WO2006026330A2 - Aluminum automotive structural members - Google Patents
Aluminum automotive structural members Download PDFInfo
- Publication number
- WO2006026330A2 WO2006026330A2 PCT/US2005/030194 US2005030194W WO2006026330A2 WO 2006026330 A2 WO2006026330 A2 WO 2006026330A2 US 2005030194 W US2005030194 W US 2005030194W WO 2006026330 A2 WO2006026330 A2 WO 2006026330A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- sheet product
- max
- range
- slab
- accordance
- Prior art date
Links
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 46
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 46
- 238000000034 method Methods 0.000 claims abstract description 73
- 229910000838 Al alloy Inorganic materials 0.000 claims abstract description 70
- 238000005266 casting Methods 0.000 claims abstract description 37
- 239000002245 particle Substances 0.000 claims abstract description 37
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 28
- 239000000956 alloy Substances 0.000 claims abstract description 28
- 238000004519 manufacturing process Methods 0.000 claims abstract description 25
- 229910052742 iron Inorganic materials 0.000 claims abstract description 22
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 19
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 19
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 18
- 239000012535 impurity Substances 0.000 claims abstract description 17
- 229910018084 Al-Fe Inorganic materials 0.000 claims abstract description 16
- 229910018192 Al—Fe Inorganic materials 0.000 claims abstract description 16
- 229910019752 Mg2Si Inorganic materials 0.000 claims abstract description 15
- 229910002551 Fe-Mn Inorganic materials 0.000 claims abstract description 14
- 238000000137 annealing Methods 0.000 claims description 46
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 31
- 238000005098 hot rolling Methods 0.000 claims description 29
- 238000005096 rolling process Methods 0.000 claims description 24
- 239000011777 magnesium Substances 0.000 claims description 20
- 239000011572 manganese Substances 0.000 claims description 19
- 238000005097 cold rolling Methods 0.000 claims description 18
- 238000009827 uniform distribution Methods 0.000 claims description 13
- 238000002788 crimping Methods 0.000 claims description 12
- 238000007711 solidification Methods 0.000 claims description 7
- 230000008023 solidification Effects 0.000 claims description 7
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 6
- 238000005304 joining Methods 0.000 claims description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 5
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims 12
- 239000003351 stiffener Substances 0.000 claims 2
- 238000009826 distribution Methods 0.000 abstract description 3
- 239000000047 product Substances 0.000 description 38
- 238000009749 continuous casting Methods 0.000 description 21
- 239000000463 material Substances 0.000 description 18
- 229910052751 metal Inorganic materials 0.000 description 16
- 239000002184 metal Substances 0.000 description 16
- 239000000203 mixture Substances 0.000 description 9
- 238000012545 processing Methods 0.000 description 7
- 239000010959 steel Substances 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 5
- 238000005336 cracking Methods 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 230000006698 induction Effects 0.000 description 5
- 238000005275 alloying Methods 0.000 description 4
- 238000010791 quenching Methods 0.000 description 4
- 238000001953 recrystallisation Methods 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 238000005452 bending Methods 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 230000009977 dual effect Effects 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 229910000765 intermetallic Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000009957 hemming Methods 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 230000013011 mating Effects 0.000 description 2
- 238000001000 micrograph Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 238000004826 seaming Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 229910019064 Mg-Si Inorganic materials 0.000 description 1
- 229910019406 Mg—Si Inorganic materials 0.000 description 1
- 229910018104 Ni-P Inorganic materials 0.000 description 1
- 229910018536 Ni—P Inorganic materials 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012850 fabricated material Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000009751 slip forming Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
- C22C21/08—Alloys based on aluminium with magnesium as the next major constituent with silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/05—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys of the Al-Si-Mg type, i.e. containing silicon and magnesium in approximately equal proportions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B3/00—Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/001—Continuous casting of metals, i.e. casting in indefinite lengths of specific alloys
- B22D11/003—Aluminium alloys
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/06—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
- B22D11/0605—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars formed by two belts, e.g. Hazelett-process
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
Definitions
- This invention relates to aluminum alloy vehicular structural parts or members and more particularly, it relates to a method of casting aluminum alloy into sheet having good forming characteristics and to forming the sheet into vehicular structural parts or members such as dash panel, floor panel, door panel, window trim, radio bracket, reinforcements for panels, etc.
- continuous casting of molten aluminum into slab utilizing twin belt, twin roll or block casters is favored over DC casting because continuous casting can result in substantial energy savings and total conversion cost savings compared to the DC cast method.
- molten metal is continuously introduced to an advancing mold and a slab is produced which may be continuously formed into a sheet product which is collected or wound into a coil.
- the continuous casting is not without problems. For example, it has been discovered that the alloy composition and the processing steps must be carefully controlled in order to have the formability level to avoid cracking during forming and yet have the requisite strength properties in the final product.
- the alloy and the processing thereof must be carefully controlled to provide sheet having the formability suited to the fabricating steps necessary to form the final product or vehicular structural parts. If the alloy and processing steps are not controlled, then in the forming steps, fracture can occur and the formed parts have to be scrapped.
- thermal mechanical processing methods which provide a sheet product having forming characteristics and strength properties which permit forming operations such as bending, stamping, deep drawing, stretching or crimping to hold fasteners during production of vehicular structural parts or members while avoiding problems of fracturing or cracking, for example.
- U.S. Patent 5,976,279 discloses a process for continuously casting aluminum alloys and improved aluminum alloy compositions.
- the process includes the steps of continuously annealing the cold rolled strip in an intermediate anneal using an induction heater and/or continuously annealing the hot rolled strip in an induction heater.
- the alloy composition has mechanical properties that can be varied selectively by varying the time and temperature of a stabilizing anneal.
