WO2008062975A1 - Polymer particles having polymer brush and method of preparing the same - Google Patents
Polymer particles having polymer brush and method of preparing the same Download PDFInfo
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- WO2008062975A1 WO2008062975A1 PCT/KR2007/005802 KR2007005802W WO2008062975A1 WO 2008062975 A1 WO2008062975 A1 WO 2008062975A1 KR 2007005802 W KR2007005802 W KR 2007005802W WO 2008062975 A1 WO2008062975 A1 WO 2008062975A1
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- Prior art keywords
- polymer particle
- particle according
- preparing
- polymer
- brush
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
- C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/30—Assembling printed circuits with electric components, e.g. with resistor
- H05K3/32—Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits
- H05K3/321—Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits by conductive adhesives
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/02—Fillers; Particles; Fibers; Reinforcement materials
- H05K2201/0203—Fillers and particles
- H05K2201/0206—Materials
- H05K2201/0221—Insulating particles having an electrically conductive coating
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/02—Fillers; Particles; Fibers; Reinforcement materials
- H05K2201/0203—Fillers and particles
- H05K2201/0206—Materials
- H05K2201/0233—Deformable particles
Definitions
- the present invention relates to a polymer particle and a method of preparing the same, more precisely a polymer particle with improved elastic recovery rate and optimum impact strength resulted from the grafting of brush having softness on the surface of a monodisperse polymer particle and a method of preparing the same.
- Background Art To prepare a polymer of at least 1 jean in mean diameter, a modified radical process such as suspension polymerization, dispersion polymerization, emulsion polymerization or precipitation polymerization is generally used. In suspension polymerization, a monomer and water are stirred at high speed to form droplets, so the resultant polymer has a wide range of mean diameter.
- Dispersion polymerization is a method to produce a polymer by using a stabilizer and a solvent in which the monomer is soluble but the produced polymer is insoluble, so the polymerization result can be very vulnerable with the characteristics of a solvent, a stabilizer and their contents.
- the mean diameter of the produced polymer is less than 1 ⁇ m.
- the swelling method using a seed has to be hired but then reaction process becomes very complicated and reaction time is extended [Colloid Polymer Science Vol. 279, 146-152(2001)].
- anion dispersion polymerization can be used to produce a polymer, for example polystyrene [Journal of Polymer Science; Part A; Polymer Chemistry Vol. 34, 2633-2649(1996)].
- This method facilitates a simple and fast reaction and thus favors the production of a monodisperse polymer.
- the monodisperse polymer produced by the anion disperse polymerization does not have such good properties including impact resistance and elastic recovery rate.
- conductive adhesive for mechanical and electric connection of FPC (Flexible Printed Circuit) to glass display has been used in LCD packaging.
- the conductive adhesive is largely divided into isotropic conductive adhesive and anisotropic conductive film (ACF) 5 and basically they all have the same structure in which monodisperse conductive particles (conductive balls) are dispersed in a thermosetting or thermoplastic insulating resin.
- the conductive ball is composed of an insulating, cross-linked monodisperse polymer core particle of 1 - 10 ⁇ m in diameter having preferable elastic modulus and recovery rate and the surface of the polymer particle is coated with a metal such as Ni or Au to increase conductivity.
- the monodisperse polymer particle can be formed by polystyrene resin, polyacrylate resin and urethane resin, etc.
- the monodisperse polystyrene resin prepared by anion dispersion polymerization can be used for the conductive ball, but in that case the improvement of physical properties including impact resistance and elastic recovery rate is required.
- the polymer particle of the invention contains a brush formed by the graft- polymerization of a conjugated diene based monomer onto the surface of a monodisperse polymer particle.
- the monodisperse polymer is formed by the anion dispersion polymerization and has mean diameter of 1 — 15 ⁇ m and size distribution less than 1.5, and is composed of 50 — 100 weight% of a styrene based monomer and 0 - 50 weight% of a comonomer.
- the preferable weight average molecular weight of the brush of the polymer particle of the invention is 5,000 - 100,000.
- the preferable graft efficiency of the brush is at least 40% and more preferably 60%.
- the preferable graft density of the brush is 0.5 x 10 6 - 6.5 x 10 6 chains/ ⁇ m 2 .
- the present invention also provides a method of preparing a polymer particle.
