WO2006022494A1 - Method for manufacturing a brake disk for vehicles - Google Patents

Method for manufacturing a brake disk for vehicles Download PDF

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Publication number
WO2006022494A1
WO2006022494A1 PCT/KR2005/002747 KR2005002747W WO2006022494A1 WO 2006022494 A1 WO2006022494 A1 WO 2006022494A1 KR 2005002747 W KR2005002747 W KR 2005002747W WO 2006022494 A1 WO2006022494 A1 WO 2006022494A1
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WO
WIPO (PCT)
Prior art keywords
cast iron
graphite cast
vehicles
spherical graphite
heat
Prior art date
Application number
PCT/KR2005/002747
Other languages
French (fr)
Inventor
Kwang Rae Lee
Original Assignee
Kwang Rae Lee
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Filing date
Publication date
Application filed by Kwang Rae Lee filed Critical Kwang Rae Lee
Publication of WO2006022494A1 publication Critical patent/WO2006022494A1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/04Cast-iron alloys containing spheroidal graphite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/26Methods of annealing
    • C21D1/32Soft annealing, e.g. spheroidising
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D5/00Heat treatments of cast-iron
    • C21D5/02Heat treatments of cast-iron improving the malleability of grey cast-iron
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/08Making cast-iron alloys
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D65/00Parts or details
    • F16D65/02Braking members; Mounting thereof
    • F16D65/12Discs; Drums for disc brakes
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/009Pearlite
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D2200/00Materials; Production methods therefor
    • F16D2200/0004Materials; Production methods therefor metallic
    • F16D2200/0008Ferro
    • F16D2200/0013Cast iron
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D2250/00Manufacturing; Assembly
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D2250/00Manufacturing; Assembly
    • F16D2250/0092Tools or machines for producing linings

Definitions

  • the present invention relates to the method for manufacturing a brake disk for vehicles, and more particularly to a method for manufacturing brake disks for vehicles, whereby the fuel expense economy is improved through the decrease in the weight of vehicle, the vehicle's life is extended through the increase in wear resistance and the environmental pollution is prevented.
  • the brake disk for vehicle which is a braking means for decelerating and stopping a vehicle through the friction with a brake pad
  • the brake disk for vehicle is manufactured based on ordinary cast iron system including Fe, C, Si, Mn, P and S.
  • ordinary cast iron system including Fe, C, Si, Mn, P and S.
  • defects can result during heat treatments due to severe segregations and ununiform composition, so that the heat treatment is generally avoided and the chrome is added before use, instead of heat treatment, in order to improve the resistance to heat and wear.
  • such an ordinary grey cast iron has the advantage of low production cost due to the easy manufacturing process and the exemption of heat treatment but likewise has the problem of incapability to make the product light-weighted because the thickness of the product can not but be large in order to compensate for the weakened physical property including low toughness and low impact strength.
  • the above-described grey cast iron has the limit in extending the life of product due to the increased wear during use, because the heat treatment is ordinarily not conducted and the additive like chrome is used to increase the hardness in the production steps.
  • the chrome component which is added to the material to increase the heat and wear resistances of brake disks made of grey cast iron and which is plated on the surface of disks to enhance the aesthetic effect of the products, is also associated with the environmental pollution because the Cr component can emit to the atmosphere during the course of friction with brake pads at the time of braking.
  • the present invention was created to resolve the above-described problems.
  • the object of the invention is to provide a method for manufacturing brake disks for vehicles, wherein spherical graphite cast iron is used following heat treatment in manu- factoring brake disks for vehicles so as to realize the light-weight of products to thereby improve the fuel economy for vehicles, the life of products is prolonged due to the increased wear resistance and the environmental pollution is also prevented because the predetermined resistance to heat and wear is provided despite the absence of the chrome.
  • a method for manufacturing brake disks for vehicles which comprises the steps of: heating spherical graphite cast iron in the form of a brake disk for vehicle in a non-oxidizing atmosphere so that the core of the cast iron material reaches 850 ⁇ 950°C, said spherical graphite cast iron including 3.0 ⁇ 3.8 wt.% of C, 2.0 ⁇ 2.8 wt.% of Si, 0.1 ⁇ 0.4 wt.% of Mn, 0.01 ⁇ 0.08 wt.% of P, 0.001 ⁇ 0.02 wt.% of S and 0.01 ⁇ 0.05 wt.% of Mg and optionally including either all or two out of the three components of 0.15 ⁇ 0.4 wt.% of Mo, 0.5 ⁇ 1.2 wt.% of Cu and 0.6 ⁇ 2.0 wt.% of Ni, and the balance of Fe as well as inevitable impurity, said spherical graphite cast iron in the form of a brake disk for vehicle in a non-
  • the method for man ⁇ ufacturing brake disks for vehicles wherein prior to the above-described heat treatment, the core of the above-described material is heated to 700 ⁇ 950 °C and maintained at the same temperature for 10 min. ⁇ 1 hr. followed by air-cooling or furnace-cooling.
