WO2009014852A3 - Process for epoxidizing crude polyenes - Google Patents
Process for epoxidizing crude polyenes Download PDFInfo
- Publication number
- WO2009014852A3 WO2009014852A3 PCT/US2008/068313 US2008068313W WO2009014852A3 WO 2009014852 A3 WO2009014852 A3 WO 2009014852A3 US 2008068313 W US2008068313 W US 2008068313W WO 2009014852 A3 WO2009014852 A3 WO 2009014852A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- polyenes
- crude
- epoxidizing
- polyoxometallate
- polyene
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0239—Quaternary ammonium compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
- C07D303/06—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms in which the oxirane rings are condensed with a carbocyclic ring system having three or more relevant rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
- C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
- C07D493/08—Bridged systems
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/22—Di-epoxy compounds
- C08G59/24—Di-epoxy compounds carbocyclic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
- B01J2231/72—Epoxidation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
- B01J2531/98—Phase-transfer catalysis in a mixed solvent system containing at least 2 immiscible solvents or solvent phases
- B01J2531/985—Phase-transfer catalysis in a mixed solvent system containing at least 2 immiscible solvents or solvent phases in a water / organic solvent system
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Epoxy Compounds (AREA)
Abstract
A process for the epoxidation of a crude polyene, which process comprises the reaction of a mixture of unsaturated hydrocarbons which comprises one or more compounds selected from (especially polycyclic) polyenes and (co) oligomers thereof in a total concentration of from about 20 % to about 95 % by weight with aqueous hydrogen peroxide in the presence of a polyoxometallate-based catalytic system.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US95110807P | 2007-07-20 | 2007-07-20 | |
US60/951,108 | 2007-07-20 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2009014852A2 WO2009014852A2 (en) | 2009-01-29 |
WO2009014852A3 true WO2009014852A3 (en) | 2009-06-25 |
Family
ID=39874196
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2008/068313 WO2009014852A2 (en) | 2007-07-20 | 2008-06-26 | Process for epoxidizing crude polyenes |
Country Status (2)
Country | Link |
---|---|
TW (1) | TW200916452A (en) |
WO (1) | WO2009014852A2 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101912672B1 (en) * | 2014-11-12 | 2018-10-29 | 쇼와 덴코 가부시키가이샤 | Process for producing polyvalent glycidyl compound |
CN113087717A (en) * | 2019-12-23 | 2021-07-09 | 中国石油化工股份有限公司 | Method for preparing dicyclopentadiene dioxide and olefin oxide by combining titanium silicalite molecular sieve catalyst |
Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2055821A (en) * | 1979-07-19 | 1981-03-11 | Donegani Guido Ist | Process for the catalytic epoxidization of olefins with hydrogen peroxide |
US4595671A (en) * | 1982-11-10 | 1986-06-17 | Montedison S.P.A. | Peroxide compositions based on tungsten and phosphorus or arsenic, and processes and uses relative thereto |
JPH05213919A (en) * | 1992-02-04 | 1993-08-24 | Tosoh Corp | Epoxidization of alicyclic olefin |
JPH0827136A (en) * | 1994-07-14 | 1996-01-30 | Mitsui Toatsu Chem Inc | Production of epoxy compound |
US5767150A (en) * | 1997-04-10 | 1998-06-16 | Sartomer Company | Cycloaliphatic epoxide compounds |
WO1998028338A1 (en) * | 1996-12-23 | 1998-07-02 | Sartomer Company, Inc. | Method for the epoxidation of unsaturated polymers |