- the method of preparing a polymer particle of the invention comprises the following steps: (a) loading a reaction solvent, monodisperse polymer particles and a chelating ligand in a reactor and regulating a reaction temperature to 50 - 80 ° C ; (b) inducing a reaction by adding an anion polymerization initiator; (c) grafting a brush by the anion polymerization after adding a conjugated diene based monomer; and (d) terminating the reaction by adding a polymerization terminator.
- the method of the present invention additionally includes the step of eliminating the anion polymerization initiator remaining in the reactor between step (b) and step (c).
- brush indicates a short polymer chain enveloping the surface of the polymer particle in which one of the two ends is attached on the surface of the polymer particle.
- the brush can be prepared by surface initiation polymerization and is characterized by planting the functions wanted on the newly formed surface.
- the present inventors established a method of preparing a polymer particle by anion polymerization of a conjugated diene based monomer after generating anions in the double bond on the surface of the monodisperse polymer particle by reacting the monodisperse polymer particle with an anion polymerization initiator and further completed this invention by confirming that the polymer particle prepared by the above method had optimum impact strength and improved elastic recovery rate by grafting the brush having softness on the surface of the monodisperse polymer particle.
- the polymer particle of the present invention is characteristically prepared by grafting the brush having softness onto the surface of the monodisperse polymer particle, particularly the monodisperse copolymer particle.
- the monodisperse polymer of the present invention is the polymer prepared by the anion dispersion polymerization using a monomer, a stabilizer, a dispersion solvent and an anion polymerization initiator.
- the monodisperse copolymer is the copolymer prepared by anion dispersion polymerization using a monomer, a comonomer, a stabilizer, a dispersion solvent and an anion polymerization initiator.
- the monomer herein can be any monomer that is appropriate for anion polymerization, and preferably the monomer or a monomer mixture composed of at least two different monomers selected from the group consisting of vinyl aromatic monomers having nonpolar substituents, conjugated diene monomers and acrylic acid ester monomers. Among them, styrene is more preferred.
- the monomer can be added by 50 — 100 weight% for the total monomer or comonomer weight to prepare the monodisperse polymer or copolymer.
- the comonomer also can be selected from the above group. But, divinylbenzene is preferably used.
- the comonomer can be added by 0 - 50 weight% for the total monomer or comonomer weight to prepare the monodisperse polymer or copolymer.
- the preferable content of the monomer and comonomer in the reaction mixture composed of a monomer, a comonomer, and a dispersion solvent is 5 - 50 weight% for 100 weight% of the reaction mixture and more preferable content is 10 - 20 weight%.
- the stabilizer added for the preparation of the monodisperse polymer plays a role in stabilizing the polymer particle in the dispersion solvent, which can be a double or triple block copolymer composed of vinyl aromatic hydrocarbon blocks and conjugated diene blocks.
- the stabilizer can change the length of each block according to the total monomer content and is preferably the one that has weight average molecular weight of 5,000 - 1,000,000 and more preferably the one that has weight average molecular weight of 10,000 - 300,000.
- the stabilizer can be dispersed evenly in the reaction solvent, producing the stability of the resultant polymer particle.
- the weight ratio of vinyl aromatic hydrocarbon block to conjugated diene block of the block copolymer forming the stabilizer is preferably 1:9 - 9:1 and is more preferably 2:8 — 6:4. If the vinyl aromatic hydrocarbon block in (he block copolymer is short, the interaction between Lhe block and the formed polymer chain will be too weak to generale polymer particles. On the contrary, the block is too long, solubility in the reaction solvent will be reduced to bring poor dispersion.
- the content of the stabilizer in the total monomer content is 0.1 — 10 weight% and 0.5 — 5 weight% is more preferred.
- the dispersion solvent is any solvent that is appropriate for anion polymerization in which the monomer or copolymer is soluble but the prepared copolymer is insoluble.
- the dispersion solvent can be one or a mixture of at least two selected from the group consisting of C 5 - C 20 hydrocarbon solvents, aromatic hydrocarbon solvents and ether solvents.
- the anion polymerization initiator can be any organic lithium compound appropriate for anion polymerization, and n-butyllithium, s-butyllithium or t- butyllithium is preferred.
- the content of the anion polymerization initiator in the total monomer content is 0.0001 - 0.001 weight% and 0.0003 - 0.0007 weight% is more preferred.
- the monodisperse copolymer can be prepared by anion dispersion polymerization using all the above components at 0 - 50 "C for 0.5 - 12 hours.