  • the method for manufacturing brake disks for vehicles wherein after the above-described heat treatment, the above-described material is machined to form surface of contact with brake pads, surface for mounting on wheel and holes for receiving bolts, heated so that the core of material reaches 300 ⁇ 600°C and maintained at the same temperature for 10 min. ⁇ 1 hr. and thereafter the material is air-cooled or water-cooled.
  • FIG. 1 shows the perspective view of a brake disk for vehicle according to the invention.
  • Fig. 2 shows the diagram illustrating the austempering heat-treating cycle according to a preferred embodiment of the invention
  • Fig. 3 shows the diagram illustrating the heat-treating cycle for the material before the austempering heat-treating of the above-described embodiment
  • Fig. 4 shows the diagram illustrating the heat-treating cycle for the machined workpiece after the austempering heat-treating of the above-described embodiment.
  • FIG. 1 shows the perspective view of a brake disk for vehicle according to the invention
  • Fig. 2 shows the diagram illustrating the austempering heat-treating cycle according to a preferred embodiment of the invention
  • Fig. 3 shows the diagram il ⁇ lustrating the heat-treating cycle for the material before the austempering heat-treating of the above-described embodiment
  • Fig. 4 shows the diagram illustrating the heat- treating cycle for the machined workpiece after the austempering heat-treating of the above-described embodiment.
  • the present invention includes roughly a manufacturing process in which the mass of scrap iron and recovered iron mixed with carbon additive is charged into a low-frequency induction furnace, heated to be molted bath, this molted bath is discharged to a container, Fe-Si-Mg are inoculated in the container for a spherizing treatment, and the treated molted iron mass is injected to a sand mold having the shape of a brake disk and left to be cooled, resulting in spherical graphite cast iron; then, an austempering heat-treatment for providing the disk-formed spherical graphite cast iron with mechanical properties such as the heat resistance, wear resistance, elongation and impact strength; optionally an annealing heat-treatment as a pre-treatment before the austempering treatment to relieve the internal stress in cast structures; a machining operation for giving the brake disk the finished shape; and finally an after-treatment for removing the stress generated during the machining.
  • C should preferably range from 3.0 to 3.8 wt.%.
  • C is below 3.0 Wt.%, the chance of segregating in the course of the graphite aggregating to balls is high.
  • 3.8 wt.% is exceeded, the elongation of the material tends to decrease after the heat treatment.
  • Mn at the content of 0.1 ⁇ 0.4 wt.% acts to promote bainitization during the heat treatment.
  • Mg is usually contained at 0.01 ⁇ 0.05 wt.% and should be used at over 0.01 wt.% at least in order to spherize the graphite, but makes the material brittle and unable to obtain the predetermined elongation rate, when 0.05 wt.% is exceeded.
  • Mo contained at 0.15 ⁇ 0.4 wt.% acts to regulate the cooling speed during the heat-treatment, that is, to cause the formation of uniform structures up to the core of the product with large thickness difference and further acts to suppress the structure variance due to the cooling speed in the course of generating the bainite so as to achieve a uniform structure.
  • the content of Mo is below 0.15 wt.%, structure becomes ununiform during the cooling. If the content of Mo exceeds 0.4 wt.%, however, segregation tends to be caused and a long retaining hours at a high temperature are required for graphitization.
  • Cu and Ni have respectively the same effect as Mo and so act to uniformly distribute the spherized grains of graphite and improve the tensile property, and par ⁇ ticularly increase the share of pearlites to thereby improve the impact strength via heat treating step.
  • Cu and Ni are below 0.5 wt.% and 0.6 wt.% respectively, the effect of heat treatment vanishes.
  • the added quantity is more than required, only manufacturing cost would rise, and therefore Cu and Ni should be kept below 1.2 wt.% and 2.0 wt.% respectively.
  • all of Cu, Ni and Mo may be added together, only two components can be added for the reason of reducing the casting cost.
  • the contents given for Si and P are those as applied for ordinary cast iron alloys.
  • the ferrite structure and the pearlite structure are distinctively formed depending on the cooling speed of spherized graphite cast iron, wherein less than 60% of pearlite structures would lead to an ununiform structure of the product after the heat treatment, decreasing the effect of the latter so as to cause the irregularity of tensile strength and elongation property, and more than 98% of pearlite structures, on the other hand, would impair the increase of elongation after the heat treatment, obstructing the procurement of product with desired properties.
