WO2006069753A1 - Method of producing metal to glass, metal to metal or metal to ceramic connections - Google Patents
Method of producing metal to glass, metal to metal or metal to ceramic connections Download PDFInfo
- Publication number
- WO2006069753A1 WO2006069753A1 PCT/EP2005/013968 EP2005013968W WO2006069753A1 WO 2006069753 A1 WO2006069753 A1 WO 2006069753A1 EP 2005013968 W EP2005013968 W EP 2005013968W WO 2006069753 A1 WO2006069753 A1 WO 2006069753A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- metal
- glass
- oxide
- grain size
- connections
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
- C03C27/04—Joining glass to metal by means of an interlayer
- C03C27/042—Joining glass to metal by means of an interlayer consisting of a combination of materials selected from glass, glass-ceramic or ceramic material with metals, metal oxides or metal salts
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
- C03C27/04—Joining glass to metal by means of an interlayer
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C29/00—Joining metals with the aid of glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/24—Fusion seal compositions being frit compositions having non-frit additions, i.e. for use as seals between dissimilar materials, e.g. glass and metal; Glass solders
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B37/00—Joining burned ceramic articles with other burned ceramic articles or other articles by heating
- C04B37/02—Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B37/00—Joining burned ceramic articles with other burned ceramic articles or other articles by heating
- C04B37/02—Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles
- C04B37/023—Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles characterised by the interlayer used
- C04B37/025—Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles characterised by the interlayer used consisting of glass or ceramic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
- H01M8/028—Sealing means characterised by their material
- H01M8/0282—Inorganic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2311/00—Metals, their alloys or their compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
- C04B2237/02—Aspects relating to interlayers, e.g. used to join ceramic articles with other articles by heating
- C04B2237/10—Glass interlayers, e.g. frit or flux
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
- C04B2237/30—Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
- C04B2237/32—Ceramic
- C04B2237/34—Oxidic
- C04B2237/343—Alumina or aluminates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
- C04B2237/30—Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
- C04B2237/40—Metallic
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M2008/1293—Fuel cells with solid oxide electrolytes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Definitions
- the present invention relates to a method of producing metal to glass, metal to metal and metal to ceramic connections.
- Said connections may, for example, be used in solid oxide fuel cell (SOFC) applications.
- SOFC solid oxide fuel cell
- SOFCs of the flat plate design comprise a stack of multiple cells, each of them comprising an electrolyte sandwiched by two electrodes.
- the electrodes of each cell are in contact with interconnect layers which make the series connection between the individual cells. Gas tight sealings are virtually important for the performance, durability and safely operation of a fuel cell.
- Glasses are suitable as sealing materials for SOFCs since the physical and chemical properties of glasses can be tailored within a wide range.
- Different glass and glass-ceramic compositions have been examined within the group of alkali silicate, alkali aluminosilicates, alkaline earth silicates, alkaline earth aluminoborosilicates, phosphate and borosilicate glasses.
- alkali silicate, alkali aluminosilicates, alkaline earth silicates, alkaline earth aluminoborosilicates, phosphate and borosilicate glasses have been able to fulfill all the requirements of mechanical performance, e.g. viscosity and match of thermal expansion and chemical compatibility, e.g. wetting and bonding.
- Oxides of the metallic elements themselves are well known constituents in the so-called ground coats when bonding vitreous enamels to ferrous alloys and are characterized by their ability to partially oxidize metallic Fe and form vitreous or mixed oxide phases, often characterized by dendrite formation at various oxidation states, cf. Donald, I. W., "Preparation, properties and chemistry of glass and glass-ceramic-to-metal seals and coatings, J. Mat, Sci. 28 (1993), p. 2841-86 and Eppler, R. A "Glazes and glass coatings", The American Ceramic Society, Westen/ille, Ohio (2000).
- Said object is achieved by a method of manufacturing metal to glass, metal to metal, and metal to ceramic connections and which is able to engineer the boundary phases, so as to obtain a strong bond independent of the metal alloy composition and a protective oxidation scale developed during use characterized by said connections being produced to a desired layer thickness as a mixture of a base glass powder and a metal oxide powder, preferably of predetermined particle sizes and in a binder system, referred to as a glassy connection layer, the bonding being provided at elevated temperatures under controlled conditions, wherein the metal oxide powder is selected from the group consisting of:
- Said object is moreover achieved by a method of manufacturing metal to glass, metal to metal, and metal to ceramic connections, characterized by said connections being produced with a mixture comprising a base glass powder and a metal oxide powder having a grain size of 5 ⁇ m or less.
- Fig. 1 illustrates the general concept and method.
- Fig. 2A-2E illustrate the method of manufacturing the connections and specific embodiments of the method.
- Fig. 3A-3B illustrate a special embodiment of the method.
- the base glass powder is a glass matrix with a high coefficient of thermal expansion.
- the base glass powder is preferably selected from the group consisting of alkali aluminosilicates, (NAS), alkaline earth aluminoborosilicates, (CAS), and phosphate glasses, (MAP), to which metal oxides are added, e.g. magnesium oxide, in order to control the local wetting properties, henceforth referred to as a glassy connection layer.
- NAS alkali aluminosilicates
- CAS alkaline earth aluminoborosilicates
- MAP phosphate glasses
- Alkali alumosilicates, (NAS), suitable for the present invention comprise 10-25 mole % sodium oxide, 40-80 mole % silicon dioxide, 5-20 mole % aluminium oxide, and may optionally comprise 0-10 mole % boric oxide, 0-10 mole % magnesium oxide, 0-10 mole % calcium oxide, 0-10 mole % barium oxide, 0-2 mole % fluorine, and 0-5 mole % phosphor oxide.
- Alkaline earth alumoborosilicates suitable for the present invention comprise 40-80 mole % silicon dioxide, 5-20 mole % aluminium oxide, 20-45 mole % calcium oxide, and may optionally comprise 0-5 mole % sodium oxide, 0-10 mole % boric oxide, 0-10 mole % magnesium oxide, 0-2 mole % barium oxide, 0-2 mole % fluorine, and 0-5 mole % phosphor oxide.
- Phosphate glasses (MAP) suitable for the present invention comprise 5-25 mole % aluminium oxide, 10-30 mole % magnesium oxide, 5-20 mole % calcium oxide, 40-60 mole % phosphor oxide and may optionally comprise 0-5 mole % sodium oxide, 0-12 mole % silicon dioxide, 0-10 mole % boric oxide, 0-5 mole % barium oxide, and 0-2 mole % fluorine.
- Table 1 illustrates the compositional range for the base glasses used as defined above. Table !
- Interconnects develop a protective chromium-containing scale having a microstructure and composition which depend on the intrinsic alloy.
- surface coatings are applied onto the interconnect which form strong and chemically compatible interfaces between the two components.
- the inherent properties of the glass used in the composite seal parts have been altered locally at the metal-coat interface by addition of e.g. MgO, in order to control the viscosity and wetting, and at the same time maintain the bulk properties, e.g. high coefficient of thermal expansion of the base glass towards the seal components.
- the base glass composition has been selected so that a considerable amount of residual glass remains after bonding and partially crystallization of the glass composite seal and the glassy connection layer.
- the grain size of the base glass powder to be used in accordance with the present invention is preferably from 0.05 ⁇ m to 100 ⁇ m, more preferably from 0.05 ⁇ m to 50 ⁇ m, and most preferred from 0.05 ⁇ m to 30 ⁇ m.
