WO2006116344A3 - Asymmetric hydroformylation process - Google Patents

Asymmetric hydroformylation process Download PDF

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Publication number
WO2006116344A3
WO2006116344A3 PCT/US2006/015532 US2006015532W WO2006116344A3 WO 2006116344 A3 WO2006116344 A3 WO 2006116344A3 US 2006015532 W US2006015532 W US 2006015532W WO 2006116344 A3 WO2006116344 A3 WO 2006116344A3
Authority
WO
WIPO (PCT)
Prior art keywords
hydroformylation process
asymmetric hydroformylation
asymmetric
hydroesterification
hydrocarboxylation
Prior art date
Application number
PCT/US2006/015532
Other languages
French (fr)
Other versions
WO2006116344A2 (en
Inventor
Jerzy Klosin
Gregory T Whiteker
Christopher Cobley
Original Assignee
Dow Global Technologies Inc
Jerzy Klosin
Gregory T Whiteker
Christopher Cobley
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc, Jerzy Klosin, Gregory T Whiteker, Christopher Cobley filed Critical Dow Global Technologies Inc
Priority to JP2008507990A priority Critical patent/JP2008538585A/en
Priority to EP06751294A priority patent/EP1874711A2/en
Priority to CNA2006800132076A priority patent/CN101443293A/en
Publication of WO2006116344A2 publication Critical patent/WO2006116344A2/en
Publication of WO2006116344A3 publication Critical patent/WO2006116344A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00—Asymmetric syntheses

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

The present invention comprises synthetically useful processes in which an olefin undergoes an asymmetric reaction selected from the group consisting of hydroformylation, hydrocyanation, hydrocarboxylation and hydroesterification, in the presence of, as catalyst, a transition metal complex of an enantiomerically enriched chiral bis(phospholane) ligand.
PCT/US2006/015532 2005-04-22 2006-04-21 Asymmetric hydroformylation process WO2006116344A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2008507990A JP2008538585A (en) 2005-04-22 2006-04-21 Asymmetric hydroformylation process
EP06751294A EP1874711A2 (en) 2005-04-22 2006-04-21 Asymmetric hydroformylation process
CNA2006800132076A CN101443293A (en) 2005-04-22 2006-04-21 Unsymmetrical hydrogenation formyl reaction method

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US67405705P 2005-04-22 2005-04-22
US60/674,057 2005-04-22

Publications (2)

Publication Number Publication Date
WO2006116344A2 WO2006116344A2 (en) 2006-11-02
WO2006116344A3 true WO2006116344A3 (en) 2007-05-18

Family

ID=37215385

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/015532 WO2006116344A2 (en) 2005-04-22 2006-04-21 Asymmetric hydroformylation process

Country Status (4)

Country Link
EP (1) EP1874711A2 (en)
JP (1) JP2008538585A (en)
CN (1) CN101443293A (en)
WO (1) WO2006116344A2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4500289B2 (en) * 2005-07-25 2010-07-14 国立大学法人 千葉大学 2,3-bis (dialkylphosphino) pyrazine derivative, method for producing the same, and metal complex having the derivative as a ligand
JP2009046469A (en) * 2007-07-26 2009-03-05 Chiba Univ Method for preparing optically active allyl compound
DE102010043558A1 (en) * 2010-11-08 2012-05-10 Evonik Oxeno Gmbh Process for the hydroformylation of unsaturated compounds

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997003943A1 (en) * 1995-07-17 1997-02-06 Shell Internationale Research Maatschappij B.V. Process for the continuous carbonylation of olefins
WO1999059721A1 (en) * 1998-05-18 1999-11-25 The Penn State Research Foundation Catalytic asymmetric hydrogenation, hydroformylation, and hydrovinylation via transition metal catalysts with phosphines and phosphites
WO2000011008A1 (en) * 1998-08-21 2000-03-02 The Penn State Research Foundation Asymmetric catalysis based on chiral phospholanes
FR2835833A1 (en) * 2002-02-13 2003-08-15 Rhodia Polyamide Intermediates PROCESS FOR THE PRODUCTION OF NITRILIC COMPOUNDS FROM ETHYLENE-UNSATURATED COMPOUNDS
WO2003084971A1 (en) * 2002-04-04 2003-10-16 Degussa Ag Bisphosphines as bidentate ligands

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5008457A (en) * 1990-05-17 1991-04-16 E. I. Du Pont De Nemours And Company Chiral phospholane transition metal catalysts
US6545183B1 (en) * 1997-11-07 2003-04-08 Chirotech Technology Limited Process for preparing cyclic phosphines
DE69813297T2 (en) * 1997-12-17 2003-12-11 Chirotech Technology Ltd ASYMMETRIC HYDRATION

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997003943A1 (en) * 1995-07-17 1997-02-06 Shell Internationale Research Maatschappij B.V. Process for the continuous carbonylation of olefins
WO1999059721A1 (en) * 1998-05-18 1999-11-25 The Penn State Research Foundation Catalytic asymmetric hydrogenation, hydroformylation, and hydrovinylation via transition metal catalysts with phosphines and phosphites
WO2000011008A1 (en) * 1998-08-21 2000-03-02 The Penn State Research Foundation Asymmetric catalysis based on chiral phospholanes
FR2835833A1 (en) * 2002-02-13 2003-08-15 Rhodia Polyamide Intermediates PROCESS FOR THE PRODUCTION OF NITRILIC COMPOUNDS FROM ETHYLENE-UNSATURATED COMPOUNDS
WO2003084971A1 (en) * 2002-04-04 2003-10-16 Degussa Ag Bisphosphines as bidentate ligands

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
AXTELL, ALEX T. ET AL: "Highly regio- and enantioselective asymmetric hydroformylation of olefins mediated by 2,5-disubstituted phospholane ligands", ANGEWANDTE CHEMIE, INTERNATIONAL EDITION , 44(36), 5834-5838 CODEN: ACIEF5; ISSN: 1433-7851, 2005, XP009059533 *
HUANG, JINKUN ET AL: "A highly enantioselective catalyst for asymmetric hydroformylation of [2.2.1]-bicyclic olefins", TETRAHEDRON LETTERS , 46(45), 7831-7834 CODEN: TELEAY; ISSN: 0040-4039, 2005, XP002417439 *
PARRINELLO, G. ET AL: "Platinum-catalyzed asymmetric hydroformylation with a polymer-attached optically active phosphine ligand", JOURNAL OF ORGANIC CHEMISTRY , 51(22), 4189-95 CODEN: JOCEAH; ISSN: 0022-3263, 1986, XP002417437 *
TANAKA, MASATO ET AL: "Diphosphine-rhodium complex-catalyzed hydroformylation of .alpha.,.beta.-unsaturated esters", BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN , 50(9), 2351-7 CODEN: BCSJA8; ISSN: 0009-2673, 1977, XP002417438 *
TOTH, IMRE ET AL: "Synthesis of Pt compounds containing chiral (2S,4S)-pentane-2,4-diyl- bis(5H-dibenzo[b]phosphindole) as ligand and their use in asymmetric hydroformylation of styrene derivatives", JOURNAL OF ORGANOMETALLIC CHEMISTRY , 540(1-2), 15-25 CODEN: JORCAI; ISSN: 0022-328X, 1997, XP004082250 *

Also Published As

Publication number Publication date
WO2006116344A2 (en) 2006-11-02
EP1874711A2 (en) 2008-01-09
JP2008538585A (en) 2008-10-30
CN101443293A (en) 2009-05-27

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