WO2006136617A2 - Mixture of sulfide dyes - Google Patents
Mixture of sulfide dyes Download PDFInfo
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- WO2006136617A2 WO2006136617A2 PCT/EP2006/066325 EP2006066325W WO2006136617A2 WO 2006136617 A2 WO2006136617 A2 WO 2006136617A2 EP 2006066325 W EP2006066325 W EP 2006066325W WO 2006136617 A2 WO2006136617 A2 WO 2006136617A2
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- alkyl
- crc
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- hydrogen
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- 0 CCC(CC)(*[N+](*)(*)C(CC)(CC)N)[N+](*)(*)*=C Chemical compound CCC(CC)(*[N+](*)(*)C(CC)(CC)N)[N+](*)(*)*=C 0.000 description 3
- DHYDDIAKNYIPMG-UMOLYRQISA-O CCN(CC)c(c(C(OC)=O)c1)cc(O2)c1C(c1ccccc1C(OCCSSCCOC(c(cccc1)c1C(c(c(O1)c3)cc(C(OC)=O)c3N(CC)CC)=C(C=C3)C1=CC3=[N+](CC)CC)=O)=O)=C(C=C1)C2=C/C1=[NH+]/CC Chemical compound CCN(CC)c(c(C(OC)=O)c1)cc(O2)c1C(c1ccccc1C(OCCSSCCOC(c(cccc1)c1C(c(c(O1)c3)cc(C(OC)=O)c3N(CC)CC)=C(C=C3)C1=CC3=[N+](CC)CC)=O)=O)=C(C=C1)C2=C/C1=[NH+]/CC DHYDDIAKNYIPMG-UMOLYRQISA-O 0.000 description 1
- GYNBRTUYPVOSGE-BUHFOSPRSA-N CN(C)c(cc1)ccc1/N=N/c1ncc[s]1 Chemical compound CN(C)c(cc1)ccc1/N=N/c1ncc[s]1 GYNBRTUYPVOSGE-BUHFOSPRSA-N 0.000 description 1
- KJSNPHZBXNRACE-UHFFFAOYSA-O CN(C)c(cc1)ccc1N=NC(Sc(cccc1)c1[NH2+]CCSSCC[n+]1c(N=Nc(cc2)ccc2N(C)C)[s]c2c1cccc2)=C Chemical compound CN(C)c(cc1)ccc1N=NC(Sc(cccc1)c1[NH2+]CCSSCC[n+]1c(N=Nc(cc2)ccc2N(C)C)[s]c2c1cccc2)=C KJSNPHZBXNRACE-UHFFFAOYSA-O 0.000 description 1
- QOBNFHWLKCDWML-UHFFFAOYSA-P C[n]1c(NNc(cc2)ccc2NCC[NH+](C)C)[n+](C)cc1 Chemical compound C[n]1c(NNc(cc2)ccc2NCC[NH+](C)C)[n+](C)cc1 QOBNFHWLKCDWML-UHFFFAOYSA-P 0.000 description 1
- WCZZSWFMSGKDIF-UHFFFAOYSA-N Nc(c(C(c1c2cccc1)=O)c1C2=O)ccc1NCCC[n]1cncc1 Chemical compound Nc(c(C(c1c2cccc1)=O)c1C2=O)ccc1NCCC[n]1cncc1 WCZZSWFMSGKDIF-UHFFFAOYSA-N 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
- A61K8/4913—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid
- A61K8/492—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid having condensed rings, e.g. indol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
- A61K8/4926—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having six membered rings
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
- A61K8/4946—Imidazoles or their condensed derivatives, e.g. benzimidazoles
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
- A61K8/496—Triazoles or their condensed derivatives, e.g. benzotriazoles
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
- A61K8/498—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom having 6-membered rings or their condensed derivatives, e.g. coumarin
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0034—Mixtures of two or more pigments or dyes of the same type
Definitions
- the present invention relates to mixtures of sulfide dyes, compositions thereof, and to their use for the dyeing of organic materials, such as keratin fibers, wool, leather, silk, cellulose or polyamides, especially keratin-containing fibers, cotton or nylon, and preferably hair, more preferably human hair.
- organic materials such as keratin fibers, wool, leather, silk, cellulose or polyamides, especially keratin-containing fibers, cotton or nylon, and preferably hair, more preferably human hair.
- cationic dyes can be used for the dyeing of organic material, for example keratin, silk, cellulose or cellulose derivatives, and also synthetic fibers, for example polyamides. Cationic dyes exhibit very brilliant shades. A disadvantage is their unsatisfactory fastness to washing.
- the technical problem is to provide dyes that are distinguished by deep dying having good fastness properties with respect to washing, light, shampooing and rubbing.
- the present invention relates to a dye composition
- a dye composition comprising a mixture of dyes selected from the compounds of formula (1 ) D 1 — (Z 1 ). — Y 1 — S — A , wherein
- A is hydrogen; a radical of formula (1a) * — S-Y 2 - — (Z 2 ) r — D 2 ; or a thio ester group of
- E E is O; S; or N-R 3 ;
- B 1 is -OR b ; -NR b R c , or -SR b ;
- R 3 , Rb and R c independently from each other are hydrogen; d-C ⁇ alkyl; C6-Ci 2 aryl; or Ce- Ci 2 aryl-Ci-Ci 2 alkyl;
- D 1 and D 2 independently from each other is a radical of formula (I a 1 ) ;
- the mixture comprisies at least two compounds of formula (1 ), and/or at least two compounds of formula (2) and/or at least one compound of formula (1 ) and at least one compound of formula (2), wherein
- Ri, R 2 and R 3 independently from each other hydrogen; halogen; CrCi 6 alkyl, which is saturated or unsaturated, linear or branched, substituted or unsubstituted, or interrupted or uninterrupted with heteroatoms; phenyl, which substituted or unsubstituted; a carboxylic acid radical; sulfonic acid radical; hydroxy; nitrile; CrCi 6 alkoxy, (poly)-hydroxy-
- Rd and R e independently from each other are hydrogen; unsubstituted or substituted C 1 - C i4 alkyl; C 2 -C 14 alkenyl; C 5 -Ci 0 aryl; Ci-Cioalkyl-C 5 -Cioaryl; or C 5 -Cioaryl-Ci-Ci O alkyl;
- R 33 and R 34 independently from each other are hydrogen; CrCi 2 alkyl, which may be substituted by one or more CrC 5 alkyl, CrC 5 -alkoxy, hydroxy or -(CO)-H;
- phenyl or phenyl-CrC 4 alkyl wherein the phenyl moiety may be substituted by one or more CrC 5 alkyl, CrC 5 alkoxy, halogen, -NH 2 , mono-Cr C 5 alkylamino, di-Ci-C 5 alkylamino, -NO 2 , carboxy or hydroxy;
- R 4 , R 5 and Re independently from each other are hydrogen; Ci-C 2 oalkyl or Ci-C 2 oalkoxy, which may be substituted by one or more CrC 5 alkoxy, halogen, -NH 2 , mono-Ci-C 5 alkylamino, di-Ci-C 5 alkylamino, -NO 2 or hydroxy; C 3 -C 6 cycloalkyl; -C(O)H; -C(O)-C r C 5 alkyl; halogen;
- W 1 , W 2 , W 3 or W 4 is -N + ; and the radical ⁇ (Z-OrY 1 -S-A is bonded to W 1 or W 2 ;
- R 35 and R 36 independently from each other are hydrogen;
- R 7 , R 8 , Rg and R 10 independently from each other are hydrogen; CrC 20 alkyl; CrC 20 alkoxy; C 3 -
- X 1 is CrCi 8 alkylene; -(CO)-CrCi 8 alkylene CrCi 8 arylene; C 6 -Ci8arylene-Ci-Ci 2 alkylene; or -(OCH 2 CH 2 ) n2 -O-;
- T 2 is a radical of formula (I c 2 ) * — N " -x,- ; or -0-(X 3 )Si
- Q 2 is a cationic biradical of a saturated, aromatic or heteroaromatic group; or a radical of
- R f , R g and R h independently from each other are hydrogen; Ci-Ci 4 alkyl; C 2 -Ci 4 alkenyl; C 6 -Ci 0 aryl; C 6 -Cioaryl-Ci-Ci O alkyl; or Ci-Cioalkyl(C 5 -Cioaryl);
- X 2 , X 3 and X 4 independently from each other are CrC 18 alkylene;
- R 37 is hydrogen; or CrC 20 alkyl
- R 38 , R 3 g and R 40 independently from each other are hydrogen, CrC 20 alkyl, C 4 -Ci 2 cycloalkyl, C 6 -Ci 3 aralkyl; phenyl-CrC 5 alkyl; or R 38 and R 3 g together with the linking nitrogen atom form a C 4 -Ci 2 -membered heterocyclic ring which may be interrupted by one or more than one -O- or -NH- goups; n-[ is is 0 or 1 ; p is 0; or 1 ; s is 0; or 1 ; t is O; or 1 ; u is O or i ;
- R 11 , R 12 and R 13 independently from each other are hydrogen; CrC 2 oalkyl or CrC 2 oalkoxy, which may be substituted by one or more CrC 5 alkoxy, halogen, -NH 2 , mono-d- C 5 alkylamino, di-CrC 5 alkylamino, -NO 2 or hydroxy; C 3 -Cecycloalkyl; -C(O)H; -C(O)-C 1 - C 5 alkyl; -C(O)OH; -C(O)O-C r C 5 alkyl; halogen; NO 2 ; OH; SH; phenyl, which may be substituted by one or more C- ⁇ -C 5 alkyl, C- ⁇ -C 5 alkoxy, halogen, -NH 2 , mono-Cr
- Q 3 is is -C(O)-; -C(O)O-; -OCO-; -N(R)-X 5 -; -CON(R)-; -(R)NC(O)-; -0-; -S-; -S(O)-; or -S(O) 2 -; T 3 is the direct bond; *— N— * ; or a cationic biradical of a saturated, aromatic or
- R heteroaromatic group
- R 1 , R k , Ri independently from each other are CrCi 4 alkyl; C 2 -Ci 4 alkenyl; C 6 -Ci 0 aryl; C 6 -Ci 0 aryl- d-Cioalkyl; or Ci-Cioalkyl(C 5 -Cioaryl);
- R 4 i and R 42 independently from each other are hydrogen; d-C ⁇ alkyl, which may be substituted by one or more CrC 5 alkyl, CrC 5 -alkoxy, hydroxy or -(CO)-H; -(CO)-Cr C 5 alkyl; phenyl or phenyl-Ci-C 4 alkyl, wherein the phenyl moiety may be substituted by one or more CrC 5 alkyl, CrC 5 alkoxy, halogen, -NH 2 , mono-Ci-C 5 alkylamino, di-Cr
- R 45 at least one of the radicals Rn, Ri 2 or R 13 is NO 2 ;
- R 43 , R 44 and R 45 independently from each other are hydrogen; Ci-Ci 4 alkyl; C 2 -Ci 4 alkenyl; C 6 -
- Ciocycloalkylene C 5 -Ci 0 arylene; or C 5 -Cioarylene-(Ci-Ci O alkylene); R i4 is N + R 46 R 47 ;
- R 46 and R 47 independently from each other are hydrogen; Ci-Ci 2 alkyl; or phenyl-Ci-C 4 alkyl; or R 46 and/or R 47 are a bivalent C 3 -C 6 alkylene radical which is linked to the carbon atoms C 1 or C 2 in formula (1 e) respectively and, together with the linking nitrogen atom form a 6 to 16- membered carbocyclic ring; Ris is is NR 48 R 49 ; or OR 48 ;
- R 48 and R 49 independently from each other are hydrogen; Ci-Ci 2 alkyl; or phenyl-Ci-C 4 alkyl; or R 48 and R 49 are a bivalent C 3 -C 6 alkylene radical which is linked to the carbon atoms C 3 or C 4 in formula (1e) respectively and, together with the linking nitrogen or oxygen atom form a 6 to 16-membered carbocyclic ring; or R 48 and R 49 together with the linking nitrogen atom form a 4 to 8 membered carbocyclic ring; Ri 6 , Ri 7 , Ri 8 , Ri 9 and R 20 independently form each other are hydrogen; Ci-Ci 2 alkyl; halogen;
- NR 5 oR 5 i or a radical of formula (1 ei) * — / ; o R 5O and R 5 i independently from each other are hydrogen; d-C ⁇ alkyl; phenyl-Ci-C 4 alkyl; or a
- V 1 is -O-; Or -NR 53 ;
- R 52 and R 53 independently from each other are hydrogen; or Ci-C 5 alkyl; Hal is a halogen atom; and wherein at least one of Ri 6 , R 1 7, R 1 8, R 1 9 and R 20 is hydrogen; B 2 and B 3 , independently from each other are C6-Cioaryl; or a 5-7-membered heterocyclic compound, which may be substituted by Ci-Ci 2 alkyl, Ci-Ci 2 alkoxy, phenyl, hydroxy, halogen, sulfonic acid, carboxylate, or by the radical -NR 54 R 55 or -OR 5 6; B 4 is C 6 -Ci 0 arylene, or a bivalent radical of a 5-7-membered heterocyclic compound, which may be substituted by CrCi 2 alkyl, Ci-Ci 2 alkoxy, phenyl, hydroxy, halogen, sulfonic acid, carboxylate, or by the radical -NR 54 R 55 or -OR 56 ;
- R 54 and R 55 together with the linking nitrogen atom form a 5 to 7 membered heterocyclic ring
- R 23 , R 24 R 25 and R 26 each independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted CrCi 4 alkyl, C 2 -Ci 4 alkenyl, C 6 -Ci 0 aryl, C 6 -Cioaryl-Ci-Ci O alkyl or C 5 -Cioalkyl(C 5 -Cioaryl); or
- R 23 and R 24 and/or R 25 and R 26 together with the linking nitrogen atom form a 5 to 7 membered carbocyclic ring which may contain one or more than one hetero atom; or R 23 is linked to Ci together with N + forming a 5-7 membered carbocyclic ring; or R 24 is linked to C 2 together with N + forming a 5-7 membered carbocyclic ring; X 7 is -O-; Or -N(R 24 )-; or -S-; R 27 is hydrogen; or d-C 5 alkyl;
- R 2 S is a radical of formula (Ig 1 ) ; (ig 2 ) or
- R 27 and R 28 together with the linking carbon atom 1 C form a 6 to 10 membered carbocyclic ring which may optionally be a condensated aromatic system and may contain one or more than one hetero atom;
- R 57 , R 58 and R 59 independently from each other are hydrogen; or Ci-C 5 alkyl;
- R 2 g, R 30 , R3 1 and R 32 independently from each other are hydrogen; hydroxy; -S-H; -S-Cr
- (CO)-CrC 5 alkyl C 6 -Ci 2 aryl, C 6 -Ci 2 aryl-Ci-C 4 alkyl or C 6 -Ci 2 aryl-Ci-C 4 alkoxy, wherein the aryl moiety may be substituted by one or more CrC 5 alkyl, CrC 5 alkoxy, -(CO)-H or -(CO)-CrC 5 alkyl; -NR 69 R 70 ; -NO 2 ; -(CO)-H; or -(CO)-C r C 5 alkyl;
- R 69 and R 70 independently from each other are hydrogen; hydroxy; CrCi 2 alkyl; hydroxy-Cr C i2 alkyl; -(CO)-H; -(CO)-C r C 5 alkyl; phenyl or phenyl-C r C 5 alkyl, wherein the phenyl moiety may be substituted by one or more CrC 5 alkyl, CrC 5 alkoxy, halogen, -NH 2 , mono- Ci-C 5 alkylamino, di-Ci-C 5 alkylamino, -NO 2 , carboxy or hydroxy; Yi and Y 2 independently from each other are unsubstituted or substituted, straight-chain or branched, interrupted or uninterrupted CrCi O alkylene; C 5 -Ci 0 cycloalkylene; C 5 -Ci 0 arylene; or-C 5 -Ci 0 arylene-(Ci-Ci 0 alkylene);
- Z 1 and Z 2 independently from each other are *-(CH 2 ) q -C(O)-**; *-(CH 2 CH 2 -O) w -**;
- G 1 and G 2 independently from each other are N; -O-; -S-; or a radical of CRe 4 ;
- the asterix * indicates the linkage to D 1 and/or D 2 ;
- the asterix ** indicates the linkage to Y 1 and/or Y 2 ;
- R 6 O, R 6 i, R ⁇ 2 , R ⁇ 3 and R 64 independently from each other are hydrogen; CrC 14 alkyl; C 2 -
- C 14 alkenyl; C 6 -C 10 aryl; R 2 g, R 30 , R 31 and R 32 independently from each other are hydrogen; hydroxy; -S-H; -S-C- ⁇ -C 12 alkyl; halogen; CrC 12 alkyl or CrC 12 alkoxy, which may be substituted by one or more C r C 5 alkyl, C r C 5 -alkoxy, hydroxy, -(CO)-H or -(CO)-C r C 5 alkyl; -NR 65 R 66 ; -NO 2 ; -(CO)H or (CO)-C r C 5 alkyl; C 6 -C 12 aryl, C 6 -C 12 aryl-C r C 4 alkyl or Ce-C ⁇ aryl-d-C ⁇ lkoxy, wherein the aryl moiety may be substituted by one or more CrC 5 alkyl, C- ⁇ -C 5 alkoxy, -(CO)-H or
- CrC 12 alkyl is for example, methyl, ethyl, propyl, isopropyl, n-butyl, sec-butyl, tert-butyl, n-pentyl, 2-pentyl, 3-pentyl, 2,2'-dimethylpropyl, cyclopentyl, cyclohexyl, n-hexyl, n-octyl, 1 ,1 ',3,3'-tetramethylbutyl or 2-ethylhexyl, nonyl, decyl,.
