WO2005070832A1 - 酸化物固溶体粉末 - Google Patents
酸化物固溶体粉末 Download PDFInfo
- Publication number
- WO2005070832A1 WO2005070832A1 PCT/JP2005/000053 JP2005000053W WO2005070832A1 WO 2005070832 A1 WO2005070832 A1 WO 2005070832A1 JP 2005000053 W JP2005000053 W JP 2005000053W WO 2005070832 A1 WO2005070832 A1 WO 2005070832A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- oxide
- abrasive
- solid solution
- polishing
- calcium
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F17/00—Compounds of rare earth metals
- C01F17/20—Compounds containing only rare earth metals as the metal element
- C01F17/206—Compounds containing only rare earth metals as the metal element oxide or hydroxide being the only anion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9445—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
- B01D53/9454—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific device
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/02—Oxides or hydroxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F17/00—Compounds of rare earth metals
- C01F17/20—Compounds containing only rare earth metals as the metal element
- C01F17/206—Compounds containing only rare earth metals as the metal element oxide or hydroxide being the only anion
- C01F17/224—Oxides or hydroxides of lanthanides
- C01F17/229—Lanthanum oxides or hydroxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F17/00—Compounds of rare earth metals
- C01F17/20—Compounds containing only rare earth metals as the metal element
- C01F17/206—Compounds containing only rare earth metals as the metal element oxide or hydroxide being the only anion
- C01F17/224—Oxides or hydroxides of lanthanides
- C01F17/235—Cerium oxides or hydroxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F17/00—Compounds of rare earth metals
- C01F17/30—Compounds containing rare earth metals and at least one element other than a rare earth metal, oxygen or hydrogen, e.g. La4S3Br6
- C01F17/32—Compounds containing rare earth metals and at least one element other than a rare earth metal, oxygen or hydrogen, e.g. La4S3Br6 oxide or hydroxide being the only anion, e.g. NaCeO2 or MgxCayEuO
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G25/00—Compounds of zirconium
- C01G25/02—Oxides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/14—Anti-slip materials; Abrasives
- C09K3/1409—Abrasive particles per se
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
- C01P2002/54—Solid solutions containing elements as dopants one element only
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Definitions
- the present invention relates to an oxide solid solution, and more particularly to a powder of an oxide solid solution containing a rare earth oxide such as cerium oxide as a main component.
- Rare earth oxides such as cerium oxide are used in various applications such as abrasives, catalyst carriers, and ultraviolet absorbers.
- rare earth oxides containing cerium oxide as a main component are known to be suitable as an abrasive, and include glass materials such as glass substrates for optical disks, magnetic disks, LCDs, and HDs. It is used as an abrasive.
- an abrasive IR earth oxide having a high polished surface precision is required.
- abrasive used in such a field for example, when preparing an abrasive slurry, cerium fluoride and calcium sulfate are mixed with a bastnasite-based abrasive containing cerium oxide, and water is further mixed. There is a slurry abrasive obtained by the above method (see Patent Document 1). The presence of calcium ions in the slurry prevents the precipitation of particles in the slurry and the clogging of the polishing pad, thereby preventing the occurrence of polishing scratches.
- calcium chloride is mixed with a rare earth carbonate and a rare earth oxide, which are main raw materials of the abrasive, before the roasting step in the production of the abrasive, and thereafter, the mixture is roasted.
- abrasive there is an abrasive to be manufactured (see Patent Document 2). If calcium chloride is mixed before roasting, abnormal grain growth during roasting is suppressed, the average particle size and particle size distribution during roasting are easily controlled, and polishing with a small average particle size is performed. The material can be manufactured more easily. As a result, it is possible to manufacture an abrasive which does not contain a fluorine component and in which the accuracy of the polished surface is prevented from lowering.