- U.S. Patent 6,264,765 discloses a method and apparatus for casting, hot rolling and annealing non-heat treatment aluminum alloys.
- the method and apparatus comprises continuous casting, hot rolling and in-line inductively heating the aluminum sheet to obtain the mechanical properties within the specification tolerance of the hot rolled product.
- U.S. Patent 5,985,058 discloses a process for continuously casting aluminum alloys and improved aluminum alloy compositions.
- the process includes the step of heating the cast strip before, during or after hot rolling to a temperature in excess of the output temperature of the cast strip from the chill blocks.
- the alloy composition has a relatively low magnesium content yet possesses superior strength properties.
- U.S. Patent 5,993,573 discloses a process for continuously casting aluminum alloys and improved aluminum alloy compositions. The process includes the steps of (a) heating the cast strip before, during or after hot rolling to a temperature in excess of the output temperature of the cast strip from the chill blocks and (b) stabilization or back annealing in an induction heater of cold rolled strip produced from the cast strip.
- U.S. Patent 5,833,775 discloses an aluminum alloy sheet and a method for producing an aluminum alloy sheet.
- the aluminum alloy sheet is useful for forming into drawn and ironed container bodies.
- the sheet preferably has an after-bake yield strength of at least about 37 ksi and an elongation of at least about 2 percent.
- Preferably the sheet also has earing of less than about 2 percent.
- U.S. Patent 6,086,690 discloses a process of producing an aluminum alloy sheet article of high yield strength and ductility suitable, in particular, for use in manufacturing automotive panels.
- the process comprises casting a non heat-treatable aluminum alloy to form a cast slab, and subjecting said cast slab to a series of rolling steps to produce a sheet article of final gauge, preferably followed by annealing to cause recrystallization.
- the rolling steps involve hot and warm rolling the slab to form an intermediate sheet article of intermediate gauge, cooling the intermediate sheet article, and then warm and cold rolling the cooled intermediate sheet to final gauge at a temperature in the range of ambient temperature to 34O 0 C. to form said sheet article.
- the series of rolling steps is carried out continuously without intermediate coiling or full annealing of the intermediate sheet article.
- the invention also relates to the alloy sheet article produced by the process.
- U.S. Patent 5,244,516 discloses an aluminum alloy plate for discs superior in Ni-P platability and adhesionability of plated layer and having a high surface smoothness with a minimum of nodules and micropits, said aluminum alloy plate comprising an aluminum alloy containing as essential elements Mg in an amount more than 3% and equal to or less than 6%, Cu in an amount equal to or more than 0.03% and less than 0.3%, and Zn in an amount equal to or more than 0.03% and equal to or less than 0.4%, and as impurities Fe in an amount equal to or less than 0.07% and Si in an amount equal to or less than 0.06% in the case of semi-continuous casting, or Fe in an amount equal to or less than 0.1% and Si in an amount equal to or less than 0.1% in the case of strip casting, and also containing Al-Fe phase intermetallic compounds, with the maximum size being smaller than lO ⁇ m and the number of particles larger than 5 ⁇ m being less than 5 per 0.2 mm 2 , and Mg-Si phase
- U.S. Patent 5,514,228 discloses a method for manufacturing aluminum sheet stock which includes hot rolling an aluminum alloy sheet stock, annealing and solution heat treating it without substantial intermediate cooling and rapid quenching.
- Formability when used herein is used to describe the ease with which a sheet of metal can be shaped through plastic deformation. Formability of a metal can be evaluated by measuring strength, ductility, and the amount of deformation to cause failure.
- aluminum when used herein is meant to include aluminum and its alloys.
- It is another object of the invention to provide a process for casting a molten alloy comprising 2.7 to 3.6 wt.% Mg, 0.1 to 0.4 wt.% Mn, 0.02 to 0.2 wt.% Si, 0.05 to 0.30 wt.% Fe, 0.1 wt.% max. Cu, 0.25 wt.% max. Cr, 0.2 wt.% max. Zn, 0.15 wt.% max. Ti, the remainder aluminum, incidental elements and impurities, casting the alloy into a slab which is hot rolled and annealed to provide a sheet product suitable for forming into a vehicular structural part or frame member where good formability is necessary.
- a process for producing aluminum vehicular structural parts or members from molten aluminum alloy using a continuous caster to cast the alloy into a slab comprises providing a molten aluminum alloy consisting essentially of 2.7 to 3.6 wt.% Mg, 0.1 to 0.4 wt.% Mn, 0.02 to 0.2 wt.% Si, 0.05 to 0.25 wt.% Fe, 0.1 wt.% max. Cu, 0.25 wt.% max. Cr, 0.2 wt.% max. Zn, 0.15 wt.% max. Ti, the remainder aluminum, incidental elements and impurities and providing a continuous caster such as a belt caster for continuously casting the molten aluminum alloy.
- the molten aluminum alloy is cast into a slab having Al-Fe, Al-Fe-Mn or Mg 2 Si containing intermetallic particles.
- the slab is rolled into a sheet product which is then annealed to provide a sheet product having a substantially uniform distribution or less striations of intermetallic particles for improved formability.
- the sheet product is formed into a vehicular structural part or member such as a panel member for a door or hood, for example, having fasteners crimped thereto.
- the hot rolled sheet may be cold rolled after hot rolling, and then annealed prior to the forming steps.
- the hot rolled sheet may be annealed or even homogenized and then cold rolled to a cold rolled sheet product.
- the cold rolled product can be annealed to provide a product suited to the various forming steps.
- Fig. 1 is a schematic of a continuous caster, hot rolling mill and rolls of sheet material.
- Fig. 2 is a flow chart showing steps in the invention.
- Fig. 3 is a micrograph showing microstructure of D.C. cast material.
