WO2005072154A2 - Vertical gate cmos with lithography-independent gate length - Google Patents

Vertical gate cmos with lithography-independent gate length Download PDF

Info

Publication number
WO2005072154A2
WO2005072154A2 PCT/US2005/001313 US2005001313W WO2005072154A2 WO 2005072154 A2 WO2005072154 A2 WO 2005072154A2 US 2005001313 W US2005001313 W US 2005001313W WO 2005072154 A2 WO2005072154 A2 WO 2005072154A2
Authority
WO
WIPO (PCT)
Prior art keywords
dielectric
polysilicon
spacer
layer
region
Prior art date
Application number
PCT/US2005/001313
Other languages
French (fr)
Other versions
WO2005072154A3 (en
Inventor
Bohumil Lojek
Original Assignee
Atmel Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US10/761,876 external-priority patent/US6846709B1/en
Application filed by Atmel Corporation filed Critical Atmel Corporation
Priority to EP05705754A priority Critical patent/EP1709680A4/en
Publication of WO2005072154A2 publication Critical patent/WO2005072154A2/en
Publication of WO2005072154A3 publication Critical patent/WO2005072154A3/en

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/786Thin film transistors, i.e. transistors with a channel being at least partly a thin film
    • H01L29/78642Vertical transistors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
    • H01L21/28008Making conductor-insulator-semiconductor electrodes
    • H01L21/28017Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon
    • H01L21/28026Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor
    • H01L21/28123Lithography-related aspects, e.g. sub-lithography lengths; Isolation-related aspects, e.g. to solve problems arising at the crossing with the side of the device isolation; Planarisation aspects
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/77Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate
    • H01L21/78Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices
    • H01L21/82Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components
    • H01L21/822Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components the substrate being a semiconductor, using silicon technology
    • H01L21/8232Field-effect technology
    • H01L21/8234MIS technology, i.e. integration processes of field effect transistors of the conductor-insulator-semiconductor type
    • H01L21/8238Complementary field-effect transistors, e.g. CMOS
    • H01L21/823885Complementary field-effect transistors, e.g. CMOS with a particular manufacturing method of vertical transistor structures, i.e. with channel vertical to the substrate surface
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66234Bipolar junction transistors [BJT]
    • H01L29/66272Silicon vertical transistors
    • H01L29/66287Silicon vertical transistors with a single crystalline emitter, collector or base including extrinsic, link or graft base formed on the silicon substrate, e.g. by epitaxy, recrystallisation, after insulating device isolation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66477Unipolar field-effect transistors with an insulated gate, i.e. MISFET
    • H01L29/66666Vertical transistors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/70Bipolar devices
    • H01L29/72Transistor-type devices, i.e. able to continuously respond to applied control signals
    • H01L29/73Bipolar junction transistors
    • H01L29/732Vertical transistors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/7827Vertical transistors