  • the spherization rate and the number of graphites are determined in accordance with the added amount of inoculants and the number of inoculations for spherization in the state of cast iron ware, wherein in the case of less than 70% of sperization rate, partial segregation is generated after the heat treatment to cause an un- uniformity of hardness, so that a long time of graphitization at a high temperature is required, which undesirably increases the heat treating cost.
  • the elongation after the heat treatment is improved as the number of graphites within structures is increased, wherein the elongation and the impact strength are abruptly dropped after the heat treatment, if the umber is less than 100/mm .
  • compositions and the hardness before heat treatment for spherical graphite cast iron products having the composition and metal structures as described in the above according to the invention and for a conventional grey cast iron product are given in Table 1 for comparison. It is found from the table that the spherical graphite cast iron products according to the invention, in contrast to the conventional grey cast iron product, include Mg used as the inoculant for spherization but does not include Cr, a known hardness improving additive, in respect of the composition, and have relatively higher hardness even in the state before heat treating in respect of the hardness and besides the inventive cast iron products are excellent in the strength, wear resistance, heat resistance, oxidation resistance etc., but on the other hand, the inventive cast iron products are poor in castability and so not applicable to the products with unusually complicated shapes and are so sensitive to the thickness as to cause generation of chills on thinner areas, requiring a heat treating operation to follow after the casting.
  • Example 1 Austempering Heat-Treatment
  • the spherical graphite cast iron products as given above were subjected to austempering heat-treatment with varying temperature condition.
  • the austempering heat-treatment refers to the heat treatment wherein after austenizing treatment for transforming to the austenizing structure the mixed structure of pearlite and ferrite rep ⁇ resenting the structure of material for casting after heating the latter, tempering treatment is conducted, in which the treated austenite structure is cooled and maintained in an oil furnace maintained at a predetermined temperature to be transformed to bainite structure.
  • the most important element in the above- described austempering heat-treatment is the tempering temperature at which the austenite structure is transformed to the bainite structure on the ground that the bainite structure exhibits the excellence in all physical properties including the strength, hardness, elongation, impact value, and wear resistance.
  • the products fulfilling the predetermined physical properties was produced, by heating spherical graphite cast iron products in an oxygen-free furnace until the core of the material reaches 850 ⁇ 950°C and maintaining for 10 min. ⁇ 2 hr. after the foregoing temperature is reached to complete the austenizing treatment, then maintaining the cast iron articles in a low-temperature salt bath furnace or oil furnace maintained at 300 ⁇ 420°C and kept in agitation for 1 ⁇ 2 hr. in order to conduct the tempering treatment, and finally causing the cast iron articles to be air-cooled or water- cooled. (Refer to Fig. 2).
  • the retaining or maintaining periods were varied somewhat depending on the quantities of the products charged into the heat-treating furnace.
  • the annealing heat treatment as indicated in Fig. 3 refers to the pre-treatment conducted before the austempering heat-treatment of the spherical graphite cast iron.
  • the brake disks for vehicles according to the invention are round flat circular disks as shown in Fig. 1.
  • the spherical graphite cast iron as the raw material of brake disks is of cast structures, which were formed after the hot molted bath was cooled, and therefore has considerable internal stress generated in the course of heating and cooling. Accordingly, in the case of directly austempering heat-treating the spherical graphite cast iron product having been cast, thermal stains would tend to be caused during heating due to the geometric improperness and internal stresses so as to disfavor after-machining. Further, In that case, the temperature of brake disks would rise due to the friction with brake pads at the time of braking a vehicle, with the result that the frictional braking force would fall.
  • the thermal strain of products during austempering heat treatment is minimized to facilitate the after-machining and the thermal strain is prevented even under the friction heat of brake disks with brake pads when braking vehicles, whereby frictional braking power can be preserved.
  • the heat treatment for removing machining stress as depicted in Fig. 4 refers to the after-treatment performed after the austempering heat treatment and machining of the spherical graphite cast iron article are finished.
  • the brake disk for vehicle according to the invention is subjected to the machining operation onto contacting surfaces 2 with brake pads 1, an assembling surface 3 on a wheel and many through-holes for bolts 4, covering a considerably wide area, so that there remains considerate machining stress on the machined surfaces, which residual stress causes the product to minutely distort with time, or causes so-called age-strain.
  • the brake disks so age-strained undergo the decrease in their contacting surfaces with brake pads to cause the curtailment of braking capability.
  • the machining stress relieving heat treatment wherein the brake disk products for vehicles, on which machining has been completed, are heated so that the core part reaches 300 ⁇ 600°C and subsequently maintained at that temperature for 10 min. ⁇ 1 hr. and then air-cooled or water-cooled.
  • the retaining or maintaining periods may vary somewhat depending on the quantities of the products charged into the heat-treating furnace.