- the grain size of the metal oxide powder to be used with the base glass powder in accordance with the present invention is 5 ⁇ m or less, preferably from 0.05 ⁇ m to 5 ⁇ m, more preferably from 0.05 ⁇ m to 3 ⁇ m, and most preferred from 0.05 ⁇ m to 1.5 ⁇ m.
- the bonding in accordance with the present invention is provided under elevated temperatures, depending on the specific components used, particularly the base glass powder.
- Preferred temperatures for the bonding are from 400 0 C to 1100 0 C. It is also preferred to select the temperature to be from 200 to 400 0 C above the glass transition temperature in question and even more preferred from 250 to 35O 0 C above the glass transition temperature in question.
- the conditions for the bonding are controlled to achieve optimal bonding strength of the connections by firstly supplying air to the joint for oxidizing the organic binder during heat up through a temperature range from room temperature to 55O 0 C. Secondly, at higher temperatures an orthogonal sealing pressure, typically between 0.1 kPa and 1000 kPa and preferably between 10 kPa and 400 kPa is applied and held constant during the bonding process, which typically lasts from 0.1 to 10 hours.
- the metal surface is coated with a metallic coating.
- Said coating may be alloyed into the surface by heating to high temperature, preferably between 750 to 95O 0 C for relatively short time, preferably 0.5 to 5 hours in a controlled atmosphere, where the oxygen and nitrogen partial pressures are held lower than ⁇ 10 "20 bar.
- a transition-metal oxide coating may be applied to the metal surface by spraying or dip-coating prior to the application of the base glass powder and the metal oxide.
- transition metal oxides in particular cobalt-, nickel-, and manganese oxide, which are preferably applied as a surface coating on the metal, together with the glassy connection layer, encompasses a tunable base coat, which is used for instance in a SOFC environment for providing a strong bonding component between the metal parts and the neighbor components in form of glassy composite seal parts, other metal parts or ceramic parts.
- the transition metal oxides may also be added to the glass in smaller amounts.
- Specific connections are produced by coating a composite seal part with a dispersed metal oxide suspension. This may be carried out by, for example, dip coating or spraying.
- Examples of the metal oxides to be added to the base glass powder in order to control the glass wetting properties are boron oxide, magnesium oxide, sodium oxide, potassium oxide and vanadium oxide, with boron oxide, magnesium oxide and sodium oxide being particularly preferred.
- Examples of the metal oxides to be added to the base glass powder or preferably as a surface coat on the metallic part in order to control the glass bonding and adhesion properties are manganese oxide, nickel oxide, cobalt oxide, molybdenum oxide, copper oxide or mixtures thereof.
- Preferred oxides are manganese oxide, nickel oxide, and cobalt oxide, with nickel oxide and cobalt oxide being particularly preferred.
- connections are produced as a mixture of a base glass powder and a metal oxide powder in a binder system.
- Metallic materials have been divided into three groups; one which develops a duplex seal of chromia and Cr-Mn-spinel (exemplified by Krupp-Thyssen, Crofer 22APU), a second which develops a single layer scale of chromia (exemplified by Sandvik 0YC44), and a third which develops a protective alumina scale (exemplified by Fe Cr alloy). Interconnect materials of ferritic chromium steel were cut to shape before treated with surface coatings.
- Silicate glass samples were produced by melting analytical grade chemicals Na 2 CO 3 , SiO 2 , AI 2 O 3 , B 2 O 3 , MgO, NaF, and CaCO 2 in a platinum crucible at 1500 0 C for 4 hr. The glass was quenched, crushed, re-melted and finall milled into powder (d50 ⁇ 5 ⁇ m, as measured by a Beckman coulter I/S particle size analyser).
- Phosphate glasses were prepared by mixing analytical grade MgHPO 4 (3H 2 O), AI(PO 3 ) 3 , H 3 BO 3 and SiO 2 by ball milling, melting in alumina crucibles at 1500 0 C for 30 minutes while stirring before quenching, crushing and final milling into powder (d50 ⁇ 5 ⁇ m).
- Thin films having a dried thickness of 5-45 ⁇ m were made by screen-printing of glass powder or mixtures of glass powder and metal oxide powders.
- Glass foils typically in the range of 200-400 ⁇ m were made by tape casting of glass powder or mixtures of glass powder and metal oxide powder.
- Table 2 illustrates the three prepared base glass samples.
- a Crofer 22APU (c) was coated with a 15 ⁇ m thick layer of glass No
- a Sandvik 0YC44 (c) was coated with nominally 0.1 ⁇ m metallic nickel (d) and by screen-printing coated with a 45 ⁇ m thick layer of glass No 1/MgO glassy connection layer (2 wt% MgO, d ⁇ 1.1 ⁇ m (b), cf. Fig. 2 B).
- Glass No 1 was prepared and combined with 55 wt% coarse MgO for the composite seal part (a).
- Metal and composite seal were held together by 400 kPa during heating to 950° for 4 h before cooling to 750 0 C in an argon/hydrogen mixture, where the connection was aged for 500 h before being thermally cycled twice to room temperature.
- a Sandvik 0YC44 (c) was coated with nommlaly 0.1 ⁇ m Mn-metal (d) and preheated in argon (pO 2 ⁇ 10 '20 atm.) to alloy the coating into the surface and after cooling to room temperature coated with a 15 ⁇ m thick layer of glass No 3/MgO/NaO glassy connection layer (10 wt% MgO, d ⁇ 1.3 ⁇ m; 1 wt% Na 2 O, (d ⁇ 2 ⁇ m) by screen printing (b), cf. Fig. 2B. Glass No 3 was prepared and combined with 79 wt% metal powder (SS316) for the composite seal part (a).
- SS316 79 wt% metal powder
- a Crofer 22 APU (c) was coated with metallic cobalt (d), cf. Fig. 2B, preheated at
- 1/MgO glassy connection layer (20 wt% MgO) by screen printing (b). Glass No 1 was prepared and combined with 55 wt% coarse MgO for the composite seal part (a). Metal and composite seal were- heated to 400 0 C in air and then held together by 400 kPa during heating to 950° for 4 h and cooling to 750° in an argon/hydrogen mixture, where the connection was aged for 500 h before being thermally cycled twice to room temperature.
- a Sandvik 0YC44 (c) was coated with Mn-metal and preheated (d) at 85O 0 C for 0.5 h in argon (pO 2 ⁇ 10 "20 atm.) to alloy the coating into the surface and after cooling to room temperature coated with a 45 ⁇ m thick layer of glass No 1/MgO glassy connection layer (2 wt% MgO) by screen printing, (b) in Fig. 2 B. Glass No 1 was prepared and combined with 55 wt% coarse MgO for the composite seal part (a). Metal and composite seal were heated to 400°C in air and then held together by 400 kPa during heating to 750° for 4 h before cooling to 550°C, where the connection was aged for 500 h before being thermall cycled twice to room temperature.
- Example 6 A Crofer 22 APU (c) was coated with a 5 ⁇ m thick layer of cobalt oxide (e) and then coated with a 15 ⁇ m thick layer of glass No 1/MgO glassy connection layer (5 wt% MgO) by screen-printing (b), cf. Fig. 2C. Glass No 1 was prepared and combined with 55 wt% coarse MgO for the composite seal part (a). Metal and composite seal were heated to 400 0 C in air and then held together by 400 kPa during heating Io 950° for 4 h before cooling to 75O 0 C, where the connection was aged for 500 h before being thermally cycled twice to room temperature.
