WO2009004219A3 - Additive for reducing hexavalent chromium, method for obtaining same and applications of said additive particularly in cement-based products - Google Patents
Additive for reducing hexavalent chromium, method for obtaining same and applications of said additive particularly in cement-based products Download PDFInfo
- Publication number
- WO2009004219A3 WO2009004219A3 PCT/FR2008/051048 FR2008051048W WO2009004219A3 WO 2009004219 A3 WO2009004219 A3 WO 2009004219A3 FR 2008051048 W FR2008051048 W FR 2008051048W WO 2009004219 A3 WO2009004219 A3 WO 2009004219A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- additive
- cement
- hexavalent chromium
- applications
- based products
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
- C04B22/08—Acids or salts thereof
- C04B22/14—Acids or salts thereof containing sulfur in the anion, e.g. sulfides
- C04B22/142—Sulfates
- C04B22/149—Iron-sulfates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/52—Grinding aids; Additives added during grinding
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/10—Compositions or ingredients thereof characterised by the absence or the very low content of a specific material
- C04B2111/1075—Chromium-free or very low chromium-content materials
- C04B2111/1081—Chromium VI, e.g. for avoiding chromium eczema
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Removal Of Specific Substances (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention relates to an additive for reducing hexavalent chromium in products such as, in particular, cement, slag or gypsum, that comprises a stabilised aqueous solution of a chromium reducing agent, containing: water; a chromium reducing agent such as heptahydrated ferrous sulphate; an acid; an oxygen reducing agent dissolved in excess in water. The solution may have a pH from 4 to 6. In order to improve the grinding, the additive may further include ethanolamine. The additive can be sprayed on cement during grinding, or added in a concrete mixer.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP08805983A EP2162407A2 (en) | 2007-06-12 | 2008-06-12 | Additive for reducing hexavalent chromium, method for obtaining same and applications of said additive particularly in cement-based products |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0704153 | 2007-06-12 | ||
FR0704153A FR2917401B1 (en) | 2007-06-12 | 2007-06-12 | CHROMIUM HEXAVALENT REDUCING ADDITIVE, PROCESS FOR OBTAINING THE SAME, AND APPLICATIONS THEREOF, IN PARTICULAR CEMENT PRODUCTS. |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2009004219A2 WO2009004219A2 (en) | 2009-01-08 |
WO2009004219A3 true WO2009004219A3 (en) | 2009-02-12 |
Family
ID=39288097
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2008/051048 WO2009004219A2 (en) | 2007-06-12 | 2008-06-12 | Additive for reducing hexavalent chromium, method for obtaining same and applications of said additive particularly in cement-based products |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP2162407A2 (en) |
FR (1) | FR2917401B1 (en) |
WO (1) | WO2009004219A2 (en) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2953511B1 (en) * | 2009-12-04 | 2011-11-18 | Lafarge Sa | PROTECTING A DISPERSANT DURING A GRINDING |
US8629202B2 (en) * | 2009-08-05 | 2014-01-14 | Lafarge | Protection of a dispersing agent during a grinding operation |
CN102189093B (en) * | 2010-03-09 | 2015-02-04 | 刘杰 | Method for detoxicating chromium residues and comprehensive utilization of detoxicated chromium residues |
CN104496251B (en) * | 2014-11-25 | 2017-03-22 | 中国建筑材料科学研究总院 | Liquid hexavalent chromium reducing agent and preparation method thereof, cement and preparation method thereof |
RU2675016C1 (en) * | 2017-08-29 | 2018-12-14 | Акционерное общество "Калужский научно-исследовательский институт телемеханических устройств" | Method for recovery of chromium (+6) in liquid waste of electroplating industry |
CN109652034A (en) * | 2018-12-18 | 2019-04-19 | 中国石油集团川庆钻探工程有限公司 | Method for maintaining pH value of water-based drilling fluid under high-temperature and high-salt-content conditions |
CN113480219A (en) * | 2021-07-15 | 2021-10-08 | 内蒙古宏尔高新材料科技有限公司 | Chromium reducing agent for reducing water-soluble chromium (VI) in cement and preparation method thereof |
CN115043611B (en) * | 2021-09-16 | 2023-09-05 | 安徽成弘建新材料有限公司 | Neutral high-temperature-resistant liquid cement hexavalent chromium reducing agent and preparation method thereof |
CN113912317B (en) * | 2021-11-12 | 2022-10-25 | 哈尔滨三发新型节能建材有限责任公司 | Cement production method by adding naphthalene sulfonate water reducing agent |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1505045A1 (en) * | 2003-08-01 | 2005-02-09 | Dr. Paul Lohmann GmbH KG | Admixture for the reduction of hexavalent chromium in cement compositions and method for preparing said admixture |
WO2005037728A1 (en) * | 2003-10-07 | 2005-04-28 | W. R. Grace & Co.-Conn | Amine-based, hexavalent chronmium reducing agents for cement |
EP1533287A1 (en) * | 2003-11-21 | 2005-05-25 | W.R. Grace & Co.-Conn. | Dispersion comprising tin sulfate or ferrous sulfate for reducing chromate in cement |
WO2005076858A2 (en) * | 2004-02-04 | 2005-08-25 | W.R. Grace & Co.-Conn. | Liquid additive for intergrinding cement |
EP1661871A1 (en) * | 2004-11-25 | 2006-05-31 | Mapei S.p.A. | Additive for the manufacture of cement free of soluble chromates |
-
2007
- 2007-06-12 FR FR0704153A patent/FR2917401B1/en not_active Expired - Fee Related
-
2008
- 2008-06-12 WO PCT/FR2008/051048 patent/WO2009004219A2/en active Application Filing
- 2008-06-12 EP EP08805983A patent/EP2162407A2/en not_active Withdrawn
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1505045A1 (en) * | 2003-08-01 | 2005-02-09 | Dr. Paul Lohmann GmbH KG | Admixture for the reduction of hexavalent chromium in cement compositions and method for preparing said admixture |
WO2005037728A1 (en) * | 2003-10-07 | 2005-04-28 | W. R. Grace & Co.-Conn | Amine-based, hexavalent chronmium reducing agents for cement |
EP1533287A1 (en) * | 2003-11-21 | 2005-05-25 | W.R. Grace & Co.-Conn. | Dispersion comprising tin sulfate or ferrous sulfate for reducing chromate in cement |
WO2005076858A2 (en) * | 2004-02-04 | 2005-08-25 | W.R. Grace & Co.-Conn. | Liquid additive for intergrinding cement |
EP1661871A1 (en) * | 2004-11-25 | 2006-05-31 | Mapei S.p.A. | Additive for the manufacture of cement free of soluble chromates |
Also Published As
Publication number | Publication date |
---|---|
WO2009004219A2 (en) | 2009-01-08 |
FR2917401A1 (en) | 2008-12-19 |
EP2162407A2 (en) | 2010-03-17 |
FR2917401B1 (en) | 2010-08-13 |
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