- Fig. 4 is a micrograph showing microstructure of sheet material formed by continuous casting (CC) and rolling in accordance with the invention.
- Fig. 5 is a schematic of a vehicular rear hatch door or lift gate.
- Fig. 6 is a side view of a vehicle showing rear door open.
- Fig. 7 is a perspective view showing structural members of a rear hatch door separated.
- Fig. 8 is a cross-sectional view showing structural members hemmed together.
- Fig. 9 is a cross-section of a threaded fastener crimped into the metal.
- the vehicular structural parts or members, for example, of the invention are comprised of an aluminum base alloy containing controlled amounts of magnesium, iron, silicon and manganese for the required strength and formability in the sheet product produced by the casting and thermomechanical process.
- the total amounts of the alloying elements are required to be controlled to meet the strength requirement without causing casting difficulty in the process. Further, the amount of alloying elements also is required to be controlled to meet the formability requirements, especially the amount of iron, manganese and silicon.
- Al-Fe, Al-Fe-Mn or Mg 2 Si intermetallic particles form during solidification. That is, the distribution, size and amount of such intermetallic particles after rolling of continuous cast slab can drastically influence the formability of the sheet material.
- the Al-Fe, Al-Fe-Mn or Mg 2 Si containing intermetallic particles form during solidification.
- the distribution of such intermetallic particles after rolling of continuous belt cast aluminum slab can be severely striated or lined causing forming problems.
- direct chill (D.C.) ingot cast material has a more uniform distribution of intermetallic particles providing good formability.
- Striations of intermetallic particle structure causes stress concentration during plastic deformation which deteriorate formability of the sheet product.
- the rolled sheet of the invention has a substantially uniform distribution or less striations of intermetallic particles to provide for improved formability.
- the aluminum base alloy consists essentially of 2.7 to 3.6 wt.%
- Mg 0.1 to 0.4 wt.% Mn, 0.02 to 0.2 wt.% Si, 0.05 to 0.3 wt.% Fe, 0.1 wt.% max. Cu, 0.25 wt.% max. Cr, 0.2 wt.% max. Zn, 0.15 wt.% max. Ti, the remainder aluminum, incidental elements and impurities.
- magnesium is maintained in the range of 2.8 to 3.3 or 3.5 wt.% and manganese is preferably maintained in the range of 0.1 to 0.25 or 0.35 wt.%.
- iron is maintained in the range of 0.05 or 0.10 to 0.25 wt.%, typically 0.05 to 0.2 wt.% and silicon is maintained in the range of 0.05 to 0.15 wt.%.
- Impurities are preferably limited to not more than 0.05 wt.% each and the combination of impurities should not be greater than 0.15 wt.% total.
- the slab produced by continuous casting the sheet formed from the slab and automotive member fabricated from the sheet must be prepared in accordance with specific method steps in order to produce sheet and automotive structural parts or members therefrom having the desirable characteristics. That is, the process must be controlled in order to produce product having near formability properties of DC ingot fabricated material without the cost penalties of the DC ingot process.
- Fig. 1 there is shown a schematic illustration of a belt caster 2 and rolling mill for producing sheet suitable for forming into vehicular structural parts or members in accordance with the invention.
- molten aluminum 10 is provided in a furnace or reservoir 12. Molten aluminum from reservoir 12 is directed along line 14 to a tundish 16 from where it is metered through a nozzle 18 into an advancing mold created by revolving belts 20 and 22 and side dam blocks (not shown). Belts 20 and 22 are turned by means of rolls 24. Molten metal, e.g., molten aluminum, is solidified to form a continuous slab 15 between belts 20 and 22 which are chilled using coolant spray 26.
- Belt caster 2 is described in U.S. Patents 3,864,973; 3,921,697; 4,648,438; 4,940,076 and 4,972,900, incorporated herein by reference as if specifically set forth. Improved nozzles for a belt caster are set forth in U.S. Patent 5,452,827, incorporated herein by reference.
- Another casting apparatus that may be used in the present invention is a block caster wherein the blocks are connected to form belts and is included herein as a belt caster.
- a tundish and nozzle are provided to transfer molten metal to the block belts of the block caster wherein solidification occurs to provide a solidified slab 15 and the blocks are chilled to aid in solidification of the molten metal.
- Yet another apparatus that maybe utilized to cast a continuous strip or slab 15 is a roll caster which includes two rolls which rotate to provide the continuously advancing mold.
- a tundish and nozzle are used to transfer molten aluminum to the mold defined by the two rolls. Again, the rolls are normally chilled to aid in solidification of the molten metal into a strip or slab.
- the different casters are described in U.S. Patent 5,452,827. By the use of the term “continuous caster” is meant to include all these casters.
- Molten aluminum alloy of the invention is introduced to the caster in a temperature range of about 1220° to 132O 0 F, typically 1250° to 1285 0 F, and exits the caster at a temperature in the range of 750° to 115O 0 F, typically 860° to 95O 0 F.
- typically the continuous slab exiting the belt caster has a thickness in the range of 0.2 to 2 inches, for example, 0.2 to 1 inch.
- a typical slab thickness for the belt caster is about 0.6 to 0.875 inch.
- Belt casting speed can range from 10 to 40 ft/min, depending on the thickness of the slab.
- the present invention provides continuous cast slab for forming into sheet material with near DC cast properties to obtain the cost savings and yet retain the desirable properties such as formability.
- the slab 15 is directed to rolling mill 30 where it is rolled to form a rolled strip or flat product 34 using preferably a hot mill.
- Hot mill 30 is comprised of one or more pairs of oppositely opposed rolls 32 which reduces the thickness of the slab a controlled amount as it passes between each stand of rolls.
- Three sets of hot stands or rolls are illustrated in Fig. 1.
