WO2008027890A2 - Electro-optic lenses employing resistive electrodes - Google Patents
Electro-optic lenses employing resistive electrodes Download PDFInfo
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- WO2008027890A2 WO2008027890A2 PCT/US2007/076994 US2007076994W WO2008027890A2 WO 2008027890 A2 WO2008027890 A2 WO 2008027890A2 US 2007076994 W US2007076994 W US 2007076994W WO 2008027890 A2 WO2008027890 A2 WO 2008027890A2
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- WIPO (PCT)
- Prior art keywords
- liquid crystal
- electrodes
- electrode set
- patterned electrode
- resistive
- Prior art date
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Classifications
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1343—Electrodes
- G02F1/13439—Electrodes characterised by their electrical, optical, physical properties; materials therefor; method of making
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B26/00—Optical devices or arrangements for the control of light using movable or deformable optical elements
-
- G—PHYSICS
- G02—OPTICS
- G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
- G02C7/00—Optical parts
- G02C7/02—Lenses; Lens systems ; Methods of designing lenses
- G02C7/08—Auxiliary lenses; Arrangements for varying focal length
- G02C7/081—Ophthalmic lenses with variable focal length
- G02C7/083—Electrooptic lenses
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/29—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the position or the direction of light beams, i.e. deflection
- G02F1/292—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the position or the direction of light beams, i.e. deflection by controlled diffraction or phased-array beam steering
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1343—Electrodes
- G02F1/134309—Electrodes characterised by their geometrical arrangement
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F2203/00—Function characteristic
- G02F2203/28—Function characteristic focussing or defocussing
Definitions
- the present invention is in the field of optical lenses.
- Ophthalmic lenses with fixed focusing properties have been widely used as spectacles and contact lenses to correct presbyopia and other conditions.
- Ophthalmic lenses are most useful if they have adjustable focusing power (i.e., the focusing power is not static). Adjustable focusing power provides the eye with an external accommodation to bring objects of interest at different distances into focus.
- Adjustable focusing power can be achieved using a mechanical zoom lens.
- the mechanical approach makes the spectacle bulky and costly.
- Different optical techniques have been exploited in bifocal lenses to allow both near and distance vision.
- the user may have lenses providing different focusing power to each eye, one for near objects and the other for distant objects.
- bifocal diffractive lens or other division techniques both near and distant objects are imaged onto the retina simultaneously and the brain distinguishes the images.
- the field of view using these optical techniques is small.
- these optical techniques do not work well when the pupil is small, since the iris blocks the beam that passes through the annular portion of the lens.
- an electro-optic device comprising: a liquid crystal layer between a pair of opposing transparent substrates; a resistive patterned electrode set positioned between the liquid crystal layer and the inward-facing surface of the first transparent substrate; and a conductive layer between the liquid crystal layer and the inward-facing surface of the second transparent substrate, wherein the conductive layer and resistive patterned electrode set are electrically connected, and wherein said resistive patterned electrode set comprises one or more electrically- separated electrodes, wherein the desired voltage drop is applied across each electrode to provide the desired phase retardation profile.
- Also provided is a method of diffracting light comprising applying the desired voltage drop across each electrode in a patterned electrode set as described herein.
- Figure 1 shows an illustration of a liquid crystal cell.
- Figure 2 shows voltage applied across a liquid crystal cell.
- Figure 3 shows various embodiments of electrode configurations.
- Figure 3A shows deposited conduction rings.
- Figure 3B shows examples of engineered resistance, where (1 ) rings and film are formed from one material, with the film etched to a thinner thickness; (2) resistance of the film altered by dimples; (3) resistance of the film altered by holes; (4) resistance of the film altered by a lattice; and (5) a codeposition with a second (insulating) material beyond the percolation threshold (top to bottom).
- Figure 3C shows a side view of single-layer electrodes.
- Figure 3D shows a side view of multi-layer electrodes.
- Figure 4 shows various voltage bus configurations.
- Figure 4A shows a simple 1 -bus (with direct connections to rings on the same layer or by vias).