- the prepared monodisperse copolymer is a random or a block copolymer which is at least 1 ⁇ m in mean diameter, preferably 1 — 15 ⁇ m. in mean diameter, and has the size distribution less than 1.5.
- the brush is grafted on the surface of the monodisperse polymer particle or monodisperse copolymer particle by the anion polymerization, which is composed of conjugated diene monomers.
- the conjugated diene monomer can be one or a mixture of at least two of those selected from the group consisting of 1,3 -butadiene, 2,3 -dimethyl- 1,3 -butadiene, piperylene, 3-butyl-l,3-octadiene, isoprene and 2-phenyl-l,3-butadiene, and particularly 1,3 -butadiene or isoprene are preferred.
- the weight average molecular weight of the brush is preferably 5,000 - 100,000.
- weight average molecular weight is less than 5,000, physical properties of the product will not be improved to the wanted level. If the weight average molecular weight is more than 100,000, viscosity of the particle surface will be growing, resulting in the coagulation of particles.
- the graft efficiency of the brush is preferably at least 40% and more preferably at least 60%.
- the graft density of the brush is preferably 0.5 x 10 6 - 6.5 x 10 5 chains/ ⁇ m .
- the method of the present invention is to prepare the polymer particle with optimum impact strength and improved elastic recovery rate by grafting a conjugated diene monomer onto the surface of a styrene copolymer particle via anion dispersion polymerization. So, the graft efficiency, graft density and molecular weight of the brush are important factors affecting not only impact strength and elastic recovery rate but also other physical properties of the polymer particle. But, when the graft efficiency of the brush is increased, the graft density is reduced and vise-versa. So, it is important to regulate the graft efficiency and density properly at the same time to guarantee the satisfactory levels of physical properties. The followings are embodiments realizing such regulation according to the method of the invention.
- the present invention provides a method of preparing a polymer
- anions are first formed on the surface of the monodisperse polymer particle by using an anion polymerization initiator or anions are formed in the double bond formed on the surface of the monodisperse copolymer particle, and then the conjugated diene monomer is added thereto, followed by anion polymerization to graft the brush.
- the method of preparing a polymer particle of the invention comprises the following steps:
- step (d) terminating the reaction by adding a polymerization terminator.
- the step (a) is the process to make proper conditions for the initiation of the reaction on the surface of the monodisperse polymer or copolymer particles by loading a reaction solvent, monodisperse polymer particles or monodisperse copolymer particles and a chelating ligand in a reactor and regulating the reaction temperature.
- the chelating ligand is a kind of polar additive which is exemplified by tetra methylethylenediamine (TMEDA), tetrahydrofurane (THF) 3 diglyme, dioxane and tetramethyl ethylenediphosphine.
- TEDA tetra methylethylenediamine
- THF tetrahydrofurane
- the chelating ligand plays a role in helping an anion polymerization initiator such as butyllithium form anions on the surface of the polystyrene or styrene-divinylbenzene copolymer particle.
- step (b) The reaction temperature of step (a) is preferably 50 - 80 "C .
- step (b) an anion polymerization initiator is added to the reaction mixture of step (a) by 0.1 - 5 weight% for the content of the monodisperse polymer particle, followed by reaction for 1 - 5 hours to form anions on the surface of the monodisperse polymer particle.
- the anion polymerization initiator is exemplified by n-butyllithium, s- butyllithium or t-butyllithium.
- the molar ratio of the chelating ligand to the anion polymerization initiator is preferably 0.05 - 1 : 1.
- the weight ratio of the anion polymerization initiator to the monodisperse polymer and the molar ratio of the chelating ligand to the anion polymerization initiator are important factors affecting the amount of anion formed on the surface of the monodisperse polymer particle, the amount of free-anion polymerization initiator (indicating the amount of anion polymerization initiator that remains without being used for forming anions on the surface of the monodisperse polymer particle), the graft polymerization of the conjugated diene monomer on the surface of the monodisperse polymer particle, the initiation of the polymerization of the conjugated diene monomer by the free anion polymerization initiator and the chain extension. Therefore, it is important to regulate these factors in the mentioned range in order to obtain the product with satisfactory physical properties.
- anions are generated by using protons in the position of benzyl or in the benzene ring on the surface of the polystyrene particle.
