WO2009014852A3 - Process for epoxidizing crude polyenes - Google Patents

Process for epoxidizing crude polyenes Download PDF

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Publication number
WO2009014852A3
WO2009014852A3 PCT/US2008/068313 US2008068313W WO2009014852A3 WO 2009014852 A3 WO2009014852 A3 WO 2009014852A3 US 2008068313 W US2008068313 W US 2008068313W WO 2009014852 A3 WO2009014852 A3 WO 2009014852A3
Authority
WO
WIPO (PCT)
Prior art keywords
polyenes
crude
epoxidizing
polyoxometallate
polyene
Prior art date
Application number
PCT/US2008/068313
Other languages
French (fr)
Other versions
WO2009014852A2 (en
Inventor
Anna Forlin
Original Assignee
Dow Global Technologies Inc
Anna Forlin
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc, Anna Forlin filed Critical Dow Global Technologies Inc
Publication of WO2009014852A2 publication Critical patent/WO2009014852A2/en
Publication of WO2009014852A3 publication Critical patent/WO2009014852A3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0239—Quaternary ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • C07D303/06—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms in which the oxirane rings are condensed with a carbocyclic ring system having three or more relevant rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/08—Bridged systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C08G59/24—Di-epoxy compounds carbocyclic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/72—Epoxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/98—Phase-transfer catalysis in a mixed solvent system containing at least 2 immiscible solvents or solvent phases
    • B01J2531/985—Phase-transfer catalysis in a mixed solvent system containing at least 2 immiscible solvents or solvent phases in a water / organic solvent system

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Epoxy Compounds (AREA)

Abstract

A process for the epoxidation of a crude polyene, which process comprises the reaction of a mixture of unsaturated hydrocarbons which comprises one or more compounds selected from (especially polycyclic) polyenes and (co) oligomers thereof in a total concentration of from about 20 % to about 95 % by weight with aqueous hydrogen peroxide in the presence of a polyoxometallate-based catalytic system.
PCT/US2008/068313 2007-07-20 2008-06-26 Process for epoxidizing crude polyenes WO2009014852A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US95110807P 2007-07-20 2007-07-20
US60/951,108 2007-07-20

Publications (2)

Publication Number Publication Date
WO2009014852A2 WO2009014852A2 (en) 2009-01-29
WO2009014852A3 true WO2009014852A3 (en) 2009-06-25

Family

ID=39874196

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2008/068313 WO2009014852A2 (en) 2007-07-20 2008-06-26 Process for epoxidizing crude polyenes

Country Status (2)

Country Link
TW (1) TW200916452A (en)
WO (1) WO2009014852A2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101912672B1 (en) * 2014-11-12 2018-10-29 쇼와 덴코 가부시키가이샤 Process for producing polyvalent glycidyl compound
CN113087717A (en) * 2019-12-23 2021-07-09 中国石油化工股份有限公司 Method for preparing dicyclopentadiene dioxide and olefin oxide by combining titanium silicalite molecular sieve catalyst

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2055821A (en) * 1979-07-19 1981-03-11 Donegani Guido Ist Process for the catalytic epoxidization of olefins with hydrogen peroxide
US4595671A (en) * 1982-11-10 1986-06-17 Montedison S.P.A. Peroxide compositions based on tungsten and phosphorus or arsenic, and processes and uses relative thereto
JPH05213919A (en) * 1992-02-04 1993-08-24 Tosoh Corp Epoxidization of alicyclic olefin
JPH0827136A (en) * 1994-07-14 1996-01-30 Mitsui Toatsu Chem Inc Production of epoxy compound
US5767150A (en) * 1997-04-10 1998-06-16 Sartomer Company Cycloaliphatic epoxide compounds
WO1998028338A1 (en) * 1996-12-23 1998-07-02 Sartomer Company, Inc. Method for the epoxidation of unsaturated polymers
WO1999043729A1 (en) * 1998-02-27 1999-09-02 Vantico Ag Curable composition comprising epoxidised natural oils
WO2000077066A2 (en) * 1999-06-12 2000-12-21 Vantico Ag Process for the preparation of reaction products of cycloaliphatic epoxides with multifunctional hydroxy compounds
US20070117993A1 (en) * 2003-12-15 2007-05-24 Yoji Hori Novel multicomponent oxidation catalyst and process for producing epoxy compound therewith
WO2007075769A1 (en) * 2005-12-22 2007-07-05 Dow Global Technologies Inc. A curable epoxy resin composition and laminates made therefrom
WO2008002416A1 (en) * 2006-06-23 2008-01-03 Dow Global Technologies Inc. Process for producing epoxides from olefinic compounds