- Example 7 A Crofer 22 APU (c) was coated with a 5 ⁇ m thick layer of cobalt oxide (e) and then coated with a 15 ⁇ m thick layer of glass No 1/MgO glassy connection layer (5 wt% MgO) by screen-printing (b), cf. Fig. 2C. Glass No
- a Sandvik 0YC44 (c) was coated with Mn-metal, (d) in Fig. 2D and preheated at 850 0 C for 0.5 h in argon (p ⁇ 2 ⁇ 10 "20 atm.) to ally the coating into the surface.
- the metal was then slurry coated with a 10 ⁇ m thick cobalt oxide (e).
- Example 8 A Sandvik 0YC44 (c) was coated with nominally 0.1 ⁇ m metallic nickel, (d) In Fig. 2B and by screen-printing coated with a 45 m thick layer of glass No 3/MgO/Na 2 O (10 wt% MgO, 2 wt% Na 2 O) glassy connection layer (b). Glass No
- Example 9 A Sandvik 0YC44 (c) was spray-coated with nominally 10 ⁇ m layer of nickel oxide (d 25 ⁇ 1.5 ⁇ m) (e) dispersed in a binder system, dried and coated with a 45 ⁇ m thick layer of glass No 3/MgO/NaO glassy connection layer (3 wt% MgO;
- a glass No 1 , cf. table 2 was prepared and combined with 55 wt% coarse MgO (a) in 5 Fig. 2E-1.
- the powders were mixed with an organic vehicle (paraffin dissolved in EtOH) and composite seal parts made by uniaxial pressing.
- Magnesium manganese spinel (MgMn 2 O 4 ) powder (d 5 o 2 ⁇ m) was dispersed and mixed with an organic vehicle.
- the composite seal parts were subsequently coated with the spinel-slurry by dip-coating (e).
- Crofer 22APU (c) and the coated seal pan were held together by approximately 10 kPa and heated to 900 0 C where the load was increased to 40 kPa while keeping the temperature. After 2 h the temperature was reduced to 750 0 C, where the connection was aged for 500 h before being thermally cycled twice to room temperature.
- a Crofer 22 APU (c) was coated with metallic cobalt (25 ⁇ m/cm 2 ) (d) and preheated at 900 0 C for 2h in argon (pO 2 ⁇ 10 "20 atm.) to alloy the coating into the surface. After cooling to room temperature, the metal and the coated seal part were held together by approximately 10 kPa and heated to 900 0 C, where the load was increased to 40 kPa while keeping the temperature. After 2 h the temperature was reduced to 750 0 C, where the connection was aged for 500 h before being thermally cycled twice to room temperature.
- Example 12 A Sandvik 0YC44 (e) was coated with nominally 0.1 ⁇ m metallic nickel, (d) in fig. 3B and by screen-printing coated with a 5 ⁇ m thick layer of cobalt oxide (e).
- Crofer 22APU (g) was coated with a 15 my thick layer of glass No 3/MgO/Co 3 O 4 glassy connection layer by screen-printing (b).
- a Crofer 22APU (c) in Fig. 2A was coated with a 15 ⁇ m thick layer of glass No
- connection layer (5wt% Co 3 O 4 , d ⁇ 1.5 ⁇ m) by screen-printing (b).
- Glass No 2 was prepared and combined with 79 wt% metal powder (0YC44) for the compos-ite seal part (a).
- Metal and composite seal were held together by 200 kPa during heating to 700°C for 4 h before cooling to 55O 0 C, where the connection was aged for 500 h before being thermally cycled twice to room temperature.
- a Sandvik 0YC44 (c) was coated with Mn-metal, (d) m Fig. 2D and preheated at 85O 0 C for 0.5 h in argon/hydrogen (pO 2 ⁇ 10 '20 atm.) to alloy the coating into the surface.
- the metal was then slurry coated with a 10 ⁇ m thick cobalt oxide layer (e), preheated in air to 800 0 C for 0.5 h to alloy and oxidize the coating, and after cooling to room temperature coated with 45 m thick layer of glass No 2/MgO (2 wt% MgO) glassy connection layer by screen printing (b).
- Glass No 2 was prepared and combined with 55 wt% coarse MgO for the composite seal part (a).
- Metal and composite seal were held together by 100 kPa during heating to 700 0 C for 4 h before cooling to 550 0 C, where the connection was aged for 500 h before being thermally cycled twice to room temperature.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Electrochemistry (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Structural Engineering (AREA)
- Sustainable Energy (AREA)
- Inorganic Chemistry (AREA)
- Glass Compositions (AREA)
- Fuel Cell (AREA)
- Joining Of Glass To Other Materials (AREA)
- Gasket Seals (AREA)
- Ceramic Products (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP05822618.4A EP1844512B1 (en) | 2004-12-28 | 2005-12-23 | Method of producing metal to glass, metal to metal or metal to ceramic connections |
CA2594168A CA2594168C (en) | 2004-12-28 | 2005-12-23 | Method of producing metal to glass, metal to metal or metal to ceramic connections |
AU2005321530A AU2005321530B2 (en) | 2004-12-28 | 2005-12-23 | Method of producing metal to glass, metal to metal or metal to ceramic connections |
JP2007548740A JP5639737B2 (en) | 2004-12-28 | 2005-12-23 | A method of producing a metal-to-metal, metal-to-metal or ceramic-to-ceramic connection. |
KR1020077017245A KR100886882B1 (en) | 2004-12-28 | 2005-12-23 | Method of producing metal to glass, metal to metal or metal to ceramic connections |
US11/813,074 US8002166B2 (en) | 2004-12-28 | 2005-12-23 | Method of producing metal to glass, metal to metal or metal to ceramic connections |
NO20073274A NO20073274L (en) | 2004-12-28 | 2007-06-27 | Process for making metal-to-glass, metal-to-metal or ceramic-metal connections |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DKPA200402011 | 2004-12-28 | ||
DKPA200402011 | 2004-12-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006069753A1 true WO2006069753A1 (en) | 2006-07-06 |
Family
ID=36062513
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2005/013968 WO2006069753A1 (en) | 2004-12-28 | 2005-12-23 | Method of producing metal to glass, metal to metal or metal to ceramic connections |
Country Status (10)
Country | Link |
---|---|
US (1) | US8002166B2 (en) |
EP (1) | EP1844512B1 (en) |
JP (2) | JP5639737B2 (en) |
KR (1) | KR100886882B1 (en) |
CN (1) | CN100568598C (en) |
AU (1) | AU2005321530B2 (en) |
CA (1) | CA2594168C (en) |
NO (1) | NO20073274L (en) |
RU (1) | RU2366040C2 (en) |
WO (1) | WO2006069753A1 (en) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU2005321530B2 (en) * | 2004-12-28 | 2009-01-08 | Technical University Of Denmark | Method of producing metal to glass, metal to metal or metal to ceramic connections |
EP2104172A1 (en) * | 2008-03-20 | 2009-09-23 | The Technical University of Denmark | A composite glass seal for a solid oxide electrolyser cell stack |