- Ci-Ci 2 alkylene is for example methylene, ethylene, propylene, isopropylene, n-butylene, sec- butylene, tert-butylene, n-pentylene, 2-pentylene, 3-pentylene or 2,2'-dimethylpropylene, n- hexylene, n-octylene, 1 ,1',3,3'-tetramethylbutylene, 2-ethylhexylene, nonylene, decylene, undecylene or dodecylene.
- Alkylene may be straight-chain, branched, or, from C 5 alkyl upwards, monocyclic or polycyclic, and may be interrupted by hetero atoms, such as such as O, S, -CO-, N, NH, NR 54 -OCO-, - CO(OR 4 )-, -CONR 4 -, -(R 5 )NC(O)-; for example C-i-C-ioalkylene may be a resisue such as: - CH 2 CH 2 -O-CH 2 CH 2 -O-CH 2 CH 2 - -CH 2 CH 2 -O-CH 2 CH 2 - -CH 2 CH 2 -O-CH 2 -, -CH 2 -O-CH 2 -, - CH 2 CH 2 -CH 2 CH 2 -O-CH 2 -, -CH 2 CH 2 -CH(N(CH 3 ) 2 )-CH 2 -CH 2 -, CH 2 -NH 2
- C 5 -Ciocycloalkylene is for example cyclopentylene, cyclohexylene, cycloheptylene, cyclooctylene, cyclononylene or cyclodecylene.
- C 5 -Ci 0 arylene is for example phenylene or naphthylene.
- Aryl-alkylene is for example C 5 -Cioaryl-Ci-Ci O alkylene.
- Alkyl-arylene is for example Ci-Cioalkyl-C 5 -Ci O arylene.
- Preferred is a dye mixture, wherein in formula (1 ) Yi and Y 2 are Ci-C 5 alkylene.
- Z 1 and Z 2 independently from each are other -N(R 60 )-; — N— ; -CON(R 60 )-; -(CH 2 ) q NC(0)-;
- R 60 R 6 i and q are defined as in formula (1 ).
- Preferred is a composition, wherein D 1 is a radical of a cationic aromatic substituted or unsubstituted heterocyclic compound of formulae
- D 1 and D 2 independently from each other are a radical of formula
- R 1 , R 2 , Q 1 and T 1 independently from each other are defined as in formula (1 ).
- T 1 is preferablya bivalent radical of formulae ;
- the asterix * indicates the bond to Q 1 ; the asterix ** indicates the bond to D 1 ; and the heteroaromatic cycles of these radicals may be interrupted by one or more than one -O-, -S-, -(SO 2 )-, -d-Cioalkylene or -(NR 82 )-; are independently from each other hydrogen; halogen; CrC 14 alkyl, which is saturated or unsaturated, linear or branched, substituted or unsubstituted, or interrupted or uninterrupted with heteroatoms; a radical of phenyl, which substituted or unsubstituted; a of carboxylic acid radical; sulfonic acid radical; hydroxy; nitrile; CrC 16 alkoxy, (poly)- hydroxy-C 2 -C 4 -alkoxy; halogen; SO 2 NR 33 R 34 ; SR 83 , NR 83 R 84 ; OR 831 ; SO 2 ; COOR 83
- the dyes are selected from the compounds of formula
- R 6 9, R70, R7 2 and R 73 independently from each other are hydrogen; unsubstituted or substituted CrCi 4 alkyl; C 5 -Ci 0 cycloalkyl; C 2 -Ci 4 alkenyl; C 5 -Cioaryl-(Ci-Ci O alkyl); C r Cioalkyl-(C 5 - Cioaryl); C 5 -Ci 0 aryl;
- R 7 i is hydrogen; or a radical of formula (2a) " NR 7 ⁇
- An is an anion
- Yi is defined as in formula (1 ).
- the dyes are selected from the compounds of formula
- the dyes are selected from the compounds of formula
- R 1 and R 2 independently from each other are hydrogen; unsubstituted or substituted Cr Ci 4 alkyl; C 5 -Ci 0 cycloalkyl; C 2 -Ci 4 alkenyl; C 5 -Ci 0 aryl; Ci-Cioalkyl-(C 5 -Cioaryl); C 5 -Ci 0 aryl-
- dyes of formula (1) wherein D 1 and D 2 are selected from the radicals of formula (Ia 1 ) - (Ia 7 ) are:
- one of W 1 or W 2 is -N + - the other is -CH; and the biradical .-(Z 1 J n -Y 1 -S-S-Y 2 -(Z 1 )-* j s bonded to -N + ; and
- R 4 , R 5 , Re, Y-i, Y 2 , Z 1 and r are defined as in formula (1 ).
- R 4 , R 5 , R 6 , Z 1 , Y 1 , Y 2 , An and r are defined as in formula (1 ).
- dyes of formula (1 ), wherein D 1 and D 2 are selected from the radicals of formula (1 b) are:
- compositions wherein the dyes are selected from the compounds of formula
- FL O T 2 is a radical of formula * N- -C- -XO ; or -O-(X 2 ) S ;
- Re is hydrogen; Ci-C 2 oalkyl; NH 2 ; or hydroxy; and R f , Q 2 , Z 1 , Y 1 , X 2 , p and r are defined as in formula (1 ).
- dyes of formula (1 ), wherein D 1 and D 2 are selected from the radicals of formula (1 c) are:
- R 11 , R 12 and R 13 independently from each other are hydrogen; CrC 5 alkyl; -(CO)-; -C(O)H;
- Y 1 is CrC 10 alkylene; C 5 -C 10 cycloalkylene; C 5 -C 10 arylene; or Cs-doarylene- ⁇ rdoalkylene);
- Xe is the direct bond: or C- ⁇ -C 5 alkylene;
- T 3 is the direct bond
- R ⁇ and R k each independently from each other are hydrogen; Ci-Ci 4 alkyl; C 2 -C-i 4 alkenyl; Ce- C 10 aryl; Ce-C ⁇ aryl-d-doalkyl; or Crdoalky ⁇ Cs-C ⁇ aryl).
- R 11 , R 12 and R- 1 3 independently from each other are hydrogen; NO 2 ; NH 2 ; carboxy; -C(O)OH;
- Y 1 is CrC 5 alkylene
- T 3 is the direct bond; or R 1 and R k each independently from each other are hydrogen; or CrC 14 alkyl.
- nitro-sulfide dyes (NIT-01 ) used in the present invention are derived form nitro-dyes, ie.
- nitro dyes well known in the literature, for example the following nitro dyes listed in the table below:
- dyes are selected from the compounds of formula (1 ), wherein
- D 1 and D 2 independently from each other are a radical of formula (1e);
- R 48 and R 49 independently from each other are hydrogen; CrC 12 alkyl; or phenyl-CrC 4 alkyl; and
- R 16 , R , R 18 , R 1 Ci, R20 and V 1 are defined as in formula (1 ); or compounds of formula (1 ), wherein
- D 1 and D 2 independently from each other are a radical of formula (1e);
- R 15 is NR 48 R 49 ; or OR 48 ;
- R 48 and R 49 independently from each other are hydrogen; CrC 12 alkyl; or phenyl-CrC 4 alkyl; and
- R 16 , R , R 18 , R 19 , R 2 o and V 1 are defined as in formula (1 ); or compounds of formula (1 ), wherein
- D 1 and D 2 independently from each other are a radical of formula (1e); R 14 is N + R 46 R 47 ;
- R 46 and/or R 47 independently from each other are hydrogen; CrC 12 alkyl; or phenyl-CrC 4 alkyl; and
- R 16 , R 17 , R 1 S, Ri9, R20 and V 1 are defined as in formula (1 ); or compounds of formula (1 ), wherein
- D 1 and D 2 independently from each other are a radical of formula (1e);
- R 15 is NR 48 R 49 ; Or OR 48 ;
- R 1O and R 11 independently from each other are hydrogen; CrC 12 alkyl; or phenyl-C- ⁇ -C 4 alkyl; and
- R 16 , R 17 , R 18 , R 19 , R 20 and V 1 are defined as in formula (1 ).
- mixtures comprising a compound of formula (1 ), wherein D 1 and D 2 independently from each other are a radical of formula
- Ri5, Ri 6 , Ri7, R18, Ri 9 , R20, R 46 and R 48 and V 1 are defined as in formula (1 ).
- Ri4, Ri5, Rr 16 , Ri7, R 1 S, R19, R20, Yi, Y2 and V 1 are defined as in formula (1 ).
- mixtures are preferred which comprise a dye of formula
- R m is CrCi 2 alkyl, CrCi 2 alkoxy, phenyl, hydroxy, halogen, sulfonic acid, carboxylate, or the radical -NR n R 0 or -OR n ; and R n , R 0 , B 1 and B 2 are defined as in formula (1 ).
- mixtures which comprise a dye of formula (1 ), wherein D 1 and D 2 independently from each other are a radical of formula (1g), wherein R 2 3 and R 24 and R 25 and R 2 6 together with the linking nitrogen atom form a piperidine ring of
- Furrthermore mixtures are preferred, which comprise a dye of formula
- R p is hydrogen; CrC 12 alkyl; or phenyl-CrC 4 alkyl;
- Yi is CrCi 2 alkylene; C 2 -Ci 2 alkenylene; C 5 -Ci 0 cycloalkylene; C 5 -Ci 0 arylene; or C 5 -
- Ci O arylene-Ci-Ci O alkylene; D 1 is the residue of an organic dye which corresponds to the formula
- R 27 is hydrogen; or Ci-C 5 alkyl
- R 28 is a radical of formula (I h 1 ) or
- a 6 to 10 membered carbocyclic ring which may optionally be a condensated aromatic system and may contain one or more than one hetero atom;
- R 57 , R 58 and R 5 g independently form each other are hydrogen, or CrC 5 alkyl;
- a 1 is H; or a thio ester group of formula (1 b) -f- wherein
- E is O; S; or N-R 3 ;
- B 1 is -OR b ; -NR b R c , or -SR b ;
- R 3 , Rb and R c independently from each other are hydrogen; d-C ⁇ alkyl; C6-Ci 2 aryl; or Ce- Ci 2 aryl-Ci-Ci 2 alkyl.
- a 1 , Y 1 , Rp and B 1 are defined as in formula (PRO-01 ).
- D 1 is selected from the radicals of formulae (1 h 3 )
- mixtures which comprise a dye of formula (2), wherein R30, R31 and R 32 are hydrogen; or d-C ⁇ alkyl; and R 32 is defiend as formula (2).
- R 31 is hydrogen; Ci-C 5 -alkoxy; halogen; or -NR 6 gR7o, wherein
- R 6 g and R 70 independently from each other are hydrogen; Ci-Ci 2 alkyl; -(CO)-H; or
- the mixture of dyes according to the invention are suitable for dyeing organic materials, such as keratin-containing fibers, wool, leather, silk, cellulose or polyamides, cotton or nylon, and preferably human hair.
- the dyeings obtained are distinguished by their depth of shade and their good fastness properties for example to washing, fastness to light, shampooing and rubbing.
- the stabilities, in particular the storage stability of the dyes and the dyes in formulations according to the invention are excellent.
- hair dyeing agents on a synthetic base may be classiefied itnto three groups: temporary dyeing agents semipermanent dyeing agents, and permanent dyeing agents.
- temporary dyeing agents semipermanent dyeing agents temporary dyeing agents.
- permanent dyeing agents permanent dyeing agents. The multiplicity of shades of the dyes can be increased by combination with other dyes.
- the mixture of dyes of the present invention may be combined with dyes of the same or other classes of dyes, especially with direct dyes, oxidation dyes; dye precursor combinations of a coupler compound as well as a diazotized compound, or a capped diazotized compound; and/or cationic reactive dyes.
- Direct dyes are of natural origin or may be prepared synthetically. They are uncharged, cationic or anionic, such as acid dyes.