- Figure 4B shows a commensurate structure (electrodes are connected in a repeated pattern to independent buses, which allows focal change by shunting).
- Figures 4C and 4D show incommensurate configuration where each electrode has a dedicated bus.
- Figure 4C shows an independent split-bus, which allows connection in a single-layer structure.
- Figure 4D shows a normal bus configuration.
- FIG. 5 shows bus-line-to-ring connections which are interdigitated (same layer).
- Other bus-line-to-ring connections include vias (holes through insulating layers filled with conducting material); and bridges/subways (bus lines run over/under an insulating layer separating the line from electrodes until the location of a connection need where the insulating layer is removed to allow contact with the conducting ring) (not shown).
- Vias and bridges/subways allow the use of unbroken electrodes (annulae and rings).
- This invention provides electro-optic lenses filled with liquid crystal material that can be realigned in an electric field.
- the lenses function as diffractive-optical-elements (DOE).
- DOE are the result of applying voltages across a thin liquid-crystal layer which responds by altering the director- orientation field and creates nonuniform refractive-index patterns which then lead to a nonuniform phase-transmission-function (PTF) across the face of the cell.
- PTF phase-transmission-function
- resistive patterned electrode set is one or more areas of electrically conductive material (electrodes) that are electrically separated from each other and to which a desired voltage drop can be applied. If there are two or more electrodes in a resistive patterned electrode set, the electrodes are separated by insulating material, such as SiO2, or other materials known in the art.
- the electrodes in a resistive patterned electrode set can be configured in any desired configuration, including concentric annular rings, which may contain one or more voltage connections.
- the electrodes in a resistive patterned electrode set can be positioned on one horizontal plane, separated by insulating material, or can be on one or more different horizontal planes, each electrode and each plane separated by insulating material.
- annular indicates that electrodes are non-overlapping, substantially ring-like with different radii.
- substantially when referring to ring-like is intended to indicate that the ring may not be complete, for example, when electrical contacts are made, or that the ring-like structure may not form a perfect geometric form of a ring, but that the overall effect is more nearly a ring than not.
- “desired voltage drop” is the voltage drop across the resistive patterned electrode set that provides the desired voltage behavior across the resistive patterned electrode set.
- the electro-optic lens used in the present invention is a diffractive lens using a resistive patterned electrode set to produce the desired distribution of phase retardations that allows the lens to function as a zone-plate lens.
- Diffractive lenses are known in the art.
- the function of a diffractive lens is based on near-field diffraction by a Fresnel zone pattern. Each point emerging from the structure serves as an emitter of a spherical wave.
- the optical field at a particular observing point is a summation of the contributions of the emitted spherical waves over the entire structure. Constructive interference of the spherical waves coming from the various points creates a high intensity at the observation point, corresponding to a high diffraction efficiency.
- Liquid crystal cells are known in the art. All art-known cell configurations and operations of liquid crystal cells are incorporated by reference to the extent they are not incompatible with the disclosure herewith.
- the substrates can be any material that can provide desired optical transmission and can function in the devices and methods described herein, such as quartz, glass or plastic, as known in the art.
- Conductive layer 30 is patterned with a resistive patterned electrode set to provide the desired diffraction pattern. In Figure 1 , the resistive patterned electrode set shows two electrodes.
- the resistive patterned electrode set is fabricated by photolithographic processing of a conductive layer deposited on a glass substrate, or other techniques, as known in the art.
- Conductive layer 40 is not patterned.
- the conductive material used for the conductive layers may be any suitable material, including those specifically described herein, and other materials known in the art. It is preferred that the conductive material be transparent, such as indium oxide, tin oxide or indium tin oxide (ITO).
- the thickness of each conducting layer is typically between 30 nm and 200 nm. The layer must be thick enough to provide adequate conduction, but it is preferred the layer not be so thick as to provide excess thickness to the overall lens structure.
- the substrates are kept at a desired distance with spacers (60), or other means known in the art.