US7601183B2 (en) | 2005-02-02 | 2009-10-13 | Technical University Of Denmark | Method for producing a reversible solid oxide fuel cell |
JP2009252747A (en) * | 2008-04-07 | 2009-10-29 | Topsoee Fuel Cell As | Fuel cell stack |
US7745031B2 (en) | 2004-06-10 | 2010-06-29 | Technical University Of Denmark | Solid oxide fuel cell |
WO2011000847A1 (en) | 2009-07-03 | 2011-01-06 | Commissariat à l'énergie atomique et aux énergies alternatives | Glass compositions for joints of devices operating at high temperatures, and assembly method using same |
WO2011121095A2 (en) | 2010-04-01 | 2011-10-06 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Glass-ceramic compositions for joints of appliances operating at high temperatures, and assembly method using said compositions |
CN101514277B (en) * | 2009-04-01 | 2011-11-30 | 北京化工大学 | High temperature resistance adhesive with low-expansion coefficients |
CN104276838A (en) * | 2013-07-12 | 2015-01-14 | 中国科学院上海硅酸盐研究所 | Double vitrifying sealing method of ceramic and metal |
US9263758B2 (en) | 2005-08-31 | 2016-02-16 | Technical University Of Denmark | Reversible solid oxide fuel cell stack and method for preparing same |
CN107342377A (en) * | 2017-07-20 | 2017-11-10 | 东莞威胜储能技术有限公司 | A kind of high temperature battery |
Families Citing this family (46)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8039175B2 (en) * | 2005-01-12 | 2011-10-18 | Technical University Of Denmark | Method for shrinkage and porosity control during sintering of multilayer structures |
RU2354013C1 (en) * | 2005-01-31 | 2009-04-27 | Текникал Юниверсити Оф Денмарк | Anode resistant to oxidation-reduction |
DK1930974T3 (en) * | 2006-11-23 | 2012-07-09 | Univ Denmark Tech Dtu | Process for the preparation of reversible solid oxide cells |
US8197979B2 (en) * | 2006-12-12 | 2012-06-12 | Corning Incorporated | Thermo-mechanical robust seal structure for solid oxide fuel cells |
KR100901087B1 (en) * | 2008-08-11 | 2009-06-08 | 소우섭 | Glass structure attached fine powder and method of manufacturing the same |
US8858745B2 (en) * | 2008-11-12 | 2014-10-14 | Applied Materials, Inc. | Corrosion-resistant bonding agents for bonding ceramic components which are exposed to plasmas |
DK2228858T3 (en) * | 2009-03-13 | 2013-07-29 | Topsoee Fuel Cell As | fuel cell stack |
RU2561097C2 (en) * | 2009-10-06 | 2015-08-20 | Топсеэ Фюэль Селл А/С | Glass sealant for batteries of solid oxide electrolysis cells (soec) |
US9267184B2 (en) | 2010-02-05 | 2016-02-23 | Ati Properties, Inc. | Systems and methods for processing alloy ingots |
US10207312B2 (en) | 2010-06-14 | 2019-02-19 | Ati Properties Llc | Lubrication processes for enhanced forgeability |
US8789254B2 (en) * | 2011-01-17 | 2014-07-29 | Ati Properties, Inc. | Modifying hot workability of metal alloys via surface coating |
CN103128181A (en) * | 2011-11-23 | 2013-06-05 | 苏州工业园区协诚精密五金有限公司 | Fixing structure of thin metal plate connection joint column |
TWI463710B (en) * | 2012-10-05 | 2014-12-01 | Subtron Technology Co Ltd | Mrthod for bonding heat-conducting substraye and metal layer |
JP2016505501A (en) | 2012-12-19 | 2016-02-25 | プラクスエア・テクノロジー・インコーポレイテッド | Method for sealing an oxygen transport membrane assembly |
US9212113B2 (en) | 2013-04-26 | 2015-12-15 | Praxair Technology, Inc. | Method and system for producing a synthesis gas using an oxygen transport membrane based reforming system with secondary reforming and auxiliary heat source |
US9296671B2 (en) | 2013-04-26 | 2016-03-29 | Praxair Technology, Inc. | Method and system for producing methanol using an integrated oxygen transport membrane based reforming system |
US9938145B2 (en) | 2013-04-26 | 2018-04-10 | Praxair Technology, Inc. | Method and system for adjusting synthesis gas module in an oxygen transport membrane based reforming system |
CN104276839B (en) * | 2013-07-12 | 2016-05-18 | 中国科学院上海硅酸盐研究所 | The method for sealing of glass-ceramic |
CN104347438A (en) * | 2013-08-06 | 2015-02-11 | 鸿富锦精密工业(深圳)有限公司 | Method for combining glass base plate with metal base plate |
US9452401B2 (en) | 2013-10-07 | 2016-09-27 | Praxair Technology, Inc. | Ceramic oxygen transport membrane array reactor and reforming method |
WO2015160609A1 (en) | 2014-04-16 | 2015-10-22 | Praxair Technology, Inc. | Method and system for oxygen transport membrane enhanced integrated gasifier combined cycle (igcc) |
US10087101B2 (en) | 2015-03-27 | 2018-10-02 | Goodrich Corporation | Formulations for oxidation protection of composite articles |
US10441922B2 (en) | 2015-06-29 | 2019-10-15 | Praxair Technology, Inc. | Dual function composite oxygen transport membrane |
DE102015220395A1 (en) | 2015-10-20 | 2017-04-20 | Bayerische Motoren Werke Aktiengesellschaft | soot sensor |
US10118823B2 (en) | 2015-12-15 | 2018-11-06 | Praxair Technology, Inc. | Method of thermally-stabilizing an oxygen transport membrane-based reforming system |
WO2017112677A1 (en) * | 2015-12-21 | 2017-06-29 | Praxair Technology, Inc. | Apparatus including a ceramic component, a metal component, and a glass sealing material and a process of forming the apparatus |
US9938146B2 (en) | 2015-12-28 | 2018-04-10 | Praxair Technology, Inc. | High aspect ratio catalytic reactor and catalyst inserts therefor |
KR102154420B1 (en) | 2016-04-01 | 2020-09-10 | 프랙스에어 테크놀로지, 인코포레이티드 | Catalyst-containing oxygen transport membrane |
JP6605721B2 (en) * | 2016-05-06 | 2019-11-13 | 住友精密工業株式会社 | Fuel cell manufacturing method and fuel cell |
US10377675B2 (en) | 2016-05-31 | 2019-08-13 | Goodrich Corporation | High temperature oxidation protection for composites |
US10465285B2 (en) * | 2016-05-31 | 2019-11-05 | Goodrich Corporation | High temperature oxidation protection for composites |
US10508206B2 (en) | 2016-06-27 | 2019-12-17 | Goodrich Corporation | High temperature oxidation protection for composites |
DE102016214742A1 (en) * | 2016-08-09 | 2018-02-15 | Siemens Aktiengesellschaft | Method for joining materials and composite material |
US10767059B2 (en) | 2016-08-11 | 2020-09-08 | Goodrich Corporation | High temperature oxidation protection for composites |
US10010876B2 (en) | 2016-11-23 | 2018-07-03 | Praxair Technology, Inc. | Catalyst for high temperature steam reforming |
US10526253B2 (en) | 2016-12-15 | 2020-01-07 | Goodrich Corporation | High temperature oxidation protection for composites |