Definitions

  • a present invention described herein relates generally to a process for fabricating an integrated circuit structure, and more specifically to electronic devices having semiconductor junctions and to a process for their manufacture.
  • limit-of- resolution, level-to-level alignment, and depth-of-focus are physically constrained parameters.
  • Typical photolithographic techniques are limited by physical constraints of the photolithographic system involving actinic radiation wavelength, ⁇ , and geometrical configurations of the projection system optics. According to Rayleigh's criterion,
  • DUV deep ultraviolet illumination
  • NA NA 0.7
  • the lower limit of resolution is 168 nanometers (1680 A) .
  • Techniques such as phase-shifted masks can extend this limit downward, but photomasks required in this technique are extremely expensive. This expense becomes greatly compounded with a realization that an advanced semiconductor process may employ more than 25 photomasks.
  • U.S. Patent No. 6,413,802 to Hu et al . describes a device fabricated in a silicon layer overlying an insulating layer (e.g., SIMOX) with the device extending from the insulating layer as a fin.
  • U.S. Patent No. 6,525,403, to Inaba et al . describes a process with a gate, source, and drain in a modified horizontal configuration.
  • a potential overetch produces a damaged region in the silicon and may result in excessive consumption of silicon underlying a contact. Further, formation of an oxide spacer without an etch stop presents manufacturing difficulties as timing and other recipe tolerances become overly stringent . For at least the aforementioned reasons, integrated circuit manufacturers have been unable to sufficiently reduce a size of electronic devices while still maintaining high performance.
  • the aforementioned art has limitations on either device performance or anufacturability due to structures use (e.g., SOI or SIMOX) , limitations due to required lithography steps, or requirements for gate oxides to be performed late in a process, thereby limiting flexibility in design.
  • CMOS transistor Formation of elements of a vertical transistor is described, particularly, a gate-source-drain arrangement of a CMOS transistor. Improved methods for vertical transistor formation, which are not limited by constraints of photolithography due to a novel use of spacers and self-aligning techniques, have great utility and importance. Those of skill in the art will appreciate that the techniques described herein may be used to fabricate other types of devices as well . For example, junctions of a bipolar transistor (as well as other device junction types) may be fabricated using the methods described herein.
  • a method of fabricating an electronic device includes implanting a dopant into an area of a semiconducting substrate where the area is located within a region isolated by a dielectric isolator.
  • a film stack is then deposited over the implanted and dielectric separator areas .
  • the film stack includes, inter alia, a first dielectric layer and a first polysilicon layer.
  • a dielectric window is then etched through the first dielectric layer and a second dielectric layer is deposited into the dielectric window and over the film stack.
  • the second dielectric layer is etched anisotropically to form a first spacer. The spacer is used to reduce the size of transistor features well below the limits of photolithography.
  • Portions of the film stack lying between the implanted area and the first dielectric layer are then anisotropically etched to form an epitaxial via.
  • the via is filled with epitaxial silicon, thereby forming an epitaxial channel.
  • a second polysilicon layer is formed over the epitaxial channel and a third dielectric layer is deposited over the second polysilicon layer and surrounding areas.
  • the third dielectric layer is consequently etched anisotropically to form a second spacer and the first polysilicon layer is anisotropically etched.
  • a fourth dielectric layer is deposited over the second polysilicon layer and the first polysilicon layer and the fourth dielectric layer is etched to form a third spacer.
  • a semiconductor substrate having thereon at least one dopant-implanted region laterally enclosed by a dielectric isolation region. A topmost surface of the dielectric isolation region and the implanted region are substantially coplanar with a principal surface of the substrate.
  • An epitaxial channel is disposed on the topmost surface of the implanted region and is electrically coupled to the implanted region. A periphery of the epitaxial channel is defined by a first dielectric spacer.
  • a polysilicon region is peripherally disposed to and surrounds the epitaxial channel . The polysilicon region at least partially overlays the implanted region and is isolated from direct electrical coupling with the implanted region by a dielectric layer.
  • FIG. 1 shows an exemplary embodiment of an isolated implant area used to create an electronic device structure of the present invention.
  • FIG. 2 is a schematic cross-sectional view of the isolated implant area of FIG. 1 with a film stack.
  • FIG. 3 shows the deposited films of FIG. 1 with an etched dielectric mask window.
  • FIG. 4 shows a conformal blanket deposition of a dielectric layer filling the mask window of FIG. 3.
  • FIG. 5 shows the conformal blanket deposition of FIG. 4 anisotropically etched, forming a dielectric spacer.
  • FIG. 6 shows an anisotropic etch of film layers down to the implant area through the window formed by the dielectric spacer of FIG. 5.
  • FIG. 7 shows the removal of overlying dielectric layers of FIG. 6 with a vertical sidewall gate oxidation.
  • FIG. 8 shows an epitaxial channel fill of a gate area formed on FIGS. 6 and 7.
  • FIG. 9 shows the epitaxial fill area of FIG. 8 after chemical-mechanical planarization of the epitaxial silicon and deposition of polysilicon and photoresist.
  • FIG. 10 shows the photoresist layer of FIG. 9 after development and etch.
  • FIG. 11 shows an etched polysilicon layer of FIG. 10, which will become a gate area of the electronic device .
  • FIG. 12 shows the etched polysilicon layer of FIG. 11 with an etched underlying nitride layer, further defining the gate area.
  • FIG. 13 shows a conformal dielectric blanket layer deposited over the gate area of FIG. 12.
  • FIG. 14 shows the dielectric blanket layer of FIG. 13 after an anisotropic etch, leaving an oxide spacer.
  • FIG. 15 shows a developed and etched photoresist layer over the gate area of FIG. 14.
  • FIG. 16 shows an etched drain area formation remaining after polysilicon etch and removal of the photoresist layer of FIG. 15.
  • FIG. 17 shows a conformal dielectric blanket layer over the gate and drain areas of FIG. 16.
  • FIG. 18 shows the dielectric blanket layer of FIG. 17 after an anisotropic etch and leaving an oxide spacer surrounding the drain area .