- slab 15 having a thickness of about 0.2 to 1 inch would be reduced to a sheet product having a thickness of about 0.01 to 0.25 inch.
- the sheet product would have a thickness in the range of 0.02 to 0.1 or 0.2 inch, for example, depending on the application.
- the temperature of the slab entering hot mill 30 would typically be in the range of about 700° to HOO 0 F, if no heat is added.
- temperature of sheet product exiting mill 30 would be in the range of 350° to 700 0 F.
- the slab from caster 3 may be heated prior to hot rolling (not shown in Fig. 1) to a temperature of 800° to 1100 0 F to increase the rolling temperature prior to hot rolling.
- slab entering the hot mill can have temperatures of about 800° to 1100 0 F.
- Hot mill 30 can reduce the thickness of the slab about 60 to 95% of its original thickness, with typical reduction being 75 to 95%.
- heat may be applied to the strip or slab between hot stands in addition to or instead of heating prior to the hot mill.
- the temperature of the aluminum alloy sheet exiting the hot mill can be in the range of about 400° to 825°F, depending on whether there was heat input before or during hot rolling.
- hot rolled strip 34 can have a deformation texture and deformed grain structure.
- the hot rolled strip can have a partially or fully recrystallized grain structure with an optimum texture depending on previous heat input and rolling reduction. If the structure remains deformed and a recrystallized grain structure is necessary for the end product, then annealing of the hot rolled strip 34 can be applied to promote recrystallization of the deformed structures. For example, it is important for automotive application using the aluminum alloy of the invention to have a fine, fully recrystallized grain structure with random texture for the purpose of forming automotive parts in accordance with the invention.
- Hot rolled sheet be fully annealed to O-temper in annealer 40.
- Hot rolled sheet in the fully annealed condition can have a tensile strength in the range of 28 to 35 ksi, a yield strength in the range of 12 or 13 to 17.5 ksi and an elongation greater than 19%.
- the hot rolled sheet product is directed to a continuous annealer 40, using a heater such as an infrared, solenoidal or transverse flux induction heater. While any continuous heater may be used, an induction heater is preferred. Continuous anneal may also be required if cold rolling (not shown in Fig. 1) of the hot rolled strip is necessary.
- the hot or cold rolled strip may be continuously annealed in annealer 40 in a temperature range of 600° to 1100 0 F in time periods from 0.5 to 60 seconds in order to effect fully recrystallized sheet having fine grains and highly desired formability properties.
- care is required that the sheet product is not over annealed to the point where secondary recrystallization occurs. Secondary recrystallization is the growth of fine grains into undesirable coarse grains which are detrimental to formability.
- the hot rolled sheet may be batch annealed. That is, hot rolled sheet 42 is wound into coils 48 or 49. These coils are then placed in a furnace and soaked in a temperature range of 600° to 1000 0 F for 2 to 10 hours to provide the rolled sheet in a fully annealed or O-temper condition. If the slab has been hot rolled to a gauge suitable for forming, then no further thermal mechanical processing is necessary and the sheet is in condition for the forming steps. If the slab has been hot rolled to an intermediate gauge, then after annealing, the annealed material is subjected to cold rolling followed by further annealing to provide sheet in the O-temper for forming operations.
- the hot rolled sheet or flat product may be allowed to cool prior to other operations.
- the resulting strip 42 may be cold rolled (not shown in Fig. 1) to a sheet product having a final gauge.
- the cold rolling may be performed by passing strip 42 through several pairs or stands comprising a cold mill to provide the cold rolling required to produce the final gauge.
- Cold rolling can reduce the thickness of strip 42 by 20% to 80% or 90%.
- Final gauge can range from 0.02 to 0.09 or even 0.2 inch, typically 0.03 to 0.12 inch, for automotive ' applications. It will be appreciated that the cold rolling, which is rolling at lower than 300°F, can be performed in a cold rolling line separate from the subject continuous casting and rolling line.
- the sheet product is subject to further anneal to ensure the required crystallographic texture and grain structure necessary for forming into the final automotive product.
- Hot rolling or annealing sheet 42 may be subject to a continuous rapid quenching such as cold water quench 50 prior to further operations.
- Quench 50 if used and shown after anneal, can be located at different locations in the process.
- annealed hot rolled sheet may subject cold rolling followed by further annealing prior to forming, hi a further embodiment or alternate process, after hot rolling, the sheet may be directly cold rolled followed by annealing of the cold rolled sheet prior to being formed into a vehicular structural part or member.
- the cold rolled and annealed sheet, along the rolling direction, can have a tensile strength in the range of 28 to 35 ksi, a yield strength in the range of 12 to 17.5 ksi and an elongation greater than 19%.
- the finish gage coils may go through one or combination of steps before the forming process, such as tension leveling, slitting, surface pretreatment, lubrication or cut-to-length.
- Figs. 3 and 4 show the microstructure of CC 5754 alloy with controlled chemistry while Fig. 3 shows that of the commercially used DC 5754 alloy sheet. Both sheets are 0.060 inch in thickness and are in the O-temper condition. SEM inspection of the particles which were formed during solidification shows that they are comprised of Al-Fe, Al-Fe-Mn and Mg2Si.
- the particle structure of CC sheet is substantially uniformly distributed with only minimal striations or lines while the intermetallic particles of DC sheet are uniformly distributed.
- the intermetallic particle size of CC material ranges from about 0.1 to 7 ⁇ m while that of DC material ranges from about 0.5 to 10 ⁇ m.
- the area fraction of intermetallic particles is 0.43% for CC material while the area fraction is 0.56% for DC material.
- CC sheet has a finer grain structure than DC sheet.
- the measurement of the grain size shows that CC material has an average grain size of 16.6 ⁇ m while DC material has an average grain size of 17.8 ⁇ m.