WO1999043729A1 (en) * | 1998-02-27 | 1999-09-02 | Vantico Ag | Curable composition comprising epoxidised natural oils |
WO2000077066A2 (en) * | 1999-06-12 | 2000-12-21 | Vantico Ag | Process for the preparation of reaction products of cycloaliphatic epoxides with multifunctional hydroxy compounds |
US20070117993A1 (en) * | 2003-12-15 | 2007-05-24 | Yoji Hori | Novel multicomponent oxidation catalyst and process for producing epoxy compound therewith |
WO2007075769A1 (en) * | 2005-12-22 | 2007-07-05 | Dow Global Technologies Inc. | A curable epoxy resin composition and laminates made therefrom |
WO2008002416A1 (en) * | 2006-06-23 | 2008-01-03 | Dow Global Technologies Inc. | Process for producing epoxides from olefinic compounds |
-
2008
- 2008-06-26 WO PCT/US2008/068313 patent/WO2009014852A2/en active Application Filing
- 2008-07-18 TW TW097127387A patent/TW200916452A/en unknown
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2055821A (en) * | 1979-07-19 | 1981-03-11 | Donegani Guido Ist | Process for the catalytic epoxidization of olefins with hydrogen peroxide |
US4595671A (en) * | 1982-11-10 | 1986-06-17 | Montedison S.P.A. | Peroxide compositions based on tungsten and phosphorus or arsenic, and processes and uses relative thereto |
JPH05213919A (en) * | 1992-02-04 | 1993-08-24 | Tosoh Corp | Epoxidization of alicyclic olefin |
JPH0827136A (en) * | 1994-07-14 | 1996-01-30 | Mitsui Toatsu Chem Inc | Production of epoxy compound |
WO1998028338A1 (en) * | 1996-12-23 | 1998-07-02 | Sartomer Company, Inc. | Method for the epoxidation of unsaturated polymers |
US5767150A (en) * | 1997-04-10 | 1998-06-16 | Sartomer Company | Cycloaliphatic epoxide compounds |
WO1999043729A1 (en) * | 1998-02-27 | 1999-09-02 | Vantico Ag | Curable composition comprising epoxidised natural oils |
WO2000077066A2 (en) * | 1999-06-12 | 2000-12-21 | Vantico Ag | Process for the preparation of reaction products of cycloaliphatic epoxides with multifunctional hydroxy compounds |
US20070117993A1 (en) * | 2003-12-15 | 2007-05-24 | Yoji Hori | Novel multicomponent oxidation catalyst and process for producing epoxy compound therewith |
WO2007075769A1 (en) * | 2005-12-22 | 2007-07-05 | Dow Global Technologies Inc. | A curable epoxy resin composition and laminates made therefrom |
WO2008002416A1 (en) * | 2006-06-23 | 2008-01-03 | Dow Global Technologies Inc. | Process for producing epoxides from olefinic compounds |
Non-Patent Citations (5)
Title |
---|
DATABASE WPI Week 9338, Derwent World Patents Index; AN 93-299623, XP002079746 * |
DATABASE WPI Week 9614, Derwent World Patents Index; AN 1996-136290, XP002506091 * |
JIAN XIGAO ET AL: "Catatlytic epoxidation of styrene-butadiene triblock copolymer with hydrogen peroxide", JOURNAL OF POLYMER SCIENCE - PART A - POLYMER CHEMISTRY, WILEY & SONS, HOBOKEN, NJ, US, vol. 29, 1 January 1991 (1991-01-01), pages 1183 - 1189, XP002447499, ISSN: 0887-624X * |
VENTURELLO C ET AL: "Quaternary Ammonium Tetrakis(diperoxotungsto) phosphates(3-) as a New Class of Catalysts for Efficient Alkene Epoxidation with Hydrogen Peroxide", JOURNAL OF ORGANIC CHEMISTRY, AMERICAN CHEMICAL SOCIETY, EASTON.; US, vol. 53, no. 7, 1 January 1988 (1988-01-01), pages 1553 - 1557, XP002235620, ISSN: 0022-3263 * |
WANG M-L ET AL: "Kinetic study of the phase transfer catalytic epoxidation of dicyclopentadiene in a two-phase medium", CHEMICAL ENGINEERING COMMUNICATIONS JANUARY 2004 TAYLOR AND FRANCIS LTD. GB, vol. 191, no. 1, January 2004 (2004-01-01), pages 27 - 46, XP009109187 * |
Also Published As
Publication number | Publication date |
---|---|
TW200916452A (en) | 2009-04-16 |
WO2009014852A2 (en) | 2009-01-29 |
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