- the monodisperse polymer prepared from a single monomer can be used but preferably the comonomer comprising the monomer and at least two different vinyl functional groups, for example the monodisperse copolymer generated from the copolymerization of styrene and divinylbenzene, can be used.
- the step (b) can additionally include the step of eliminating the non-reacted anion polymerization initiator remaining in the reactor by repeated washing after forming anions on the surface of the monodisperse polymer particle.
- the elimination of the non-reacted anion polymerization initiator results in the increase of graft density and efficiency and also be an important tool to provide effective condition for grafting on the surface of the monodisperse polymer particle.
- step (c) 5 - 50 weight% of the conjugated diene monomer is added to the monodisperse polymer having anions formed on the particle surface, followed by anion polymerization to lead graft polymerization of the brush.
- the graft efficiency of the conjugated diene monomer on the surface of the monodisperse polymer particle is calculated by the following mathematical formula 1 and the graft density ( ⁇ , the number of brush grafted on the unit area on the monodisperse polymer particle) is calculated by the following mathematical formula 2.
- ⁇ the number of brush grafted on the unit area on the monodisperse polymer particle
- Graft efficiency (%) total weight (weight%) of the brush grafted / input amount of the conjugated diene monomer (weight%) x 100
- D diameter of the monodisperse copolymer particle ( ⁇ m)
- Pp density of the monodisperse copolymer particle (g/ ⁇ m 3 )
- N A Avogadro's number
- the anion polymerization is performed at 40 - 80 ° C for 1 — 10 hours.
- step (d) a polymerization terminator is added to terminate the reaction of step
- the polymerization terminator herein can be carbon dioxide, water, alcohol or a hydrogen ion containing reagent and the preferable content of the polymerization terminator is 0.1 - 2 weight% for the content of the monodisperse copolymer particle.
- the polymer particle prepared by the method of the invention has excellent impact strength and elastic recovery rate owing to the grafting of the brush comprising the conjugated diene monomer on the surface of the monodisperse polymer or copolymer particle.
- Fig. 1 is a SEM photograph of the polymer particle having the brush prepared in
- chelating ligand the temperature of the reactor was raised to 60 ° C .
- the anion polymerization initiator n-butyllithium was added thereto by for 1 g of the monodisperse copolymer, followed by stirring for 2 hours to induce the reaction of n- butyllithium with the double bond on the surface of the poly(styrene-co- divinylbenzene)copolymer particle.
- 1 g of the conjugated diene monomer isoprene was added thereto, followed by reacting for 5 hours to prepare a polymer brush.
- 2-propanol was added to terminate the reaction and then 1 weight% of an antioxidant was added and dispersed evenly, followed by filtering.
- the graft efficiency was increased with the decrease of the polymerization initiator content in Examples 1 — 5. As the graft efficiency goes high, the chances of producing a polymer brush having high weight average molecular weight are high.
- n-butyllithium was reacted with the double bond on the surface of the poly(styrene-divinylbenzene)copolymer particle, followed by washing over several times to eliminate the non-reacted polymerization initiator.
- the polymerization initiator content was reduced but yield was as high as at least 90% and the molecular weight of the brush was also high, and as a result the graft efficiency was improved up to 83%.
- the polar additive content was regulated in Examples 9 - 10. With the increase of the polar additive content, the graft efficiency and density was reduced. When the ratio of the content of the polar additive to the anion polymerization initiator was 0.1:1, the highest graft density was observed.
- Example 12 - 14 the content of isoprene was regulated in Example 12 - 14. With the increase of the content of isoprene, the weight average molecular weight of the brush was increased.
- the polymer particles of Examples 1 - 8 which contain the brush comprising isoprene grafted on the surface of the monodisperse poly(styrene- divinylbenzene)copolymer particle, had excellent impact strength and elastic recovery rate, comparing with the polymer particles which did not contain the brush (Comparative Example 1).
- Figure 1 is a SEM photograph illustrating the polymer particle of Example 9. As shown in this figure, the brush was grafted on the surface of the monodisperse copolymer particle.
- the present invention provides a polymer particle having optimum impact strength and improved elastic recovery rate by grafting the brush having softness onto the surface of the monodisperse polymer particle, in particular the polymer particle having preferable physical properties for the use as a polymer core particle of a conductive ball of conductive adhesive.