- Patent Document 1 JP-A-6-330025
- Patent Document 2 JP-A-2002-155269
- Patent Document 3 JP-A-10-237425
- Patent Document 4 JP 2001-126236 A
- Patent Document 5 Patent No. 2736869
- Patent Document 6 JP 2001-30732 A
- the present invention has been made in view of the above problems, and is an oxide solid solution powder containing a rare earth oxide such as cerium oxide as a main component, and can be used as an abrasive. It is an object of the present invention to provide a material capable of obtaining a polished surface having a high polished surface accuracy when used as an abrasive.
- the inventor of the present invention first studied the above-described conventional technology. As a result, it was judged that it was not easy to obtain a material having a higher polished surface accuracy by making the abrasive particles, that is, the rare earth oxide particles finer. Therefore, we decided to develop an abrasive (rare earth oxide) with excellent polishing surface accuracy by focusing on another viewpoint. As a result of repeated studies, it was found that cerium oxide, a type of rare-earth oxide, has chemical polishing properties, that is, the property that cerium oxide and glass undergo a chemical reaction during polishing to break the bond between glasses (a type of (Polishing action).
- the present invention is an oxide solid solution powder in which calcium oxide is dissolved in a rare earth oxide containing cerium oxide as a main component.
- a glass material such as a glass substrate is polished using the oxide solid solution powder as a polishing material, a polished surface with high polished surface accuracy can be obtained. That is, the polishing method using the oxide solid solution powder according to the present invention as an abrasive is suitable as a method for polishing a glass substrate.
- the oxide solid solution obtained by dissolving calcium element in cerium oxide such as cerium oxide has a large amount of oxygen vacancies generated in the solid solution. It is thought that a higher polishing surface accuracy can be obtained than the chemical polishing power of the steel.
- the present invention relates to an oxide solid solution powder, that is, an abrasive itself, and it is necessary to add an additive when preparing an abrasive slurry by mixing the abrasive and a solvent (for example, water).
- a solvent for example, water
- the polishing surface accuracy has been improved by reducing the size of abrasive particles constituting the abrasive.
- the present invention has been described in the background art, but as described above, the present invention is to improve the polished surface accuracy by dissolving calcium element in cerium oxide, and to make the particles finer.
- the technical content is fundamentally different from the technology of improving the accuracy of the polished surface. That is, the abrasive according to the present invention has higher polished surface accuracy as compared with the conventional abrasive even if the particle diameter is the same.
- it is not necessary to atomize the abrasive particles it is not necessary to enhance grinding and classification to solve the problem. Can be.
- the average particle diameter is about 2 ⁇ -3 ⁇ m, and the average surface roughness (Ra) is 3 A or less.
- Ra average surface roughness
- a polished surface with a high polished surface accuracy of 2 A or less can be obtained.
- the average particle size is not limited by the relationship with the polishing surface accuracy, but for example, the polishing speed is generally higher for the larger particle size. Therefore, in applications where a material having a relatively high polishing rate is preferred, it can be said that the oxide solid solution powder having an average particle size of 2 ⁇ im ⁇ or more is more preferable, with an average particle size of 1 / im or more being preferred. In applications in which the occurrence of abrasive flaws is to be prevented as much as possible, the oxide solid solution powder having an average particle diameter of 3 ⁇ or less is more preferable.
- the ratio of the mass of calcium element to the total oxide mass of the oxide solid solution be 10.7% by mass or less. % Is more preferable. If the above ratio exceeds the upper limit, the calcium element is not completely dissolved in the rare earth oxide such as cerium oxide, and the calcium element may appear outside the rare earth oxide particles in the form of calcium oxide. On the other hand, if such calcium oxide is present in the abrasive, it will cause abrasive flaws and the adherence of abrasive (hills). The effect of improving the polished surface accuracy is obtained according to the solid solution amount of the calcium oxide.
- the calcium element is dissolved in a minimum amount (for example, May be 0.01% by mass or more), but 2.0% by mass or more is more preferable for the purpose of obtaining a certain effect.