JP2018129245A (en) * | 2017-02-10 | 2018-08-16 | Toto株式会社 | Fuel cell unit and fuel cell stack |
CN107010849B (en) * | 2017-05-10 | 2020-06-16 | 北京工业大学 | Laser welding process method for molybdenum group glass and kovar alloy |
CN107470081A (en) * | 2017-08-07 | 2017-12-15 | 苏州雾联医疗科技有限公司 | A kind of atomizing piece metal mesh sheet |
DE102017216422B3 (en) * | 2017-09-15 | 2019-01-03 | Schott Ag | High-expansion bonded glass with improved water resistance and its applications |
EP3797085A1 (en) | 2018-05-21 | 2021-03-31 | Praxair Technology, Inc. | Otm syngas panel with gas heated reformer |
US11046619B2 (en) | 2018-08-13 | 2021-06-29 | Goodrich Corporation | High temperature oxidation protection for composites |
CN110972418B (en) * | 2018-09-30 | 2022-01-07 | 比亚迪股份有限公司 | Electronic device case, electronic device, and composite body |
US11634213B2 (en) | 2018-11-14 | 2023-04-25 | Goodrich Corporation | High temperature oxidation protection for composites |
JP6684341B1 (en) * | 2018-12-27 | 2020-04-22 | 日本碍子株式会社 | Zygote |
CN112845906B (en) * | 2021-02-02 | 2023-04-18 | 四川中雅科技有限公司 | Formed foil connecting method |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0446680A1 (en) * | 1990-03-15 | 1991-09-18 | Asea Brown Boveri Ag | Current collector for conducting current between neighbouring piled high temperature fuel cells |
DE19650704A1 (en) * | 1996-12-06 | 1998-06-10 | Forschungszentrum Juelich Gmbh | Material for fuel cell interconnectors |
DE19710345C1 (en) * | 1997-03-13 | 1999-01-21 | Forschungszentrum Juelich Gmbh | Material for electrical contact layers between an electrode of a high-temperature fuel cell and a connecting element |
US20030082434A1 (en) * | 2001-10-19 | 2003-05-01 | Conghua Wang | Solid oxide fuel cells and interconnectors |
Family Cites Families (101)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3023492A (en) * | 1958-11-19 | 1962-03-06 | Gen Electric | Metalized ceramic member and composition and method for manufacturing same |
DE2019732A1 (en) | 1969-04-21 | 1970-11-26 | Minnesota Mining & Mfg | Metal powder filter |
US4209147A (en) * | 1972-08-10 | 1980-06-24 | Jones Allen Jr | Steering and stabilization apparatus for aerial missile |
US4472223A (en) * | 1982-10-06 | 1984-09-18 | Emerson Electric Co. | Method of forming glass seal |
US4702971A (en) * | 1986-05-28 | 1987-10-27 | Westinghouse Electric Corp. | Sulfur tolerant composite cermet electrodes for solid oxide electrochemical cells |
US5058799A (en) * | 1986-07-24 | 1991-10-22 | Zsamboky Kalman F | Metallized ceramic substrate and method therefor |
US4957673A (en) * | 1988-02-01 | 1990-09-18 | California Institute Of Technology | Multilayer ceramic oxide solid electrolyte for fuel cells and electrolysis cells and method for fabrication thereof |
JPH0219406A (en) | 1988-07-05 | 1990-01-23 | Nippon Steel Corp | Manufacture of iron porous body |
JPH0616897Y2 (en) * | 1988-07-19 | 1994-05-02 | 日本電気株式会社 | Glass sealed |
US5021304A (en) * | 1989-03-22 | 1991-06-04 | Westinghouse Electric Corp. | Modified cermet fuel electrodes for solid oxide electrochemical cells |
EP0424732A1 (en) * | 1989-10-27 | 1991-05-02 | Asea Brown Boveri Ag | Current conduction element for stacked hightemperature fuel cells and method of manufacture |
US5162167A (en) * | 1990-09-11 | 1992-11-10 | Allied-Signal Inc. | Apparatus and method of fabricating a monolithic solid oxide fuel cell |
DK167163B1 (en) | 1991-02-13 | 1993-09-06 | Risoe Forskningscenter | FAST OXIDE FUEL CELLS FOR OXIDATION OF CH4 |
JPH05135787A (en) * | 1991-03-28 | 1993-06-01 | Ngk Insulators Ltd | Manufacture of solid electrolyte film and manufacture of solid electrolyte fuel cell |
JP3151933B2 (en) | 1992-05-28 | 2001-04-03 | 株式会社村田製作所 | Solid oxide fuel cell |
DE4237602A1 (en) | 1992-11-06 | 1994-05-11 | Siemens Ag | High temperature fuel cell stack and process for its manufacture |
US5368667A (en) * | 1993-01-29 | 1994-11-29 | Alliedsignal Inc. | Preparation of devices that include a thin ceramic layer |
DK94393D0 (en) * | 1993-08-18 | 1993-08-18 | Risoe Forskningscenter | PROCEDURE FOR THE PREPARATION OF CALCIUM-DOPED LANTHANCHROMITE |
US5592686A (en) * | 1995-07-25 | 1997-01-07 | Third; Christine E. | Porous metal structures and processes for their production |
JP3547062B2 (en) * | 1995-10-26 | 2004-07-28 | 東燃ゼネラル石油株式会社 | Sealing material for fuel cells |
US5670270A (en) * | 1995-11-16 | 1997-09-23 | The Dow Chemical Company | Electrode structure for solid state electrochemical devices |
DE19547700C2 (en) * | 1995-12-20 | 1998-09-17 | Forschungszentrum Juelich Gmbh | Electrode substrate for a fuel cell |
US5702837A (en) * | 1996-02-05 | 1997-12-30 | Alliedsignal Inc. | Bonding materials for anode to anode bonding and anode to interconnect bonding in solid oxide fuel cells |
AUPN876896A0 (en) * | 1996-03-18 | 1996-04-18 | Ceramic Fuel Cells Limited | An electrical interconnect for a planar fuel cell |
JP3599894B2 (en) | 1996-04-03 | 2004-12-08 | 株式会社フジクラ | Fuel electrode of solid oxide fuel cell |
WO1998021769A1 (en) * | 1996-11-11 | 1998-05-22 | Gorina, Liliya Fedorovna | Method for manufacturing a single unit high temperature fuel cell and its components: a cathode, an electrolyte, an anode, a current conductor, and interface and insulating layers |
US6210612B1 (en) * | 1997-03-31 | 2001-04-03 | Pouvair Corporation | Method for the manufacture of porous ceramic articles |
DE19782271T1 (en) | 1997-04-30 | 2000-04-27 | Dow Chemical Co | Electrode structure for solid electrochemical devices |
US6099985A (en) * | 1997-07-03 | 2000-08-08 | Gas Research Institute | SOFC anode for enhanced performance stability and method for manufacturing same |
ATE198519T1 (en) * | 1997-09-11 | 2001-01-15 | Sulzer Hexis Ag | ELECTROCHEMICALLY ACTIVE ELEMENT FOR A SOLID OXIDE FUEL CELL |
US5908713A (en) * | 1997-09-22 | 1999-06-01 | Siemens Westinghouse Power Corporation | Sintered electrode for solid oxide fuel cells |
JP3408732B2 (en) | 1997-11-07 | 2003-05-19 | 三菱重工業株式会社 | Base material for fuel cell |
WO1999056899A1 (en) | 1998-05-04 | 1999-11-11 | Colorado School Of Mines | Porous metal-containing materials, method of manufacture and products incorporating or made from the materials |