- the mixture of dyes may be used in combination with at least one single direct dye different from the dyes of formula (1 ) and (2).
- Direct dyes do not require any addition of an oxidizing agent to develop their dyeing effect. Accordingly the dyeing results are less permanent than those obtained with permanent dyeing compositions. Direct dyes are therefore preferably used for semipermanent hair dyeings.
- More preferred direct dyes which are useful for the combination with the mixture of dyes of the present invention, especially for semi permanent dyeing are: 2-amino-3-nitrophenol, 2-amino- 4-hydroxyethylamino-anisole sulfate, 2-amino-6-chloro-4-nitrophenol, 2-chloro-5-nitro-N- hydroxyethylene-p-phenylendiamine, 2-hydroxyethyl-picramic acid, 2,6-diamino-3-((pyridine- 3yl)-azo)pyridine, 2-nitro-5-glyceryl-methylaniline, 3-methylamino-4-nitro-phenoxyethanol, 4- amino-2-nitrodiphenyleneamine-2'-carboxilic acid, 6-nitro-1 ,2,3,4,-tetrahydroquinoxaline, 4-N- ethyl-1 ,4-bis(2'-hydroxyethylamino-2-nitrobenzene hydrochloride, 1 -methyl-3-nitro-4-(2'- hydroxyethyl
- mixture of dyes of the present invention may be combined with at least one cationic azo dye, for example the compounds disclosed in GB-A-2 319 776 as well as the oxazine dyes described in DE-A-299 12 327 and mixtures thereof with the other direct dyes mentioned therein, and even more preferred with cationic dyes such as Basic Yellow 87, Basic Orange 31 or Basic Red 51 , or with cationic dyes as described in WO 01/66646, especially example 4, or with cationic dyes as described in WO 02/31056, especially example 6 (compound of formula 106); or the cationic dye of formula (3) as described in EP-A-714,954, or with a yellow cationic dye of formula
- R 1 and R 2 are each independently of the other a Ci-C ⁇ alkyl; or an unsubstituted or substituted benzyl;
- R3 is hydrogen; d-C ⁇ alkyl; d-C ⁇ alkoxy; cyanide; or halide; preferably hydrogen; and X " is an anion; and preferably a compound of formula (DD1 ), wherein R 1 is methyl; R 2 is benzyl; R 3 is hydrogen; and X " is an anion; or wherein R 1 is benzyl; R 2 is benzyl; R 3 is hydrogen; and X " is an anion; or wherein R 1 is benzyl; R 2 is methyl; R 3 is hydrogen; and X " is an anion.
- cationic nitroaniline and anthraquinone dyes are useful for a combination with mixture of dyes of the present invenion, for example the dyes as described in the following patent specifications: US-5 298 029, especially in col 2, 1. 33 to col 5, 1. 38; US-5 360 930, especially in col 2, I. 38 to col 5, I. 49; US-5 169 403, especially in col 2, 1. 30 to col 5, I. 38; US-5 256 823, especially in col 4, 1. 23 to col 5, I. 15; US-5 135 543, especially in col 4, 1. 24 to col 5, 1. 16; EP-A-818 193, especially on p. 2, 1. 40 to p. 3, 1. 26; US-5 486 629, especially in col 2, I. 34 to col 5, 1. 29; and EP-A-758 547, especially on p. 7, 1. 48 to p. 8, 1. 19.
- the mixture of dyes of the present invention may also be combined with acid dyes, for example the dyes which are known from the international names (Color index), or trade names.
- Preferred acid dyes which are useful for the combination with the mixture of dyes of the present invention are described in US Patent 6,248,314. They include Red Color No. 120, Yellow Color No. 4, Yellow Color No. 5, Red Color No. 201 , Red Color No. 227, Orange Color No. 205, Brown Color No. 201 , Red Color No. 502, Red Color No. 503, Red Color No. 504, Red Color No. 506, Orange Color No. 402, Yellow Color No. 402, Yellow Color No. 406,
- Yellow Color No. 407 Red Color No. 213, Red Color No. 214, Red Color No. 3, Red Color No. 104, Red Color No. 105(1 ), Red Color No. 106, Green Color No. 2, Green Color No. 3, Orange Color No. 207, Yellow Color No. 202(1 ), Yellow Color No. 202(2), Blue Color No. 202, Blue Color No. 203, Blue Color No. 205, Blue Color No. 2, Yellow Color No. 203, Blue Color No. 201 , Green Color No. 201 , Blue Color NO. 1 , Red Color No. 230(1 ), Red Color No. 231 , Red Color No. 232, Green Color No. 204, Green Color No. 205, Red Color No. 401 , Yellow Color No. 403(1 ), Green Color No. 401 , Green Color No. 402, Black Color No. 401 and Purple Color No. 401 , especially Black Color No. 401 , Purple Color 401 , Orange Color No. 205.
- These acid dyes may be used either as single component or in any combination thereof.
- Hair dye compositions comprising an acid dye are known. They are for example described in "Dermatology", edited by Ch. Culnan, H. Maibach, Verlag Marcel Dekker Inc., New York, Basle, 1986, Vol. 7, Ch. Zviak, The Science of Hair Care, chapter 7, p. 248-250, especially on p. 253 and 254.
- Hair dye compositions which comprise an acid dye have a pH of 2-6, preferably 2-5, more preferably 2.5-4.0.
- the mixture of dyes of the present invention may also readily be used in combination with acid dyes and/or adjuvants, for example
- - acid dyes and an alkylene carbonate as described in US patent 6,248,314, especially in examples 1 and 2;
- - acid hair dye compositions comprising various kinds of organic solvents represented by benzyl alcohol as a penetrant solvent have good penetrability into hair, as described in Japanese Patent Application Laid-Open Nos. 210023/1986 and 101841/1995;
- the mixture of dyes of the present invention may also be combined with uncharged dyes, for example selected from the group of the nitroanilines, nitrophenylenediamines, nitroaminophenols, anthraquinones, indophenols, phenazines, phenothiazines, bispyrazolons, ⁇ bispyrazol aza derivatives and methines.
- uncharged dyes for example selected from the group of the nitroanilines, nitrophenylenediamines, nitroaminophenols, anthraquinones, indophenols, phenazines, phenothiazines, bispyrazolons, ⁇ bispyrazol aza derivatives and methines.
- mixture of dyes of the present invention may also be used in combination with oxidation dye systems.
- Oxidation dyes which, in the initial state, are not dyes but dye precursors are classified according to their chemical properties into developer and coupler compounds.
- Suitable oxidation dyes are described for example in
- Preferred developer compounds are for example primary aromatic amines, which are substituted in the para- or ortho- position with a substituted or unsubstituted hydroxy- or amino residue, or diaminopyridine derivatives, heterocyclic hydrazones, 4-aminopyrazol derivatives, 2,4,5,6-tetraaminopyrimidine derivatives, or unsaturated aldehydes as described in DE 19 717 224, especially on p. 2, I. 50 to I. 66 and on p. 3 I. 8 to I. 12, or cationic developer compounds as described in WO 00/43367, especially on p., 2 I. 27 to p. 8, 1. 24, in particular on p. 9, I. 22 to p. 1 1 , I. 6.
- developer compounds in their physiological compatible acid addition salt form such as hydrochloride or sulfate can be used.
- Developer compounds, which have aromatic OH radicals are also suitable in their salt form together with a base, such as alkali metal- phenolates.
- Preferred developer compounds are disclosed in DE 19959479, p. 2, I. 8 - 29.
- More preferred developer compounds are p-phenylendiamine, p-toluylendiamine, p-, m- o- aminophenol, N,N-bis-(2-hydroxyethyl)-p-phenylenediamine sulfate, 2-amino-4-hydroxy- ethylaminoanisole sulfate, hydroxyethyl-3,4-methylenedioxyaniline, 1-(2'-hydroxyethyl)-2,5-di- aminobenzene, 2,6-dimethoxy-3,5-diamino-pyridine, hydroxypropyl-bis-(N-hydroxyethyl-p- phenylenediamine) hydrochloride, hydroxyethyl-p-phenylenediamine sulfate, 4-amino-3-me- thylphenol, 4-methylaminophenol sulfate, 2-aminomethyl-4-aminophenol, 4,5-diamino-1-(
- Preferred coupler compounds are m-phenylendiamine derivatives, naphthole, resorcine and resorcine derivatives, pyrazolone and m-aminophenol derivatives, and most preferably the coupler compounds disclosed in DE 19959479, p.1 , 1. 33 to p. 3, I. 1 1.
- the mixture of dyes of the present invention may also be used together with unsaturated aldehydes as disclosed in DE 19 717 224 (p. 2, 1. 50 to I. 66 and on p. 3 I. 8 to I. 12) which may be used as direct dyes or, alternatively together with oxidation dye precursors.
- oxidation dye precursors the developer/-coupler combination 2,4,5,6-tetraaminopyrimidine and 2-methylresorcine for assessing of red shades; p-toluenediamine and 4-amino-2-hydroxytoluene for assessing of blue-violet shades; p-toluenediamine and 2-amino-4-hydroxyethylaminoanisole for assessing of blue shades; p-toluenediamine and 2,4-diamino-phenoxyethynol for assessing of blue shades; methyl-4-aminophenol and 4-amino-2-hydroxytteoluene for assessing of orange shades; p-toluenediamine and resorcine for assessing of brown-green shades; - p-toluenediamine and 1-naphthol for assessing of blue-violet shades, or p-toluenediamine
- autooxidizable compounds may be used in combination with the mixture of dyes according to the present invention.
- Autooxidizable compounds are aromatic compounds with more than two substituents in the aomatic ring, which have a very low redox potential and will therefore be oxidized when exposed to the air.
- the dyeings obtained with these compounds are very stable and resistant to schampoo.
- Autooxidizable compounds are for example benzene, indol, or indoline, especially 5,6-dihydro- xyindol or 5,6-dihydroxyindoline derivatives as described in WO 99/20234, especially on p. 26, I. 10 to p. 28, I. 15, or in WO 00/28957 on p. 2, third paragraph.
- Preferred autooxidizable benzene derivatives are 1 ,2,4-trihydroxybenzene, 1-methyl-2,4,5- trihydroxybenzene, 2,4-diamnio-6-methylphenol, 2-amino-4-methylaminophenol, 2,5-diamino- 4-methyl-phenol, 2,6-diamino-4-diethylaminophenol, 2,6-diamino-1 ,4-dihydroxybenzene, and the salts of these compounds, which are accessible with acid.
- Preferred autooxidizable indol derivatives are 5,6-dihydroxyindol, 2-methyl-5,6-dihydroxyindol, 3-methyl-5,6-dihydroxyindole, 1-methyl-5,6-dihydroxyindol, 2,3-dimethyl-5,6-dihydroxyindol, 5- methoxy-6-dihydroxyindol, 5-acetoxy-6-hydroixyindol, 5,6-diacetoxyindol, acid of 5,6- dihydroxyindol-2-carbon acid, and the salts of these compounds, which are accessible with acid.
- the mixture of dyes of the present invention may also be used in combination with naturally occurring dyes, such as henna red, henna neutral, henna black, camomile blossom, sandalwood, black tea, Rhamnus frangula bark, sage, campeche wood, madder root, catechu, sedre and alkanet root.
- naturally occurring dyes such as henna red, henna neutral, henna black, camomile blossom, sandalwood, black tea, Rhamnus frangula bark, sage, campeche wood, madder root, catechu, sedre and alkanet root.
- Naturally occurring dyes such as henna red, henna neutral, henna black, camomile blossom, sandalwood, black tea, Rhamnus frangula bark, sage, campeche wood, madder root, catechu, sedre and alkanet root.
- mixture of dyes of the present invention may also be used in combination with capped dia-zotised compounds.
- Suitable diazotised compounds are for example the compounds of formulae (1 ) - (4) in WO 2004/019897 (bridging pages 1 and 2) and the corresponding watersoluble coupling components (I) -(IV) as disclosed in the same reference.
- DC-01 WO 95/01772, wherein mixtures of at least two cationic dyes are disclosed, especially p. 2, 1. 7 to p. 4, 1. 1 , preferably p. 4, 1. 35 to p. 8, 1. 21 ; formulations p. 1 1 , last ⁇ - p. 28, 1. 19;
- DC-09 DE-A-19 713 698, wherein the combinations of direct dyes and permanent-wave fixing comprising an oxidation agent, an oxidation dye and a direct dye are disclosed; especially p. 4, 1. 65 to p. 5, 1. 59;
- DC-10 EP 850 638, wherein developer compounds and oxidizing agents are disclosed; especially p. 2, I. 27 to p. 7, I. 46 and preferably p. 7, 1. 20 to p. 9, I. 26; dyeing formulations p. 2, 1. 3-12 and I. 30 to p. 14, and p. 28, 1. 35 - p. 30, 1. 20; preferably p. 30, I. 25 - p. 32, 1. 30;
- DC-1 1 US 6,190,421 wherein extemporaneous mixtures of a composition (A) containing one or more oxidation dye precursors and optionally one or more couplers, of a composition (B), in powder form, containing one or more direct dyes (col. 5, 1. 40 - col. 7, 1. 14), optionally dispersed in an organic pulverulent excipient and/or a mineral pulverulent excipient, and a composition (C) containing one or more oxidizing agents are disclosed; formulations col. 8, 1. 60 - col. 9, I. 56;
- DC-12 US 6,228,129, wherein a ready-to-use composition comprising at least one oxidation base, at least one cationic direct dye and at least one enzyme of the 2-electron oxidoreductase type in the presence of at least one donor for the said enzyme are disclosed; especially col. 8, 1. 17 - col. 13, 1. 65; dyeing formulations in col. 2, I. 16 to col.
- DC-13 WO 99/20235, wherein compositions of at least one cationic dye and at least one nitrated benzene dye with cationic direct dyes and nitro benzene direct dyes are described; on p. 2, I. 1 to p. 7, 1. 9, and p. 39, I. 1 to p. 40 I. 1 1 , preferably p. 8, I. 12 to p. 25 I. 6, p. 26, I. 7 to p. 30, I. 15; p. 1 , I. 25 to p. 8, I. 5, p. 30, I. 17 to p. 34 I. 25, p. 8, I. 12 to p. 25 I. 6, p. 35, I. 21 to 27, especially on p. 36, 1. 1 to p. 37;
- DC-14 WO 99/20234, wherein compositions comprising at least one direct cationic dye and at least one autooxidisable dye, especially benzene, indol and indoline derivatives are described, preferably direct dyes on p. 2, 1. 19 to p. 26, 1. 4, and autooxidisable dyes as dislosed especially on p. 26, 1. 10 to p. 28, I. 15; dyeing formulations especially on p. 34, 1.