- FIG. 5 there is illustrated an automotive lift gate 100 provided as part of a sports utility vehicle (SUV).
- the lift gate is comprised of a bottom metal portion 102 and a window frame portion 104 covered with glass.
- Lift gate 100 is mounted to roof 108 of the SUV using hinges 106 and is closed or secured to the vehicle using handle 110.
- sides 112, bumper 114 and roof 108 define the opening closed by the lift gate.
- lift gate 100 is shown partially open and supported by strut 116.
- a lift gate fabricated from an aluminum alloy of the invention can result in substantial weight savings which can be as much as 20 pounds, depending on the vehicle. Further, lighter and less costly struts can be used to open and support the lift gate, adding to the weight savings.
- strut 116 is fastened to lift gate 100 at 118 which requires the aluminum alloy to have good forming characteristics to hold a threaded fastener.
- Fig. 7 shows an exploded view of an automotive lift gate structure comprised of an outer panel 120 and an inner panel 122 which are peripherally joined to provide a dual panel lift gate structure. It will be appreciated that doors, hoods, fenders and the like can employ the same type of construction, i.e., inner and outer panels. Further, it will be seen from Figs. 7 and 8 that outer panel 120 employs a generally curved, smooth shape. Also from Fig. 7 it will be seen that outer panel 120 configuration shows window frame 104 as an integral part of bottom portion 102. Referring further to Fig.
- inner panel 122 uses a more complicated design which includes dished portions 124 and can have raised channels and open portions (not shown), particularly when used for doors or hoods.
- the inner panel with its dished portions and raised portions serves to increase the flexural strength of the lift gate.
- the inner panel or outer panel can be shaped from a single sheet using stamping between mating dies to provide the structural features necessary to the lift gate assembly. While the outer panel is relatively smooth and curved, as noted, the inner panel will usually be shaped to form a channel 126 (Fig. 8) to provide increased strength to the window frame portion.
- outer panel 120 can be formed of steel or, for example, aluminum alloys AA6111 or AA5083, the composition of which is provided in the Aluminum Association publication entitled “International Alloy Designations and Chemical Composition Limits for Wrought Aluminum and Wrought Aluminum Alloys", dated January 2001, all of which is incorporated herein by reference as if specifically set forth.
- Fig. 8 shows a cross section of a lift gate employing outer panel 120 hemmed or seamed to inner panel 122.
- outer panel 120 is relatively smooth and inner panel 122 has recessed areas and employs a channel around the window frame 104 for increased strength.
- the lift gate derives its strength from the dual or plural structure of the two formed panels.
- Formed panels can include doors, hoods, trunk lids, fenders, floors, wheels and bumper backup bars and can be formed from flat sheets of aluminum alloy formed between mating dies to provide a three-dimensional structure.
- the dual or plural structure as depicted employs peripheral seaming or hemming to provide the vehicular structural member; however, other means of joining can include welding, riveting, adhesive bonding and thus the inner and outer panels can be joined by any of these methods and such is contemplated.
- the seaming or hemming referred to is shown in Fig. 8 where outer panel 120 is hemmed around inner panel 122.
- outer panel 120 should be capable of forming or bending 180° without cracking where the radius of the bend is about half the thickness of the metal.
- the structural member may include a combination of steel and aluminum alloy, but such structure would not provide the same weight savings.
- the alloy of the invention is required to have good formability for yet another reason. That is, hinges 106 and struts 116, for example, are preferred to be joined to steel threaded fasteners. Thus, at 118 where strut 116 is connected to lift gate 100, it is preferred to use a metal fastener such as a steel fastener. Accordingly, a threaded fastener 130 is crimped into the sheet metal of the inner panel as shown in Fig. 9. The crimping must be of a severity to pull the sheet metal around shoulder 132 of the threaded fastener without forming cracks in the sheet metal.
- the locking of the threaded fastener in the sheet metal must be sufficiently tight to permit screwing a bolt through an eye in the strut into the fastener.
- Crimping in this manner obviates welding and readily permits joining of aluminum to a steel threaded fastener for ease of fabrication.
- Crimping is alloy sensitive and if the iron is too high, the metal can crack during the crimping operation. Thus, for purposes of crimping, it is preferred to keep iron less than 0.25 wt.% and preferably in the range of 0.05 or 0.1 to 0.2 wt.%.
- aluminum alloy vehicular parts or members produced in accordance with the foregoing practices provide material having the strength and formability for use as vehicular or automotive sheet which can be formed into many different automotive structural members.
- AU ranges provided herein are meant to include all the numbers within the range as if specifically set forth, e.g., 1 to 5 would include 1.1, 1.2, 1.3, etc., or e.g., 2, 3, 4.
- Example 2 is further illustrative of the invention.
- An aluminum base alloy containing 3.267 wt.% Mg, 0.201 wt.% of Mn, 0.080 wt.% Si, 0.164 wt.% Fe, 0.020 wt.% Cu, 0.004 wt.% Cr and 0.024 wt.% Zn was fed to a twin belt caster at a temperature of 126O 0 F and solidified to produce a 0.875 inch thick slab existing the caster at a temperature of 900°F.
- the slab was directly fed into a three stand hot rolling mills and rolled to final gauge of 0.100 inch.
- the temperature of introducing the slab to the hot rolling mill was at about 820°F and the temperature of exiting the mill was at about 520°F.
- the hot rolled sheet was wound into a coil.
- the coil was annealed in an anneal furnace at a temperature of 730°F for 4 hours.
- the annealed coil was tension leveled and slit into the required width and then the coil was given a surface pretreatment and lubricated.