DE19836132B4 (en) | 1998-08-10 | 2006-11-23 | Siemens Ag | High temperature solid electrolyte fuel cell (SOFC) for a wide operating temperature range |
US6458170B1 (en) * | 1998-12-03 | 2002-10-01 | The Regents Of The University Of California | Method for making thin, flat, dense membranes on porous substrates |
DK1010675T3 (en) * | 1998-12-15 | 2009-04-14 | Topsoe Fuel Cell As | High temperature sealing material |
US6248468B1 (en) * | 1998-12-31 | 2001-06-19 | Siemens Westinghouse Power Corporation | Fuel electrode containing pre-sintered nickel/zirconia for a solid oxide fuel cell |
US6589680B1 (en) * | 1999-03-03 | 2003-07-08 | The Trustees Of The University Of Pennsylvania | Method for solid oxide fuel cell anode preparation |
JP4207218B2 (en) | 1999-06-29 | 2009-01-14 | 住友電気工業株式会社 | Metal porous body, method for producing the same, and metal composite using the same |
US6605316B1 (en) * | 1999-07-31 | 2003-08-12 | The Regents Of The University Of California | Structures and fabrication techniques for solid state electrochemical devices |
US6682842B1 (en) * | 1999-07-31 | 2004-01-27 | The Regents Of The University Of California | Composite electrode/electrolyte structure |
DK174654B1 (en) * | 2000-02-02 | 2003-08-11 | Topsoe Haldor As | Solid oxide fuel cell and its applications |
US6743395B2 (en) * | 2000-03-22 | 2004-06-01 | Ebara Corporation | Composite metallic ultrafine particles and process for producing the same |
JP2001335388A (en) | 2000-03-22 | 2001-12-04 | Toto Ltd | Ceramic film and solid electrolyte fuel cell |
DE10014403A1 (en) | 2000-03-24 | 2001-09-27 | Wolfgang Kochanek | Process for the powder metallurgy production of metal bodies comprises mixing a metal compound powder such as oxide powder with a rheology-improving additive, removing the additive; and reducing the metal compound using a reducing gas |
CA2308092C (en) * | 2000-05-10 | 2008-10-21 | Partho Sarkar | Production of hollow ceramic membranes by electrophoretic deposition |
DE10025108A1 (en) * | 2000-05-20 | 2001-11-29 | Forschungszentrum Juelich Gmbh | High temperature material |
JP2002015755A (en) * | 2000-06-30 | 2002-01-18 | Honda Motor Co Ltd | Manufacturing method of phosphoric acid fuel cell |
WO2002009116A1 (en) | 2000-07-25 | 2002-01-31 | Bae Systems | High-performance high-density cmos sram cell |
GB2368450B (en) * | 2000-10-25 | 2004-05-19 | Imperial College | Fuel cells |
US8007954B2 (en) * | 2000-11-09 | 2011-08-30 | The Trustees Of The University Of Pennsylvania | Use of sulfur-containing fuels for direct oxidation fuel cells |
JP3674840B2 (en) | 2000-11-28 | 2005-07-27 | 日産自動車株式会社 | Fuel cell stack and method for manufacturing the same |
US6878651B2 (en) * | 2000-12-01 | 2005-04-12 | Ford Global Technologies, Llc | Glass compositions for ceramic electrolyte electrochemical conversion devices |
FR2817860B1 (en) * | 2000-12-07 | 2003-09-12 | Air Liquide | PROCESS FOR THE PREPARATION OF A LOW THICKNESS CERAMIC MATERIAL WITH CONTROLLED SURFACE POROSITY GRADIENT, CERAMIC MATERIAL OBTAINED, ELECTROCHEMICAL CELL AND CERAMIC MEMBRANE COMPRISING THE SAME |
US6863209B2 (en) * | 2000-12-15 | 2005-03-08 | Unitivie International Limited | Low temperature methods of bonding components |
US20020127455A1 (en) * | 2001-03-08 | 2002-09-12 | The Regents Of The University Of California | Ceria-based solid oxide fuel cells |
US7709124B2 (en) * | 2001-04-10 | 2010-05-04 | Northwestern University | Direct hydrocarbon fuel cells |
JP3841149B2 (en) | 2001-05-01 | 2006-11-01 | 日産自動車株式会社 | Single cell for solid oxide fuel cell |
AT4810U1 (en) * | 2001-05-31 | 2001-11-26 | Plansee Ag | CURRENT COLLECTOR FOR SOFC FUEL CELLS |
FR2826956B1 (en) * | 2001-07-04 | 2004-05-28 | Air Liquide | PROCESS FOR PREPARING A LOW THICKNESS CERAMIC COMPOSITION WITH TWO MATERIALS, COMPOSITION OBTAINED, ELECTROCHEMICAL CELL AND MEMBRANE COMPRISING IT |
US6772501B2 (en) * | 2001-07-23 | 2004-08-10 | Itn Energy Systems, Inc. | Apparatus and method for the design and manufacture of thin-film electrochemical devices |
CN1649802B (en) * | 2001-08-02 | 2012-02-01 | 3M创新有限公司 | Ceramic materials, abrasive particles, abrasive articles, and methods of making and using the same |
CN1409427A (en) | 2001-09-18 | 2003-04-09 | 中国科学技术大学 | PEN multilayer film of middle temperature solid oxide fuel cell and its producing method |
JP2003132906A (en) | 2001-10-24 | 2003-05-09 | Nissan Motor Co Ltd | Single cell for fuel cell and solid electrolytic fuel cell |
DE10161538B4 (en) | 2001-12-10 | 2004-09-09 | Deutsches Zentrum für Luft- und Raumfahrt e.V. | Carrier for an electrochemical functional unit of a high-temperature fuel cell and high-temperature fuel cell |
US6824907B2 (en) | 2002-01-16 | 2004-11-30 | Alberta Reasearch Council, Inc. | Tubular solid oxide fuel cell stack |
US6893762B2 (en) * | 2002-01-16 | 2005-05-17 | Alberta Research Council, Inc. | Metal-supported tubular micro-fuel cell |
US8114551B2 (en) * | 2002-03-04 | 2012-02-14 | Sulzer Hexis Ag | Porous structured body for a fuel cell anode |
GB2386126B (en) | 2002-03-06 | 2006-03-08 | Ceres Power Ltd | Forming an impermeable sintered ceramic electrolyte layer on a metallic foil substrate for solid oxide fuel cell |
JP3922063B2 (en) | 2002-03-25 | 2007-05-30 | 住友電気工業株式会社 | Porous metal and solid polymer fuel cell using the same |
EP1353394B1 (en) * | 2002-03-27 | 2005-06-29 | Haldor Topsoe A/S | Thin film solid oxide fuel cell (SOFC) and its method of production |
AU2003256251A1 (en) * | 2002-04-24 | 2003-11-10 | The Regents Of The University Of California | Planar electrochemical device assembly |
CA2429899A1 (en) * | 2002-05-29 | 2003-11-29 | Sanyo Electric Co., Ltd. | Solid oxide fuel cell |
JP2005529464A (en) | 2002-06-06 | 2005-09-29 | ザ・トラスティーズ・オブ・ザ・ユニバーシティ・オブ・ペンシルバニア | Ceramic anode and method for producing the same |
US6843960B2 (en) * | 2002-06-12 | 2005-01-18 | The University Of Chicago | Compositionally graded metallic plates for planar solid oxide fuel cells |
US20030232230A1 (en) * | 2002-06-12 | 2003-12-18 | Carter John David | Solid oxide fuel cell with enhanced mechanical and electrical properties |
US20030235752A1 (en) * | 2002-06-24 | 2003-12-25 | England Diane M. | Oxygen getters for anode protection in a solid-oxide fuel cell stack |
JP3976181B2 (en) | 2002-07-19 | 2007-09-12 | 東邦瓦斯株式会社 | Solid oxide fuel cell single cell and solid oxide fuel cell using the same |