- oxidation dyeing compositions comprising at least one oxidation base selected from para-phenylenediamines and bis(phenyl)alkylenediamines, and the acid-addition salts thereof, at least one coupler selected from meta-diphenols, and the acid-addition salts thereof, at least one cationic direct dye, and at least one oxidizing agent are disclosed, especially p. 6, 1. 50 to p. 8, 1. 44 are discloseded; dyeing formulations p. 21 , 1. 30 - p. 22, I. 57;
- the mixture of dyes of the present invention may be added to the dye combinations or dyeing formulations or may be replaced with the mixture of dyes of the present invention.
- the present invention also releates to formulations, which are used for the dyeing of organic materials, preferably keratin-containing fibers, and most preferably human hair, comprising mixture of dyes of the present invention.
- the formulations comprise at least 2 dyes as defined in formula (1 ) and (2). According to the desired color results the mixtures may comprise 3, 4, 5 or more than 5 dyes of formula (1 ) and/or (2).
- the mixture of dyes of the present invention are incorporated into the composition for treating organic material, preferably for dyeing in amounts of 0.001 - 5% b.w. (hereinafter indicated merely by "%"), particularly 0.005 - 4%, more particularly 0.2 - 3%, based on the total weight of the composition.
- the formulations may be applied on the keratin-containing fiber, preferably the human hair in different technical forms.
- formulations are for example a solution, especially a thickened aqueous or aqueous alcoholic solution, a cream, foam, shampoo, powder, gel, or emulsion.
- Customary the dyeing compositions are applied to the keratin-containing fiber in an amount of 50 to 10O g.
- formulations are ready-to-use compositions or multi-compartment dyeing devices or 'kits' or any of the multi-compartment packaging systems with compartments as described for example in US 6,190,421 , col 2, I. 16 to 31.
- the pH value of the ready-to-use dyeing compositions is usually from 2 to 11 , preferably from 5 to 10.
- the dyeing compositions which are not stable to reduction, are prepared with oxidizing agent free compositions just before the dyeing process.
- One preferred embodiment of the present invention relates to the formulation of dyes, wherein the mixture of dyes of the present invention are in powder form.
- Powder formulations are preferably used if stability and/or solubility problems as for example described in DE 197 13 698, p. 2, I. 26 to 54 and p. 3, 1. 51 to p. 4, 1. 25, and p. 4, 1. 41 to p. 5 1. 59.
- Suitable cosmetic hair-care formulations are hair-treatment preparations, e.g. hair-washing preparations in the form of shampoos and conditioners, hair-care preparations, e.g. pre- treatment preparations or leave-on products such as sprays, creams, gels, lotions, mousses and oils, hair tonics, styling creams, styling gels, pomades, hair rinses, treatment packs, intensive hair treatments, hair-structuring preparations, e.g. hair-waving preparations for permanent waves (hot wave, mild wave, cold wave), hair-straightening preparations, liquid hair- setting preparations, hair foams, hairsprays, bleaching preparations, e.g.
- hair-treatment preparations e.g. hair-washing preparations in the form of shampoos and conditioners
- hair-care preparations e.g. pre- treatment preparations or leave-on products such as sprays, creams, gels, lotions, mousses and oils, hair tonics, styling creams, styling gels, po
- the dyeing compositions of the present invention can usually be incorporated into an aqueous cosmetic carrier.
- Suitable aqueous cosmetic carriers include, for example W/O, O/W, 0/W/O, W/O/W or PIT emulsions and all kinds of microemulsions, creams, sprays, emulsions, gels, powders and also surfactant-containing foaming solutions, e.g. shampoos or other preparations, that are suitable for use on keratin-containing fibers.
- surfactant-containing foaming solutions e.g. shampoos or other preparations
- the dyeing compositions are also excellently suitable for the dyeing method described in DE-A-3 829 870 using a dyeing comb or a dyeing brush.
- the constituents of the aqueous carrier are present in the dyeing compositions of the present invention in the customary amounts, for example emulsifiers may be present in the dyeing compositions in concentrations from 0.5 to 30 % b.w. and thickeners in concentrations from 0.1 to 25 % b.w. of the total dyeing composition.
- a shampoo has, for example, the following composition:
- the mixture of dyes of the present invention may be stored in a liquid to paste-like preparation (aqueous or non-aqueous) or in the form of a dry powder.
- the preparation should be substantially anhydrous in order to reduce reaction of the compounds.
- the dyeing compositions according to the invention may comprise any active ingredients, additives or adjuvants known for such preparations, like surfactants, solvents, bases, acids, perfumes, polymeric adjuvants, thickeners and light stabilisers.
- non-ionic polymers for example vinylpyrrolidone/vinyl acrylate copolymers, polyvinyl- pyrrolidone and vinylpyrrolidone/vinyl acetate copolymers and polysiloxanes
- cationic polymers such as quaternised cellulose ethers, polysiloxanes having quaternary groups, dimethyldiallylammonium chloride polymers, copolymers of dimethyldiallyl- ammonium chloride and acrylic acid, as available commercially under the name Merquat ® 280 and the use thereof in hair dyeing as described, for example, in DE-A-4 421 031 , especially p.
- acrylamide/dimethyldiallylammonium chloride copolymers diethyl-sulfate-quaternised dimethylaminoethyl methacrylate/vinylpyrrolidone copolymers, vinylpyrrolidone/- imidazolinium methochloride copolymers
- quaternised polyvinyl alcohol: - zwitterionic and amphoteric polymers such as acrylamido-propyltrimethylammonium chloride/acrylate copolymers and octylacrylamide/methyl methacry- late/tert-butylaminoethyl methacrylate/2-hydroxypropyl methacrylate copolymers
- anionic polymers such as, for example, polyacrylic acids, crosslinked polyacrylic acids, vinyl acetate/crotonic acid copolymers, vinylpyrrolidone/vinyl acrylate copolymers, vinyl
- protein hydrolysates especially elastin, collagen, keratin, milk protein, soya protein and wheat protein hydrolysates, condensation products thereof with fatty acids and also quaternised protein hydrolysates
- perfume oils dimethyl isosorbitol and cyclodextrins, solubilisers, such as ethanol, isopropanol, ethylene glycol, propylene glycol, glycerol and diethylene glycol
- anti-dandruff active ingredients such as piroctones, olamines and zinc Omadine, substances for adjusting the pH value
- UV absorbers which may be use in the dyeing compositions of the present invention
- UV absorbers can effectively protect natural and dyed hair from the damaging rays of the sun and increase the wash fastness of dyed hair. Furthermore, the following UV absorbers or combinations may be used in the dyeing compositions according to the invention:
- Suitable cosmetic preparations may usually contain 0.05 to 40 % b.w., preferably 0.1 to 20 % b.w., based on the total weight of the composition, of one or more UV absorbers; consistency regulators, such as sugar esters, polyol esters or polyol alkyl ethers; fats and waxes, such as spermaceti, beeswax, montan wax, paraffins, fatty alcohols and fatty acid esters; fatty alkanolamides; - polyethylene glycols and polypropylene glycols having a molecular weight from 150 to
- glycerol for example glycerol, propylene glycol, propylene glycol monoethyl ether, butyl glycol, benzyl alcohol, carbonates, hydrogen carbonates, guanidines, ureas and also primary, secondary and tertiary phosphates, imidazoles, tannins, pyrrole; opacifiers, such as latex; pearlising agents, such as ethylene glycol mono- and di-stearate; propellants, such as propane-butane mixtures, N 2 O, dimethyl ether, CO 2 and air; antioxidants; preferably the phenolic antioxidants and hindered nitroxyl compounds disclosed in ip.com (IPCOM # 000033153D); sugar-containing polymers, as described in EP-A-970 687; - quaternary ammonium salts, as described in WO 00/10517;
- Bacteria inhibiting agents like preservatives that have a specific action against gram- positive bacteria, such as 2,4,4'-trichloro-2'-hydroxydiphenyl ether, chlorhexidine (1 ,6-di(4- chlorophenyl-biguanido)hexane) or TCC (3,4,4'-trichlorocarbanilide).
- gram- positive bacteria such as 2,4,4'-trichloro-2'-hydroxydiphenyl ether, chlorhexidine (1 ,6-di(4- chlorophenyl-biguanido)hexane) or TCC (3,4,4'-trichlorocarbanilide).
- a large number of aromatic substances and ethereal oils also have antimicrobial properties. Typical examples are the active ingredients eugenol, menthol and thymol in clove oil, mint oil and thyme oil.
- a natural deodorising agent of interest is the terpene alcohol farnesol (3,7,11- trimethyl-2,6,10-dodecatrien-1-ol), which is present in lime blossom oil. Glycerol monolau- rate has also proved to be a bacteriostatic agent.
- the amount of the additional bacteria- inhibiting agents present is usually from 0.1 to 2 % b.w., based on the solids content of the preparations;
- the dyeing compositions according to the present invention generally comprise at least one surfactant.
- Suitable surfactants are zwitterionic or ampholytic, or more preferably anionic, non-ionic and/or cationic surfactants.
- Suitable anionic surfactants in the dyeing compositions according to the present invention include all anionic surface-active substances that are suitable for use on the human body. Such substances are characterised by an anionic group that imparts water solubility, for example a carboxylate, sulfate, sulfonate or phosphate group, and a lipophilic alkyl group having approximately 10 to 22 carbon atoms.
- anionic group that imparts water solubility
- a carboxylate, sulfate, sulfonate or phosphate group for example a carboxylate, sulfate, sulfonate or phosphate group, and a lipophilic alkyl group having approximately 10 to 22 carbon atoms.
- glycol or polyglycol ether groups, ester, ether and amide groups and also hydroxy groups may be present in the molecule.
- Preferred anionic surfactants are alkyl sulfates, alkyl polyglycol ether sulfates and ether carboxylic acids having 10 to 18 carbon atoms in the alkyl group and up to 12 glycol ether groups in the molecule, and also especially salts of saturated and especially unsaturated C 8 -C 22 carboxylic acids, such as oleic acid, stearic acid, isostearic acid and palmitic acid.
- zwitterionic surfactants that carry at least one quaternary ammonium group and at least one -COO " or -SO3 " group in the molecule are terminated zwitterionic surfactants.
- betaines such as the N-alkylN,N-dimethylammonium glycinates, for example cocoalkyldimethylammonium glycinate, N-acylaminopropyl-N,N-dimethylammonium glycinates, for example cocoacylaminopropyldimethylammonium glycinate, and 2-alkyl-3- carboxymethyl-3-hydroxyethylimidazoline having from 8 to 18 carbon atoms in the alkyl or acyl group and also cocoacylaminoethylhydroxyethylcarboxymethyl glycinate.
- a preferred zwitterionic surfactant is the fatty acid amide derivative known by the CTFA name cocoamidopropyl betaine.
- Ampholytic surfactants are surface-active compounds that, in addition to a C 8 -Ci 8 -alkyl or -acyl group and contain at least one free amino group and at least one -COOH or -SO3H group in the molecule and are capable of forming internal salts.
- ampholytic surfactants include N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids, each having approximately from 8 to 18 carbon atoms in the alkyl group.
- Ampholytic surfactants to which special preference is given are N-cocoalkylaminopropionate, cocoacylaminoethylaminopro- pionate and Ci 2 -Cieacylsarcosine.
- Non-ionic surfactants are described in WO 00/10519, especially p. 45, 1. 1 1 to p. 50, I. 12.
- Non-ionic surfactants contain as hydrophilic group, for example, a polyol group, a poly- alkylene glycol ether group or a combination of polyol and polyglycol ether groups.
- Such compounds are, for example: addition products of 2 to 30 mol of ethylene oxide and/or 0 to 5 mol of propylene oxide with linearar fatty alcohols having 8 to 22 carbon atoms, with fatty acids having 12 to 22 carbon atoms and with alkylphenols having 8 to 15 carbon atoms in the alkyl group,
- the surfactants which are addition products of ethylene and/or propylene oxide with fatty alcohols or derivatives of such addition products may either be products having a "normal” homologue distribution or products having a restricted homologue distribution.
- "Normal” homologue distribution are mixtures of homologues obtained in the reaction of fatty alcohol and alkylene oxide using alkali metals, alkali metal hydroxides or alkali metal alcoholates as catalysts.
- Restricted homologue distributions are obtained when, for example, hydrotalcites, alkali metal salts of ether carboxylic acids, alkali metal oxides, hydroxides or alcoholates are used as catalysts.
- ammonium halides such as alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, for example cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, distearyldimethy-lammonium chloride, lau- ryldimethylammonium chloride, lauryldimethylbenzylammonium chloride and tricetylmethyl- ammonium chloride.
- Further cationic surfactants that can be used in accordance with the invention are quaternised protein hydrolysates.
- cationic silicone oils such as, for example, the commercially available products Q2-7224 (manufacturer: Dow Corning; a stabilised trimethylsilylamodimethicone), Dow Corning 929 emulsion (comprising a hydroxylamino-modified silicone, which is also referred to as amodimethicone), SM-2059 (manufacturer: General Electric), SLM-55067 (manufacturer: Wacker) and also Abil ® -Quat 3270 and 3272 (manufacturer: Th. Goldschmidt; diquaternary polydimethylsiloxanes, quaternium-80), or silicones, as described in WO 00/12057, especially p. 45, I. 9 to p. 55, I. 2.
- Alkylamidoamines especially fatty acid amidoamines, such as the stearylamidopropyl- dimethylamine obtainable under the name Tego Amid ® 18 are alos preffered as surfactants in the present dyeing compositions. They are distinguished not only by a good conditioning action but also especially by their good biodegradability.
- estersquats such as the methyl hydroxyalkyl- dialkoyloxyalkylammonium methosulfates marketed under the trademark Stepantex ® , are also very readily biodegradable.
- quaternary sugar derivative that can be used as cationic surfactant is the commercial product Glucquat ® 100, according to CTFA nomenclature a "lauryl methyl glu- ceth-10 hydroxypropyl dimonium chloride".
- the alkyl-group-containing compounds used as surfactants may be single substances, but the use of natural raw materials of vegetable or animal origin is generally preferred in the preparation of such substances, with the result that the substance mixtures obtained have different alkyl chain lengths according to the particular starting material used.
- the mixture of dyes of the present invention are suitable for the dyeing of organic material, perferably keratin-containig fibers.
- a further preferred embodiment of the present invention relates to a method of treating keratin-containig fibers with the mixture of dyes of the present invention.
- the process comprises
- a further preferred method comprises treating the hair in the presence of a reduction agent.
- Preferred reduction agents are for example thioglycol acid or salts therof, gycerine monothio- glycolat, cystein, 2-mercaptopropionic acid, 2-mercaptoethylamine, thiolactic acid, thioglyce- rine, sodium sulfite, dithionithe, ammonium sulfite, sodium bisulfite, sodium metabisulfite, hydroquinone, phosphines, borhydride, cyanoborohydride, triacetoxy borohydride, trimethoxy borohydride salts (sodium, lithium, potassium, calcium auaternary salts).