  • the effect of reducing the weight of vehicle is realized due to the decreased thickness of product and nevertheless the mechanical properties like wear resistance, toughness and impact strength are excellent so as to extend the service life of the product, by using spherical graphite cast iron after heat treating for manufacturing the brake disk for vehicle, in comparison to the con ⁇ ventional grey cast iron product manufactured with a large thickness to compensate for insufficient toughness and weak impact strength.
  • one brake disk according to the invention is lighter than the conventional one by 3 ⁇ 5 kg and so the reduction in weight will amount to 6 ⁇ 10 kg when both wheels are mounted with the brake disks according to the invention, whereby the effect of reducing the vehicle weight equivalent to 60 - 100 kg would be achieved, in conjunction with evident fuel economy, on the ground that the reduction in the weight of the wheels as the final power transmitting means in a vehicle corresponds to the weight reduction as increased by 10 times for the vehicle in the practical effect, e.g. 1 kg of reduction in the weight of wheels will correspond to 10 kg of reduction in the weight of vehicle as a whole.
  • the spherical graphite cast iron according to the invention has the advantage of preventing the environmental pollution due to Cr, because the additives like Cr for improving the hardening ability are not required due to the excellent mechanical properties through heat treatment such as wear resistance, toughness and impact strength, and the Cr plating for appearance is not needed due to the sufficiently elegant appearance compared to the grey cast iron, in contrast to the conventional grey cast iron, wherein the Cr component, used as additive for casting to improve the resistance to heat and wear due to lacking heat treatment and used as plating for aesthetic surface of the product, is emitted to the atmosphere due to friction with brake pads at the time of braking vehicles to cause the air pollution.
  • the thermal strain of products during the austempering heat treatment is minimized according to the invention to facilitate the after-machining, by virtue of the annealing treatment as the pre-treatment prior to the austempering treatment to relieve the internal stress in the cast structures, and thermal strain due to the frictional heat generated between brake disks and brake pads at the time of braking is prevented from taking place so as to preserve the braking capability.

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  • Mechanical Engineering (AREA)
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  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
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Abstract

The present invention relates to a method for manufacturing brake disks for vehicles, whereby the fuel expense economy is improved through the decrease in the weight of vehicle, the vehicle's life is extended through the increase in wear resistance and the environmental pollution is prevented.

Description

Description
METHOD FOR MANUFACTURING A BRAKE DISK FOR
VEHICLES
Technical Field
[1] FIELD OF THE INVENTION
[2] The present invention relates to the method for manufacturing a brake disk for vehicles, and more particularly to a method for manufacturing brake disks for vehicles, whereby the fuel expense economy is improved through the decrease in the weight of vehicle, the vehicle's life is extended through the increase in wear resistance and the environmental pollution is prevented.
[3]
[4] BACKGROUND OF THE INVENTION
[5] Generally the brake disk for vehicle, which is a braking means for decelerating and stopping a vehicle through the friction with a brake pad, is manufactured based on ordinary cast iron system including Fe, C, Si, Mn, P and S. However, defects can result during heat treatments due to severe segregations and ununiform composition, so that the heat treatment is generally avoided and the chrome is added before use, instead of heat treatment, in order to improve the resistance to heat and wear.
[6] Incidentally, such an ordinary grey cast iron has the advantage of low production cost due to the easy manufacturing process and the exemption of heat treatment but likewise has the problem of incapability to make the product light-weighted because the thickness of the product can not but be large in order to compensate for the weakened physical property including low toughness and low impact strength. Further, the above-described grey cast iron has the limit in extending the life of product due to the increased wear during use, because the heat treatment is ordinarily not conducted and the additive like chrome is used to increase the hardness in the production steps.
[7] Furthermore, the chrome component, which is added to the material to increase the heat and wear resistances of brake disks made of grey cast iron and which is plated on the surface of disks to enhance the aesthetic effect of the products, is also associated with the environmental pollution because the Cr component can emit to the atmosphere during the course of friction with brake pads at the time of braking.
[8]
[9] SUMMARY OF THE INVENTION
[10] The present invention was created to resolve the above-described problems. Thus, the object of the invention is to provide a method for manufacturing brake disks for vehicles, wherein spherical graphite cast iron is used following heat treatment in manu- factoring brake disks for vehicles so as to realize the light-weight of products to thereby improve the fuel economy for vehicles, the life of products is prolonged due to the increased wear resistance and the environmental pollution is also prevented because the predetermined resistance to heat and wear is provided despite the absence of the chrome.