  • FIG. 19 shows the electronic device structure of FIG. 18 after significant back-end-of-line processing steps associated with the present invention are completed.
  • FIG. 1 shows an exemplary embodiment of an isolated implant area 105 used to create an electronic device structure of the present invention.
  • FIG. 1 includes a base substrate 101, an isolation dielectric area 103, and the implanted substrate area 105.
  • An extent 107 of the implanted area 105 is shown in a plan view at the top of FIG. 1. All areas are formed by processes well-known to one of skill in the art.
  • the base substrate 101 is frequently a silicon wafer. In this embodiment, the specific silicon wafer is doped within the confines of the isolation dielectric area to form the implant area 105.
  • FIG. 2 is a schematic cross-sectional view of the isolated implant area 105 of FIG. 1 with an overlying film stack.
  • the film stack includes a pad oxide 201, a first polysilicon layer 203, a nitride layer 205, a dielectric hard mask 207, and a photoresist layer 209.
  • the dielectric hard mask 207 may be, for example, a CVD-deposited oxide.
  • nominal film thicknesses and methods of deposit are provided as follows: the pad oxide 201 is a deposited 500 A - 1000 A oxide, the first polysilicon layer 203 is 1000 A thick, the nitride layer 205 is 300 A thick, the dielectric (e.g., oxide) layer 207 is 2000 A - 3000 A thick, and the photoresist layer 209 is 0.5 ⁇ m - 1.5 ⁇ m thick.
  • FIG. 3 shows the deposited films of FIG. 1, after exposing the photoresist layer 209, developing, and etching through the photoresist layer 209 and underlying hard mask 207, and producing a mask window 301.
  • Etching through the hard mask 207 may be accomplished through various wet etch (e.g., in hydrofluoric acid, such as contained in a standard buffered oxide etch, or orthophosphoric acid) or dry etch (e.g., reactive-ion etch (RIE) ) techniques.
  • RIE reactive-ion etch
  • the photoresist layer 209 is stripped.
  • a plan view at the top of FIG. 3 shows a limit 303 to conventional lithography.
  • the limit 303 with contemporary lithography is 0.18 ⁇ m.
  • a conformal blanket deposition of an oxide spacer layer 401 fills the mask window 301 and overlies the surrounding hard mask 207.
  • the oxide spacer layer 401 is then anisotropically etched, for example, by RIE.
  • An etchant is chosen with a high selectivity ratio between oxide and nitride allowing the nitride layer 205 to act as an etch stop.
  • the remaining oxide spacer 501 (FIG. 5) , substantially extends the limit 303 of conventional lithography as shown by a reduced-dimension mask opening 503. For example, a typical 0.18 ⁇ m design rule with an oxide spacer 501 thickness of 0. ; 05 ⁇ m at the base produces a 0.08 ⁇ m mask opening 503.
  • the oxide spacer 501 along with the hard mask 207, provide an mask for anisotropic etching through the underlying layers (i.e., the nitride layer 205, the first polysilicon layer 203, and the pad oxide 201) , and down to the implanted area 105, thereby producing an epitaxial ("epi") via 601.
  • the overlying hard mask 207 and oxide spacer 501 are stripped by, for example, a buffered-oxide wet-etch technique.
  • a thermal oxidation step produces a gate oxide 701 on vertical walls of the first polysilicon layer 203.
  • any oxide regrowth on the bottom of the bottom of the epi via 601 may be remove by techniques such as RIE. Precautions are taken to minimize or eliminate any native oxide growth on the bottom of the epi via 601 after etch. Techniques to minimize native oxide growth from silicon are well known in the art and will not be discussed herein.
  • Thermal oxide growth techniques combine oxygen with underlying silicon (i.e., the first polycrystalline silicon layer 103) . Mechanisms for thermal oxide growth are well understood with approximately 44% of the underlying polysilicon 103 being consumed to form the gate oxide 701.
  • the epi via 601 is then filled (FIG. 8) with an epitaxial silicon 801 channel deposition.
  • the epitaxial silicon forms a channel of the transistor, channel 901 (FIG. 9) .
  • a second polysilicon layer 903 and a second photoresist layer 905 are then deposited.
  • the second polysilicon layer 903 and the second photoresist layer are nominally 1000 A and 5000 A thick, respectively.
  • the second photoresist layer 905 is then exposed, developed, and etched leaving a second photoresist etch mask 1005 (FIG. 10) . Areas of the first polysilicon not under the second photoresist etch mask 1005 layer 203 are then etched, for example, by RIE, leaving a gate polysilicon 1103 (FIG. 11) .
  • a conformal oxide layer 1301 is deposited (e.g., by an LPCVD process) over the gate polysilicon and surrounding area, and is then anisotropically etched, leaving an oxide spacer 1401 (FIG. 14) .
  • the oxide spacer provides for a self-aligning area that allows for overlay of features beyond what typical lithography and alignment techniques would ordinarily permit. Therefore, level -to-level alignment issues with multiple masks are eliminated as the levels are self-aligned.
  • photoresist is deposited and etched leaving a photoresist mask 1501.
  • the photoresist mask 1501 serves as an etch mask for a polysilicon etch producing a polysilicon gate area 1601 (FIG. 16) .
  • a final CVD oxide is conformally deposited 1701 (FIG. 17) , and anisotropically etched, leaving a gate area oxide spacer 1801 (FIG. 18) .
  • the gate area oxide spacer has the same self-aligning qualities as the oxide spacer
  • a final anisotropic etch reveals the implanted substrate area 105 and forms a source region 1901, a drain region 1903, and a gate region 1905.
  • techniques well known to a skilled artisan are completed to form, for example, additional implants diffused into the drain polysilicon, metallization, electronic-test, and packaging steps to complete the semiconductor device.
  • a process and arrangement for forming a vertical gate CMOS device has been discussed herein. However, the invented process and arrangements of layers and regions described herein are also useful for forming a wide range of other device types and structures having utility as individual devices or in combinations.
  • CMOS complementary metal-oxide-semiconductor
  • CMOS complementary metal-oxide-semiconductor
  • the techniques described herein are also readily amenable to constructing features such as double gates by expanding the gate-masking step with a separation of gate areas by dielectric deposition or growth.
  • a thin-film head (TFH) process in the data storage industry or an active matrix liquid crystal display (AMLCD) in the flat panel display industry could readily make use of the processes and techniques described herein.
  • THF thin-film head
  • AMLCD active matrix liquid crystal display
  • semiconductor should be recognized as including the aforementioned and related industries.