- It is the total oxide equivalent mass of the oxide solid solution. If the composition of the oxide solid solution is known, calculate the oxide equivalent mass for each element in the oxide solid solution. Is required. In the calculation of the oxide equivalent mass of each rare earth element in the present invention, the reduced mass of a rare earth oxide in which other substances such as a calcium component did not form a solid solution was calculated.
- the total rare earth oxide equivalent (TREO) used in the following description is the total mass of rare earth oxides when all the rare earth elements contained in the target substance are present as rare earth oxides. That is.
- the oxide solid solution powder As a substance (solute) used for dissolving calcium element in cerium oxide, calcium nitrate, calcium salt calcium, calcium carbonate or the like is preferable. Among these, calcium nitrate is particularly preferred in that it has excellent solution reactivity.
- the rare earth oxide is an oxide of a rare earth element such as cerium, lanthanum, praseodymium, and neodymium.
- the oxide solid solution powder used as the abrasive is a rare earth oxide containing cerium oxide as a main component, in which lanthanum oxide and Z or praseodymium oxide are in solid solution. Is preferred.
- a polishing test showed that the oxide solid solution powder in which the lanthanum element and / or praseodymium element was dissolved was less susceptible to polishing scratches than the oxide solid solution powder in which these elements were not dissolved. This is because the surface accuracy was excellent.
- the oxide solid solution powder should have a ratio of the total mass of the lanthanum oxide mass and the praseodymium oxide mass to the total oxide equivalent mass of the oxide solid solution of 1 mass% or more. preferable.
- the proportion exceeds 40% by mass, the stability as an oxide solid solution becomes low, and the lanthanum element and praseodymium element in the oxide solid solution are precipitated outside the oxide solid solution as lanthanum oxide and praseodymium oxide. Failures are more likely to occur. Therefore, from this viewpoint, the above ratio is preferably 40% by mass or less.
- the oxide solid solution powder used as the abrasive includes an oxide solid solution powder in which the ratio of the cerium oxide mass to the total oxide equivalent mass of the oxide solid solution is 50% by mass or more. Body powder is preferred. In other words, an oxide solid solution powder containing cerium oxide as a main component is preferable.
- cerium oxide is the most important polishing component. However, if the cerium oxide ratio is less than 50% by mass, a stable polishing rate cannot be secured. is there.
- an oxide solid solution powder in which all of the calcium element and the zirconium element are dissolved in the rare earth oxide is excellent in the polishing surface accuracy, because the force s is inferior to the polishing surface accuracy. That is, as the oxide solid solution powder for the abrasive, an oxide solid solution powder in which calcium oxide and dinoconium oxide are dissolved in a rare earth oxide containing cerium oxide as a main component is preferable. Then, the suitable content of the zirconium element in the solid solution was examined. As a result, the ratio of the mass of dinolenium oxide to the total mass of the oxide solid solution powder in terms of oxide is preferably 0.01% by mass to 15% by mass.
- the ratio exceeds the above upper limit, the crystallinity of the polished particles is reduced and the mechanical polishing force is reduced. If the ratio is less than the lower limit, the polishing rate cannot be improved. In order to obtain a sufficient polishing rate, the above ratio is more preferably not less than 2.2% by mass.
- the oxide solid solution powder of the present invention has excellent properties such as a force suitable for an abrasive because of its excellent polished surface accuracy, and other properties. Is also suitable.
- the oxide solid solution powder of the present invention is mainly composed of a rare earth oxide such as cerium oxide and a solid solution of calcium oxide and / or zirconium oxide. Excellent weatherability, corrosion resistance, and safety. In addition, it has high oxygen storage capacity (OSC) and no photocatalytic activity to decompose organic components. . Therefore, the oxide solid solution powder of the present invention is also suitable as a catalyst or co-catalyst for automobiles.