[11] The above-described object is achieved according to a preferred aspect of the invention by a method for manufacturing brake disks for vehicles, which comprises the steps of: heating spherical graphite cast iron in the form of a brake disk for vehicle in a non-oxidizing atmosphere so that the core of the cast iron material reaches 850~950°C, said spherical graphite cast iron including 3.0 ~ 3.8 wt.% of C, 2.0 ~ 2.8 wt.% of Si, 0.1 ~ 0.4 wt.% of Mn, 0.01 ~ 0.08 wt.% of P, 0.001 ~ 0.02 wt.% of S and 0.01 ~ 0.05 wt.% of Mg and optionally including either all or two out of the three components of 0.15 ~ 0.4 wt.% of Mo, 0.5 ~ 1.2 wt.% of Cu and 0.6 ~ 2.0 wt.% of Ni, and the balance of Fe as well as inevitable impurity, said spherical graphite cast iron consisting of 2 ~ 40 % of ferrite structure and 60 ~ 98 % of pearlite structure, said spherical graphite cast iron having over 70 % of spherizing rate, said spherical graphite cast iron having the number of graphites at over 100/mm ; after maintaining for 10 min. ~ 2 hr. after said temperature of 850~950°C is reached, maintaining for 1 ~ 2 hr. in a low- temperature salt bath furnace or oil furnace maintained at 300 ~ 420 °C and stirred; and subjecting the brake disk of graphite cast iron so treated to air-cooling or water- cooling.
[12] According to another aspect of the invention, there is provided the method for man¬ ufacturing brake disks for vehicles, wherein prior to the above-described heat treatment, the core of the above-described material is heated to 700 ~ 950 °C and maintained at the same temperature for 10 min. ~ 1 hr. followed by air-cooling or furnace-cooling.
[13] According to still other aspect of the invention, there is provided the method for manufacturing brake disks for vehicles, wherein after the above-described heat treatment, the above-described material is machined to form surface of contact with brake pads, surface for mounting on wheel and holes for receiving bolts, heated so that the core of material reaches 300 ~ 600°C and maintained at the same temperature for 10 min. ~ 1 hr. and thereafter the material is air-cooled or water-cooled.
[14]
[15] BRIEF DESCRIPTION OF THE DRAWINGS
[16] Fig. 1 shows the perspective view of a brake disk for vehicle according to the invention.
[17] Fig. 2 shows the diagram illustrating the austempering heat-treating cycle according to a preferred embodiment of the invention [18] Fig. 3 shows the diagram illustrating the heat-treating cycle for the material before the austempering heat-treating of the above-described embodiment
[19] Fig. 4 shows the diagram illustrating the heat-treating cycle for the machined workpiece after the austempering heat-treating of the above-described embodiment.
[20]
[21] DETAILED DESCRIPTION OF THE INVENTION
[22] A preferred embodiment of the invention is described in detail below by referring to the accompanying drawings.
[23] Fig. 1 shows the perspective view of a brake disk for vehicle according to the invention, Fig. 2 shows the diagram illustrating the austempering heat-treating cycle according to a preferred embodiment of the invention, Fig. 3 shows the diagram il¬ lustrating the heat-treating cycle for the material before the austempering heat-treating of the above-described embodiment, and Fig. 4 shows the diagram illustrating the heat- treating cycle for the machined workpiece after the austempering heat-treating of the above-described embodiment.
[24] Referring to these figures, the present invention includes roughly a manufacturing process in which the mass of scrap iron and recovered iron mixed with carbon additive is charged into a low-frequency induction furnace, heated to be molted bath, this molted bath is discharged to a container, Fe-Si-Mg are inoculated in the container for a spherizing treatment, and the treated molted iron mass is injected to a sand mold having the shape of a brake disk and left to be cooled, resulting in spherical graphite cast iron; then, an austempering heat-treatment for providing the disk-formed spherical graphite cast iron with mechanical properties such as the heat resistance, wear resistance, elongation and impact strength; optionally an annealing heat-treatment as a pre-treatment before the austempering treatment to relieve the internal stress in cast structures; a machining operation for giving the brake disk the finished shape; and finally an after-treatment for removing the stress generated during the machining.
[25] C should preferably range from 3.0 to 3.8 wt.%. When C is below 3.0 Wt.%, the chance of segregating in the course of the graphite aggregating to balls is high. On the other hand, when 3.8 wt.% is exceeded, the elongation of the material tends to decrease after the heat treatment. Mn at the content of 0.1 ~ 0.4 wt.% acts to promote bainitization during the heat treatment. When the content of Mn is below 0.1 wt.%, the bainitization is decreased during heat treatment, whereas the elongation and impact resistance are decreased due to brittleness, because the local hardening is caused and the uniform structure is not formed because of the segregation, when the content exceeds 0.4 wt.%. Although S is desirably contained at 0.001 ~ 0.02 wt.%, the added quantity of Mn gets decreased as the quantity of S increases.