Landscapes

  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Insulated Gate Type Field-Effect Transistor (AREA)
  • Metal-Oxide And Bipolar Metal-Oxide Semiconductor Integrated Circuits (AREA)

Abstract

Formation of elements of a vertical transistor is described, particularly, a gate (1905)- source (1901) - drain (1903) arrangement of a CMOS transistor. Vertical transistors are used frequently in the integrated circuit art. Accordingly, improved methods for their formation, which are not limited by constraints of photolithography, have great utility and importance. Those of skill in the art will appreciate that the techniques described may be used to fabricate other types of devices as well. For example, junctions of a bipolar transistor (as well as other device junction types) may be fabricated using the methods described herein.

Description

Description
VERTICAL GATE CMOS WITH LITHOGRAPHY- INDEPENDENT GATE LENGTH
TECHNICAL FIELD A present invention described herein relates generally to a process for fabricating an integrated circuit structure, and more specifically to electronic devices having semiconductor junctions and to a process for their manufacture.
BACKGROUND ART There is a need in the integrated circuit art for obtaining increasingly smaller devices without sacrificing device performance. The small device size requires small device regions, precise and accurate alignment between regions, and minimization of parasitic resistances and capacitances. Device size can be reduced by putting more reliance on fine line lithography, but as discussed below, it becomes impractical or impossible to continue to reduce feature size and achieve the required greater increase in alignment accuracy. As lithography is pushed to its physical limits, yield and production throughput decrease. Four governing performance parameters of a photolithographic system are limit-of-resolution, Lr, level-to-level alignment accuracy, depth-of-focus, and throughput. For purposes of this discussion, limit-of- resolution, level-to-level alignment, and depth-of-focus are physically constrained parameters. Typical photolithographic techniques are limited by physical constraints of the photolithographic system involving actinic radiation wavelength, λ , and geometrical configurations of the projection system optics. According to Rayleigh's criterion,
0.6U Lr NA
where NA is the numerical aperture of the optical system and is defined as NA = nsina , where n is the index of refraction of the medium which the radiation traverses (usually air for this application, so n ≤ 1) and is a half-angle of the divergence of the actinic radiation. For example, using deep ultraviolet illumination (DUV) with λ =193 nm, and NA = 0.7, the lower limit of resolution is 168 nanometers (1680 A) . Techniques such as phase-shifted masks can extend this limit downward, but photomasks required in this technique are extremely expensive. This expense becomes greatly compounded with a realization that an advanced semiconductor process may employ more than 25 photomasks. Along with the limit-of-resolution, the second parameter, level-to-level alignment accuracy becomes more critical as feature sizes on photomasks decrease and a number of total photomasks increases. For example, if photomask alignment by itself causes a reduction in device yield to 95% per layer, then 25 layers of photomask translates to a total device yield of 0.95 = 0.28 or 28% yield (assuming independent errors) . Therefore, a more complicated mask, such a phase-shifted mask is not only more expensive but can cause device yield to suffer dramatically. Further, although the numerical aperture of the photolithographic system may be increased to lower the limit-of-resolution, the third parameter, depth-of-focus, will suffer as a result. Depth-of-focus is inversely proportional to NA2 . Therefore, as NA increases, limit- of-resolution decreases but depth-of-focus decreases more rapidly. The reduced depth-of-focus makes accurate focusing more difficult especially on non-planar features such as "Manhattan Geometries" becoming increasingly popular in advanced semiconductor devices. Recently, techniques have been developed to make smaller scale transistors and related devices. One such method of making transistors is described in a paper presented at the 1999 International Electron Devices Meeting and sponsored by IEEE, entitled Λ,The Vertical Replacement-Gate (VRG) MOSFET: A 50-nm Vertical MOSFET with Lithography-Independent Gate Length, by J.M. Hergenrother et al . Here, Hergenrother et al . describes a method utilizing a vertical transistor technology wherein the gate and gate oxide are required to be applied in the final steps of the process. U.S. Patent No. 6,413,802 to Hu et al . , describes a device fabricated in a silicon layer overlying an insulating layer (e.g., SIMOX) with the device extending from the insulating layer as a fin. Further, U.S. Patent No. 6,525,403, to Inaba et al . , describes a process with a gate, source, and drain in a modified horizontal configuration. U.S. Patent Application Publication No. 2002/0060338 by Zhibo Zhang describes a vertical FET device whereby source and drain regions are formed at respective ends of a vertical channel, and an insulated gate is formed adjacent the vertical channel. Still other art has focused on vertical devices like those mentioned above with formation occurring on silicon-on-insulator (SOI) . SOI and SIMOX have several disadvantages. These disadvantages include poor performance for memory devices (since the body of the device is floating) , a requirement for extreme lithography on one or more of the process steps, and a drastic increase in price for the SOI material . Additionally, in a conventional method for fabricating a bipolar device, a source window is directly opened without some means of providing an etch stop. A potential overetch produces a damaged region in the silicon and may result in excessive consumption of silicon underlying a contact. Further, formation of an oxide spacer without an etch stop presents manufacturing difficulties as timing and other recipe tolerances become overly stringent . For at least the aforementioned reasons, integrated circuit manufacturers have been unable to sufficiently reduce a size of electronic devices while still maintaining high performance. The aforementioned art has limitations on either device performance or anufacturability due to structures use (e.g., SOI or SIMOX) , limitations due to required lithography steps, or requirements for gate oxides to be performed late in a process, thereby limiting flexibility in design. In view of the desire for integrated circuits having higher device counts, smaller device sizes, and greater circuit performance, a need continues to exist for an improved process to manufacture the required devices without resorting to unrealistic and expensive photolithography requirements . Accordingly, what is needed is a way to provide an improved process and structure for fabricating integrated circuit devices. Such a structure for producing integrated circuit devices would have devices with a reduced size with reasonable photolithographic tolerances .