- the material had properties in the rolling direction before forming into automotive parts of: ultimate tensile strength of 32.8 ksi, yield strength of 15.5 ksi, elongation of 21.4%. All these properties met the requirement identified by Aluminum for Automotive Body Sheet Panels, published by The Aluminum Association.
- the material was formed into inner structural panels, and threaded fasteners were crimped into the sheet with satisfied quality inspection.
- the alloy can be cast in a twin belt caster, rolled into a sheet product, stamped or shaped into an automotive structural part or member with sufficient strength and formability.
- the continuous caster can be used to produce a slab which can be thermomechanically treated to form a sheet product having the properties for forming into vehicular parts or members.
Landscapes
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Metal Rolling (AREA)
- Continuous Casting (AREA)
- Body Structure For Vehicles (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Laminated Bodies (AREA)
Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200580028822XA CN101166845B (en) | 2004-08-27 | 2005-08-25 | Aluminum automotive structural members |
AT05791238T ATE504371T1 (en) | 2004-08-27 | 2005-08-25 | MANUFACTURING PROCESS OF MULTIPLE PLATE MOTOR VEHICLE PARTS |
CA002578195A CA2578195A1 (en) | 2004-08-27 | 2005-08-25 | Aluminum automotive structural members |
MX2007002179A MX2007002179A (en) | 2004-08-27 | 2005-08-25 | Aluminum automotive structural members. |
DE602005027365T DE602005027365D1 (en) | 2004-08-27 | 2005-08-25 | Manufacturing method of multi-panel automotive parts |
EP05791238A EP1794338B1 (en) | 2004-08-27 | 2005-08-25 | Method for producing plural panel automotive members |
JP2007530106A JP5107039B2 (en) | 2004-08-27 | 2005-08-25 | Aluminum automotive structural members |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/926,704 | 2004-08-27 | ||
US10/926,704 US20060042727A1 (en) | 2004-08-27 | 2004-08-27 | Aluminum automotive structural members |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2006026330A2 true WO2006026330A2 (en) | 2006-03-09 |
WO2006026330A3 WO2006026330A3 (en) | 2008-01-03 |
Family
ID=35941371
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2005/030194 WO2006026330A2 (en) | 2004-08-27 | 2005-08-25 | Aluminum automotive structural members |
Country Status (11)
Country | Link |
---|---|
US (1) | US20060042727A1 (en) |
EP (1) | EP1794338B1 (en) |
JP (1) | JP5107039B2 (en) |
KR (1) | KR20070091600A (en) |
CN (1) | CN101166845B (en) |
AT (1) | ATE504371T1 (en) |
CA (1) | CA2578195A1 (en) |
DE (1) | DE602005027365D1 (en) |
ES (1) | ES2364275T3 (en) |
MX (1) | MX2007002179A (en) |
WO (1) | WO2006026330A2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2022223634A1 (en) | 2021-04-21 | 2022-10-27 | Constellium Neuf-Brisach | 5xxx aluminium sheets with high formabilty |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2588046C (en) * | 2004-07-30 | 2014-09-30 | Nippon Light Metal Co., Ltd. | Aluminum alloy sheet and method for manufacturing the same |
DE102005052774A1 (en) * | 2004-12-21 | 2006-06-29 | Salzgitter Flachstahl Gmbh | Method of producing hot strips of lightweight steel |
US20080041501A1 (en) * | 2006-08-16 | 2008-02-21 | Commonwealth Industries, Inc. | Aluminum automotive heat shields |
US20080248214A1 (en) * | 2007-04-09 | 2008-10-09 | Xueyuan Nie | Method of forming an oxide coating with dimples on its surface |
KR100943794B1 (en) * | 2007-12-26 | 2010-02-24 | 주식회사 포스코 | The aluminium alloy bar continuous manufacturing equipment in the series appratus rolling |
DE102008017977A1 (en) * | 2008-04-09 | 2009-10-15 | Daimler Ag | Lightweight component for a vehicle body |
CN102505081B (en) * | 2011-12-29 | 2013-09-11 | 西南铝业(集团)有限责任公司 | Manufacturing method for high magnesium aluminum alloy sheets |
JP2015522898A (en) * | 2012-04-11 | 2015-08-06 | ヴァレリオ,テオドール | Heat sink formed from stacked fin elements interleaved with flexible deformable plates |
US20150101382A1 (en) * | 2012-11-02 | 2015-04-16 | Golden Aluminum, Inc. | Method and composition for recycling aluminum containers |
CN103320729B (en) * | 2013-05-31 | 2015-07-22 | 浙江巨科铝业股份有限公司 | Preparation method of Al-Mg alloy plate for automobile body |
CN103243247A (en) * | 2013-05-31 | 2013-08-14 | 浙江巨科铝业有限公司 | Aluminum alloy and preparation method thereof |
FR3008427B1 (en) * | 2013-07-11 | 2015-08-21 | Constellium France | ALUMINUM ALLOY SHEET FOR AUTOMOBILE BODY STRUCTURE |
CN103725937B (en) * | 2013-11-27 | 2016-04-13 | 余姚市吴兴铜业有限公司 | A kind of trolley part high-performance aluminium alloy |
CN103725938B (en) * | 2013-11-27 | 2016-01-13 | 余姚市吴兴铜业有限公司 | A kind of High-performance aluminum alloy automobile part |
CN105463352B (en) * | 2015-12-04 | 2017-10-31 | 中国航空工业集团公司洛阳电光设备研究所 | The heat treatment method and 3D printing thin-wall part of a kind of 3D printing thin-wall part using AlSi10Mg as substrate |
CN105506413A (en) * | 2015-12-18 | 2016-04-20 | 西南铝业(集团)有限责任公司 | 6-series aluminum alloy for vehicle structural part |
MX2018008367A (en) | 2016-01-08 | 2018-12-10 | Arconic Inc | New 6xxx aluminum alloys, and methods of making the same. |
CN107868891A (en) * | 2016-09-23 | 2018-04-03 | 镇江龙源铝业有限公司 | A kind of fender aluminum alloy plate materials new material |