- Spacers may be any desired material such as Mylar, glass or quartz, or other materials useful to provide the desired spacing.
- the liquid crystal layer In order to achieve efficient diffraction the liquid crystal layer must be thick enough to provide one wave of activated retardation (d > ⁇ / ⁇ n ⁇ 2.5 ⁇ m, where ⁇ n is the birefringence of the liquid crystal media), but thicker liquid crystal layers help to avoid saturation phenomena. Disadvantages of thicker cells include long switching times (varying as d 2 ) and loss of electro-optic feature definition.
- the transparent substrates are spaced between three and 20 microns apart, and all individual values and ranges therein. One useful spacing is 5 microns.
- the surfaces of the substrates may be coated with an alignment layer (50), such as polyvinylalcohol (PVA) or nylon 6,6 which is treated by rubbing to give a homogeneous molecular orientation. It is preferred that the alignment layer on one substrate is rubbed antiparallel from the alignment layer on the other substrate as shown by the arrows in Figure 2. This allows proper alignment of the liquid crystal, as known in the art.
- PVA polyvinylalcohol
- nylon 6,6 nylon 6,6
- Voltage is applied to the resistive patterned electrode set and conductive layer using means known in the art.
- a voltage is applied to the inner conductive surfaces of the substrates as shown in Figure 2. Both terminals of the power source must be connected to the patterned electrodes since the voltage is ohmically dropped across the electrodes.
- the unpatterned conductive layer (40 in Figure 1 ) serves as ground.
- one driver circuit is attached to the conductive layer and a separate driver circuit is attached to the resistive patterned electrode set. Electrical contacts can be made to the electrodes using thin wires or conductive strips at the edge of the lens, or by a set of conducting vias down the lens, as known in the art.
- the voltages supplied to the conductive layer and resistive patterned electrode set are dependent on the particular liquid crystal used, the thickness of the liquid crystal in the cell, the desired optical transmission, and other factors, as known in the art.
- the actual voltages used to produce the desired voltage drop can be determined by one of ordinary skill in the art without undue experimentation using the knowledge of the art and the disclosure herein. It is known in the art that various methods of controlling all aspects of the voltage applied to electrodes can be used, including a processor, a microprocessor, an integrated circuit, and a computer chip.
- layer does not require a perfectly uniform film. Some uneven thicknesses, cracks or other imperfections may be present, as long as the layer performs its intended purpose, as described herein.
- Zone-plate lenses activated by the application of specific voltages to capacitive electrode structures are known.
- voltages are applied individually to many small discrete annular electrodes to create a stepped-phase zone-plate.
- voltage is smoothly dropped in an ohmic fashion along fewer (and larger) annular resistive electrodes (forming a resistive patterned electrode set), providing ease of fabrication and operation, since there are fewer electrodes that require control electronics.
- the resistive electrodes are formed from a single layer of indium tin oxide (ITO) (preferably high-resistivity ITO).
- Diffraction efficiency into the desired focusing order is high in the present invention due to the close correspondence of voltage profiles to desired phase retardation curves. If required, systematic errors can be reduced by use of etch- textures in the electrodes, that is, by "resistance engineering” (as known in the art).
- thicker liquid-crystal layers can be used than using capacitance. This allows simultaneous phase-wrapping of different orders for three or more visible-light wavelength regions.
- the controllable retardation is less than that required for the functioning of a lens of reasonable size.
- the retardation curve can be "wrapped" by integer multiples of 2 ⁇ . It is convenient and orderly to do this at periodic values of u, producing a circular, radially linearly-stepped grating. Permanent zone-plate lenses are well known. One can approximate the retardation curves with steps of equal size in u which yields the well known sine dependence of diffraction efficiency in the "design" focusing-order. Resistance
- the drop of voltage in the resistive patterned electrode set is used to establish the desired optical phase retardation profile instead of the stepped function known for use in capacitive lenses.
- the resistance of annular slabs of uniform resistive material approximate the "ideal" optical phase retardation profile.
