WO2008017838A1 - Fuel synthesis - Google Patents
Fuel synthesis Download PDFInfo
- Publication number
- WO2008017838A1 WO2008017838A1 PCT/GB2007/003015 GB2007003015W WO2008017838A1 WO 2008017838 A1 WO2008017838 A1 WO 2008017838A1 GB 2007003015 W GB2007003015 W GB 2007003015W WO 2008017838 A1 WO2008017838 A1 WO 2008017838A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- ions
- membrane
- cathode
- electrode compartment
- anode
- Prior art date
Links
- 239000000446 fuel Substances 0.000 title description 10
- 238000003786 synthesis reaction Methods 0.000 title description 9
- 230000015572 biosynthetic process Effects 0.000 title description 8
- 239000012528 membrane Substances 0.000 claims abstract description 42
- 150000002500 ions Chemical class 0.000 claims abstract description 26
- 238000000034 method Methods 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 14
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 14
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 9
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 7
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- 239000007788 liquid Substances 0.000 claims description 18
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 16
- 230000002745 absorbent Effects 0.000 claims description 11
- 239000002250 absorbent Substances 0.000 claims description 11
- 239000006096 absorbing agent Substances 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 3
- 239000011736 potassium bicarbonate Substances 0.000 claims description 3
- 229910000028 potassium bicarbonate Inorganic materials 0.000 claims description 3
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical group [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 claims description 3
- 230000001172 regenerating effect Effects 0.000 claims description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 50
- 229910002092 carbon dioxide Inorganic materials 0.000 description 49
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 8
- 239000000243 solution Substances 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 239000010411 electrocatalyst Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 229910000027 potassium carbonate Inorganic materials 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- -1 K2CO3) Chemical class 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 2
- 230000036571 hydration Effects 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- 239000011244 liquid electrolyte Substances 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000002551 biofuel Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000012982 microporous membrane Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000009919 sequestration Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000008400 supply water Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/50—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon dioxide with hydrogen
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/20—Processes
- C25B3/25—Reduction
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
- C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0656—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants by electrochemical means
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Definitions
- GB2418430 describes a method of permanent sequestration of carbon dioxide.
- Hydrocarbon fuels are manufactured using CO 2 from the atmosphere and hydrogen generated from a "carbon-free” or “low carbon” process, such as electrolysis.
- the method of hydrocarbon synthesis exemplified is the well-known Fischer-Tropsch(F-T) process, which converts syngas (a mixture of CO and H 2 ) into hydrocarbons, according to the equation:
- the syngas needed for this reaction can be prepared from CO 2 and H 2 : CO 2 + H 2 - « ⁇ * * CO + H 2 O (water gas shift reaction).
- An alternative method of CO 2 capture is to use a hydrophobic hollow fibre membrane and KOH as a solvent for the selective absorption of CO 2 from atmospheric air, as described by Stucki et al (1995 International Journal of Hydrogen Energy 20(8), pp. 653-663).
- the regeneration of KOH can thus be achieved in an electrochemical cell from which a mixture of CO 2 and hydrogen is extracted; this could potentially be used to feed, for example, a conventional methanol synthesis reactor.
- This reactor also makes use of the water/gas shift reaction and F-T chemistry.
- the present invention is a method for the manufacture of a hydrocarbon using an electrolysis cell having first and second electrode compartments separated by a membrane across which ions can migrate, which comprises forming ions from water in the first electrode compartment, and supplying CO 2 to the second electrode compartment, where it can undergo reduction by the ions.
- Figure 1 is a schematic cross-section of a synthesis cell suitable for carrying out the method of the invention. Description of the Preferred Embodiments
- An electrolytic cell suitable for use in the invention comprises a membrane electrode assembly, the membrane electrode assembly comprising a membrane across which ions can migrate, separating catalyst electrode layers at the cathode and anode.
- the membrane is a proton exchange membrane.
- the membrane may be an anionic membrane.
- the membrane across which ions can migrate is a proton exchange membrane.
- water may be oxidised at the anode to form oxygen and H + ions.
- the H + ions can then migrate through the membrane to the cathode, where they can reduce CO 2 .
- the CO 2 , H + ions and electrons can react on the surface of a suitable catalyst to form one or more hydrocarbons. Examples of such reactions are as follows:
- the membrane across which ions can migrate is an anionic exchange membrane.