- OSC oxygen storage capacity
- the term "catalyst" described in the claims of the present application is used as a term that includes a so-called promoter as a promoter. Have been. Further, the oxide solid solution powder of the present invention has no photocatalytic activity capable of decomposing organic components, and thus is also suitable as an ultraviolet absorber used in cosmetics, paints, and the like. It is.
- the use of the powdered rare earth oxide solid solution for purposes such as a catalyst carrier, a catalyst, a catalyst, or an ultraviolet absorber is a well-known method of use, and a description of the method of use and the like will be omitted.
- the oxide solid solution powder according to the present invention is used as, for example, an abrasive
- the glass material of the glass substrate can be polished with a high level of polished surface accuracy, and can be used as a catalyst support for automobiles and the like. If used, it can provide a catalyst carrier that is excellent in A / F (air-fuel ratio) atmosphere control characteristics and nitrogen oxide removal performance. It can be used as a UV absorber in cosmetics, paints, etc. Reasonable description of drawings that can provide UV absorbers with UV absorbing ability
- FIG. 1 is a flowchart showing a manufacturing process.
- FIG. 2 is an XRD chart of the abrasive obtained in each example of the first embodiment.
- FIG. 3 is a graph showing the relationship between the ratio of calcium element in the abrasive slurry and the polishing surface accuracy.
- FIG. 4 is an XRD chart of the abrasive obtained in each example of the third embodiment.
- FIG. 5 is a graph showing the results of measuring oxygen storage and desorption abilities of the fourth embodiment.
- FIG. 6 DSR of N ⁇ x adsorbed species and adsorption ability of the fourth embodiment.
- FIG. 7 A DSR of the fourth embodiment in which N ⁇ x adsorbed species and adsorption capacity were investigated.
- FIG. 8 is a DSR of the fourth embodiment in which the N ⁇ x adsorbed species and the adsorbability were investigated.
- FIG. 9 DSR of N 4x adsorbed species and adsorption ability of the fourth embodiment.
- First embodiment bear In this embodiment bear, cerium carbonate, lanthanum carbonate, praseodymium carbonate, and calcium carbonate are prepared, and these are individually dissolved in an aqueous nitric acid solution to remove foreign substances. After being removed by filtration, the purified water was removed, and a 200 g / L (gram / liter) cerium nitrate aqueous solution, a lanthanum nitrate aqueous solution, a praseodymium nitrate aqueous solution and a nitric acid aqueous solution of calcium nitrate were prepared.
- aqueous solution (2 L, 84 g ZL) was prepared. Then, while stirring the entire amount of the mixed solution obtained above, the mixture was dropped into an aqueous solution of ammonium hydrogen carbonate in a vigorously stirred state at 350 rpm to obtain coprecipitated particles of carbonate (Step 2). The feed speed at the time of dropping was 50 mlZ minutes. Next, the suspension containing the coprecipitated particles was aged for 2 hours at room temperature (Step 3), and the aged suspension was diluted to 20 L with pure water. The diluted suspension was allowed to stand for 3 hours to precipitate coprecipitated particles (Step 4).
- Step 5 After standing, decantation was performed until the volumetric force of the precipitated coprecipitated particles reached less than 3 ⁇ 4L (Step 5), and then washing was performed using a ceramic cleaning device (Step 6). In this washing, washing was performed until the nitrate ion concentration in the suspension became 20 ppm or less, and a suspension containing coprecipitated particles was obtained. After washing, the suspension containing the coprecipitated particles was filtered to obtain a cake of coprecipitated particles (step 7).
- the obtained cake is dried with a hot air drier (hot air temperature 120 ° C, drying time 8 hours) (Step 8), and the obtained dried product is crushed (Step 9).
- a hot air drier hot air temperature 120 ° C, drying time 8 hours
- Step 9 the obtained dried product is crushed.