- the film can be textured to locally modify the resistance, as known in the art.
- the resistance R(r 1 , r 2 ) between two perfectly conducting concentric cylinders with radii ⁇ > r 2 defining an annular structure in a film or slab of material of uniform thickness t with resistivity p can be derived from the differential relationship (t is thickness):
- a thin film of liquid crystal is stressed by the voltage difference between two electrodes on opposite sides of the film, at least one of which has been patterned to allow application of voltages which create a distribution of phase retardations that function as a zone-plate lens.
- a smoothly varying voltage profile is established along a resistive electrode in the resistive patterned electrode set between two highly- conducting connections from the voltage source to the ring. (More connections allow for insertion of intermediate highly-conducting rings to "pin" voltages at specific values along the electrode, if desired). Total current I is injected across the electrode. The radial voltage distribution will mimic the resistance radial distribution of Eqs.
- Eqs. (4) represent the stress-inducing voltage drop across the liquid-crystal film.
- An insulating gap between successive annular electrodes is needed. Only one gap per phase-wrap is needed. It is located at the phase wrap, regardless of the integral multiple of 2 ⁇ in the phase-wrap. In these gaps the voltage applied is not high enough to reorient the liquid crystal and so the liquid crystal adopts the subthreshold configuration. This information can be included in the electrode design; since this is the correct retardation at this location (in the usual capacitive zone-plate configuration), the electrode can just pick up the work of setting the retardation at a larger value of r at a higher voltage value.
- Equation (4b) can resemble the line of Equation (1 ) due to (A) the automatic resynchronization of the phase retardations (usually at zero value) at each wrap and (B) the adjustment of the magnitude of I in each electrode because, even though the resistance changes in successive electrodes, the boundary conditions are set by the terminal voltages, which would usually be the same for all electrodes. In the first zone, Equation (4b) is not ideal.
- Equation (4b) has a consistent curvature. The magnitude of this curvature is very small after only a few phase wraps.
- the calculated average phase-retardation error (expressed as percentage of the total phase wrap), including the systematic error due to curvature - which is approximately half of the error, is ⁇ 5.8, 3.3, 2.4, 1.8, 1.3, 0.8, and 0.4 ⁇ in the wrap- zones following wrap number ⁇ 1 , 2, 3, 4, 5, 10, and 20 ⁇ , respectively, using the present invention. This is far and away superior to the calculated values ⁇ 12.5, 6.3, 3.1 , or 1.6 ⁇ in the ⁇ 2, 4, 8 or 16 ⁇ step approximations, respectively, in the stepped- phase capacitive case; these values are independent of location, and do not contain systematic offset error.
- a resistive lens using the simple voltage-pinned, segment-wise approximation of the perfect zone-plate lens is very good in the case of low-magnitude phase wraps. Since the relative error depends on radius, larger lenses work well for higher-magnitude phase wraps.
- Focusing with zone-plates is highly chromatic. It is chromatic with respect to (a) focal length in the design diffraction order, and (b) variation of efficiency of diffractions into that order.
- Eq. (8) shows that in addition to the efficiency being maximized at the ⁇ m , disregarding the weak dispersion of ⁇ n, the focal powers of the dominant diffraction orders for all m are identical. Thus the huge dispersion over the whole visible range which occurs when there is only diffraction via a fixed wrap-order is reduced. There are now several wavelengths (related by ratios of integers m'/m) which maximally diffract with identical focal power. There is still dispersion of f, but as ⁇ moves from ⁇ m toward ⁇ m ⁇ 1 . If one designs for 2 ⁇ n wrapping at 550 nm, one can calculate the satellite co-focusing wavelengths.
- the patterned resistive electrode set approach can approach nearly unity efficiency. As shown earlier, the nature of the wrapping and electro-optic driving force high compliance in uniform, untextured, resistive materials.
- a practical limitation to the creation of larger lenses is that the size of zones scales as r "1 while the number of zones scales as r 2 .
- the fabrication restrictions for these lenses are associated with insulating gaps and conducting-hng connections. These restrictions can be improved by using larger values of m.