- water may be split at the cathode to form hydrogen and OH " ions.
- the OH " ions can then migrate through the membrane to the anode, where they can reduce CO 2 .
- the membrane is a hydrophilic ionic membrane (e.g. as disclosed in WO03/023890, the content of which is incorporated herein by reference). Membrane materials of this nature make it possible to supply water only one side of the electrolysis cell, whilst still maintaining hydration of the membrane.
- a hydrophilic ionic membrane is used as a cationic exchange membrane i.e. transport H + ions, water may not need to be supplied to the cathode; the water from the anode can be sufficient to hydrate the entire membrane.
- a hydrophilic ionic membrane is used as an anionic exchange membrane, i.e. to transport OH " ions, water may not need to be supplied to the anode; the water from the cathode can be sufficient to hydrate the entire membrane.
- a method for the manufacture of hydrocarbons comprises absorbing CO 2 from the atmosphere using of membrane absorber containing a liquid absorbent, regenerating the liquid absorbent by desorbing CO 2 in an electrochemical cell, and supplying CO 2 to an electrolysis cell of the invention.
- the fuel produced will have a neutral effect on the environment in terms of carbon emissions.
- membrane absorber is a porous, water- repelling membrane for the transfer of compounds between a gas and a liquid.
- the membrane forms a gas-permeable barrier between a liquid and a gas, where components can diffuse through the pores and are absorbed by a suitable liquid (liquid absorbent).
- the membrane absorber comprises a hydrophobic microporous hollow fibre membrane.
- liquid absorbent is any liquid compound that is capable of reversibly binding CO 2 .
- the liquid absorbent is KOH.
- a KOH solution is transformed into a solution of carbonates (including K 2 CO 3 ), the relative amounts of carbonate and bicarbonate depending on the CO 2 partial pressure.
- Regeneration of liquid absorbent and CO 2 from CO 2 -bound liquid absorbent occurs in an electrochemical cell.
- the liquid absorbent is KOH
- K 2 CO 3 enters the electrochemical at the anode.
- a net replacement of the potassium ions by hydonium takes place, to form KHCO 3 in a first step, and eventually H 2 CO 3 , with subsequent stripping of the CO 2 with the oxygen stream.
- KOH is regenerated in the cathode compartment.
- atmospheric CO 2 is absorbed by a hydrophobic microporous hollow fibre membrane absorber operating with a KOH solution as the liquid absorber.
- the K 2 CO 3 solution is fed to a membrane electrolyser, where the CO 2 and KOH are regenerated by the electrolysis process.
- the regenerated KOH is recycled to the membrane absorber, and the CO 2 stream is fed to the final component of the process, a second electrolysis cell.
- water is oxidised at the anode to form oxygen and hydrogen ions.
- the CO 2 , H + ions and electrons react on the surface of a suitable catalyst.
- Example 1 illustrates the invention.
- a test rig incorporating a cell with the configuration shown in Figure 1 can be constructed.
- This cell comprises a Proton Exchange Membrane (3) separating a platinum mesh anode (1) and a copper mesh cathode (5).
- the Proton Exchange Membrane (3) made of a hydrophilic ionic material as described in WO03/023890, divides the structure into two chambers.
- the platinum mesh (1) is mounted and wired to serve as a the current collector for the anode.
- An electrocatalyst (4) used in the cathode is a mixture of Cu, Zn and Al oxides with an approximate composition 45 wt% CuO, 27.5 wt% ZnO and 27.5 wt% AI 2 O 3 , deposited on a carbon cloth to obtain a final loading of 1 mg/cm 2 CuO, and mounted in the cell in intimate contact with the PEM (3).
- the current collector for the cathode is the copper mesh (5) connected to an external lead.
- the cell is designed in such way that the assembly of the current collectors (1 ,5), electrocatalysts (2,4) and PEM (3) is compressed together by the cell structure to ensure a good transfer of ions, electrons and molecules to the reaction points on the electrocatalyst.
- the CO 2 introduced into the cathode chamber (6) is initially passed through a moisture trap, a hydrocarbons trap and an oxygen trap (Agilent).