- thioglycol acid or salts therof gycerine monothio- glycolat, cystein, 2-mercaptopropionic acid, 2-mercaptoethylamine, thiolactic acid, thioglyce- rine, sodium sulfite, dithionithe, ammonium sulfite
- the present invention relates to a process, comprising treating the hair with (a) optionally a reduction agent,
- step (c) with an oxidizing agent.
- the step (a) may be of short duration from o.1 sec to 30 minutes, fro example from 0.1 seconds to 10 minutes with a rducing agent mentioned above.
- the application of the dye mixture on the hair may be arried out at temperatures ranging from 15° to 100°C. Generally the application is carried out at room temperature.
- the sequence of the reaction steps is generally not important, the reduction agent can be applied first or in a final step.
- the oxidizing agent is applied together with an acid or a base.
- the acid is for example citric acid, phosphoric acid or tartrate acid.
- the base is for example sodium hydroxide, ammonia or monoethanolamine.
- the mixture of dyes of the present invention are suitable for all-over dyeing of the hair, that is to say when dyeing the hair on a first occasion, and also for re-dyeing subsequently, or dyeing of locks or parts of the hair.
- the mixture of dyes of the present invention is applied on the hair for example by massage with the hand, a comb, a brush, or a bottle, or a bottle, which is combined with a comb or a nozzle.
- a process for dyeing keratin-containing fibers which comprises treating the keratin-containing fiber with mixture of dyes of the present invention, a base and an oxidizing agent.
- the oxidation dyeing process usually involves lightening, that is to say that it involves applying to the keratin-containing fibers, at basic pH, a mixture of bases and aqueous hydrogen peroxide solution, leaving the applied mixture to stand on the hair and then rinsing the hair. It allows, particularly in the case of hair dyeing, the melanin to be lightened and the hair to be dyed. Lightening the melanin has the advantageous effect of creating a unified dyeing in the case of grey hair, and, in the case of naturally pigmented hair, of bringing out the color, that is to say of making it more visible.
- the oxidizing agent containing composition is left on the fiber for 0.1 seconds to 15 minutes, in particular for 0.1 seconds to 5 minutes at 15 to 45°C, usually in amounts of 30 to 20Og.
- Oxidizing agents are for example persulfate or diluted hydrogen peroxide solutions, hydrogen peroxide emulsions or hydrogen peroxide gels, alkaline earth metal peroxides, organic peroxides, such as urea peroxides, melamine peroxides. Alkalimetalbromate fixations or enzymes are also appropriate if a shading powder on the basis of semi-permanent, direct hair dyes is used.
- oxidizing agents are oxidizing agents to achieve lightened coloration, as described in WO 97/20545, especially p. 9, I. 5 to 9, oxidizing agents in the form of permanent-wave fixing solution, as described in
- Most preferred oxidizing agent is hydrogen peroxide, preferably used in a concentration from about 2 to 30 %, more preferably about 3 to 20% by, and most preferably from 6 to 12% b.w. the corresponding composition.
- the oxidizing agents may be present in the dyeing compositions according to the invention preferably in an amount from 0.01 % to 6 %, especially from 0.01 % to 1 %, based on the total dyeing composition.
- the dyeing with an oxidative agent is carried out in the presence of a base, for example ammonia, alkali metal carbonates, earth metal (potassium or lithium) carbonates, alkanol amines, such as mono-, di- or triethanolamine, alkali metal (sodium) hydroxides, earth metal hydroxides or compounds of the formula R 3 FL
- a base for example ammonia, alkali metal carbonates, earth metal (potassium or lithium) carbonates, alkanol amines, such as mono-, di- or triethanolamine, alkali metal (sodium) hydroxides, earth metal hydroxides or compounds of the formula R 3 FL
- R is a propylene residue, which may be substituted with OH or Ci-C 4 alkyl
- R 3 , R 4 , R 5 and R 6 are independently or dependently from each other hydrogen, d-C 4 alkyl or hydroxy-(CrC 4 )alkyl.
- the pH-value of the oxidizing agent containing composition is usually about 2 to 7, and in particular about 2 to 5.
- One preferred method of applying formulations comprising the mixture of dyes of the present invention on the keratin-containing fiber, preferably the hair is by using a multi-compartment dyeing device or "kit” or any other multi-compartment packaging system, as described for example in WO 97/20545 on p. 4, 1. 19 to I. 27.
- the first compartment contains for examle the mixture of dyes of the present invention and optionally furhter direct dyes and a basifying agent, and in the second compartment an oxidizing agent; or in the first compartment the mixture of dyes of the present invention and optionally futhter direct dyes, in the second compartment a basifiying agent and in the third compartment an oxidizing agent.
- a further preferred embodiment of the present invention relates to a method of dyeing hair with oxidative dyes, which comprises
- step (a) mixing at least one dye of formula (1 ) and optionally at least one coupler compound and at least one developer compound, and an oxidizing agent, which optionally contains at least one further dye, and (b) contacting the keratin-containing fibers with the mixture as prepared in step (a).
- the pH-value of the oxidizing agent free composition is usually from 3 to 1 1 , and in particular from 5 to 10, and most particular about 9 to 10.
- a ready-to-use composition is prepared according to a first preferred embodiment by a process which comprises a preliminary step which involves separately storing, on the one hand, a composition (A) comprising, in a medium which is suitable for dyeing, at least one developer compound, especially selected from para-phenylenediamines and bis(phenyl)- alkylenediamines, and the acid-addition salts thereof, at least one coupler, especially selected from meta-phenylenediamines and the acid-addition salts thereof, and the mixture of dyes of the present invention, on the other hand, a composition (B) containing, in a medium which is suitable for dyeing, at least one oxidizing agent and mixing (A) and (B) together immediately before applying this mixture to the keratin-containing fibers.
- a composition (A) comprising, in a medium which is suitable for dyeing, at least one developer compound, especially selected from para-phenylenediamines and bis(phenyl)- alkylenedi
- the process includes a preliminary step which involves separately storing, on the one hand, a composition (A) comprising, in a medium which is suitable for dyeing, at least one developer compound, especially selected from para-phenylenediamines and bis- (phenyl)alkylenediamines, and the acid-addition salts thereof, at least one coupler compound, especially selected from meta-phenylenediamines and the acid-addition salts thereof; on the other hand, a composition (A) comprising, in a medium which is suitable for dyeing, at least one dye of formula (1 ), and, finally, a composition (B) containing, in a medium which is suitable for dyeing, at least one oxidizing agent as defined above, and mixing them together at the time of use immediately before applying this mixture to the keratin-containing fibers.
- a composition (A) comprising, in a medium which is suitable for dyeing, at least one developer compound, especially selected from para-phenylenediamines and bis- (phenyl
- composition (A') used according to this second embodiment may optionally be in powder form, the mixture of dyes of the present invention constituting, in this case, all of the composition (A) or optionally being dispersed in an organic and/or inorganic pulverulent excipient.
- the organic excipient may be of synthetic or natural origin and is selected in particular from crosslinked and non-crosslinked synthetic polymers, polysaccharides such as celluloses and modified or unmodified starches, as well as natural products such as sawdust and plant gums (guar gum, carob gum, xanthan gum, etc.).
- the inorganic excipient may contain metal oxides such as titanium oxides, aluminium oxides, kaolin, talc, silicates, mica and silicas.
- Aw very suitable excipient in the dyeing compositions according to the invention is sawdust.
- the powdered composition (A') may also contain binders or coating products in an amount which preferably does not exceed approximately 3% b.w. relative to the total weight of composition (A'). These binders are preferably selected from oils and liquid fatty substances of inorganic, synthetic, animal or plant origin.
- the present invention relates to a process of dyeing of keratin-containig fibers with the mixture of dyes of the present invention and autooxidable compounds and optionally further dyes.
- the present invention relates to a process for dyeing keratin-containig fibers with the mixture of dyes of the present invention and capped diazotised compounds, which comprises,
- the capped diazotised compound and coupler compound and optionally the oxidizing agent and developer compound can be applied in any desired order successively, or simultaneously.
- the capped diazotised compound and the coupler compound are applied simultaneously, in a single composition.
- Alkaline conditions denotes a pH in the range from 8 to 10, preferably 9-10, especially 9.5- 10, which are chieved by the addition of bases, for example sodium carbonate, ammonia or sodium hydroxide.
- the bases may be added to the hair, to the dye precursors, the capped diazotised compound and/or the water-soluble coupling component, or to the dyeing compositions comprising the dye precursors.
- Acids are for example tartaric acid or citric acid, a citric acid gel, a suitable buffer solution with optionally an acid dye.
- the ratio of the amount of alkaline dyeing composition applied in the first stage to that of acid dyeing composition applied in the second stage is preferably about from 1 :3 to 3:1 , especially about 1 :1.
- the present invention relates to a process for dyeing keratin-containig fibers with the mixture of dyes of the present invention and at least one acid dye.
- the obtained diazo solution is dropped to a 273 K cold solution of 7.4 g imidazole in 30 ml water, whereby the pH of the solution is maintained in the range of pH 10 to 11 by adding 36% of asodium hydroxide solution.
- the obtained suspension is warmed up to 295 K, the pH is adjusted to 10.5 with 36% sodium hydroxide solution.
- the suspension is filtered off and washed twice with 50 ml water to obtain 55 g of a humid product, which is suspended in 200 ml water and 3 weight equivalents dimethyl sulfate and sodium hydroxide are simultaneously added for maintaining the pH at 10-10.3 and the temperature at 298-303K.
- reaction is allowed to stand for one more hour to finish the hydrolysis of excess of dimethyl sulfate.
- the obtained diazo solution is dropped to a 273 K cold solution of 7.4 g imidazole in 30 ml water, whereby the pH of the solution is maintained in the range of pH 10 to 11 by adding 36% sodium hydroxide solution.
- the obtained suspension is warmed up to 295 K and the pH is adjusted to 10.5 with 36% sodium hydroxide solution.
- the suspension is filtered off and then washed twice with 50 ml water to obtain 55 g of the humid product, which is suspended in 500 ml water.
- 0.3 mol dimethyl sulfate and sodium hydroxide are simoultaniously added for maintaining the pH in the range of 10- 10.3 and the temperature at 298-303K.
- the reaction mixture is hold for one hour. Then the water is evaporated. About 40 g humid solid, which gives 27 g of dryed product of the formula
- the reaction mixture is stirred for further 3 hours.
- the hot mass is separated through filtration the residue washed with 100 ml ethanol.
- the filtrate and wash solution are cooled to 380 K with mixing, when cristallization of the product takes place.
- the product is separated by filtration, washed with cold ethanol and dryed in a vacuum dryer.
- the dried material is dissolved in 132 ml water and 110 ml of 32% hydrochloric acid at 295 K.
- the reaction mixture is cooled to 273 K and 86.4 g 36% sodium nitrite solution are dropped at such a rate that the temperature of the mixture is maintained in the range of 273 to 276 K.
- the mixture is further stirred for one hour. If no excess of nitrite is detected during one hour (detection by using a potassium iodide/starch paper) further amounts of sodium nitrite solution are added. After this one hour the remaining excess of nitrite is destroyed with sulfamic acid.
- the obtained diazo solution is dropped to a 273 K cold solution of 33.4 g imidazole in 130 ml water, whereby the pH of the solution is maintained in the range of pH 10 to 11 by adding 36% of a sodium hydroxide solution.
- the obtained suspension is warmed up to 295 K and the pH is adjusted to 10.5 with 36% sodium hydroxide solution.
- the suspension is filtered off and then washed twice with 100 ml water to obtain 200 g of the humid product.
- the filtercake from the previouse step is suspended in water and 3 weight equivalents dimethylsulfate and sodium hydroxide are simultaniously added for maintaining the pH in the range of 10-10.3 and the temperature at 300 K.
- the reaction mixture is hold for one more hour to finish the hydrolysis of excess of dimethylsulfate.
- the suspension is separated by filtration.
- About 240 g of a humid solid which gives 140 g dryed product of formula
- the acetyl derivative is solved in 520 ml ethanol and continuously added to 130 g iron in 35 ml concentrated chlorhidric acid and 220 ml water at 363K during 1 hour. The temperature drops to 353 K. The reaction mixture is stirred for further 3 hours. The hot mass is separated through filtration, the residuu washed with 100 ml ethanol. The filtrate and wash solution is cooled to 380 K with mixing, when cristallization of the product takes place. The product is separated by filtration, washed with cold ethanol and dryed in a vacuum dryer. The dried material is dissolved in 132 ml water and 1 10 ml of 32% hydrochloric acid at 295 K.
- reaction mixture is cooled to 273 K and 86.4 g 36% sodium nitrite solution is dropped at such a rate that the temperature of the mixture is maintained in the range of 273 to 276 K.
- sodium nitrite solution After the addition of the sodium nitrite solution, the mixture is stirred for one hour. If no excess of nitrite is detected during one hour (detection by using a potassium iodide/starch paper), further amounts of sodium nitrite solution is added. After this one hour the remaining excess of nitrite is destroyed with sulfamic acid.
- the obtained diazo solution is dropped to a 273 K cold solution of 33.4 g imidazole in 130 ml water, whereby the pH of the solution is maintained in the range of pH 10 to 1 1 by adding 36% sodium hydroxide solution.
- the obtained suspension is warmed up to 295 K, the pH is adjusted to 10.5 with 36% sodium hydroxide solution. After one hour stirring at this pH and temperature, the suspension is filtrated and then washed twice with 100 ml water to obtain 200 g of the humid product
- the filtercake from the previouse step is suspended in water and 3 weight equivalents dimethylsulphate and sodium hydroxide simoultaniously added for maintaining the pH in the range of 10-10.3 and the temperature at 300 K. Then, the reaction mixture is hold for one more hour, to finish the hydrolysis of excess of dimethylsulphate. Then, the suspension is separated by filtration. About 240 g humid solid, which gives 14O g dryed product of formula
- the reaction mixture is stirred for further 3 hours.
- the hot mass is separated through filtration, the residue washed with 100 ml ethanol.
- the filtrate and wash solution are cooled to 380 K with mixing when cristallization of the product takes place.
- the product is separated by filtration, washed with cold ethanol and dryed in a vacuum dryer.
- the dried material is dissolved in 132 ml water and 110 ml of 32% hydrochloric acid at 295 K.
- the reaction mixture is cooled to 273 K and 86.4 g of a 36% sodium nitrite solution are dropped at such a rate that the temperature of the mixture is maintained in the range of 273 to 276 K.
- the mixture is stirred for one hour.