- Is calcined in an electric furnace (calcining temperature: 300 ° C, calcining time: 3 hours) (Step 10), and the calcined product (so-called decarbonated particles) is crushed (Step 11).
- the product is roasted in an electric furnace (roasting temperature 900 ° C, roasting time 3 hours) (Step 12), and a rare earth oxide containing cerium oxide (Ce ⁇ ) as a main component is converted to calcium oxide (Ca).
- an oxide solid solution (rare earth element-Ca complex oxide) in which O) was dissolved was obtained. Then, this oxide solid solution was crushed (step 13) to obtain an abrasive (oxide solid solution powder).
- the average particle size of the obtained abrasive was 2.0 zm.
- the term “rare earth oxide” is used, including an oxide solid solution containing a rare earth oxide as a main component in one form of the rare earth oxide. Therefore, regarding the abrasive particles of the abrasive obtained in each of the examples and comparative examples, "Rare earth” When the term “similar oxide” is used, the "rare earth oxide” includes an oxide solid solution in which an oxide other than the rare earth oxide is dissolved in the rare earth oxide.
- Examples 2-5 and Comparative Examples 1 and 2 These Examples and Comparative Examples differ from Example 1 in the ratio of the weight of each rare earth element in terms of oxide in a mixed state.
- the mixing ratios in the respective examples and comparative examples are as shown in Table 1. The other points are the same as in the first embodiment, and the description thereof is omitted.
- Comparative Examples 4-1 7 These comparative examples are different from Comparative Example 3 in the ratio of the weight of each rare earth element in terms of oxide in the state of a mixture.
- the ratio in each comparative example is as shown in Table 1.
- Comparative Example 8 In this comparative example, a high-purity colloidal silica known for precision polishing of a glass substrate was prepared. The average particle size of the colloidal silica was 0.06 ⁇ m.
- X-ray Diffraction Apparatus MXP18: manufactured by Mac Science Co., Ltd.
- XRD measurement was performed using.
- Cu copper
- the measurement results are as shown in FIG.
- FIG. 2 in order to facilitate reading of the chart, the charts of the abrasives other than the abrasive of Example 2 are shown on the graph with the base level shifted upward.
- the abrasives obtained in each of the examples and comparative examples were subjected to an abrasive test using an Oscar-type abrasive.
- the polishing test method is to simultaneously grind three disk-shaped glass materials (made of BK-7, polished material) with a diameter of 30 mm using a 180 mm-diameter normal plate to which polyurethane polishing pads are attached. there were.
- 0.1 L of an abrasive slurry was prepared using the abrasives obtained in the respective Examples and Comparative Examples, and the prepared abrasive slurry was circulated and supplied at a rate of 3 L / min to perform an abrasive test.
- the rotation speed of the polishing pad was 33 rpm
- the swing rotation speed was 30 rpm
- the swing width was 60 mm.
- the polishing pressure was 19.6 kPa (200 g / cm 2 ), and the polishing time was 30 minutes.
- the preparation of the abrasive slurry in the polishing test was as follows. In each of the examples and comparative examples 1 and 2, the powdered abrasive and pure water were mixed and stirred at room temperature to form an abrasive slurry in which the proportion of the abrasive in the entire abrasive slurry was 10% by mass. 0.1 L was prepared. In Comparative Example 37, the powdered abrasive, the calcium chloride powder, and water were mixed and stirred at room temperature to form an abrasive slurry in which the ratio of the abrasive to the entire slurry was 10% by mass. One liter was prepared.
- the mixing amount of the calcium chloride powder in Comparative Examples 3-7 was such that the mass ratio of the calcium element in the abrasive slurry became the value shown in Table 1.
- the mixing amount is the same as the mass ratio of calcium element in the abrasive slurry of Example 15 and the mass ratio of calcium ions (Ca 2+ ) in the suspension of the abrasive slurry of Comparative Example 37. It is the amount determined based on the standard of making it around.