CN107868892A (en) * | 2016-09-23 | 2018-04-03 | 镇江龙源铝业有限公司 | A kind of cable armouring protects thin wall type flexible pipe Al-alloy material |
EA037441B1 (en) * | 2016-09-30 | 2021-03-29 | Общество с ограниченной ответственностью "Объединенная Компания РУСАЛ Инженерно-технологический центр" | Method for making deformed semi-finished products from aluminium alloys |
CN110023524A (en) * | 2016-12-09 | 2019-07-16 | 通用汽车环球科技运作有限责任公司 | The artificial aging method of aluminium-silicon alloys for die casting |
CN107739924B (en) * | 2017-11-14 | 2019-07-12 | 中铝东南材料院(福建)科技有限公司 | A kind of new-energy automobile vacuum booster shell aluminium alloy strips and preparation method |
CN108248700A (en) * | 2017-12-18 | 2018-07-06 | 合肥亿恒智能科技股份有限公司 | A kind of automobile front floor assembly |
CN109055788A (en) * | 2018-09-18 | 2018-12-21 | 天津忠旺铝业有限公司 | A kind of preparation process eliminating 5 line aluminium alloy plate surface bands |
CN109897996A (en) * | 2019-03-29 | 2019-06-18 | 中铝瑞闽股份有限公司 | A kind of high-performance abnormity round can aluminium alloy strips and preparation method thereof |
WO2021150610A1 (en) * | 2020-01-21 | 2021-07-29 | Novelis Inc. | Techniques for producing aluminum alloy products having improved formability and recyclability |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5976279A (en) | 1997-06-04 | 1999-11-02 | Golden Aluminum Company | For heat treatable aluminum alloys and treatment process for making same |
Family Cites Families (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3921697A (en) * | 1973-03-22 | 1975-11-25 | Hazelett Strip Casting Corp | Method and apparatus for controlling the operating conditions in continuous metal casting machines having a revolving endless casting belt |
US3864973A (en) * | 1973-03-22 | 1975-02-11 | Hazelett Strip Casting Corp | Method and apparatus for determining the operating conditions in continuous metal casting machines of the type having a revolving endless casting belt |
US4648438A (en) * | 1982-04-28 | 1987-03-10 | Hazelett Strip-Casting Corporation | Method and apparatus for feeding and continuously casting molten metal with inert gas applied to the moving mold surfaces and to the entering metal |
US4589932A (en) * | 1983-02-03 | 1986-05-20 | Aluminum Company Of America | Aluminum 6XXX alloy products of high strength and toughness having stable response to high temperature artificial aging treatments and method for producing |
US4897124A (en) * | 1987-07-02 | 1990-01-30 | Sky Aluminium Co., Ltd. | Aluminum-alloy rolled sheet for forming and production method therefor |
US5244516A (en) * | 1988-10-18 | 1993-09-14 | Kabushiki Kaisha Kobe Seiko Sho | Aluminum alloy plate for discs with improved platability and process for producing the same |
US4940076A (en) * | 1989-05-09 | 1990-07-10 | Hazelett Strip-Casting Corporation | Method and apparatus for steering casting belts of continuous metal-casting machines |
US4972900A (en) * | 1989-10-24 | 1990-11-27 | Hazelett Strip-Casting Corporation | Permeable nozzle method and apparatus for closed feeding of molten metal into twin-belt continuous casting machines |
JPH04214834A (en) * | 1990-12-14 | 1992-08-05 | Nkk Corp | Aluminum alloy sheet excellent in corrosion resistance and press formability and its manufacture |
US5514228A (en) * | 1992-06-23 | 1996-05-07 | Kaiser Aluminum & Chemical Corporation | Method of manufacturing aluminum alloy sheet |
US5452827A (en) * | 1993-07-13 | 1995-09-26 | Eckert; C. Edward | Nozzle for continuous caster |
JPH07252613A (en) * | 1994-03-17 | 1995-10-03 | Kobe Steel Ltd | Aluminum-magnesium alloy sheet for forming at very low temperature |
US5571347A (en) * | 1994-04-07 | 1996-11-05 | Northwest Aluminum Company | High strength MG-SI type aluminum alloy |
US5527404A (en) * | 1994-07-05 | 1996-06-18 | Aluminum Company Of America | Vehicle frame components exhibiting enhanced energy absorption, an alloy and a method for their manufacture |
JPH0890091A (en) * | 1994-07-26 | 1996-04-09 | Nippon Steel Corp | Method for forming al-mg alloy sheet with less generation of stretcher strain mark |
US5582660A (en) * | 1994-12-22 | 1996-12-10 | Aluminum Company Of America | Highly formable aluminum alloy rolled sheet |
US5772804A (en) * | 1995-08-31 | 1998-06-30 | Kaiser Aluminum & Chemical Corporation | Method of producing aluminum alloys having superplastic properties |
JPH108176A (en) * | 1996-04-25 | 1998-01-13 | Nippon Light Metal Co Ltd | Aluminum alloy sheet low in proof stress and excellent in ultimate deformability and its production |
JP3398835B2 (en) * | 1997-09-11 | 2003-04-21 | 日本軽金属株式会社 | Automotive aluminum alloy sheet with excellent continuous resistance spot weldability |
JP2001032031A (en) * | 1999-07-22 | 2001-02-06 | Kobe Steel Ltd | Aluminum alloy sheet for structural material, excellent in stress corrosion cracking resistance |
JP4164206B2 (en) * | 1999-09-28 | 2008-10-15 | 株式会社神戸製鋼所 | High-strength, high-formability aluminum alloy sheet with excellent recrystallization grain refinement during high-temperature annealing |
EP1440177A1 (en) * | 2001-09-25 | 2004-07-28 | Assan Demir VE SAC Sanayi A.S. | Process of producing 5xxx series aluminum alloys with high mechanical properties through twin-roll casting |
