WO2009004843A1 - 低級炭化水素の芳香族化触媒、芳香族化合物の製造方法 - Google Patents

低級炭化水素の芳香族化触媒、芳香族化合物の製造方法 Download PDF

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WO2009004843A1
WO2009004843A1 PCT/JP2008/056117 JP2008056117W WO2009004843A1 WO 2009004843 A1 WO2009004843 A1 WO 2009004843A1 JP 2008056117 W JP2008056117 W JP 2008056117W WO 2009004843 A1 WO2009004843 A1 WO 2009004843A1
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Prior art keywords
catalyst
formation rate
zeolite
aromatic compounds
metallosilicate
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PCT/JP2008/056117
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English (en)
French (fr)
Inventor
Shinichi Yamada
Tomohiro Yamada
Yuji Ogawa
Takuya Hatagishi
Yo Yamamoto
Yoshio Sugiyama
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Meidensha Corporation
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Priority claimed from JP2008007897A external-priority patent/JP5315698B2/ja
Priority claimed from JP2008007896A external-priority patent/JP2009028710A/ja
Priority claimed from JP2008038304A external-priority patent/JP5286815B2/ja
Application filed by Meidensha Corporation filed Critical Meidensha Corporation
Priority to US12/595,924 priority Critical patent/US8558045B2/en
Priority to CN2008800174010A priority patent/CN101678340B/zh
Priority to EP08739235A priority patent/EP2140938A4/en
Publication of WO2009004843A1 publication Critical patent/WO2009004843A1/ja

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    • C07C2/76Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
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    • B01J29/42Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
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Abstract

 メタン転換率、ベンゼン生成速度、ナフタレン生成速度及びBTX生成速度(ベンゼンとトルエンとキシレンの合計生成速度)の活性寿命安定性を向上させてベンゼン、トルエン等の有用な芳香族化合物の生成量を増大させるための低級炭化水素の芳香族化触媒は担体であるメタロシリケートにモリブデンと銀を担持してなる。前記芳香族化触媒はメタロシリケートからなるゼオライトを前記ゼオライトの細孔口径よりも大きな分子径であると共に、前記ゼオライトのブレーンステッド酸点に選択的に反応するアミノ基と直鎖炭化水素基を有するシラン化合物で修飾した後にモリブデンと銀を担持して得るとなおよい。これらの芳香族化触媒は、芳香族化合物の製造方法を製造するにあたり、低級炭化水素と炭酸ガスとを含む反応ガスを反応させる。
PCT/JP2008/056117 2007-06-29 2008-03-28 低級炭化水素の芳香族化触媒、芳香族化合物の製造方法 WO2009004843A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US12/595,924 US8558045B2 (en) 2007-06-29 2008-03-28 Catalyst for aromatization of lower hydrocarbons and process for production of aromatic compounds
CN2008800174010A CN101678340B (zh) 2007-06-29 2008-03-28 将低级烃芳构化的催化剂和制备芳族化合物的方法
EP08739235A EP2140938A4 (en) 2007-06-29 2008-03-28 CATALYST FOR LOWER HYDROCARBON AROMATISATION AND PROCESS FOR THE PRODUCTION OF AROMATIC COMPOUNDS

Applications Claiming Priority (10)

Application Number Priority Date Filing Date Title
JP2007172024 2007-06-29
JP2007172021 2007-06-29
JP2007-172021 2007-06-29
JP2007-172024 2007-06-29
JP2008007897A JP5315698B2 (ja) 2007-06-29 2008-01-17 芳香族化合物の製造方法
JP2008-007897 2008-01-17
JP2008007896A JP2009028710A (ja) 2007-06-29 2008-01-17 低級炭化水素の芳香族化触媒
JP2008-007896 2008-01-17
JP2008-038304 2008-02-20
JP2008038304A JP5286815B2 (ja) 2008-02-20 2008-02-20 低級炭化水素芳香族化触媒及び芳香族化合物の製造方法

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011042451A1 (de) * 2009-10-08 2011-04-14 Basf Se Verfahren zur herstellung eines si-gebundenen wirbelschicht-katalysators
JP2013067616A (ja) * 2011-09-21 2013-04-18 Agency For Science Technology & Research 触媒の組み合わせによるメタンの芳香族化

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WO2008114550A1 (ja) * 2007-03-20 2008-09-25 Meidensha Corporation 低級炭化水素芳香族化触媒及び芳香族化合物の製造方法
WO2010013527A1 (ja) * 2008-07-29 2010-02-04 株式会社明電舎 芳香族化合物製造方法
AR090777A1 (es) * 2012-04-23 2014-12-03 Shell Int Research Un proceso para la aromatizacion de una corriente de gas que contiene metano
US9724680B2 (en) 2012-12-07 2017-08-08 Exxonmobil Research And Engineering Company Fiber reinforced zeolite extrudates with enhanced physical properties
WO2014154429A1 (de) * 2013-03-27 2014-10-02 Basf Se Passivierung eines zeolith-katalysators in einer wirbelschicht
WO2014154509A1 (de) * 2013-03-27 2014-10-02 Basf Se Passivierung eines zeolith-katalysators für die dehydroaromatisierung
RU2525117C1 (ru) * 2013-03-28 2014-08-10 Открытое акционерное общество "Нефтяная компания "Роснефть" Способ активации молибден-цеолитного катализатора ароматизации метана
US11254882B2 (en) 2018-02-21 2022-02-22 Exxonmobil Chemical Patents Inc. Conversion of C2 hydrocarbons in the presence of methane
CN110882721A (zh) * 2018-09-10 2020-03-17 国家能源投资集团有限责任公司 芳构化催化剂及其制备方法和应用
CN109351338B (zh) * 2018-12-19 2022-02-15 浙江工业大学 一种以SiO2-APTES杂化气凝胶为吸附剂脱除燃料油中噻吩类硫化物的方法

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WO2011042451A1 (de) * 2009-10-08 2011-04-14 Basf Se Verfahren zur herstellung eines si-gebundenen wirbelschicht-katalysators
EA024080B1 (ru) * 2009-10-08 2016-08-31 Басф Се Способ получения связанного с кремнием псевдоожиженного катализатора, получаемый им гранулированный псевдоожиженный катализатор, его применение для неокислительной дегидроароматизации c-c-алифатических соединений и способ неокислительной дегидроароматизации c-c-алифатических соединений
US9486796B2 (en) 2009-10-08 2016-11-08 Basf Se Process for producing an si-bonded fluidized-bed catalyst
US9821300B2 (en) 2009-10-08 2017-11-21 Basf Se Process for producing an Si-bonded fluidized-bed catalyst
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