- the resistive- electrode approach is simply adapted to the method of improving chromatic dispersion outlined above.
- the liquid crystal(s) used in the invention include those that form nematic, smectic, or cholesteric phases that possess a long-range orientational order that can be controlled with an electric field. It is preferred that the liquid crystal have a wide nematic temperature range, easy alignability, low threshold voltage, large electro- optic response and fast switching speeds, as well as proven stability and reliable commercial availability.
- E7 a nematic liquid crystal mixture of cyanobiphenyls and cyanoterphenyls sold by Merck is used.
- nematic liquid crystals examples include pentyl-cyano- biphenyl (5CB), (n-octyloxy)-4-cyanobiphenyl (80CB).
- Electroactive polymers can also be used in the invention. Electroactive polymers include any transparent optical polymeric material such as those disclosed in "Physical Properties of Polymers Handbook" by J. E. Mark, American Institute of Physics, Woodburry, N.Y., 1996, containing molecules having unsymmethcal polarized conjugated p electrons between a donor and an acceptor group (referred to as a chromophore) such as those disclosed in Organic Nonlinear Optical Materials” by Ch. Bosshard et al., Gordon and Breach Publishers, Amsterdam, 1995. Examples of polymers are as follows: polystyrene, polycarbonate, polymethylmethacrylate, polyvinylcarbazole, polyimide, polysilane.
- Electroactive polymers can be produced by: a) following a guest/host approach, b) by covalent incorporation of the chromophore into the polymer (pendant and main-chain), and/or c) by lattice hardening approaches such as cross-linking, as known in the art.
- Polymer liquid crystals may also be used in the invention.
- Polymer liquid crystals are also sometimes referred to as liquid crystalline polymers, low molecular mass liquid crystals, self-reinforcing polymers, in situ-composites, and/or molecular composites.
- PLCs are copolymers that contain simultaneously relatively rigid and flexible sequences such as those disclosed in "Liquid Crystalline Polymers: From Structures to Applications" by W. Brostow; edited by A. A. Collyer, Elsevier, New- York-London, 1992, Chapter 1.
- Examples of PLCs are: polymethacrylate comprising 4-cyanophenyl benzoate side group and other similar compounds.
- PDLCs Polymer dispersed liquid crystals
- NCAP nematic curvilinear aligned phases
- TIPS thermally induced phase separation
- SIPS solvent-induced phase separation
- PIPS polymerization-induced phase separation
- BDH-Merck mixtures of liquid crystal E7
- NOA65 Norland products, Inc.
- PSLCs Polymer-stabilized liquid crystals
- PSLCs are materials that consist of a liquid crystal in a polymer network in which the polymer constitutes less than 10% by weight of the liquid crystal.
- a photopolymehzable monomer is mixed together with a liquid crystal and an UV polymerization initiator. After the liquid crystal is aligned, the polymerization of the monomer is initiated typically by UV exposure and the resulting polymer creates a network that stabilizes the liquid crystal.
- PSLCs see, for instance: C. M. Hudson et al. Optical Studies of Anisotropic Networks in Polymer-Stabilized Liquid Crystals, Journal of the Society for Information Display, vol.
- Self-assembled nonlinear supramolecular structures may also be used in the invention.
- Self-assembled nonlinear supramolecular structures include electroactive asymmetric organic films, which can be fabricated using the following approaches: Langmuir-Blodgett films, alternating polyelectrolyte deposition (polyanion/polycation) from aqueous solutions, molecular beam epitaxy methods, sequential synthesis by covalent coupling reactions (for example: organothchlorosilane-based self-assembled multilayer deposition). These techniques usually lead to thin films having a thickness of less than about 1 ⁇ m.
- the devices of the invention can be used in a variety of applications known in the art, including lenses used for human or animal vision correction or modification.
- the lenses can be incorporated in spectacles, as known in the art.
- Spectacles can include one lens or more than one lens.
- the devices may also be used in display applications, as known to one of ordinary skill in the art without undue experimentation.