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0822641.7A GB2451999B (en) | 2006-08-08 | 2007-08-08 | Fuel synthesis |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0615731.7 | 2006-08-08 | ||
GBGB0615731.7A GB0615731D0 (en) | 2006-08-08 | 2006-08-08 | Fuel synthesis |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2008017838A1 true WO2008017838A1 (en) | 2008-02-14 |
Family
ID=37056008
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB2007/003015 WO2008017838A1 (en) | 2006-08-08 | 2007-08-08 | Fuel synthesis |
Country Status (2)
Country | Link |
---|---|
GB (2) | GB0615731D0 (en) |
WO (1) | WO2008017838A1 (en) |
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2931168A1 (en) * | 2008-05-15 | 2009-11-20 | Areva Sa | PROCESS FOR PRODUCING CXHYOZ COMPOUNDS BY REDUCING CARBON DIOXIDE (CO2) AND / OR CARBON MONOXIDE (CO) |
WO2011055322A1 (en) * | 2009-11-04 | 2011-05-12 | Ffgf Limited | The production of hydrocarbons |
WO2012119958A1 (en) * | 2011-03-04 | 2012-09-13 | Antecy B.V. | Catalytic process for converting carbon dioxide to a liquid fuel or platform chemical |
EP2509913A2 (en) * | 2009-12-10 | 2012-10-17 | Antecy B.V. | Improved catalytic process for reacting carbon dioxide with hydrogen |
US8313634B2 (en) | 2009-01-29 | 2012-11-20 | Princeton University | Conversion of carbon dioxide to organic products |
US8500987B2 (en) | 2010-03-19 | 2013-08-06 | Liquid Light, Inc. | Purification of carbon dioxide from a mixture of gases |
US8524066B2 (en) | 2010-07-29 | 2013-09-03 | Liquid Light, Inc. | Electrochemical production of urea from NOx and carbon dioxide |
US8562811B2 (en) | 2011-03-09 | 2013-10-22 | Liquid Light, Inc. | Process for making formic acid |
US8568581B2 (en) | 2010-11-30 | 2013-10-29 | Liquid Light, Inc. | Heterocycle catalyzed carbonylation and hydroformylation with carbon dioxide |
US8592633B2 (en) | 2010-07-29 | 2013-11-26 | Liquid Light, Inc. | Reduction of carbon dioxide to carboxylic acids, glycols, and carboxylates |
WO2013178803A1 (en) * | 2012-05-31 | 2013-12-05 | Hettich Holding Gmbh & Co. Ohg | Process and apparatus for the electrolytic synthesis of methanol and/or methane |
US8658016B2 (en) | 2011-07-06 | 2014-02-25 | Liquid Light, Inc. | Carbon dioxide capture and conversion to organic products |
US8721866B2 (en) | 2010-03-19 | 2014-05-13 | Liquid Light, Inc. | Electrochemical production of synthesis gas from carbon dioxide |
US8845878B2 (en) | 2010-07-29 | 2014-09-30 | Liquid Light, Inc. | Reducing carbon dioxide to products |
US8845877B2 (en) | 2010-03-19 | 2014-09-30 | Liquid Light, Inc. | Heterocycle catalyzed electrochemical process |
US8961774B2 (en) | 2010-11-30 | 2015-02-24 | Liquid Light, Inc. | Electrochemical production of butanol from carbon dioxide and water |
US9090976B2 (en) | 2010-12-30 | 2015-07-28 | The Trustees Of Princeton University | Advanced aromatic amine heterocyclic catalysts for carbon dioxide reduction |
EP3046172A1 (en) * | 2013-09-12 | 2016-07-20 | Japan Aerospace Exploration Agency | Solid polymer power generation or electrolysis method and system |
ES2599382A1 (en) * | 2015-07-31 | 2017-02-01 | Abengoa Research, S.L. | Method of obtaining methanol from co2 and electrochemical system to perform it (Machine-translation by Google Translate, not legally binding) |
CN107099815A (en) * | 2017-04-24 | 2017-08-29 | 太原师范学院 | A kind of application of Bipolar Membrane surface powder state photochemical catalyst in CO2 reduction |
CN111655904A (en) * | 2018-01-29 | 2020-09-11 | 西门子股份公司 | Porous electrode for electrochemical reaction of organic compounds in two immiscible phases in electrochemical flow reactor |
Citations (4)