- the suspension After stirring for one hour at this pH and temperature the suspension is filtered off and then washed twice with 100 ml water to obtain 200 g of the humid product Then the filtercake from the previouse step is suspended in water and 3 weight equivalents dimethylsulfate and sodium hydroxide simoultaniously added for maintaining the pH in the range of 10-10.3 and the temperature at 300 K. Then the reaction mixture is hold for one more hour to finish the hydrolysis of excess of dimethylsulfate. Then, the suspension is separated by filtration. About 240 g of a humid solid, which gives 140 g dry product of the following formula
- Alkylating agent A mixture of 15.4 g of 2.2-dithiodiethanol in 100 ml chloroform and 24.1 g pyridine are cooled with stirring at 273K and then 41.0 g of tosyl chloride are added in small amounts, maintaining the temperature.
- Alkylating agent A mixture of 15.4 g of 2,2-dithiodiethanol in 100 ml chloroform and 24,1 g pyridine are cooled with stirring to 273 K and then 41.0 g of tosyl chloride are added in small amounts maintaining the temperature.
- Alkylating agent A mixture of 21.4 g of 2.2-dithiodiethanol in 100 ml chloroform and 24.1 g pyridine are cooled with stirring to 273K and then 41.0 g of mesyl anhydride are added in small amounts under constant temperature.
- Example AZO-10 Same preparation process as described in example A8, but with the difference that 2-amino- benzothiazol instead of 2-amino-6-methoxy-benzothiazol is used.
- Example AZO-10 Same preparation process as described in example A8, but with the difference that 2-amino- benzothiazol instead of 2-amino-6-methoxy-benzothiazol is used.
- Example AZO-10 Same preparation process as described in example A8, but with the difference that 2-amino- benzothiazol instead of 2-amino-6-methoxy-benzothiazol is used.
- the temperature is raised to 333 K while the viscosity of the reaction mixture decreases.
- the reaction mixture is stirred at this temperature during 25 hours.
- the reaction mass is stirred for 4 hours while the temperature is decreased to 295 K.
- the reaction mass is filtered off and the filter residue is washed with 45 ml of acetonitrile. Then the material is dried in vacuum to obtain 16 g of product.
- Alkylating agent A mixture of 15.4 g of 2.2-dithiodiethanol in 100 ml chloroform and 24.1 g pyridine are cooled with stirring to 273K and then 41.0 g of tosyl chloride are added in small amounts under constant temperature.
- Alkylating agent A solution of 22.5 g of cisteamine dichlorohydrate in water and 31.4 g bromoacetic chloride are cooled with stirring to 273K and then the pH is kept constant by adding NaOH solution in small amounts under constant temperature. After completion of the addition the mixture is left over night in the refrigerator. The mixture has two phases, which are separated, washed with water and dried. 3. Alkylation: The foregoing hydrazone is dissolved in methanol by stirring with the dibromide solution. The temperature is raised to 60°C and maintained at 60°C during the following 24 hours. The crystals separated in the slurry are filtrated. The product is washed with 50 ml of methanol and dried in vacuum to obtain 49 g of an orange solid product. The product is recristallized twice from methanol.
- the temperature is raised to 333K and maintained at 333K during the following 20 hours. Crystals separated in the slurry are filtrated. The product is washed with 50 ml of chloroform and dried in vacuum to obtain 80 g of a dark solid product, which is recristallized twice from methanol.
- the compound of formula (104a) (prepared in example A 4) is reacted with N,N-dimethyl- ethylendiamine according to the method as described in Example A14.
- the same alkylating agent is used and the compound of formula (116) is obtained.
- Step 1
- a mixture of 15,4 g of 2,2-dithiodiethanol in 100 ml chloroform and 24,1 g pyridine are cooled with stirring to O 0 C and then 41.0 g of tosyl chloride are added in small amounts, maintaining the temperature at O 0 C by cooling externally. After completion of the addition the mixture is left over night in the refrigerator to complete the reaction.
- the reaction mixture is mixed with a water/ hydrochloric acid and ice slurry, the phases are separated, washed with water and dried.
- the alkylation agent obtained in the 1 st reaction step is delivered from the solvent, dissolved in two equivalent amounts (18.8 g) of 4-methyl-pyridine.
- the temperature is raised to 70°C and maintained at 60°C during the following 12 hours.
- the product is characterized by the following data: -
- the HPLC-MS gives a main component of a dication of the mass 568 - 1 H-NMR data in deuterated chloroform (128 scans)/ 360MHz:
- reaction mixture is mixed with a water/hydrochloric acid and ice slurry, the phases are separated, washed with water and dried.
- reaction product is precipitated by cooling, then separated by filtration and dried in vacuum to obtain 42 g of an orange solid product.
- the product is recristallized twice from methanol.
- the product is characterized by the following data: -
- the HPLC-MS gave a main component of a dication of the mass 512 - 1 H-NMR data in deuterated chloroform (128 scans)/ 360MHz:
- a mixture of 25.4 g of cisteamine as dichlorohydrate in 100 ml water is cooled with stirring to O 0 C and 41.0 g of bromoacetic acid bromide are added in small amounts, maintaining the temperature at O 0 C by external cooling.
- the pH is adjusted with sodium hydroxide to 8.0. After completion of the addition the mixture is left for one hour with agitation to comlete the reaction.
- reaction mixture is separated by filtration, the solid washed with water and dried.
- the alkylating agent used as starting compound in the 2 reaction step is the alkylating agent used as starting compound in the 2 reaction step.
- the alkylation agent obtained in the 1 st reaction step is added to 50 ml isopropaol and dissolved in two equivalent amounts (18.8 g) of 4-methyl-pyridine. The temperature is raised to 80°C and maintained during the following 10 hours.
- reaction product is precipitated by cooling, then separated by filtration and dried in vacuum to obtain 59 g of an orange solid product.
- the product is recristallized twice from isopropanol.
- a mixture of 21.4 g 2,2-dithiodipropionic acid in 100 ml chloroform and 24.0 g thionyl chloride are added in small amounts, maintaining the temperature by external cooling. After completion of the addition the mixture is heated to remove the formed gases and the reaction was finished. The solvent is removed by distillation under low pressure and the acid chloride used as starting compound in the 2 nd reaction step.
- the dimethylsulfate as alkylation agent is used without solvent and mixed with two equivalent amounts (18.8g) 2-methyl-pyridine.
- the temperature is raised to 80°C and maintained during the following 2 hours.
- reaction product is precipitated by cooling, then separated by filtration and dried in vacuum to obtain 49 g of an orange solid product.
- the product is recristallized twice from water.
- Alkylating agent A mixture of 25.4 g of 2,2-dithiodiethylamine (cisteamine) as dichlorohydrate and 100 ml water is cooled with stirring to O 0 C and then 41.0 g of bromo acetic acid bromide are added in small amounts, maintaining the temperature by cooling externally. The pH is adjusted to 8.0 by addition of sodium hydroxide.
- reaction mixture is separated by filtration, the solid washed with water and dried.
- the alkylating agent is used as starting compound in the 2 nd reaction step.
- reaction product is precipitated by cooling, then separated by filtration and dried in vacuum to obtain 57 g of an orange solid product.
- the product is recristallized twice from methanol.
- the product is characterized by the following data: - The HPLC-MS gave a main component of a dication of the mass 682. - 1 H-NMR data in deuterated chloroform (128 scans)/ 360MHz:
- the solvent is removed by distillation under low pressure.
- the dimethylsulfate as alkylation agent is used without solvent, with two equivalent amounts (18.8 g) of 4-methyl-pyridine.
- the temperature is raised to 80°C and maintained at 80°C during the following 2 hours.
- reaction product is precipitated by cooling, then separated by filtration and dried in vacuum to obtain 55 g of an orange solid product.
- the product is recristallized twice from water.
- reaction mixture is separated by filtration; the solid washed with water and dried,
- the product may be used as such for dyeing applications.
- the solvent is removed by distillation under low pressure and the acid chloride is used as such in the 4 th reaction step.
- the dimethylsulfate as alkylation agent is used without solvent with two equivalents (18.8g) 4- methyl-pyridine.
- the temperature is raised to 70°C and maintained at 80°C during the following 2 hours.
- reaction product is precipitated by cooling, then separated by filtration and dried in vacuum to obtain 49 g of an orange solid product.
- the product is recristallized twice from water. 4.
- a mixture of 49g of the styrene compound obtained in the 3 rd reaction step in 200 ml water are cooled with stirring to O 0 C and then 35.0 g of the acid chloride obtained in the 1 st reaction step, diluted with 30 ml tetrahydrofurane are added in small amounts, maintaining the temperature at O 0 C by external cooling.
- the pH is adjusted to 6.0 by addition of sodium hydroxide. After completion of the addition the mixture is left for one hour with agitation to complete the reaction.
- the reaction mixture is separated by filtration, the solid washed with water and dried.
- the product may be used as such for dyeing applications.
- a mixture of 18.4 g 2,2-dithioglycolic acid in 100 ml chloroform and 24.0 g thionyl chloride are added in small amounts, maintaining the temperature at 2O 0 C by external cooling.
- the dimethylsulfate as alkylation agent is used without solvent, dissolved in two equivalent amounts (18.8g) of 2-methylpyridine.
- the temperature is raised to 70°C and maintained at 80°C during the following 2 hours.
- reaction product is precipitated by cooling, then separated by filtration and dried in vacuum to obtain 49 g of an orange solid product.
- the product is recristallized twice from isopropanol.
- the pH is adjusted to 6.0 by sodium hydroxide addition
- reaction mixture is separated by filtration, the solid washed with water and dried.
- the product may be used for dyeing applications.
- a mixture of 21.5 g 2-hydroxyethyl-methylamine are neutralized with hydrochloric acid and evaporated to dryness.
- the salt is suspended in chloroform and cooled under stirring to O 0 C and then 41.0 g of thionyl chloride are added in small amounts, maintaining the temperature at by O 0 C external cooling.
- the alkylation agent obtained in the 1 st reaction step is dissolved in n-butanol and two equi- valent amounts (16,8g) 4-methyl-pyridine are added.
- the temperature is raised to 120°C and maintained during the following 6 hours. Than the temperature is lowered to 70°C.
- reaction mixture is mixed with a water/hydrochloric acid and ice slurry, the phases are separated, washed with water and dried.
- the reaction mixture is cooled to ambient temperature with agitation and separated through filtration.
- the alkylation agent 2-chloroethyl-N,N-dimethylamine is dissolved in n-butanol and equivalent amounts (18.028 g) of 4-methyl-pyridine are added. The temperature is raised to 120°C and maintained at 120°C during the following 6 hours. Than the temperature is lowered to 70°C,
- reaction product is precipitated by cooling, then separated by filtration and dried in vacuum to obtain 50 g of an orange solid product.
- reaction mixture is mixed with a water/chlorhidric acid and ice slurry, the phases are separated, washed with water and dried.
- the reaction mixture is cooled to ambient temperature with agitation and separated through filtration.
- Stepi A solution of 19.39 g 1 ,3-dibromopropane in 10 ml of chloroform is stirred at room temperature and a solution of 0.50 g N,N'-tetramethylcystamine (RN 1072-1 1-3) in 10 ml of chloroform is added over a period of 8 h. After additional stirring for 2 days the resulting white precipitate is filtered off, washed with chloroform and dried under vacuum.
- N,N'-tetramethylcystamine RN 1072-1 1-3
- Step 2 The white solid prepared in step 1 is added to a solution of 1.06 g of 1-(3-dimethyl- aminopropyl)amino-4-amino-anthraquinone (RN 65274-31-9) in 10 ml DMF. The solution is stirred for 3 days at 40°C. After that time the reaction mixture is poured into 200 ml of acetone and the resulting precipitate is collected by filtration. Than the crude product is refluxed for 40 min in 120 ml of acetone. The suspension is filtered off and the collected solid is dried under vacuum at 60°C. Yield: 1.64 g of the compound of formula
- Step 1 To a solution of 61.32 g 1-(3-aminopropyl)-imidazole, 5.92 g lithium hydroxide and 1.48 g Cu(I)CI in 150 ml water, 100 g of sodium 1-amino-4-bromoanthraquinone-2-sulfonate (RN 6258-06-6) are added over a period of 15 min. The reaction mixture is stirred for 30 min at 65°C and then for 1 h at 85°C. After the resulting blue solution had cooled down to room temperature 75 ml concentrated hydrochloric acid are added. The resulting precipitate is filtered off, suspended in 200 ml acetone and stirred for 1 h.
- RN 6258-06-6 sodium 1-amino-4-bromoanthraquinone-2-sulfonate
- Step 2 To a suspension of 30.78 g of the compound of formula (105a) in 300 ml of water 34 ml sodium hydroxid solution (30 %) are added. The mixture is heated to 80°C and a solution of 16.31 g glucose in 90 ml water is added dropwise over a period of 40 min. After 30 min the suspension is cooled to room temperature and filtered. The press cake is stirred in 450 ml 4 molar sodium hydroxid solution, filtered off and washed with water. The residue is dried in a vacuum oven at 50°C to yield 19.69 g of the compound of formula MS (ES+): m/z 347 (M+1 ). UVA/IS [nm] (water/acetonitrile 1 :1 ): ⁇ i 569, ⁇ 2 612.
- Step 3 1.28 g of the compound of formula (105b) and 0.73 g of bis(2-(2-bromoacetamido)- ethyl)-disulfide (RN 697755-79-6) are dissolved in 20 ml DMF and stirred for 3 days at 40°C. The dark blue solution is than dropped slowly into 500 ml acetone under vigorous stirring. The precipitate is filtered off, washed with 100ml acetone and dried in a vacuum oven at 50°C to yield 0.935 g of the compound of formula
- Step 1 A mixture of 5.00 g of C.I. Acid Blue 25 (RN 6408-78-2), 7.93 g potassium hydroxide and 20 ml of N,N-dimethyl-ethanolamine is stirred at room temperature for 2 h. Then the reaction mixture is poured into 200 ml of water and the resulting precipitate is collected by filtration. The solid is stirred in 200 ml of water for 30 min, then filtered off and dried under vacuum at 60°C to obtain 1.69 g of the compound of formula
- Step 2 0.50 g of the compound of formula (106a) and 0.29 g of the bis(toluolsulfonate) of (2- hydroxyethyl)-disulfide (RN 69981-39-1 ) are dissolved in 3 ml of NMP and stirred at 40°C for 72 h. Then the mixture is stirred for additional 72 h at 50°C. Then the reaction mixture is dropped into 200 ml of tert-butyl-methyl-ether.
