WO2006031259A8 - Mesostructured zeolitic materials, and methods of making and using the same - Google Patents

Mesostructured zeolitic materials, and methods of making and using the same Download PDF

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Publication number
WO2006031259A8
WO2006031259A8 PCT/US2005/014256 US2005014256W WO2006031259A8 WO 2006031259 A8 WO2006031259 A8 WO 2006031259A8 US 2005014256 W US2005014256 W US 2005014256W WO 2006031259 A8 WO2006031259 A8 WO 2006031259A8
Authority
WO
WIPO (PCT)
Prior art keywords
making
methods
same
zeolitic materials
mesostructured zeolitic
Prior art date
Application number
PCT/US2005/014256
Other languages
French (fr)
Other versions
WO2006031259A2 (en
Inventor
Javier Garcia-Martinez
Original Assignee
Javier Garcia-Martinez
Massachusetts Inst Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US10/830,714 external-priority patent/US7589041B2/en
Application filed by Javier Garcia-Martinez, Massachusetts Inst Technology filed Critical Javier Garcia-Martinez
Priority to EP05812517A priority Critical patent/EP1742873A2/en
Priority to AU2005285508A priority patent/AU2005285508A1/en
Priority to CA002563822A priority patent/CA2563822A1/en
Priority to US11/578,869 priority patent/US8008223B2/en
Publication of WO2006031259A2 publication Critical patent/WO2006031259A2/en
Publication of WO2006031259A8 publication Critical patent/WO2006031259A8/en
Priority to US13/205,151 priority patent/US8524624B2/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/04—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/005—Mixtures of molecular sieves comprising at least one molecular sieve which is not an aluminosilicate zeolite, e.g. from groups B01J29/03 - B01J29/049 or B01J29/82 - B01J29/89
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/041—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B01J31/1625—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts immobilised by covalent linkages, i.e. pendant complexes with optional linking groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/12—After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/34—Reaction with organic or organometallic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/60—Synthesis on support
    • B01J2229/62—Synthesis on support in or on other molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/145—Feedstock the feedstock being materials of biological origin

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Nanotechnology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Composite Materials (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
PCT/US2005/014256 2004-04-23 2005-04-25 Mesostructured zeolitic materials, and methods of making and using the same WO2006031259A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP05812517A EP1742873A2 (en) 2004-04-23 2005-04-25 Mesostructured zeolitic materials, and methods of making and using the same
AU2005285508A AU2005285508A1 (en) 2004-04-23 2005-04-25 Mesostructured zeolitic materials, and methods of making and using the same
CA002563822A CA2563822A1 (en) 2004-04-23 2005-04-25 Mesostructured zeolitic materials, and methods of making and using the same
US11/578,869 US8008223B2 (en) 2004-04-23 2005-04-25 Mesostructured zeolitic materials, and methods of making and using the same
US13/205,151 US8524624B2 (en) 2004-04-23 2011-08-08 Mesostructured zeolitic materials, and methods of making and using the same

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US10/830,714 US7589041B2 (en) 2004-04-23 2004-04-23 Mesostructured zeolitic materials, and methods of making and using the same
US10/830,714 2004-04-23
PCT/US2005/014129 WO2006038912A2 (en) 2004-04-23 2005-04-22 Mesostructured zeolitic materials and methods of making and using the same
USPCT/US2005/14129 2005-04-22

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US11/578,869 A-371-Of-International US8008223B2 (en) 2004-04-23 2005-04-25 Mesostructured zeolitic materials, and methods of making and using the same
US13/205,151 Division US8524624B2 (en) 2004-04-23 2011-08-08 Mesostructured zeolitic materials, and methods of making and using the same

Publications (2)

Publication Number Publication Date
WO2006031259A2 WO2006031259A2 (en) 2006-03-23
WO2006031259A8 true WO2006031259A8 (en) 2009-08-20

Family

ID=36060459

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2005/014256 WO2006031259A2 (en) 2004-04-23 2005-04-25 Mesostructured zeolitic materials, and methods of making and using the same

Country Status (3)

Country Link
AU (1) AU2005285508A1 (en)
CA (1) CA2563822A1 (en)
WO (1) WO2006031259A2 (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8206498B2 (en) 2007-10-25 2012-06-26 Rive Technology, Inc. Methods of recovery of pore-forming agents for mesostructured materials
US8486369B2 (en) 2009-01-19 2013-07-16 Rive Technology, Inc. Introduction of mesoporosity in low Si/Al zeolites
US8524624B2 (en) 2004-04-23 2013-09-03 Massachusetts Institute Of Technology Mesostructured zeolitic materials, and methods of making and using the same
US8765660B1 (en) 2013-03-08 2014-07-01 Rive Technology, Inc. Separation of surfactants from polar solids
US9376324B2 (en) 2012-01-13 2016-06-28 Rive Technology, Inc. Introduction of mesoporosity into zeolite materials with sequential acid, surfactant, and base treatment
US9580329B2 (en) 2012-01-13 2017-02-28 Rive Technology, Inc. Introduction of mesoporosity into low silica zeolites
US9580328B2 (en) 2011-04-08 2017-02-28 Rive Technology, Inc. Mesoporous framework-modified zeolites