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US4547273A (en) * | 1984-06-07 | 1985-10-15 | Energy Conversion Devices, Inc. | Mobile atom insertion reaction, mobile atom transmissive membrane for carrying out the reaction, and reactor incorporating the mobile atom transmissive membrane |
US4959131A (en) * | 1988-10-14 | 1990-09-25 | Gas Research Institute | Gas phase CO2 reduction to hydrocarbons at solid polymer electrolyte cells |
US5928806A (en) * | 1997-05-07 | 1999-07-27 | Olah; George A. | Recycling of carbon dioxide into methyl alcohol and related oxygenates for hydrocarbons |
WO2006006164A2 (en) * | 2004-07-12 | 2006-01-19 | Aytec Avnim Ltd. | Method for producing fuel from captured carbon dioxide |
Family Cites Families (1)
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---|---|---|---|---|
US5599638A (en) * | 1993-10-12 | 1997-02-04 | California Institute Of Technology | Aqueous liquid feed organic fuel cell using solid polymer electrolyte membrane |
-
2006
- 2006-08-08 GB GBGB0615731.7A patent/GB0615731D0/en not_active Ceased
-
2007
- 2007-08-08 WO PCT/GB2007/003015 patent/WO2008017838A1/en active Application Filing
- 2007-08-08 GB GB0822641.7A patent/GB2451999B/en not_active Expired - Fee Related
Patent Citations (4)
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US4959131A (en) * | 1988-10-14 | 1990-09-25 | Gas Research Institute | Gas phase CO2 reduction to hydrocarbons at solid polymer electrolyte cells |
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Non-Patent Citations (1)
Title |
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WO2009150352A3 (en) * | 2008-05-15 | 2010-02-18 | Areva | Process for producing compounds of the c<sb>x</sb>h<sb>y</sb>o<sb>2</sb> type by reduction of carbon dioxide (co<sb>2</sb>) and/or carbon monoxide (co) |
CN102056866A (en) * | 2008-05-15 | 2011-05-11 | 阿海珐 | Process for producing compounds of the CxHyO2 type by reduction of carbon dioxide (CO2) and/or carbon monoxide (CO) |
FR2931168A1 (en) * | 2008-05-15 | 2009-11-20 | Areva Sa | PROCESS FOR PRODUCING CXHYOZ COMPOUNDS BY REDUCING CARBON DIOXIDE (CO2) AND / OR CARBON MONOXIDE (CO) |
RU2493293C2 (en) * | 2008-05-15 | 2013-09-20 | Арева | METHOD OF PRODUCING CxHyOz TYPE COMPOUNDS BY REDUCING CARBON DIOXIDE (CO2) AND/OR CARBON MONOXIDE (CO) |
US8313634B2 (en) | 2009-01-29 | 2012-11-20 | Princeton University | Conversion of carbon dioxide to organic products |
US8986533B2 (en) | 2009-01-29 | 2015-03-24 | Princeton University | Conversion of carbon dioxide to organic products |
US8663447B2 (en) | 2009-01-29 | 2014-03-04 | Princeton University | Conversion of carbon dioxide to organic products |
US9469910B2 (en) | 2009-11-04 | 2016-10-18 | Ffgf Limited | Production of hydrocarbons |
AU2010316702B2 (en) * | 2009-11-04 | 2016-07-21 | Ffgf Limited | The production of hydrocarbons |
RU2555841C2 (en) * | 2009-11-04 | 2015-07-10 | Эф-Эф-Дж-Эф Лимитед | Production of hydrocarbons |
CN102648307B (en) * | 2009-11-04 | 2015-05-27 | Ffgf有限公司 | Production of hydrocarbons |
CN102648307A (en) * | 2009-11-04 | 2012-08-22 | Ffgf有限公司 | The production of hydrocarbons |
WO2011055322A1 (en) * | 2009-11-04 | 2011-05-12 | Ffgf Limited | The production of hydrocarbons |
EP2509913A2 (en) * | 2009-12-10 | 2012-10-17 | Antecy B.V. | Improved catalytic process for reacting carbon dioxide with hydrogen |
US8721866B2 (en) | 2010-03-19 | 2014-05-13 | Liquid Light, Inc. | Electrochemical production of synthesis gas from carbon dioxide |
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GB0822641D0 (en) | 2009-01-21 |
GB2451999B (en) | 2012-03-07 |
GB2451999A (en) | 2009-02-18 |
GB0615731D0 (en) | 2006-09-20 |
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