SUMMARY OF THE INVENTION Formation of elements of a vertical transistor is described, particularly, a gate-source-drain arrangement of a CMOS transistor. Improved methods for vertical transistor formation, which are not limited by constraints of photolithography due to a novel use of spacers and self-aligning techniques, have great utility and importance. Those of skill in the art will appreciate that the techniques described herein may be used to fabricate other types of devices as well . For example, junctions of a bipolar transistor (as well as other device junction types) may be fabricated using the methods described herein. In one embodiment, a method of fabricating an electronic device includes implanting a dopant into an area of a semiconducting substrate where the area is located within a region isolated by a dielectric isolator. A film stack is then deposited over the implanted and dielectric separator areas . The film stack includes, inter alia, a first dielectric layer and a first polysilicon layer. A dielectric window is then etched through the first dielectric layer and a second dielectric layer is deposited into the dielectric window and over the film stack. The second dielectric layer is etched anisotropically to form a first spacer. The spacer is used to reduce the size of transistor features well below the limits of photolithography. Portions of the film stack lying between the implanted area and the first dielectric layer are then anisotropically etched to form an epitaxial via. The via is filled with epitaxial silicon, thereby forming an epitaxial channel. A second polysilicon layer is formed over the epitaxial channel and a third dielectric layer is deposited over the second polysilicon layer and surrounding areas. The third dielectric layer is consequently etched anisotropically to form a second spacer and the first polysilicon layer is anisotropically etched. A fourth dielectric layer is deposited over the second polysilicon layer and the first polysilicon layer and the fourth dielectric layer is etched to form a third spacer. Finally, any remaining layers surrounding the third spacer are etched down to a level substantially coplanar with the implant area. The present invention also defines an electronic device. In one embodiment, a semiconductor substrate is disclosed having thereon at least one dopant-implanted region laterally enclosed by a dielectric isolation region. A topmost surface of the dielectric isolation region and the implanted region are substantially coplanar with a principal surface of the substrate. An epitaxial channel is disposed on the topmost surface of the implanted region and is electrically coupled to the implanted region. A periphery of the epitaxial channel is defined by a first dielectric spacer. A polysilicon region is peripherally disposed to and surrounds the epitaxial channel . The polysilicon region at least partially overlays the implanted region and is isolated from direct electrical coupling with the implanted region by a dielectric layer.
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 shows an exemplary embodiment of an isolated implant area used to create an electronic device structure of the present invention. FIG. 2 is a schematic cross-sectional view of the isolated implant area of FIG. 1 with a film stack. FIG. 3 shows the deposited films of FIG. 1 with an etched dielectric mask window. FIG. 4 shows a conformal blanket deposition of a dielectric layer filling the mask window of FIG. 3. FIG. 5 shows the conformal blanket deposition of FIG. 4 anisotropically etched, forming a dielectric spacer. FIG. 6 shows an anisotropic etch of film layers down to the implant area through the window formed by the dielectric spacer of FIG. 5. FIG. 7 shows the removal of overlying dielectric layers of FIG. 6 with a vertical sidewall gate oxidation. FIG. 8 shows an epitaxial channel fill of a gate area formed on FIGS. 6 and 7. FIG. 9 shows the epitaxial fill area of FIG. 8 after chemical-mechanical planarization of the epitaxial silicon and deposition of polysilicon and photoresist. FIG. 10 shows the photoresist layer of FIG. 9 after development and etch. FIG. 11 shows an etched polysilicon layer of FIG. 10, which will become a gate area of the electronic device . FIG. 12 shows the etched polysilicon layer of FIG. 11 with an etched underlying nitride layer, further defining the gate area. FIG. 13 shows a conformal dielectric blanket layer deposited over the gate area of FIG. 12. FIG. 14 shows the dielectric blanket layer of FIG. 13 after an anisotropic etch, leaving an oxide spacer. FIG. 15 shows a developed and etched photoresist layer over the gate area of FIG. 14. FIG. 16 shows an etched drain area formation remaining after polysilicon etch and removal of the photoresist layer of FIG. 15. FIG. 17 shows a conformal dielectric blanket layer over the gate and drain areas of FIG. 16. FIG. 18 shows the dielectric blanket layer of FIG. 17 after an anisotropic etch and leaving an oxide spacer surrounding the drain area . FIG. 19 shows the electronic device structure of FIG. 18 after significant back-end-of-line processing steps associated with the present invention are completed.
BEST MODE FOR CARRYING OUT INVENTION With reference to FIGS. 1 - 19, an exemplary embodiment of the present invention is described in detail according to the following process steps. FIG. 1 shows an exemplary embodiment of an isolated implant area 105 used to create an electronic device structure of the present invention. FIG. 1 includes a base substrate 101, an isolation dielectric area 103, and the implanted substrate area 105. An extent 107 of the implanted area 105 is shown in a plan view at the top of FIG. 1. All areas are formed by processes well-known to one of skill in the art. The base substrate 101 is frequently a silicon wafer. In this embodiment, the specific silicon wafer is doped within the confines of the isolation dielectric area to form the implant area 105. Alternatively, another elemental group IV semiconductor or compound semiconductor (e.g., groups III-V or II-VI) may be selected for base substrate 101. The isolation dielectric area 103 is, for example, deposited or thermally grown oxide or deposited nitride. FIG. 2 is a schematic cross-sectional view of the isolated implant area 105 of FIG. 1 with an overlying film stack. In this example, the film stack includes a pad oxide 201, a first polysilicon layer 203, a nitride layer 205, a dielectric hard mask 207, and a photoresist layer 209. The dielectric hard mask 207 may be, for example, a CVD-deposited oxide. In a specific exemplary embodiment, nominal film thicknesses and methods of deposit are provided as follows: the pad oxide 201 is a deposited 500 A - 1000 A oxide, the first polysilicon layer 203 is 1000 A thick, the