[26] Mg is usually contained at 0.01 ~ 0.05 wt.% and should be used at over 0.01 wt.% at least in order to spherize the graphite, but makes the material brittle and unable to obtain the predetermined elongation rate, when 0.05 wt.% is exceeded. Mo contained at 0.15 ~ 0.4 wt.% acts to regulate the cooling speed during the heat-treatment, that is, to cause the formation of uniform structures up to the core of the product with large thickness difference and further acts to suppress the structure variance due to the cooling speed in the course of generating the bainite so as to achieve a uniform structure. When the content of Mo is below 0.15 wt.%, structure becomes ununiform during the cooling. If the content of Mo exceeds 0.4 wt.%, however, segregation tends to be caused and a long retaining hours at a high temperature are required for graphitization.
[27] Cu and Ni have respectively the same effect as Mo and so act to uniformly distribute the spherized grains of graphite and improve the tensile property, and par¬ ticularly increase the share of pearlites to thereby improve the impact strength via heat treating step. However, when Cu and Ni are below 0.5 wt.% and 0.6 wt.% respectively, the effect of heat treatment vanishes. On the other hand, when the added quantity is more than required, only manufacturing cost would rise, and therefore Cu and Ni should be kept below 1.2 wt.% and 2.0 wt.% respectively. Although all of Cu, Ni and Mo may be added together, only two components can be added for the reason of reducing the casting cost. The contents given for Si and P are those as applied for ordinary cast iron alloys.
[28] Now, regarding the reason for the above-described prescription for the metal structures of spherical graphite cast iron, the ferrite structure and the pearlite structure are distinctively formed depending on the cooling speed of spherized graphite cast iron, wherein less than 60% of pearlite structures would lead to an ununiform structure of the product after the heat treatment, decreasing the effect of the latter so as to cause the irregularity of tensile strength and elongation property, and more than 98% of pearlite structures, on the other hand, would impair the increase of elongation after the heat treatment, obstructing the procurement of product with desired properties.
[29] In addition, the spherization rate and the number of graphites are determined in accordance with the added amount of inoculants and the number of inoculations for spherization in the state of cast iron ware, wherein in the case of less than 70% of sperization rate, partial segregation is generated after the heat treatment to cause an un- uniformity of hardness, so that a long time of graphitization at a high temperature is required, which undesirably increases the heat treating cost. Further, the elongation after the heat treatment is improved as the number of graphites within structures is increased, wherein the elongation and the impact strength are abruptly dropped after the heat treatment, if the umber is less than 100/mm .
[30] The compositions and the hardness before heat treatment for spherical graphite cast iron products having the composition and metal structures as described in the above according to the invention and for a conventional grey cast iron product are given in Table 1 for comparison. It is found from the table that the spherical graphite cast iron products according to the invention, in contrast to the conventional grey cast iron product, include Mg used as the inoculant for spherization but does not include Cr, a known hardness improving additive, in respect of the composition, and have relatively higher hardness even in the state before heat treating in respect of the hardness and besides the inventive cast iron products are excellent in the strength, wear resistance, heat resistance, oxidation resistance etc., but on the other hand, the inventive cast iron products are poor in castability and so not applicable to the products with unusually complicated shapes and are so sensitive to the thickness as to cause generation of chills on thinner areas, requiring a heat treating operation to follow after the casting.
[31] Table 1 Comparison of chemical composition(wt.%) and hardness(HB)
Figure imgf000006_0001
[32] [33] Example 1 : Austempering Heat-Treatment [34] The spherical graphite cast iron products as given above were subjected to austempering heat-treatment with varying temperature condition. The austempering heat-treatment refers to the heat treatment wherein after austenizing treatment for transforming to the austenizing structure the mixed structure of pearlite and ferrite rep¬ resenting the structure of material for casting after heating the latter, tempering treatment is conducted, in which the treated austenite structure is cooled and maintained in an oil furnace maintained at a predetermined temperature to be transformed to bainite structure. Incidentally, the most important element in the above- described austempering heat-treatment is the tempering temperature at which the austenite structure is transformed to the bainite structure on the ground that the bainite structure exhibits the excellence in all physical properties including the strength, hardness, elongation, impact value, and wear resistance.
[35] Accordingly, a number of spherical graphite cast iron products as listed in Table 1 were caused to be heated to the same austenizing temperature but then subjected to different tempering temperatures to get the result as shown in the following Table 2. Thus, it was found, as appreciable from the Table, that the product with the most ideal mechanical properties fulfilling all the designated physical property values is the one tempering-treated at 300 ~ 4200C.