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2319007B1 (en) 2006-12-07 2010-02-16 Rive Technology, Inc. METHODS FOR MANUFACTURING MESOSTRUCTURED ZEOLITICAL MATERIALS.
CN100460314C (en) * 2007-01-22 2009-02-11 华东师范大学 Method for synthesizing metal oxide mesoporous material by one-step vacuum perfusion
CN101659895B (en) * 2008-08-29 2012-06-27 复旦大学 Method for preparing nanometer mesoporous electrorheological fluid material SBA-15 capable of loading
US8524625B2 (en) 2009-01-19 2013-09-03 Rive Technology, Inc. Compositions and methods for improving the hydrothermal stability of mesostructured zeolites by rare earth ion exchange
US8685875B2 (en) 2009-10-20 2014-04-01 Rive Technology, Inc. Methods for enhancing the mesoporosity of zeolite-containing materials
FR2988717B1 (en) 2012-03-29 2014-04-11 IFP Energies Nouvelles METHOD FOR DEHYDRATION AND ISOMERIZATION OF ALCOHOLS USING A CATALYST BASED ON MESOSTRUCTURE MATERIAL COMPRISING SILICON
US10835495B2 (en) 2012-11-14 2020-11-17 W. R. Grace & Co.-Conn. Compositions containing a biologically active material and a non-ordered inorganic oxide material and methods of making and using the same
US9662640B2 (en) 2013-12-27 2017-05-30 Rive Technology, Inc. Introducing mesoporosity into zeolite materials with a modified acid pre-treatment step
CN107001056B (en) * 2014-12-11 2019-04-02 瑞弗科技有限公司 Mesoporous zeolite is prepared with the processing of reduction
US10626019B2 (en) 2014-12-30 2020-04-21 W. R. Grace & Co.-Conn. Methods for preparing zeolites with surfactant-templated mesoporosity and tunable aluminum content
CN110893346A (en) * 2018-09-12 2020-03-20 华东理工大学 Bimetallic low-temperature methanation catalyst and preparation method and application thereof
CN113578375B (en) * 2020-04-30 2023-04-07 中国石油化工股份有限公司 Modified ZSM-5 zeolite, catalytic cracking catalyst, and preparation method and application thereof
CN114425411B (en) * 2020-10-14 2023-08-29 中国石油化工股份有限公司 Supported Fe-based catalyst and preparation and application thereof
CN113289675B (en) * 2021-06-16 2023-05-02 西京学院 Catalyst for heavy oil catalytic cracking and preparation method thereof
CN115920950A (en) * 2021-08-23 2023-04-07 中国石油化工股份有限公司 Preparation method of catalytic cracking catalyst with low coke formation and high BTX yield
US20240009656A1 (en) * 2022-07-05 2024-01-11 Saudi Arabian Oil Company Hierarchically ordered crystalline microporous materials with long-range mesoporous order having cubic symmetry
US20240010504A1 (en) * 2022-07-05 2024-01-11 Saudi Arabian Oil Company Hierarchically ordered crystalline microporous materials with long-range mesoporous order having lamellar symmetry
CN116216738A (en) * 2023-03-08 2023-06-06 厦门大学 Preparation method of catalyst for preparing acetic acid by methanol carbonylation

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8524624B2 (en) 2004-04-23 2013-09-03 Massachusetts Institute Of Technology Mesostructured zeolitic materials, and methods of making and using the same
US8765095B2 (en) 2004-04-23 2014-07-01 Massachusetts Institute Of Technology Mesostructured zeolitic materials and methods of making and using the same
US8835342B2 (en) 2004-04-23 2014-09-16 Massachusetts Institute Of Technology Mesostructured zeolitic materials and methods of making and using the same
US8932974B2 (en) 2004-04-23 2015-01-13 Massachusetts Institute Of Technology Mesostructured zeolitic materials, and methods of making and using the same
US8206498B2 (en) 2007-10-25 2012-06-26 Rive Technology, Inc. Methods of recovery of pore-forming agents for mesostructured materials
US8486369B2 (en) 2009-01-19 2013-07-16 Rive Technology, Inc. Introduction of mesoporosity in low Si/Al zeolites
US9580328B2 (en) 2011-04-08 2017-02-28 Rive Technology, Inc. Mesoporous framework-modified zeolites
US9376324B2 (en) 2012-01-13 2016-06-28 Rive Technology, Inc. Introduction of mesoporosity into zeolite materials with sequential acid, surfactant, and base treatment
US9580329B2 (en) 2012-01-13 2017-02-28 Rive Technology, Inc. Introduction of mesoporosity into low silica zeolites
US8765660B1 (en) 2013-03-08 2014-07-01 Rive Technology, Inc. Separation of surfactants from polar solids

Also Published As

Publication number Publication date
CA2563822A1 (en) 2006-03-23
AU2005285508A1 (en) 2006-03-23
WO2006031259A2 (en) 2006-03-23

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