nitride layer 205 is 300 A thick, the dielectric (e.g., oxide) layer 207 is 2000 A - 3000 A thick, and the photoresist layer 209 is 0.5 μm - 1.5 μm thick. FIG. 3 shows the deposited films of FIG. 1, after exposing the photoresist layer 209, developing, and etching through the photoresist layer 209 and underlying hard mask 207, and producing a mask window 301. Etching through the hard mask 207 may be accomplished through various wet etch (e.g., in hydrofluoric acid, such as contained in a standard buffered oxide etch, or orthophosphoric acid) or dry etch (e.g., reactive-ion etch (RIE) ) techniques. After the hard mask 207 etch, the photoresist layer 209 is stripped. A plan view at the top of FIG. 3 shows a limit 303 to conventional lithography. For example, the limit 303 with contemporary lithography is 0.18 μm. With reference to FIG. 4, a conformal blanket deposition of an oxide spacer layer 401 fills the mask window 301 and overlies the surrounding hard mask 207. The oxide spacer layer 401 is then anisotropically etched, for example, by RIE. An etchant is chosen with a high selectivity ratio between oxide and nitride allowing the nitride layer 205 to act as an etch stop. The remaining oxide spacer 501 (FIG. 5) , substantially extends the limit 303 of conventional lithography as shown by a reduced-dimension mask opening 503. For example, a typical 0.18 μm design rule with an oxide spacer 501 thickness of 0.;05 μm at the base produces a 0.08 μm mask opening 503. With reference to FIG. 6, the oxide spacer 501, along with the hard mask 207, provide an mask for anisotropic etching through the underlying layers (i.e., the nitride layer 205, the first polysilicon layer 203, and the pad oxide 201) , and down to the implanted area 105, thereby producing an epitaxial ("epi") via 601. In FIG. 7, the overlying hard mask 207 and oxide spacer 501 are stripped by, for example, a buffered-oxide wet-etch technique. A thermal oxidation step produces a gate oxide 701 on vertical walls of the first polysilicon layer 203. Any oxide regrowth on the bottom of the bottom of the epi via 601 (i.e., oxide on the implanted area 105) may be remove by techniques such as RIE. Precautions are taken to minimize or eliminate any native oxide growth on the bottom of the epi via 601 after etch. Techniques to minimize native oxide growth from silicon are well known in the art and will not be discussed herein. Thermal oxide growth techniques combine oxygen with underlying silicon (i.e., the first polycrystalline silicon layer 103) . Mechanisms for thermal oxide growth are well understood with approximately 44% of the underlying polysilicon 103 being consumed to form the gate oxide 701. The epi via 601 is then filled (FIG. 8) with an epitaxial silicon 801 channel deposition. The epitaxial silicon forms a channel of the transistor, channel 901 (FIG. 9) . A second polysilicon layer 903 and a second photoresist layer 905 are then deposited. In one specific exemplary embodiment, the second polysilicon layer 903 and the second photoresist layer, are nominally 1000 A and 5000 A thick, respectively. The second photoresist layer 905 is then exposed, developed, and etched leaving a second photoresist etch mask 1005 (FIG. 10) . Areas of the first polysilicon not under the second photoresist etch mask 1005 layer 203 are then etched, for example, by RIE, leaving a gate polysilicon 1103 (FIG. 11) . An additional etch of the nitride layer 205 leaving a nitride pad 1205 (FIG. 12) substantially completes the gate area. With reference to FIG. 13, a conformal oxide layer 1301 is deposited (e.g., by an LPCVD process) over the gate polysilicon and surrounding area, and is then anisotropically etched, leaving an oxide spacer 1401 (FIG. 14) . The oxide spacer provides for a self-aligning area that allows for overlay of features beyond what typical lithography and alignment techniques would ordinarily permit. Therefore, level -to-level alignment issues with multiple masks are eliminated as the levels are self-aligned. Additionally, feature sizes are determined by deposition and etching techniques and can be far smaller than features defined by photolithography and alignment alone. In FIG. 15, photoresist is deposited and etched leaving a photoresist mask 1501. The photoresist mask 1501 serves as an etch mask for a polysilicon etch producing a polysilicon gate area 1601 (FIG. 16) . A final CVD oxide is conformally deposited 1701 (FIG. 17) , and anisotropically etched, leaving a gate area oxide spacer 1801 (FIG. 18) . The gate area oxide spacer has the same self-aligning qualities as the oxide spacer
1401, supra. In FIG. 19, a final anisotropic etch reveals the implanted substrate area 105 and forms a source region 1901, a drain region 1903, and a gate region 1905. Following the final anisotropic etch, techniques well known to a skilled artisan are completed to form, for example, additional implants diffused into the drain polysilicon, metallization, electronic-test, and packaging steps to complete the semiconductor device. To facilitate an understanding of the present invention, a process and arrangement for forming a vertical gate CMOS device has been discussed herein. However, the invented process and arrangements of layers and regions described herein are also useful for forming a wide range of other device types and structures having utility as individual devices or in combinations. For example, although an embodiment depicts formation of a CMOS device, a skilled artisan will recognize that the present invention is readily adaptable to a bipolar transistor or other type of semiconducting device. Further, the techniques described herein are also readily amenable to constructing features such as double gates by expanding the gate-masking step with a separation of gate areas by dielectric deposition or growth. Additionally, many industries allied with the semiconductor industry could make use of this technique. For example, a thin-film head (TFH) process in the data storage industry or an active matrix liquid crystal display (AMLCD) in the flat panel display industry could readily make use of the processes and techniques described herein. The term "semiconductor" should be recognized as including the aforementioned and related industries. Additionally, although process steps and techniques are shown and described in detail, a skilled artisan will recognize that other techniques and methods may be utilized which are still included within the scope of the appended claims. For example, there are frequently several techniques used for depositing a film layer (e.g., chemical vapor deposition, plasma-enhanced vapor deposition, epitaxy, atomic layer deposition, etc.) . Although not all techniques are amenable to all film types described herein, one skilled in the art will recognize that multiple methods for depositing a given layer and/or film type may be used. Therefore, a scope of the present invention shall only be limited by the scope of the appended claims .