[36] Thus, the products fulfilling the predetermined physical properties was produced, by heating spherical graphite cast iron products in an oxygen-free furnace until the core of the material reaches 850 ~ 950°C and maintaining for 10 min. ~ 2 hr. after the foregoing temperature is reached to complete the austenizing treatment, then maintaining the cast iron articles in a low-temperature salt bath furnace or oil furnace maintained at 300 ~ 420°C and kept in agitation for 1 ~ 2 hr. in order to conduct the tempering treatment, and finally causing the cast iron articles to be air-cooled or water- cooled. (Refer to Fig. 2). Here, the retaining or maintaining periods were varied somewhat depending on the quantities of the products charged into the heat-treating furnace.
[37] Table 2
Comparison of mechanical properties depending on tempering temperatures.
Figure imgf000007_0001
Figure imgf000008_0001
[38] [39] The annealing heat treatment as indicated in Fig. 3 refers to the pre-treatment conducted before the austempering heat-treatment of the spherical graphite cast iron. The brake disks for vehicles according to the invention are round flat circular disks as shown in Fig. 1. The spherical graphite cast iron as the raw material of brake disks is of cast structures, which were formed after the hot molted bath was cooled, and therefore has considerable internal stress generated in the course of heating and cooling. Accordingly, in the case of directly austempering heat-treating the spherical graphite cast iron product having been cast, thermal stains would tend to be caused during heating due to the geometric improperness and internal stresses so as to disfavor after-machining. Further, In that case, the temperature of brake disks would rise due to the friction with brake pads at the time of braking a vehicle, with the result that the frictional braking force would fall.
[40] Therefore, in order to resolve such a problem, there is conducted an annealing heat treatment, wherein the brake disks for vehicles of spherical graphite cast iron are heated so that the core part reaches 700 - 950°C before the austempering heat treatment and maintained at that temperature for 10 min. - 1 hr., followed by air- cooling or furnace-cooling. (See Fig. 3). Here, the retaining or maintaining periods may be varied somewhat depending on the quantities of the products charged into the heat-treating furnace. By conducting the annealing process as the pre-treatment for relieving the internal stress of cast structures, the thermal strain of products during austempering heat treatment is minimized to facilitate the after-machining and the thermal strain is prevented even under the friction heat of brake disks with brake pads when braking vehicles, whereby frictional braking power can be preserved.
[41] The heat treatment for removing machining stress as depicted in Fig. 4 refers to the after-treatment performed after the austempering heat treatment and machining of the spherical graphite cast iron article are finished. As shown in Fig. 1, the brake disk for vehicle according to the invention is subjected to the machining operation onto contacting surfaces 2 with brake pads 1, an assembling surface 3 on a wheel and many through-holes for bolts 4, covering a considerably wide area, so that there remains considerate machining stress on the machined surfaces, which residual stress causes the product to minutely distort with time, or causes so-called age-strain. The brake disks so age-strained undergo the decrease in their contacting surfaces with brake pads to cause the curtailment of braking capability. Therefore, in order to resolve such a problem, there is conducted the machining stress relieving heat treatment, wherein the brake disk products for vehicles, on which machining has been completed, are heated so that the core part reaches 300 ~ 600°C and subsequently maintained at that temperature for 10 min. ~ 1 hr. and then air-cooled or water-cooled. (See Fig. 4). Here, the retaining or maintaining periods may vary somewhat depending on the quantities of the products charged into the heat-treating furnace. Through this after-treatment for removing machining stress from the products, the strain of the products after the machining operation is minimized and the effective friction area is preserved, preventi ng the reduction in braking capability.
[42]
[43] INDUSTRIAL APPLICABILITY
[44] As described above, according to the invention, the effect of reducing the weight of vehicle is realized due to the decreased thickness of product and nevertheless the mechanical properties like wear resistance, toughness and impact strength are excellent so as to extend the service life of the product, by using spherical graphite cast iron after heat treating for manufacturing the brake disk for vehicle, in comparison to the con¬ ventional grey cast iron product manufactured with a large thickness to compensate for insufficient toughness and weak impact strength.
[45] Particularly, referring to the effect of reducing the vehicle weight, one brake disk according to the invention is lighter than the conventional one by 3 ~ 5 kg and so the reduction in weight will amount to 6 ~ 10 kg when both wheels are mounted with the brake disks according to the invention, whereby the effect of reducing the vehicle weight equivalent to 60 - 100 kg would be achieved, in conjunction with evident fuel economy, on the ground that the reduction in the weight of the wheels as the final power transmitting means in a vehicle corresponds to the weight reduction as increased by 10 times for the vehicle in the practical effect, e.g. 1 kg of reduction in the weight of wheels will correspond to 10 kg of reduction in the weight of vehicle as a whole.
[46] Further, the spherical graphite cast iron according to the invention has the advantage of preventing the environmental pollution due to Cr, because the additives like Cr for improving the hardening ability are not required due to the excellent mechanical properties through heat treatment such as wear resistance, toughness and impact strength, and the Cr plating for appearance is not needed due to the sufficiently elegant appearance compared to the grey cast iron, in contrast to the conventional grey cast iron, wherein the Cr component, used as additive for casting to improve the resistance to heat and wear due to lacking heat treatment and used as plating for aesthetic surface of the product, is emitted to the atmosphere due to friction with brake pads at the time of braking vehicles to cause the air pollution.