US6898764B2 (en) * | 2002-04-29 | 2005-05-24 | International Business Machines Corporation | Method, system and program product for determining differences between an existing graphical user interface (GUI) mapping file and a current GUI |
JP4001059B2 (en) * | 2002-06-21 | 2007-10-31 | 日本軽金属株式会社 | Method for producing aluminum alloy sheet with excellent bake resistance |
US6811625B2 (en) * | 2002-10-17 | 2004-11-02 | General Motors Corporation | Method for processing of continuously cast aluminum sheet |
US6764559B2 (en) * | 2002-11-15 | 2004-07-20 | Commonwealth Industries, Inc. | Aluminum automotive frame members |
US7182825B2 (en) * | 2004-02-19 | 2007-02-27 | Alcoa Inc. | In-line method of making heat-treated and annealed aluminum alloy sheet |
CA2588046C (en) * | 2004-07-30 | 2014-09-30 | Nippon Light Metal Co., Ltd. | Aluminum alloy sheet and method for manufacturing the same |
-
2004
- 2004-08-27 US US10/926,704 patent/US20060042727A1/en not_active Abandoned
-
2005
- 2005-08-25 EP EP05791238A patent/EP1794338B1/en active Active
- 2005-08-25 JP JP2007530106A patent/JP5107039B2/en not_active Expired - Fee Related
- 2005-08-25 ES ES05791238T patent/ES2364275T3/en active Active
- 2005-08-25 MX MX2007002179A patent/MX2007002179A/en unknown
- 2005-08-25 KR KR1020077004464A patent/KR20070091600A/en not_active Application Discontinuation
- 2005-08-25 AT AT05791238T patent/ATE504371T1/en not_active IP Right Cessation
- 2005-08-25 DE DE602005027365T patent/DE602005027365D1/en active Active
- 2005-08-25 CA CA002578195A patent/CA2578195A1/en not_active Abandoned
- 2005-08-25 WO PCT/US2005/030194 patent/WO2006026330A2/en active Application Filing
- 2005-08-25 CN CN200580028822XA patent/CN101166845B/en not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5976279A (en) | 1997-06-04 | 1999-11-02 | Golden Aluminum Company | For heat treatable aluminum alloys and treatment process for making same |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2022223634A1 (en) | 2021-04-21 | 2022-10-27 | Constellium Neuf-Brisach | 5xxx aluminium sheets with high formabilty |
Also Published As
Publication number | Publication date |
---|---|
WO2006026330A3 (en) | 2008-01-03 |
CN101166845A (en) | 2008-04-23 |
JP5107039B2 (en) | 2012-12-26 |
EP1794338A2 (en) | 2007-06-13 |
MX2007002179A (en) | 2007-10-19 |
ES2364275T3 (en) | 2011-08-30 |
EP1794338B1 (en) | 2011-04-06 |
CN101166845B (en) | 2012-11-21 |
US20060042727A1 (en) | 2006-03-02 |
JP2008511756A (en) | 2008-04-17 |
DE602005027365D1 (en) | 2011-05-19 |
ATE504371T1 (en) | 2011-04-15 |
KR20070091600A (en) | 2007-09-11 |
EP1794338A4 (en) | 2008-08-06 |
CA2578195A1 (en) | 2006-03-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP1794338B1 (en) | Method for producing plural panel automotive members | |
US20080041501A1 (en) | Aluminum automotive heat shields | |
US6764559B2 (en) | Aluminum automotive frame members | |
US7182825B2 (en) | In-line method of making heat-treated and annealed aluminum alloy sheet | |
US6959476B2 (en) | Aluminum automotive drive shaft | |
US20050211350A1 (en) | In-line method of making T or O temper aluminum alloy sheets | |
KR20100108610A (en) | Method of producing a hot-rolled twip-steel and a twip-steel product produced thereby | |
CA3068470C (en) | High performance aluminum alloys having high amounts of recycled material and methods of making the same | |
EP0245464A1 (en) | Aluminum alloy vehicular member. | |
CA3105122C (en) | Highly formable, recycled aluminum alloys and methods of making the same | |
EP3662091A1 (en) | 6xxxx-series rolled sheet product with improved formability | |
US20080202646A1 (en) | Aluminum automotive structural members | |
CA2166615C (en) | Corrosion resistant aluminum alloy rolled sheet | |
US20090159160A1 (en) | Method for making high strength aluminum alloy sheet and products made by same | |
US6344096B1 (en) | Method of producing aluminum alloy sheet for automotive applications | |
US20040256079A1 (en) | Process of producing 5xxx series aluminum alloys with high mechanical, properties through twin-roll casting | |
JP3351947B2 (en) | Die-cast door panel and method of manufacturing the same | |
JP2024509070A (en) | Variants of high-strength 5XXX aluminum alloys and their preparation method |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A2 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KM KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NA NG NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SM SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A2 Designated state(s): BW GH GM KE LS MW MZ NA SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LT LU LV MC NL PL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: MX/a/2007/002179 Country of ref document: MX Ref document number: 2005791238 Country of ref document: EP Ref document number: 2007530106 Country of ref document: JP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 1020077004464 Country of ref document: KR Ref document number: 200580028822.X Country of ref document: CN Ref document number: 2578195 Country of ref document: CA |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
WWP | Wipo information: published in national office |
Ref document number: 2005791238 Country of ref document: EP |