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2055821A (en) * 1979-07-19 1981-03-11 Donegani Guido Ist Process for the catalytic epoxidization of olefins with hydrogen peroxide
US4595671A (en) * 1982-11-10 1986-06-17 Montedison S.P.A. Peroxide compositions based on tungsten and phosphorus or arsenic, and processes and uses relative thereto
JPH05213919A (en) * 1992-02-04 1993-08-24 Tosoh Corp Epoxidization of alicyclic olefin
JPH0827136A (en) * 1994-07-14 1996-01-30 Mitsui Toatsu Chem Inc Production of epoxy compound
WO1998028338A1 (en) * 1996-12-23 1998-07-02 Sartomer Company, Inc. Method for the epoxidation of unsaturated polymers
US5767150A (en) * 1997-04-10 1998-06-16 Sartomer Company Cycloaliphatic epoxide compounds
WO1999043729A1 (en) * 1998-02-27 1999-09-02 Vantico Ag Curable composition comprising epoxidised natural oils
WO2000077066A2 (en) * 1999-06-12 2000-12-21 Vantico Ag Process for the preparation of reaction products of cycloaliphatic epoxides with multifunctional hydroxy compounds
US20070117993A1 (en) * 2003-12-15 2007-05-24 Yoji Hori Novel multicomponent oxidation catalyst and process for producing epoxy compound therewith
WO2007075769A1 (en) * 2005-12-22 2007-07-05 Dow Global Technologies Inc. A curable epoxy resin composition and laminates made therefrom
WO2008002416A1 (en) * 2006-06-23 2008-01-03 Dow Global Technologies Inc. Process for producing epoxides from olefinic compounds

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Week 9338, Derwent World Patents Index; AN 93-299623, XP002079746 *
DATABASE WPI Week 9614, Derwent World Patents Index; AN 1996-136290, XP002506091 *
JIAN XIGAO ET AL: "Catatlytic epoxidation of styrene-butadiene triblock copolymer with hydrogen peroxide", JOURNAL OF POLYMER SCIENCE - PART A - POLYMER CHEMISTRY, WILEY & SONS, HOBOKEN, NJ, US, vol. 29, 1 January 1991 (1991-01-01), pages 1183 - 1189, XP002447499, ISSN: 0887-624X *
VENTURELLO C ET AL: "Quaternary Ammonium Tetrakis(diperoxotungsto) phosphates(3-) as a New Class of Catalysts for Efficient Alkene Epoxidation with Hydrogen Peroxide", JOURNAL OF ORGANIC CHEMISTRY, AMERICAN CHEMICAL SOCIETY, EASTON.; US, vol. 53, no. 7, 1 January 1988 (1988-01-01), pages 1553 - 1557, XP002235620, ISSN: 0022-3263 *
WANG M-L ET AL: "Kinetic study of the phase transfer catalytic epoxidation of dicyclopentadiene in a two-phase medium", CHEMICAL ENGINEERING COMMUNICATIONS JANUARY 2004 TAYLOR AND FRANCIS LTD. GB, vol. 191, no. 1, January 2004 (2004-01-01), pages 27 - 46, XP009109187 *

Also Published As

Publication number Publication date
TW200916452A (en) 2009-04-16
WO2009014852A2 (en) 2009-01-29

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