Claims

Claims
1. A method of fabricating an electronic device comprising: implanting a dopant into an area of a semiconducting substrate, the implanted area being located within a region isolated by a dielectric isolator; depositing a film stack over the implanted and dielectric isolator areas, the film stack including a first dielectric layer and a first polysilicon layer; etching a dielectric window through the first dielectric layer; depositing a second dielectric layer into the dielectric window and over the film stack; etching the second dielectric layer anisotropically to form a first spacer; etching portions of the film stack lying between the implanted area and the first dielectric layer anisotropically thereby forming an epitaxial via; filling the epitaxial via with epitaxial silicon, thereby forming an epitaxial channel; forming a second polysilicon layer over the epitaxial channel ; depositing a third dielectric layer over the second polysilicon layer and surrounding areas; etching the third dielectric layer anisotropically to form a second spacer; etching the first polysilicon layer; depositing a fourth dielectric layer over the second polysilicon layer and the first polysilicon layer; etching the fourth dielectric layer to form a third spacer; and etching any remaining layers surrounding the third spacer down to substantially a level of the implant area .
2. The method of claim 1 wherein the film stack is comprised of a pad oxide, a first polysilicon layer, a nitride layer, and an oxide mask.
3. The method of claim 1 wherein the spacer is comprised of oxide.
4. The method of claim 1 wherein the first, second, third, and fourth dielectric layers are comprised of oxide .
5. An electronic device comprising: a semiconductor substrate having thereon at least one region laterally enclosed by a dielectric isolation region, the region being implanted with a dopant, a topmost surface of the dielectric isolation region and the implanted region being substantially coplanar with a principal surface of the substrate; an epitaxial channel disposed on the topmost surface of the implanted region and electrically coupled to the implanted region, a periphery of the epitaxial channel having been defined by a first dielectric spacer; and a polysilicon region peripherally disposed to and surrounding the epitaxial channel, the polysilicon region at least partially overlaying the implanted region and isolated from direct electrical coupling with the implanted region by a dielectric layer.
6. The electronic device of claim 5, wherein the epitaxial channel is electrically coupled to the peripheral polysilicon region when a voltage exceeding a threshold voltage is applied to the epitaxial channel.
7. The electronic device of claim 5, wherein the epitaxial channel is electrically isolated from the peripheral polysilicon region when a voltage less than a threshold voltage is applied to the epitaxial channel.
8. The electronic device of claim 5, wherein the polysilicon region is circumscribed by a second dielectric spacer.
9. The electronic device of claim 5, further comprising a polysilicon cap on the topmost surface of the epitaxial channel, the polysilicon cap being circumscribed by a third dielectric spacer.
10. The electronic device of claim 9, wherein the polysilicon cap is a gate contact for a transistor.
11. The electronic device of claim 5, wherein the polysilicon region is a drain contact of a transistor.
12. The electronic device of claim 5, wherein the implanted region is a source contact of a transistor.
13. A method of fabricating an electronic device comprising: implanting a dopant into an area of a semiconducting substrate; depositing a film stack over the implanted, the film stack including a first dielectric layer and a first polysilicon layer; etching a dielectric window through the first dielectric layer; forming a first spacer within the dielectric window; etching portions of the film stack lying between the implanted area and the first dielectric layer anisotropically thereby forming an epitaxial via; filling the epitaxial via with epitaxial silicon, thereby forming an epitaxial channel; forming a second polysilicon layer over the epitaxial channel; forming a second spacer circumscribing the second polysilicon layer; etching the first polysilicon layer; and forming a third spacer circumscribing the first polysilicon layer.
14. The method of claim 13, further comprising isolating the implanted area by a dielectric isolator.
15. The method of claim 13 , wherein the first oxide spacer is formed by depositing a second dielectric layer into the dielectric window and over the film stack and then etching the second dielectric layer anisotropically to form the first spacer.
16. The method of claim 13, wherein the second spacer is formed by depositing a third dielectric layer over the second polysilicon layer and surrounding areas and anisotropically etching the third dielectric layer.
17. The method of claim 13, wherein the third spacer is formed by depositing a fourth dielectric layer over the second polysilicon layer and the first polysilicon layer and anisotropically etching the fourth dielectric layer.
18. The method of claim 17, further comprising etching any remaining layers surrounding the third spacer down to substantially a level of the implant area.
PCT/US2005/001313 2004-01-21 2005-01-18 Vertical gate cmos with lithography-independent gate length WO2005072154A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP05705754A EP1709680A4 (en) 2004-01-21 2005-01-18 Vertical gate cmos with lithography-independent gate length

