron Res | Hydrocracking catalyst comprising an amorphous aluminosilicate component, a group viii component and rhenium, and process using said catalyst |
EP0433047A1 (en) * | 1989-12-13 | 1991-06-19 | Mobil Oil Corporation | Production of gasoline and distillate fuels from light cycle oil |
FR2663946A1 (en) * | 1990-05-09 | 1992-01-03 | Inst Francais Du Petrole | PROCESS FOR CATALYTIC CRACKING IN THE PRESENCE OF A CATALYST CONTAINING A ZEOLITE ZEOLITE WITH INTERMEDIATE PORE OPENING |
WO2001060951A1 (en) * | 2000-02-16 | 2001-08-23 | Indian Oil Corporation Limited | A multi stage selective catalytic cracking process and a system for producing high yield of middle distillate products from heavy hydrocarbon feedstocks |
WO2006124175A2 (en) * | 2005-05-19 | 2006-11-23 | Uop Llc | An integrated fluid catalytic cracking process |
WO2007006473A1 (en) * | 2005-07-08 | 2007-01-18 | Eni S.P.A. | Process for improving the quality as a fuel of hydrotreated hydrocarbon blends |
Non-Patent Citations (1)
Title |
---|
AVIDAN A A ET AL: "INNOVATIVE IMPROVEMENTS HIGHLIGHT FCC'S PAST AND FUTURE. Fluid catalytic cracking report", OIL AND GAS JOURNAL, PENNWELL, HOUSTON, TX, US, vol. 88, no. 2, 8 January 1990 (1990-01-08), pages 33 - 36,38, XP000125445, ISSN: 0030-1388 * |
Also Published As
Publication number | Publication date |
---|---|
WO2009018932A2 (en) | 2009-02-12 |
EP2175987A2 (en) | 2010-04-21 |
US20110056870A1 (en) | 2011-03-10 |
RU2481388C2 (en) | 2013-05-10 |
ITMI20071610A1 (en) | 2009-02-04 |
RU2010104993A (en) | 2011-09-20 |
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