- the precipitate is separated by filtration, dissolved again in 3 ml of NMP and precipitated by dropping the solution into 50 ml tert-butyl- methyl-ether. After filtration the product is dried under vacuum to obtain 0.32 g of the compound of formula
- Step 1 1.43 g of 1-(2-chloroacetamido)-anthraquinone (RN 20149-91-1 ) and 6.46 g imidazole are mixed in 10 ml o-dichlorobenzene and stirred at 1 10°C for 1 h. The reaction mixture is cooled to room temperature and poured into 1 L water under stirring. The precipitate is filtered, washed with water and dried under vacuum at 60°C to yield 1.30 g of the compound of formula
- Step 2 1.28 g of the compound of formula (107a) and 0.726 g of bis(2-(2-bromoacetamido)- ethyl)-disulfide (RN 697755-79-6) are mixed in 5 ml dimethylformamide and stirred at 60°C for 24h. The reaction mixture is poured into 150 ml acetone under stirring. The precipitate is filtered and washed twice with 100 ml acetone. The filter cake is dried under vacuum at 50°C to yield 1.72 g of the compound of formula
- reaction mixture is stirred for 7h at 80°C and cooled down to room temperature.
- the reaction mixture is placed on a water/ice mixture and adjusted to pH 3 by addition of cone.
- the resultant precipitate is filtered off, washed with water for several times and dried in vacuo.
- the obtained suspension is refluxed for 4h, whereupon the color of the reaction mixture changes from red to orange.
- heterogenic reaction mixture is cooled down to room temperature and the pH is adjusted to 4 with 20% NaOH.
- the precipitate is filtered off and washed with 10% sodium hydrogen carbonate solution and then neutral with water.
- reaction product is separated by washing with 100 ml of a 3% hydrochloric acid solution then with 100ml water with 3% salt.
- the solution is evaporated to dryness in vacuum to obtain 12g of a reddish blue solid product.
- the reaction mixture is stirred for 24h at 293°C.
- reaction product is separated by washing with 100 ml of a 3% hydrochloric acid solution, then with 100 ml water with 3% salt.
- the solution is evaporated to dryness in vacuum to obtain 12g of a reddish blue solid product.
- the product is characterized by 1 H-NMR data in deuterated methanol (128 scans)/ 360MHz
- reaction product is separated by washing with 100 ml of a 3% hydrochloric acid solution, then with 100 ml water with 3% salt.
- the solution is evaporated to dryness in vacuum to obtain 12g of a reddish blue solid product.
- reaction mixture is mixed with a water/hydrochloric acid and ice slurry, the phases are separated, washed with water and dried.
- reaction mixture of 250 g water and 103g of the xanthene precursor obtained in reaction step (a) is adjusted to pH 9.2 with sodium carbonate. 80ml toluene and the equivalent amount (32.Og) of diester and a catalytical amount (0.6g) of tetrabutyl-ammonium bromide are added and the reaction mixture is stirred for 6 hours at 300
- the reaction product is heated to 350 K, the lower water phase is separated, the upper toluene phase washed, then 160 ml water are added and toluene distillated.
- the precipitate is separated by filtration and dried in vacuum to obtain 9Og of an orange solid product.
- the product is characterized by 1 H-NMR data in deuterated chloroform (128 scans)/360MHz 7,970 d 6,7 1 ,98 phe
- reaction product is separated by washing with 100 ml of a 3% hydrochloric acid solution, then with 100 ml water with 3% salt.
- the solution is evaporated to dryness in vacuum to obtain 12g of a reddish blue solid product.
- Step 1 6.34g of 1-(3-methoxyphenyl)-piperazine dihydrochloride are suspended in 4 ml and cooled to 0- 5°C.
- reaction mass is poured into 50 ml diethyl ether.
- the product precipitates as an oil, which is dissolved in 100ml dichloromethane and washed with a NaHC ⁇ 3 solution.
- the organic phase is dried over sodium sulphate and filtered.
- Step 2 0.88g HBr (33%) are added drop wise to a suspension of 0.5g of the compound of formula (1 o1 a) in 2 g dimethyl formamide and 2.5 g water at 0 - 5°C. After completion of the addition the yellow solution is warmed up to room temperature and 0.32g of an aqueous sodium nitrite solution (46 w.%) is added slowly.
- reaction mixture is stirred at room temperature until the test on nitrite is negative
- Step 3 0.27g 3-diethylaminophenol are dissolved in 3g dimethyl formamide and after addition of a few drops of HBr (33%) the solution is heated to 70°C.
- Step 1 A solution of 7.58g of 3-diethylamino-anisole in 37g dimethyl formamide and 45g water is cooled to 0°C. Then 19.5g HBr (33%) are added via a dropping funnel over a period of 1 h, during which time the temperature is rising to 15°C.
- reaction mixture is stirred at room temperature until the test on nitrite is negative
- Step 2 A solution of 6.68g 1 -(3-hydroxyphenyl) piperazine and 9g HBr (33%) in 10g dimethyl formamide is heated to 70°C.
- step 1 the dark solution obtained in step 1 s added via a dropping funnel over a period of 2.5h.
- Step 3 A solution of 0.5g of the compound of formula (102a), 0.24g of bis(2-(2-bromo- acetamide)ethyl)-disulfide (RN 697755-79-6) and 0.08 g of potassium carbonate in 50ml methanol is stirred at 40°C for 12h.
- reaction product is precipitated by cooling, diluted with 375ml water and salted out with
- the product is recristallized twice from methanol.
- the temperature is maintained at 80°C during the following 4 hours.
- the product is crystallized by cooling to room temperature under mixing, than separated by filtration, washed and dryed in vacuum dryer.
- the temperature is raised to reflux and maintained at 80°C during the following 48 hours.
- the product is crystallized by cooling to room temperature under mixing, than separated by filtration, washed and dried in vacuum dryer.
- the temperature is raised to reflux andmaintained at 80°C during the following 8 hours.
- the product is crystallized by cooling to room temperature under mixing, than separated by filtration, washed and dryed in vacuum dryer.
- reaction product is precipitated by cooling, then separated by filtration and dried in vacuum to obtain 24Og of an orange solid product.
- the product is recristallized twice from methanol.
- the temperature is raised to reflux and maintained at 80°C during the following 48 hours.
- the product is crystallized by cooling to room temperature under mixing, than separated by filtration, washed and dried in the vacuum dryer.
- the product is characterized by 1 H-NMR data in deuterated chloroform (128 scans)/360MHz
- the temperature is raised to reflux and maintained at 80°C during the following 4 hours.
- the product is crystallized by cooling to room temperature under mixing, than separated by filtration, washed and dried in the vacuum dryer.
- the temperature is raised to reflux and maintained at 80°C during the following 48 hours.
- the obtaiened product is dissolved in one equivalent (4.0 g) of sodium hydroxide with absolute ethanol.
- the temperature is maintained at 80°C during the following 4 hours.
- the product is crystallized by cooling to room temperature under mixing, than separated by filtration, washed and dried in the vacuum dryer.
- the temperature is raised to reflux and maintained at 80°C during the following 18 hours.
- the product is crystallized by cooling to room temperature under mixing, than separated by filtration, washed and dried in thevacuum dryer.
- step (b) Condensation the equivalent amount (15Og) 2-chloroethyl-methylamino-benzaldehyde, 250 ml ethanol and a catalitical amount (9,6 g) piperidine are added to the reaction mixture obtained in step (a) and is stirred for 18 hours at 343 K.
- reaction product is precipitated by cooling, then separated by filtration and dried in vacuum to obtain 22Og of an orange solid product of formula
- the product is recristallized twice from methanol.
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Abstract
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Priority Applications (7)
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KR1020087008245A KR101276213B1 (en) | 2005-10-11 | 2006-09-13 | Mixture of sulfide dyes |
BRPI0617339A BRPI0617339B1 (en) | 2005-10-11 | 2006-09-13 | sulfide dye mixture, composition comprising it, and method for dyeing keratin-containing fibers |
CN2006800465394A CN101326246B (en) | 2005-10-11 | 2006-09-13 | Mixture of sulfide dyes |
JP2008534960A JP5312029B2 (en) | 2005-10-11 | 2006-09-13 | Mixture of sulfide dyes |
ES06793484T ES2402574T3 (en) | 2005-10-11 | 2006-09-13 | Sulphide dyes mixture |
EP06793484A EP1937780B1 (en) | 2005-10-11 | 2006-09-13 | Mixture of sulfide dyes |
US11/992,929 US7828858B2 (en) | 2005-10-11 | 2006-09-13 | Mixture of sulfide dyes |
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EP05109445.6 | 2005-10-11 | ||
EP05109445 | 2005-10-11 |
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PCT/EP2006/066325 WO2006136617A2 (en) | 2005-10-11 | 2006-09-13 | Mixture of sulfide dyes |
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US (1) | US7828858B2 (en) |
EP (1) | EP1937780B1 (en) |
JP (1) | JP5312029B2 (en) |
KR (1) | KR101276213B1 (en) |
CN (1) | CN101326246B (en) |
BR (1) | BRPI0617339B1 (en) |
ES (1) | ES2402574T3 (en) |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1995001772A1 (en) | 1993-07-05 | 1995-01-19 | Ciba-Geigy Ag | Process for dyeing keratin-containing fibres |
EP0850637A1 (en) | 1996-12-23 | 1998-07-01 | L'oreal | Composition for the oxidative dyeing of keratinic fibres and dyeing process using this composition |
DE19717224A1 (en) | 1997-04-24 | 1998-10-29 | Henkel Kgaa | Use of unsaturated aldehydes for dyeing keratin fibers |
WO1999048856A1 (en) | 1998-03-20 | 1999-09-30 | L'oreal | Oxidation dyeing compositions containing a cationic coupling agent, novel cationic coupling agents |
WO2005097051A2 (en) | 2004-04-08 | 2005-10-20 | Ciba Specialty Chemicals Holding Inc. | Disulfide dyes, composition comprising them and method of dyeing hair |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3329477A (en) * | 1963-03-11 | 1967-07-04 | Martin Marietta Corp | Method for printing dyestuffs and printing pastes |
DE3542232A1 (en) * | 1985-11-29 | 1987-06-04 | Bayer Ag | AZO DYES |
US4783393A (en) * | 1986-10-27 | 1988-11-08 | Eastman Kodak Company | Dye mixtures and optical recording elements containing same |
WO2003099243A1 (en) * | 2002-05-29 | 2003-12-04 | Henkel Kommanditgesellschaft Auf Aktien | Cosmetic agents containing protein disulfide isomerase |
ATE437205T1 (en) * | 2005-06-16 | 2009-08-15 | Ciba Holding Inc | STYRYL SULFIDE DYES |
DE602006018292D1 (en) * | 2005-06-23 | 2010-12-30 | Basf Se | SULFUR DYES |
MX2007016551A (en) * | 2005-06-23 | 2008-03-04 | Ciba Sc Holding Ag | Nitrosulfide dyes. |
CN101253181B (en) * | 2005-07-01 | 2011-06-08 | 西巴特殊化学制品控股公司 | Pyrido-thiazinium dyes |
EP1934291B1 (en) * | 2005-10-03 | 2011-09-14 | Basf Se | Xanthene dyes |
CN101326245A (en) * | 2005-10-06 | 2008-12-17 | 西巴特殊化学制品控股公司 | Thiol dyes |
JP5254796B2 (en) * | 2005-10-06 | 2013-08-07 | チバ ホールディング インコーポレーテッド | Oxazine disulfide dye |
CN101326244B (en) * | 2005-10-06 | 2013-07-24 | 巴西特殊化学制品控股公司 | Triarylmethane dyes |
-
2006
- 2006-09-13 JP JP2008534960A patent/JP5312029B2/en active Active
- 2006-09-13 US US11/992,929 patent/US7828858B2/en active Active
- 2006-09-13 EP EP06793484A patent/EP1937780B1/en active Active
- 2006-09-13 WO PCT/EP2006/066325 patent/WO2006136617A2/en active Application Filing
- 2006-09-13 CN CN2006800465394A patent/CN101326246B/en active Active
- 2006-09-13 KR KR1020087008245A patent/KR101276213B1/en active IP Right Grant
- 2006-09-13 ES ES06793484T patent/ES2402574T3/en active Active
- 2006-09-13 BR BRPI0617339A patent/BRPI0617339B1/en active IP Right Grant
- 2006-10-05 TW TW095137072A patent/TW200734411A/en unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1995001772A1 (en) | 1993-07-05 | 1995-01-19 | Ciba-Geigy Ag | Process for dyeing keratin-containing fibres |
EP0850637A1 (en) | 1996-12-23 | 1998-07-01 | L'oreal | Composition for the oxidative dyeing of keratinic fibres and dyeing process using this composition |
DE19717224A1 (en) | 1997-04-24 | 1998-10-29 | Henkel Kgaa | Use of unsaturated aldehydes for dyeing keratin fibers |
WO1999048856A1 (en) | 1998-03-20 | 1999-09-30 | L'oreal | Oxidation dyeing compositions containing a cationic coupling agent, novel cationic coupling agents |
WO2005097051A2 (en) | 2004-04-08 | 2005-10-20 | Ciba Specialty Chemicals Holding Inc. | Disulfide dyes, composition comprising them and method of dyeing hair |
Non-Patent Citations (2)
Title |
---|
"Europaisches Inventar der Kosmetikrohstoffe", 1996, THE EUROPEAN COMMISSION |
"The Science of Hair Care", vol. 7, 1986, VERLAG MARCEL DEKKER INC., article "Dermatology", pages: 248 - 250 |
Cited By (72)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1852119A1 (en) * | 2005-02-17 | 2007-11-07 | Japan Science and Technology Agency | Pharmaceutical composition containing phenoxazinium compound as active ingredient |
EP1852119A4 (en) * | 2005-02-17 | 2008-05-28 | Japan Science & Tech Agency | Pharmaceutical composition containing phenoxazinium compound as active ingredient |
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JP4886778B2 (en) * | 2005-07-01 | 2012-02-29 | チバ ホールディング インコーポレーテッド | Pyrido-thiazinium dye |
US8562693B2 (en) | 2006-03-24 | 2013-10-22 | L'oreal | Method of dyeing and lightening keratin materials in the presence of a reducing agent comprising a fluorescent deisulphide dye |
WO2007110532A2 (en) * | 2006-03-24 | 2007-10-04 | L'oréal | Dyeing composition containing a thiol/disulphide fluorescent colorant comprising a heterocycle, with an external cationic charge, and method for lightening keratin materials using said colorant |