CA2440288A1 (en) | 2002-09-10 | 2004-03-10 | Alberta Research Council Inc. | Crack-resistant anode-supported fuel cell |
US6843406B2 (en) * | 2002-09-27 | 2005-01-18 | Battelle Memorial Institute | Gas-tight metal/ceramic or metal/metal seals for applications in high temperature electrochemical devices and method of making |
JP4009179B2 (en) | 2002-10-30 | 2007-11-14 | 京セラ株式会社 | Fuel cell and fuel cell |
US6921582B2 (en) * | 2002-12-23 | 2005-07-26 | General Electric Company | Oxidation-resistant coatings bonded to metal substrates, and related articles and processes |
DE10302122A1 (en) * | 2003-01-21 | 2004-07-29 | Elringklinger Ag | Multi cell fuel stack has sealing between cells provided by layer of insulation and layer of sealing material |
JP4438295B2 (en) * | 2003-01-21 | 2010-03-24 | 三菱マテリアル株式会社 | Fuel cell |
US6958196B2 (en) * | 2003-02-21 | 2005-10-25 | Trustees Of The University Of Pennsylvania | Porous electrode, solid oxide fuel cell, and method of producing the same |
GB2422479B (en) | 2003-04-15 | 2006-12-13 | Ceres Power Ltd | Solid oxide fuel cell with a novel substrate and a method for fabricating the same |
JP4027836B2 (en) | 2003-04-16 | 2007-12-26 | 東京瓦斯株式会社 | Method for producing solid oxide fuel cell |
BRPI0414240A (en) * | 2003-09-10 | 2006-10-31 | Btu Int | methods for manufacturing a solid oxide fuel cell and a solid oxide fuel cell stack, and a solid oxide fuel cell |
UA83400C2 (en) * | 2003-12-02 | 2008-07-10 | Нанодайнемікс, Інк. | Solid oxide fuel cells (sofc) with cermet electrolite and method for their manufacturing |
JP4696470B2 (en) * | 2004-05-13 | 2011-06-08 | 三菱マテリアル株式会社 | Fuel cell |
WO2005122300A2 (en) * | 2004-06-10 | 2005-12-22 | Risoe National Laboratory | Solid oxide fuel cell |
US20060024547A1 (en) * | 2004-07-27 | 2006-02-02 | David Waldbillig | Anode supported sofc with an electrode multifunctional layer |
EP1844512B1 (en) * | 2004-12-28 | 2017-04-19 | Technical University of Denmark | Method of producing metal to glass, metal to metal or metal to ceramic connections |
US8168347B2 (en) * | 2004-12-30 | 2012-05-01 | Delphi Technologies Inc. | SOFC assembly joint spacing |
US8039175B2 (en) * | 2005-01-12 | 2011-10-18 | Technical University Of Denmark | Method for shrinkage and porosity control during sintering of multilayer structures |
RU2354013C1 (en) * | 2005-01-31 | 2009-04-27 | Текникал Юниверсити Оф Денмарк | Anode resistant to oxidation-reduction |
ES2342489T3 (en) * | 2005-02-02 | 2010-07-07 | Univ Denmark Tech Dtu | PROCEDURE TO PRODUCE A REVERSIBLE SOLID OXIDE FUEL BATTERY. |
US8021795B2 (en) * | 2005-04-07 | 2011-09-20 | General Electric Company | Method for manufacturing solid oxide electrochemical devices |
US8173010B2 (en) * | 2005-05-19 | 2012-05-08 | Massachusetts Institute Of Technology | Method of dry reforming a reactant gas with intermetallic catalyst |
DK1930974T3 (en) * | 2006-11-23 | 2012-07-09 | Univ Denmark Tech Dtu | Process for the preparation of reversible solid oxide cells |
CN100512500C (en) | 2006-11-27 | 2009-07-08 | 华为技术有限公司 | Method for all processing, service control device, and call processing system |
-
2005
- 2005-12-23 EP EP05822618.4A patent/EP1844512B1/en not_active Not-in-force
- 2005-12-23 CN CNB2005800453301A patent/CN100568598C/en not_active Expired - Fee Related
- 2005-12-23 KR KR1020077017245A patent/KR100886882B1/en not_active IP Right Cessation
- 2005-12-23 US US11/813,074 patent/US8002166B2/en not_active Expired - Fee Related
- 2005-12-23 RU RU2007124072/09A patent/RU2366040C2/en not_active IP Right Cessation
- 2005-12-23 WO PCT/EP2005/013968 patent/WO2006069753A1/en active Application Filing
- 2005-12-23 CA CA2594168A patent/CA2594168C/en not_active Expired - Fee Related
- 2005-12-23 AU AU2005321530A patent/AU2005321530B2/en not_active Ceased
- 2005-12-23 JP JP2007548740A patent/JP5639737B2/en not_active Expired - Fee Related
-
2007
- 2007-06-27 NO NO20073274A patent/NO20073274L/en not_active Application Discontinuation
-
2013
- 2013-07-25 JP JP2013154501A patent/JP2013224262A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0446680A1 (en) * | 1990-03-15 | 1991-09-18 | Asea Brown Boveri Ag | Current collector for conducting current between neighbouring piled high temperature fuel cells |
DE19650704A1 (en) * | 1996-12-06 | 1998-06-10 | Forschungszentrum Juelich Gmbh | Material for fuel cell interconnectors |
DE19710345C1 (en) * | 1997-03-13 | 1999-01-21 | Forschungszentrum Juelich Gmbh | Material for electrical contact layers between an electrode of a high-temperature fuel cell and a connecting element |
US20030082434A1 (en) * | 2001-10-19 | 2003-05-01 | Conghua Wang | Solid oxide fuel cells and interconnectors |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7745031B2 (en) | 2004-06-10 | 2010-06-29 | Technical University Of Denmark | Solid oxide fuel cell |
AU2005321530B2 (en) * | 2004-12-28 | 2009-01-08 | Technical University Of Denmark | Method of producing metal to glass, metal to metal or metal to ceramic connections |
US7601183B2 (en) | 2005-02-02 | 2009-10-13 | Technical University Of Denmark | Method for producing a reversible solid oxide fuel cell |
US9263758B2 (en) | 2005-08-31 | 2016-02-16 | Technical University Of Denmark | Reversible solid oxide fuel cell stack and method for preparing same |
KR101173121B1 (en) | 2008-03-20 | 2012-08-14 | 테크니칼 유니버시티 오브 덴마크 | A composite glass seal for a solid oxide electrolyser cell stack |
EP2104172A1 (en) * | 2008-03-20 | 2009-09-23 | The Technical University of Denmark | A composite glass seal for a solid oxide electrolyser cell stack |
WO2009115341A1 (en) | 2008-03-20 | 2009-09-24 | Technical University Of Denmark | A composite glass seal for a solid oxide electrolyser cell stack |
US8828196B2 (en) | 2008-03-20 | 2014-09-09 | Technical University Of Denmark | Composite glass seal for a solid oxide electrolyser cell stack |
JP2009252747A (en) * | 2008-04-07 | 2009-10-29 | Topsoee Fuel Cell As | Fuel cell stack |
CN101514277B (en) * | 2009-04-01 | 2011-11-30 | 北京化工大学 | High temperature resistance adhesive with low-expansion coefficients |
WO2011000847A1 (en) | 2009-07-03 | 2011-01-06 | Commissariat à l'énergie atomique et aux énergies alternatives | Glass compositions for joints of devices operating at high temperatures, and assembly method using same |