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Graft Or Block Polymers (AREA)
Abstract
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Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009538320A JP5398536B2 (en) | 2006-11-23 | 2007-11-19 | Fine particles having polymer brush and method for producing the same |
CN2007800479334A CN101568562B (en) | 2006-11-23 | 2007-11-19 | Polymer particles having polymer brush and method of preparing the same |
US12/516,006 US8415436B2 (en) | 2006-11-23 | 2007-11-19 | Polymer particles having polymer brush and method of preparing the same |
US13/790,161 US8841385B2 (en) | 2006-11-23 | 2013-03-08 | Polymer particles having polymer brush and method of preparing the same |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
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KR10-2006-0116577 | 2006-11-23 | ||
KR20060116577 | 2006-11-23 | ||
KR1020070104820A KR100974796B1 (en) | 2006-11-23 | 2007-10-18 | Polymer particles having polymer brush and preparing method thereof |
KR10-2007-0104820 | 2007-10-18 |
Related Child Applications (2)
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US12/516,006 A-371-Of-International US8415436B2 (en) | 2006-11-23 | 2007-11-19 | Polymer particles having polymer brush and method of preparing the same |
US13/790,161 Division US8841385B2 (en) | 2006-11-23 | 2013-03-08 | Polymer particles having polymer brush and method of preparing the same |
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WO2008062975A1 true WO2008062975A1 (en) | 2008-05-29 |
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PCT/KR2007/005802 WO2008062975A1 (en) | 2006-11-23 | 2007-11-19 | Polymer particles having polymer brush and method of preparing the same |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013158183A2 (en) * | 2012-01-27 | 2013-10-24 | Carnegie Mellon University | Processable self-organizing nanoparticles |
CN115124645A (en) * | 2022-07-20 | 2022-09-30 | 大连理工大学 | Crystalline polyolefin material with alternate structure and preparation method thereof |
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WO1986003209A1 (en) * | 1984-11-30 | 1986-06-05 | The Dow Chemical Company | Process for preparing a latex of grafted copolymer particles |
JPH09241310A (en) * | 1996-03-06 | 1997-09-16 | Hitachi Chem Co Ltd | Production of fine monodisperse resin particle |
KR20040011905A (en) * | 2002-07-31 | 2004-02-11 | 주식회사 엘지화학 | Method for preparing rubber-copolymer and abs resin comprising thereof |
KR20050045290A (en) * | 2003-11-11 | 2005-05-17 | 제일모직주식회사 | Capsulized or surface functionalized monodisperse polymer particle and method of preparing the same |
JP2005205338A (en) * | 2004-01-23 | 2005-08-04 | Dainippon Toryo Co Ltd | Monodisperse particle manufacturing method |
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2007
- 2007-11-19 WO PCT/KR2007/005802 patent/WO2008062975A1/en active Application Filing
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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WO1986003209A1 (en) * | 1984-11-30 | 1986-06-05 | The Dow Chemical Company | Process for preparing a latex of grafted copolymer particles |
JPH09241310A (en) * | 1996-03-06 | 1997-09-16 | Hitachi Chem Co Ltd | Production of fine monodisperse resin particle |
KR20040011905A (en) * | 2002-07-31 | 2004-02-11 | 주식회사 엘지화학 | Method for preparing rubber-copolymer and abs resin comprising thereof |
KR20050045290A (en) * | 2003-11-11 | 2005-05-17 | 제일모직주식회사 | Capsulized or surface functionalized monodisperse polymer particle and method of preparing the same |
JP2005205338A (en) * | 2004-01-23 | 2005-08-04 | Dainippon Toryo Co Ltd | Monodisperse particle manufacturing method |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013158183A2 (en) * | 2012-01-27 | 2013-10-24 | Carnegie Mellon University | Processable self-organizing nanoparticles |
WO2013158183A3 (en) * | 2012-01-27 | 2013-12-12 | Carnegie Mellon University | Processable self-organizing nanoparticles |
US9410020B2 (en) | 2012-01-27 | 2016-08-09 | Carnegie Mellon University | Processable self-organizing nanoparticle |
CN115124645A (en) * | 2022-07-20 | 2022-09-30 | 大连理工大学 | Crystalline polyolefin material with alternate structure and preparation method thereof |
CN115124645B (en) * | 2022-07-20 | 2023-07-21 | 大连理工大学 | Polyolefin material with crystalline alternating structure and preparation method thereof |
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