[47] In addition, the thermal strain of products during the austempering heat treatment is minimized according to the invention to facilitate the after-machining, by virtue of the annealing treatment as the pre-treatment prior to the austempering treatment to relieve the internal stress in the cast structures, and thermal strain due to the frictional heat generated between brake disks and brake pads at the time of braking is prevented from taking place so as to preserve the braking capability.
[48] Furthermore, the strain of products after the machining is minimized as well so as to maintain the frictional area with braking pads and thereby prevent the braking capability from falling, by virtue of the after-machining following the perfection of machining on brake disks for vehicles for removing the machining stress from the products.

Claims

Claims
[1] a method for manufacturing brake disks for vehicles, which comprises the steps of: heating spherical graphite cast iron in the form of a brake disk for vehicle in a non-oxidizing atmosphere so that the core of the cast iron material reaches 850~950°C, said spherical graphite cast iron including 3.0 ~ 3.8 wt.% of C, 2.0 ~ 2.8 wt.% of Si, 0.1 ~ 0.4 wt.% of Mn, 0.01 ~ 0.08 wt.% of P, 0.001 ~ 0.02 wt.% of S and 0.01 ~ 0.05 wt.% of Mg and optionally including either all or two out of the three components of 0.15 ~ 0.4 wt.% of Mo, 0.5 ~ 1.2 wt.% of Cu and 0.6 ~ 2.0 wt.% of Ni, and the balance of Fe as well as inevitable impurity, said spherical graphite cast iron consisting of 2 ~ 40 % of ferrite structure and 60 ~ 98 % of pearlite structure, said spherical graphite cast iron having over 70 % of spherizing rate, said spherical graphite cast iron having the number of graphites at over 100/mm2; after maintaining for 10 min. ~ 2 hr. after said temperature of 850~950°C is reached, maintaining for 1 ~ 2 hr. in a low-temperature salt bath furnace or oil furnace maintained at 300 ~ 420 °C and stirred; and subjecting the brake disk of graphite cast iron so treated to air-cooling or water-cooling.
[2] The method for manufacturing brake disks for vehicles of claim 1, wherein prior to the above-described heat treatment, the core of the above-described material is heated to 700 ~ 950 °C and maintained at the same temperature for 10 min. ~ 1 hr. followed by air-cooling or furnace-cooling.
[3] The method for manufacturing brake disks for vehicles of claim 1, wherein after the above-described heat treatment, the above-described material is machined to form surface of contact with brake pads, surface for mounting on wheel and holes for receiving bolts, heated so that the core of material reaches 300 ~ 600°C and maintained at the same temperature for 10 min. ~ 1 hr. and thereafter the material is air-cooled or water-cooled.
PCT/KR2005/002747 2004-08-23 2005-08-19 Method for manufacturing a brake disk for vehicles WO2006022494A1 (en)

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WO2013026124A1 (en) * 2011-08-17 2013-02-28 Mahle Metal Leve S/A Cylinder liner and cast iron alloy
CN110952031A (en) * 2019-11-15 2020-04-03 中国第一汽车股份有限公司 Isothermal quenching nodular cast iron and preparation method and application thereof
CN111349844A (en) * 2020-04-29 2020-06-30 含山县朝霞铸造有限公司 Pouring method of nodular cast iron hub
US11441204B2 (en) * 2018-12-11 2022-09-13 Hyundai Motor Company Method of manufacturing cam piece for continuously variable valve duration and cam piece manufactured therefrom

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KR101996997B1 (en) * 2017-06-07 2019-07-10 효림산업 주식회사 Manufacturing method for end yoke of propeller shaft universal joini of rear wheel drive vehicles

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Publication number Priority date Publication date Assignee Title
WO2013026124A1 (en) * 2011-08-17 2013-02-28 Mahle Metal Leve S/A Cylinder liner and cast iron alloy
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US11441204B2 (en) * 2018-12-11 2022-09-13 Hyundai Motor Company Method of manufacturing cam piece for continuously variable valve duration and cam piece manufactured therefrom
CN110952031A (en) * 2019-11-15 2020-04-03 中国第一汽车股份有限公司 Isothermal quenching nodular cast iron and preparation method and application thereof
CN111349844A (en) * 2020-04-29 2020-06-30 含山县朝霞铸造有限公司 Pouring method of nodular cast iron hub
CN111349844B (en) * 2020-04-29 2021-03-05 含山县朝霞铸造有限公司 Pouring method of nodular cast iron hub

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