- the lenses of the invention can be used with conventional lenses and optics.
- Every device or combination of components described or exemplified can be used to practice the invention, unless otherwise stated. Additional components such as drivers to apply the voltages used, controllers for the voltages and any additional required optical components are known to one of ordinary skill in the art and incorporated without undue experimentation. Specific names of compounds are intended to be exemplary, as it is known that one of ordinary skill in the art can name the same compounds differently.
Abstract
Description
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Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
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BRPI0716076-3A2A BRPI0716076A2 (en) | 2006-09-01 | 2007-08-28 | ELECTRO-OPTICAL LENS USING RESISTANT ELECTRODES |
EP07853528A EP2057502A2 (en) | 2006-09-01 | 2007-08-28 | Electro-optic lenses employing resistive electrodes |
AU2007289295A AU2007289295A1 (en) | 2006-09-01 | 2007-08-28 | Electro-optic lenses employing resistive electrodes |
CA002661914A CA2661914A1 (en) | 2006-09-01 | 2007-08-28 | Electro-optic lenses employing resistive electrodes |
JP2009526867A JP2010503026A (en) | 2006-09-01 | 2007-08-28 | Electro-optic lens using resistive electrodes |
Applications Claiming Priority (2)
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US82432506P | 2006-09-01 | 2006-09-01 | |
US60/824,325 | 2006-09-01 |
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WO2008027890A2 true WO2008027890A2 (en) | 2008-03-06 |
WO2008027890A3 WO2008027890A3 (en) | 2008-08-07 |
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PCT/US2007/076994 WO2008027890A2 (en) | 2006-09-01 | 2007-08-28 | Electro-optic lenses employing resistive electrodes |
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US (1) | US20080212007A1 (en) |
EP (1) | EP2057502A2 (en) |
JP (1) | JP2010503026A (en) |
KR (1) | KR20090051111A (en) |
CN (1) | CN101548224A (en) |
AR (1) | AR062574A1 (en) |
AU (1) | AU2007289295A1 (en) |
BR (1) | BRPI0716076A2 (en) |
CA (1) | CA2661914A1 (en) |
TW (1) | TW200819816A (en) |
WO (1) | WO2008027890A2 (en) |
Cited By (4)
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EP2466364A1 (en) | 2010-12-20 | 2012-06-20 | Carl Zeiss Vision GmbH | Device with a spectacle lens with adjustable effect and method for adjusting the effect of a spectacle lens |
US9280020B2 (en) | 2009-06-19 | 2016-03-08 | Kent State University | Tunable electrode-optic liquid crystal lenses having resistive bridges and methods for forming the lenses |
US10599006B2 (en) | 2016-04-12 | 2020-03-24 | E-Vision Smart Optics, Inc. | Electro-active lenses with raised resistive bridges |
US11397367B2 (en) | 2016-04-12 | 2022-07-26 | E-Vision Smart Optics, Inc. | Electro-active lenses with raised resistive bridges |
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US9698129B2 (en) * | 2011-03-18 | 2017-07-04 | Johnson & Johnson Vision Care, Inc. | Stacked integrated component devices with energization |
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US9889615B2 (en) | 2011-03-18 | 2018-02-13 | Johnson & Johnson Vision Care, Inc. | Stacked integrated component media insert for an ophthalmic device |
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Also Published As
Publication number | Publication date |
---|---|
BRPI0716076A2 (en) | 2014-02-18 |
WO2008027890A3 (en) | 2008-08-07 |
AU2007289295A1 (en) | 2008-03-06 |
US20080212007A1 (en) | 2008-09-04 |
EP2057502A2 (en) | 2009-05-13 |
CA2661914A1 (en) | 2008-03-06 |
AR062574A1 (en) | 2008-11-19 |
JP2010503026A (en) | 2010-01-28 |
TW200819816A (en) | 2008-05-01 |
KR20090051111A (en) | 2009-05-20 |
CN101548224A (en) | 2009-09-30 |
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