WO2007110537A2 (en) * | 2006-03-24 | 2007-10-04 | L'oréal | Dyeing composition containing a thiol/disulphide fluorescent colorant comprising amine groups and having an internal cationic charge, and method for lightening keratin materials using said colorant |
WO2007110538A2 (en) * | 2006-03-24 | 2007-10-04 | L'oréal | Dyeing composition containing a masked thiol fluorescent colorant comprising a dimethylamino group, with an internal cationic charge, and method for lightening keratin materials using said colorant and disulphide colorants |
WO2007110533A2 (en) * | 2006-03-24 | 2007-10-04 | L'oréal | Dyeing composition containing a thiol/disulphide fluorescent colorant having an external cationic charge and an interrupted alkylene chain, and method for lightening keratin materials using said colorant |
US8685114B2 (en) | 2006-03-24 | 2014-04-01 | L'oreal | Composition for dyeing and lightening keratin materials comprising a fluorescent deisulphide dye compound |
WO2007110534A3 (en) * | 2006-03-24 | 2008-04-03 | Oreal | Dyeing composition comprising a thiol/disulphide fluorescent colorant having an external cationic charge, and method for lightening keratin materials using said colorant |
WO2007110537A3 (en) * | 2006-03-24 | 2008-04-10 | Oreal | Dyeing composition containing a thiol/disulphide fluorescent colorant comprising amine groups and having an internal cationic charge, and method for lightening keratin materials using said colorant |
WO2007110532A3 (en) * | 2006-03-24 | 2008-04-10 | Oreal | Dyeing composition containing a thiol/disulphide fluorescent colorant comprising a heterocycle, with an external cationic charge, and method for lightening keratin materials using said colorant |
WO2007110536A3 (en) * | 2006-03-24 | 2008-05-15 | Oreal | Dyeing composition containing a thiol/disulphide fluorescent colorant comprising an ortho-pyridinium group with an uninterrupted alkylene chain and an internal cationic charge, and method for lightening keratin materials using said colorant |
WO2007110539A2 (en) * | 2006-03-24 | 2007-10-04 | L'oréal | Dyeing composition containing a thiol/disulphide fluorescent colorant comprising a heterocycle, with an internal cationic charge, and method for lightening keratin materials using said colorant |
WO2007110539A3 (en) * | 2006-03-24 | 2008-06-19 | Oreal | Dyeing composition containing a thiol/disulphide fluorescent colorant comprising a heterocycle, with an internal cationic charge, and method for lightening keratin materials using said colorant |
WO2007110533A3 (en) * | 2006-03-24 | 2008-07-31 | Oreal | Dyeing composition containing a thiol/disulphide fluorescent colorant having an external cationic charge and an interrupted alkylene chain, and method for lightening keratin materials using said colorant |
JP2014040612A (en) * | 2006-03-24 | 2014-03-06 | L'oreal Sa | Method for dyeing and brightening keratinous matter in presence of reducing agent including fluorescent disulfide dye |
WO2007110538A3 (en) * | 2006-03-24 | 2008-10-09 | Oreal | Dyeing composition containing a masked thiol fluorescent colorant comprising a dimethylamino group, with an internal cationic charge, and method for lightening keratin materials using said colorant and disulphide colorants |
WO2007110541A2 (en) * | 2006-03-24 | 2007-10-04 | L'oreal | Dyeing composition containing a thiol/disulphide fluorescent colorant comprising a condensed cycle, with an internal cationic charge, and method for lightening keratin materials using said colorant |
WO2007110536A2 (en) * | 2006-03-24 | 2007-10-04 | L'oréal | Dyeing composition containing a thiol/disulphide fluorescent colorant comprising an ortho-pyridinium group with an uninterrupted alkylene chain and an internal cationic charge, and method for lightening keratin materials using said colorant |
JP2013079252A (en) * | 2006-03-24 | 2013-05-02 | L'oreal Sa | Dyeing and lightening method of keratinous substance in the presence of fluorescence disulfide dye-containing reducing agent |
WO2007110534A2 (en) * | 2006-03-24 | 2007-10-04 | L'oréal | Dyeing composition comprising a thiol/disulphide fluorescent colorant having an external cationic charge, and method for lightening keratin materials using said colorant |
US8070830B2 (en) | 2006-03-24 | 2011-12-06 | L'oreal S.A. | Fluorescent entity, dyeing composition containing at least one fluorescent entity comprising at least one heterocycle, with at least one internal cationic charge, and method for lightening keratin materials using said at least one fluorescent entity |
JP2009535296A (en) * | 2006-03-24 | 2009-10-01 | ロレアル | Method for dyeing and brightening keratin in the presence of reducing agents containing fluorescent disulfide dyes |
US7780743B2 (en) | 2006-03-24 | 2010-08-24 | L'oreal S.A. | Fluorescent entity, dyeing composition containing at least one fluorescent entity, and method for lightening keratin materials using said at least one fluorescent entity |
WO2007110541A3 (en) * | 2006-03-24 | 2008-08-07 | Oreal | Dyeing composition containing a thiol/disulphide fluorescent colorant comprising a condensed cycle, with an internal cationic charge, and method for lightening keratin materials using said colorant |
US7803197B2 (en) | 2006-08-17 | 2010-09-28 | Ciba Corporation | Thiol derivative dyes |
WO2008019977A2 (en) | 2006-08-17 | 2008-02-21 | Ciba Holding Inc. | Thiol derivative dyes |
WO2008019977A3 (en) * | 2006-08-17 | 2008-12-18 | Ciba Holding Inc | Thiol derivative dyes |
WO2009010694A3 (en) * | 2007-07-09 | 2009-04-09 | Oreal | Dyeing method using a styryl- or imine-type disulfide/thiol compound and stimuli, composition and device for implementing same |
FR2918667A1 (en) * | 2007-07-09 | 2009-01-16 | Oreal | METHOD FOR COLORING USING A STYRYLIC OR IMINIC TYPE DISULFIDE / THIOL AND STIMULI COMPOUND, COMPOSITION AND DEVICE FOR CARRYING OUT THE METHOD |
WO2009010694A2 (en) * | 2007-07-09 | 2009-01-22 | L'oreal | Dyeing method using a styryl- or imine-type disulfide/thiol compound and stimuli, composition and device for implementing same |
EP2018847A1 (en) | 2007-07-24 | 2009-01-28 | L'Oreal | Hair composition comprising at least one direct disulfide dye and at least one alkali hydroxide agent and method of simultaneous styling and dyeing. |
US7717964B2 (en) | 2007-09-21 | 2010-05-18 | L'oreal S.A. | Styryl thiol/disulfide compound with a hydroxy(cyclo)alkylamino unit, process for lightening keratin materials using same |
EP2062945A2 (en) | 2007-09-21 | 2009-05-27 | L'Oréal | Hemicyanin styryl thiol/disulfide dye, dye composition comprising this dye, process for lightening keratin materials using this dye |
FR2921376A1 (en) * | 2007-09-21 | 2009-03-27 | Oreal | STYRYL TETRAHYDROQUINOLINIUM THIOL / DISULFIDE COMPOUND, PROCESS FOR CLEANING KERATINIC MATERIALS FROM THAT COLORANT |
FR2921377A1 (en) * | 2007-09-21 | 2009-03-27 | Oreal | New styryl hydroxy(cyclo)alkylamino thiol/disulfide compounds useful as fluorescent dye, for coloring human keratin fibers, preferably dark keratin fibers and for lightening dark keratin fibers |
FR2921374A1 (en) * | 2007-09-21 | 2009-03-27 | Oreal | INDOLINIUM THIOL / DISULFIDE DERIVATIVE DYE, TINCTORIAL COMPOSITION COMPRISING THE DYE, METHOD FOR LIGHTENING KERATINIC MATERIALS FROM THAT COLORANT |
EP2070988A3 (en) * | 2007-09-21 | 2010-03-10 | L'Oréal | Styryl thiol/disulfide compound with a hydroxy(cyclo)alkylamino unit, process for lightening keratin materials using this dye |
US7727287B2 (en) | 2007-09-21 | 2010-06-01 | L'oreal S.A. | Hemicyanin styryl thiol/disulfide dye, composition comprising hemicyanin styryl thoil/disulfide dye, and method for lightening keratin materials using hemicyanin styryl thiol/disulfide dye |
US7744657B2 (en) | 2007-09-21 | 2010-06-29 | L'oreal S.A. | Styrl tetrahydroquinolinium thiol/disulfide dye compound and method for lightening keratin materials using the same |
US7744658B2 (en) | 2007-09-21 | 2010-06-29 | L'oreal S.A. | Indole-derived styryl dye comprising an alkylene linker, a dye composition comprising this dye, and a process for lightening keratin materials using this dye |
FR2921380A1 (en) * | 2007-09-21 | 2009-03-27 | Oreal | New substituted pyridocycloalkyl styryl thiol/disulfide compounds useful as fluorescent dye for coloring and lightening of dark human keratin fibers |
WO2009037348A1 (en) * | 2007-09-21 | 2009-03-26 | L'oreal | Indolinium-derived thiol/disulfide dye, dye composition comprisng this dye, process for lightening keratin materials using this dye |
KR101168615B1 (en) | 2007-09-21 | 2012-08-03 | 로레알 | Hemicyanin styryl thiol/disulfide dye, dye composition comprising this dye, process for lightening keratin materials using this dye |
EP2070988A2 (en) | 2007-09-21 | 2009-06-17 | L'Oréal | Styryl thiol/disulfide compound with a hydroxy(cyclo)alkylamino unit, process for lightening keratin materials using this dye |
EP2075289A1 (en) | 2007-09-21 | 2009-07-01 | L'Oréal | Styryl tetrahydroquinolinium thiol/disulfide compound, process for lightening keratin materials using this dye |
FR2921256A1 (en) * | 2007-09-24 | 2009-03-27 | Oreal | COMPOSITION FOR COLORING KERATINIC FIBERS COMPRISING AT LEAST ONE DIRECT DYE WITH DISULFURE / THIOL FUNCTION AND AT LEAST ONE THIOL-FUNCTIONAL POLYMER AND PROCESS USING THE COMPOSITION |
EP2053094A2 (en) | 2007-09-24 | 2009-04-29 | L'Oréal | Composition for dyeing keratinous fibres comprising at least one direct dye with disulphur/thiol function and at least one polymer with thiol function and method using the composition |
EP2053094A3 (en) * | 2007-09-24 | 2010-03-17 | L'Oréal | Composition for dyeing keratinous fibres comprising at least one direct dye with disulphur/thiol function and at least one polymer with thiol function and method using the composition |
WO2009090125A1 (en) | 2008-01-17 | 2009-07-23 | Basf Se | Polymeric hair dyes |
WO2011006946A2 (en) | 2009-07-15 | 2011-01-20 | Basf Se | Polymeric hair dyes |
WO2011054966A2 (en) | 2009-11-09 | 2011-05-12 | L'oreal | New dyes with heterocyclic disulphide unit, colouring composition comprising them, and method for dyeing human keratinous fibres on the basis of these dyes |
FR2955860A1 (en) * | 2010-02-03 | 2011-08-05 | Oreal | Use of substituted azophenyl-ethane diamine compounds for dyeing keratin fibers, preferably human hair |
WO2012022709A1 (en) | 2010-08-17 | 2012-02-23 | Basf Se | Disulfide or thiol polymeric hair dyes |
US9045435B2 (en) | 2010-10-05 | 2015-06-02 | Purdue Pharma, L.P. | Quinazoline compounds as sodium channel blockers |
US9168255B2 (en) | 2010-10-05 | 2015-10-27 | Purdue Pharma L.P. | Quinazoline compounds as sodium channel blockers |
WO2012069476A1 (en) | 2010-11-24 | 2012-05-31 | L'oreal | Novel direct dyes containing an ascorbic acid-based unit, dye composition comprising them and process for dyeing human keratin materials using these dyes |
US10494527B2 (en) | 2015-03-19 | 2019-12-03 | Basf Se | Cationic direct dyes |
WO2016146813A1 (en) * | 2015-03-19 | 2016-09-22 | Basf Se | Cationic direct dyes |
CN107428709A (en) * | 2015-03-19 | 2017-12-01 | 巴斯夫欧洲公司 | Cation direct dye |
CN107428709B (en) * | 2015-03-19 | 2021-10-08 | 巴斯夫欧洲公司 | Cationic direct dyes |
WO2017093558A1 (en) | 2015-12-03 | 2017-06-08 | L'oreal | Novel anionic dyes containing a disulfide heterocyclic unit, dyecomposition comprising them and process for dyeing human keratin materials using these dyes |
WO2018229294A1 (en) * | 2017-06-16 | 2018-12-20 | L'oreal | Process for dyeing keratin fibres using at least one disulfide, thiol or protected-thiol fluorescent dye and at least one activator comprising a reducing agent and at least two different alkaline agents |
FR3067599A1 (en) * | 2017-06-16 | 2018-12-21 | L'oreal | METHOD FOR COLORING KERATINIC MATERIALS USING AT LEAST ONE BLUE, PURPLE OR GREEN COLOR, AND AT LEAST ONE FLUORESCENT DYE DISULFIDE, THIOL OR THIOL PROTECTED |
FR3067598A1 (en) * | 2017-06-16 | 2018-12-21 | L'oreal | METHOD FOR COLORING KERATIN FIBERS USING AT LEAST ONE PROTECTED FLUORESCENT, THIOL OR THIOL DYE AND AT LEAST ONE ACTIVATOR COMPRISING A REDUCER AND LESS THAN TWO DIFFERENT ALKALI AGENTS |
FR3067597A1 (en) * | 2017-06-16 | 2018-12-21 | L'oreal | METHOD FOR COLORING KERATIN FIBERS USING AT LEAST ONE DIRECT DYE AND AT LEAST ONE FLUORESCENT COLOR DISULFIDE, THIOL OR THIOL PROTECTED |
WO2018229296A1 (en) | 2017-06-16 | 2018-12-20 | L'oreal | Process for dyeing keratin materials using at least one blue, purple or green dye and at least one disulfide, thiol or protected thiol fluorescent dye |
US11096880B2 (en) | 2017-06-16 | 2021-08-24 | L'oreal | Process for dyeing keratin fibres using at least one direct dye and at least one disulfide, thiol or protected-thiol fluorescent dye |
WO2018229295A1 (en) * | 2017-06-16 | 2018-12-20 | L'oreal | Process for dyeing keratin fibres using at least one direct dye and at least one disulfide, thiol or protected-thiol fluorescent dye |
US11278482B2 (en) | 2017-06-16 | 2022-03-22 | L'oreal | Process for dyeing keratin materials using at least one blue, purple or green dye and at least one disulfide, thiol or protected thiol fluorescent dye |
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US20090100610A1 (en) | 2009-04-23 |
BRPI0617339B1 (en) | 2017-04-04 |
KR20080056189A (en) | 2008-06-20 |
WO2006136617A3 (en) | 2008-03-27 |
EP1937780A2 (en) | 2008-07-02 |
TW200734411A (en) | 2007-09-16 |
US7828858B2 (en) | 2010-11-09 |
KR101276213B1 (en) | 2013-06-25 |
BRPI0617339A2 (en) | 2011-07-26 |
ES2402574T3 (en) | 2013-05-06 |
CN101326246A (en) | 2008-12-17 |
JP2009511531A (en) | 2009-03-19 |
EP1937780B1 (en) | 2013-02-13 |
CN101326246B (en) | 2012-09-05 |
JP5312029B2 (en) | 2013-10-09 |
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