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/761,876 2004-01-21
US10/761,876 US6846709B1 (en) 2003-10-06 2004-01-21 Vertical gate CMOS with lithography-independent gate length

Publications (2)

Publication Number Publication Date
WO2005072154A2 true WO2005072154A2 (en) 2005-08-11
WO2005072154A3 WO2005072154A3 (en) 2005-12-08

Family

ID=34826456

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2005/001313 WO2005072154A2 (en) 2004-01-21 2005-01-18 Vertical gate cmos with lithography-independent gate length

Country Status (4)

Country Link
EP (1) EP1709680A4 (en)
CN (1) CN100442477C (en)
TW (1) TW200531215A (en)
WO (1) WO2005072154A2 (en)

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0418421B1 (en) * 1989-09-22 1998-08-12 Siemens Aktiengesellschaft Method of making a bipolar transistor having a reduced base-collector capacitance
JP3229012B2 (en) * 1992-05-21 2001-11-12 株式会社東芝 Method for manufacturing semiconductor device
US5689127A (en) * 1996-03-05 1997-11-18 International Business Machines Corporation Vertical double-gate field effect transistor
US5786256A (en) * 1996-07-19 1998-07-28 Advanced Micro Devices, Inc. Method of reducing MOS transistor gate beyond photolithographically patterned dimension
US20010017392A1 (en) * 1997-05-19 2001-08-30 International Business Machines Corporation. Vertical transport MOSFETs and method for making the same
US6040214A (en) * 1998-02-19 2000-03-21 International Business Machines Corporation Method for making field effect transistors having sub-lithographic gates with vertical side walls
US6392271B1 (en) * 1999-06-28 2002-05-21 Intel Corporation Structure and process flow for fabrication of dual gate floating body integrated MOS transistors
US6518616B2 (en) * 2001-04-18 2003-02-11 International Business Machines Corporation Vertical gate top engineering for improved GC and CB process windows
US20030008515A1 (en) * 2001-07-03 2003-01-09 Tai-Ju Chen Method of fabricating a vertical MOS transistor

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of EP1709680A4 *

Also Published As

Publication number Publication date
EP1709680A4 (en) 2008-07-02
TW200531215A (en) 2005-09-16
CN1910748A (en) 2007-02-07
WO2005072154A3 (en) 2005-12-08
CN100442477C (en) 2008-12-10
EP1709680A2 (en) 2006-10-11

Similar Documents

Publication Publication Date Title
US6846709B1 (en) Vertical gate CMOS with lithography-independent gate length
US7781847B2 (en) Device patterned with sub-lithographic features with variable widths
US8648400B2 (en) FinFET semiconductor device with germanium (GE) fins
US8148775B2 (en) Methods of providing electrical isolation and semiconductor structures including same
US7816228B2 (en) Method of manufacturing a semiconductor device
US8389363B2 (en) Methods of forming field effect transistors, methods of forming field effect transistor gates, methods of forming integrated circuitry comprising a transistor gate array and circuitry peripheral to the gate array, and methods of forming integrated circuitry comprising a transistor gate array including first gates and second grounded isolation gates
US8278707B2 (en) Field effect transistors having a double gate structure
US20060017119A1 (en) Multi-gate transistor and method of fabricating multi-gate transistor
JP2004207705A (en) Double-gate type field effect transistor and its manufacturing method
US20060065893A1 (en) Method of forming gate by using layer-growing process and gate structure manufactured thereby
WO2006049707A1 (en) Lithography-independent fabrication of small openings
US7341916B2 (en) Self-aligned nanometer-level transistor defined without lithography
US6979651B1 (en) Method for forming alignment features and back-side contacts with fewer lithography and etch steps
US20050156224A1 (en) Method to make minimal spacing between floating gates in split gate flash
EP1709680A2 (en) Vertical gate cmos with lithography-independent gate length
US7030020B2 (en) Method to shrink cell size in a split gate flash
KR100611083B1 (en) Mos transistor and method for manufacturing the same
JP2754202B2 (en) Method for manufacturing semiconductor device
KR100497672B1 (en) Dram using aligned soi double gate transistor and process thereof
JPH11121701A (en) Semiconductor device and manufacture thereof
JPH0831537B2 (en) Method for manufacturing semiconductor device

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NA NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): BW GH GM KE LS MW MZ NA SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LT LU MC NL PL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

WWE Wipo information: entry into national phase

Ref document number: 2005705754

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 200580002918.9

Country of ref document: CN

NENP Non-entry into the national phase in:

Ref country code: DE

WWW Wipo information: withdrawn in national office

Country of ref document: DE

WWP Wipo information: published in national office

Ref document number: 2005705754

Country of ref document: EP