US9309144B2 (en) | 2009-07-03 | 2016-04-12 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Glass compositions for gaskets of apparatuses operating at high temperatures and assembling method using them |
WO2011121095A2 (en) | 2010-04-01 | 2011-10-06 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Glass-ceramic compositions for joints of appliances operating at high temperatures, and assembly method using said compositions |
US9522842B2 (en) | 2010-04-01 | 2016-12-20 | Commissariat a l'énergie atomique et aux énergies alternatives | Vitroceramic glass compositions for gaskets of apparatuses operating at high temperatures and assembling method using said compositions |
CN104276838A (en) * | 2013-07-12 | 2015-01-14 | 中国科学院上海硅酸盐研究所 | Double vitrifying sealing method of ceramic and metal |
CN104276838B (en) * | 2013-07-12 | 2016-01-06 | 中国科学院上海硅酸盐研究所 | Pottery vitrified method for sealing two with metal |
CN107342377A (en) * | 2017-07-20 | 2017-11-10 | 东莞威胜储能技术有限公司 | A kind of high temperature battery |
Also Published As
Publication number | Publication date |
---|---|
EP1844512A1 (en) | 2007-10-17 |
RU2007124072A (en) | 2009-02-10 |
CA2594168A1 (en) | 2006-07-06 |
CN100568598C (en) | 2009-12-09 |
CN101103478A (en) | 2008-01-09 |
NO20073274L (en) | 2007-09-25 |
JP2013224262A (en) | 2013-10-31 |
EP1844512B1 (en) | 2017-04-19 |
RU2366040C2 (en) | 2009-08-27 |
US20080142148A1 (en) | 2008-06-19 |
AU2005321530A1 (en) | 2006-07-06 |
JP5639737B2 (en) | 2014-12-10 |
KR20070100955A (en) | 2007-10-15 |
JP2008525304A (en) | 2008-07-17 |
CA2594168C (en) | 2011-02-22 |
AU2005321530B2 (en) | 2009-01-08 |
US8002166B2 (en) | 2011-08-23 |
KR100886882B1 (en) | 2009-03-05 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
AU2005321530B2 (en) | Method of producing metal to glass, metal to metal or metal to ceramic connections | |
Goel et al. | Stable glass-ceramic sealants for solid oxide fuel cells: influence of Bi2O3 doping | |
Da Silva et al. | Glass ceramic sealants belonging to BAS (BaO–Al2O3–SiO2) ternary system modified with B2O3 addition: A different approach to access the SOFC seal issue | |
EP2519990B1 (en) | Thin, fine grained and fully dense glass-ceramic seal for sofc stack | |
Sabato et al. | Glass-ceramic sealant for solid oxide fuel cells application: Characterization and performance in dual atmosphere | |
Reddy et al. | Study of calcium–magnesium–aluminum–silicate (CMAS) glass and glass-ceramic sealant for solid oxide fuel cells | |
Reddy et al. | Diopside–Ba disilicate glass–ceramic sealants for SOFCs: Enhanced adhesion and thermal stability by Sr for Ca substitution | |
KR20130019408A (en) | Glass-ceramic compositions for joints of appliances operating at high temperatures, and assembly method using said compositions | |
Goel et al. | Development and performance of diopside based glass-ceramic sealants for solid oxide fuel cells | |
Sabato et al. | Interface stability between bare, MnCo spinel coated AISI 441 stainless steel and a diopside-based glass-ceramic sealant | |
Reddy et al. | Study of melilite based glasses and glass-ceramics nucleated by Bi 2 O 3 for functional applications | |
Wang et al. | Characteristics of glass sealants for intermediate-temperature solid oxide fuel cell applications | |
Kaur et al. | Mechanical and thermal properties of SrO/BaO modified Y2O3-Al2O3-B2O3-SiO2 glasses and their compatibility with solid oxide fuel cell components | |
Saetova et al. | Alumina–silica glass–ceramic sealants for tubular solid oxide fuel cells | |
Sun et al. | Crystallization behavior and thermal properties of B2O3–containing MgO-Al2O3-SiO2-Li2O glass-ceramic and its wettability on Si3N4 ceramic | |
EP0975554A1 (en) | Glass ceramic material and its use as means for joining different types of material and as support | |
Kaur et al. | Microstructural study of Crofer 22 APU-glass interface for SOFC application | |
D'Isanto et al. | Glass-ceramic joining of Fe22Cr porous alloy to Crofer22APU: interfacial issues and mechanical properties | |
Ghosh et al. | Glass-based sealants for application in planar solid oxide fuel cell stack | |
Goedeke et al. | New glass ceramic sealants for SOFC | |
De La Pierre et al. | Torsional behaviour of a glass-ceramic joined alumina coated Crofer 22 APU steel | |
Gross et al. | Glass-ceramic composite as a new sealing material for SOFCs | |
CN117510073B (en) | Glass lining ground coat based on composite adhesive and preparation method thereof | |
US9160010B2 (en) | Self-healing vitreous composition, method for preparing same, and uses thereof | |
CN115304380A (en) | Silicon carbide roller rod for roller kiln transmission and preparation method and application thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
DPE2 | Request for preliminary examination filed before expiration of 19th month from priority date (pct application filed from 20040101) | ||
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 2005321530 Country of ref document: AU |
|
REEP | Request for entry into the european phase |
Ref document number: 2005822618 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2005822618 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2007548740 Country of ref document: JP Ref document number: 2594168 Country of ref document: CA |
|
WWE | Wipo information: entry into national phase |
Ref document number: 200580045330.1 Country of ref document: CN |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
ENP | Entry into the national phase |
Ref document number: 2005321530 Country of ref document: AU Date of ref document: 20051223 Kind code of ref document: A |
|
WWP | Wipo information: published in national office |
Ref document number: 2005321530 Country of ref document: AU |
|
WWE | Wipo information: entry into national phase |
Ref document number: 1020077017245 Country of ref document: KR |
|
WWE | Wipo information: entry into national phase |
Ref document number: 5895/DELNP/2007 Country of ref document: IN |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2007124072 Country of ref document: RU |
|
WWE | Wipo information: entry into national phase |
Ref document number: 11813074 Country of ref document: US |
|
WWP | Wipo information: published in national office |
Ref document number: 2005822618 Country of ref document: EP |