WO2008120666A1 - ビスフェノール化合物の製造方法、及び陽イオン交換樹脂触媒 - Google Patents

ビスフェノール化合物の製造方法、及び陽イオン交換樹脂触媒 Download PDF

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Publication number
WO2008120666A1
WO2008120666A1 PCT/JP2008/055884 JP2008055884W WO2008120666A1 WO 2008120666 A1 WO2008120666 A1 WO 2008120666A1 JP 2008055884 W JP2008055884 W JP 2008055884W WO 2008120666 A1 WO2008120666 A1 WO 2008120666A1
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WO
WIPO (PCT)
Prior art keywords
cation
exchange resin
compound
resin catalyst
mercapto group
Prior art date
Application number
PCT/JP2008/055884
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English (en)
French (fr)
Inventor
Susumu Tsutsuminai
Original Assignee
Mitsubishi Chemical Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chemical Corporation filed Critical Mitsubishi Chemical Corporation
Publication of WO2008120666A1 publication Critical patent/WO2008120666A1/ja

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
    • C07C37/20—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms using aldehydes or ketones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08—Ion-exchange resins
    • B01J31/10—Ion-exchange resins sulfonated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
    • C07C39/12—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings
    • C07C39/15—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings with all hydroxy groups on non-condensed rings, e.g. phenylphenol
    • C07C39/16—Bis-(hydroxyphenyl) alkanes; Tris-(hydroxyphenyl)alkanes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

　高転化率、且つ高選択率でビスフェノール化合物を製造することができるビスフェノール化合物の製造方法、及び、高活性を有する陽イオン交換樹脂触媒を提供する。 　下記一般式（１）で表される構成単位を有する陽イオン交換樹脂触媒及びメルカプト基或いは保護されたメルカプト基を含有する化合物、又は、下記一般式（１）で表される構成単位がメルカプト基或いは保護されたメルカプト基を含有する化合物で変性された構成単位を有する陽イオン交換樹脂触媒、の存在下、フェノール化合物とカルボニル化合物とを反応させる。 〔式（１）中、Ｒ１、Ｒ２、及びＲ３は、各々独立に、水素原子、置換基を有していてもよいアルキル基、置換基を有していてもよいアリール基、又はハロゲン原子を表し、Ｘは陽イオン交換樹脂の主鎖に結合している一つの芳香環のみに置換している電子求引性基を表し、ｎは１乃至４の整数である。〕
PCT/JP2008/055884 2007-03-30 2008-03-27 ビスフェノール化合物の製造方法、及び陽イオン交換樹脂触媒 WO2008120666A1 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007092697 2007-03-30
JP2007-092697 2007-03-30

Publications (1)

Publication Number Publication Date
WO2008120666A1 true WO2008120666A1 (ja) 2008-10-09

Family

ID=39808248

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/055884 WO2008120666A1 (ja) 2007-03-30 2008-03-27 ビスフェノール化合物の製造方法、及び陽イオン交換樹脂触媒

Country Status (4)

Country Link
JP (1) JP2008273951A (ja)
KR (1) KR20090123846A (ja)
TW (1) TW200916437A (ja)
WO (1) WO2008120666A1 (ja)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010173949A (ja) * 2009-01-28 2010-08-12 Mitsubishi Chemicals Corp ビスフェノール類の製造方法
US8445731B2 (en) 2009-01-22 2013-05-21 Mitsubishi Chemical Corporation Process for producing bisphenol compound

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5332846B2 (ja) * 2009-04-10 2013-11-06 三菱化学株式会社 ビスフェノール化合物製造用強酸性イオン交換樹脂触媒及び、それを用いたビスフェノール化合物の製造方法
KR101644362B1 (ko) * 2013-12-31 2016-08-02 주식회사 삼양사 비스페놀 합성용 양이온 교환 수지 및 그 제조 방법, 및 이 양이온 교환 수지를 이용한 비스페놀의 합성 방법
JP7371682B2 (ja) * 2019-03-18 2023-10-31 三菱ケミカル株式会社 ビスフェノールの製造方法、及びポリカーボネート樹脂の製造方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05111641A (ja) * 1991-03-07 1993-05-07 Dow Chem Co:The 酸化抵抗性陽イオン交換樹脂
JPH07116525A (ja) * 1993-10-21 1995-05-09 Tokyo Organ Chem Ind Ltd 陽イオン交換樹脂
JP2002060360A (ja) * 2000-08-16 2002-02-26 Mitsubishi Chemicals Corp ビスフェノールの製造方法
JP2003160526A (ja) * 2001-11-27 2003-06-03 Manac Inc ヒドロキノンの二量体及び三量体の製造方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05111641A (ja) * 1991-03-07 1993-05-07 Dow Chem Co:The 酸化抵抗性陽イオン交換樹脂
JPH07116525A (ja) * 1993-10-21 1995-05-09 Tokyo Organ Chem Ind Ltd 陽イオン交換樹脂
JP2002060360A (ja) * 2000-08-16 2002-02-26 Mitsubishi Chemicals Corp ビスフェノールの製造方法
JP2003160526A (ja) * 2001-11-27 2003-06-03 Manac Inc ヒドロキノンの二量体及び三量体の製造方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8445731B2 (en) 2009-01-22 2013-05-21 Mitsubishi Chemical Corporation Process for producing bisphenol compound
JP2010173949A (ja) * 2009-01-28 2010-08-12 Mitsubishi Chemicals Corp ビスフェノール類の製造方法

Also Published As

Publication number Publication date
TW200916437A (en) 2009-04-16
JP2008273951A (ja) 2008-11-13
KR20090123846A (ko) 2009-12-02

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