- 25 g of a 40% by mass colloidal silica slurry was prepared and mixed with 75 ml of pure water at room temperature and stirred, and the proportion of the abrasive in the entire abrasive slurry was 10% by mass.
- Polishing special evaluation of the polishing material After the polishing, the polished surface of the glass material was washed with pure water and dried in a dust-free state, and then the reduced thickness ( ⁇ m) of the object to be polished was measured. The polishing rate was evaluated by using the “reduced thickness per unit time ( ⁇ mZ)” calculated from the thickness and the polishing time. In addition, the average surface roughness (Ra) was measured using an atomic force microscope (AFM), and this was used to evaluate the polished surface accuracy of the polished surface. The polishing speeds and polished surface precisions of the abrasives of Examples and Comparative Examples are as shown in Table 1.
- Example 1 2.14 96.98 61.86 30.93 7.20 0.02 None 1.96-1.82 0.061
- Example 2 0.02 99.99 60.01 32.98 6.98 0.02 None 2.98-2.97 0.164
- Example 3 0.72 98.97 60.61 32.32 7.05 0.02 None 2.46-2.48 0.161
- Example 4 3.57 94.98 63.16 29.47 7.35 0.02 None 1.78-1.78 0.054
- Example 5 7.15 89.98 66.67 25.56 7.76 0.02 None 1.73-1.49 0.028
- Comparative Example 1 10.71 84.98 70.59 21.18 8.22 0.02 Yes 1.72-4.67 0.048
- Comparative Example 2 21.43 69.97 85.71 4.29 9.98 0.02 Yes 1.76-4.72 0.068
- Comparative Example 3 ⁇ 99.97 62.02 31.00 6.96 0.02 ⁇ 3.76 0.214 4.42 0.165
- Comparative Example 4 ⁇ 99.98 60.00 33.01 6.97
- the laboratory material is colloidal silica.
- the abrasives of Examples 15 to 15 had a complete solid solution of calcium element in the rare earth oxide, and as a result of XRD measurement, no calcium oxide was detected.
- the abrasives of Examples 15 to 15 the greater the proportion of the calcium element in the raw material, the better the polished surface precision.
- the abrasive of each example has a significantly larger abrasive particle diameter than the abrasive of Comparative Example 8 (colloidal silica), but has the same or better abrasive surface accuracy. The speed was also equal or higher.
- the abrasives of Comparative Examples 1 and 2 had incomplete solid solution of calcium element, and as a result of XRD measurement, calcium oxide was detected.
- the abrasives of Comparative Examples 1 and 2 had the same polishing rate as the abrasives of Examples 4 and 5 and Comparative Example 8 (colloidal silica). Despite the higher polishing rate, many polishing scratches were generated and the polishing surface accuracy was poor.
- a cerium-based abrasive in which calcium element was dissolved in rare earth oxide was produced.
- the production method of the abrasives of Examples 35 and Comparative Example 3 of Patent Document 2 ie, rare earth carbonate and the like (rare earth carbonate and / or rare earth oxide) and alkali metal salt and / or alkaline earth metal
- a method for producing an abrasive is used in which the salt is simply mixed and roasted, it is not possible to produce abrasive particles in which the alkaline earth element is completely dissolved in the rare earth oxide, and the present invention is not applicable.
- the abrasives of Comparative Examples 1 and 2 used for comparison with the example it was found that alkaline earth oxides appeared in the abrasive.
- the abrasives of Comparative Examples 3-7 in which calcium ions (Ca 2+ ) were present in the suspension of the abrasive slurry were the abrasives of Examples 15 to 15.
- the polished surface precision was remarkably inferior to the material.
- the cerium oxide is not included in the suspension of the abrasive slurry in the form of calcium ions, as in Example 15-15. It has been found that it is preferable to use an oxide solid solution powder in which calcium oxide is dissolved (completely dissolved) in a rare earth oxide as a main component as the abrasive.
- abrasive components such as bastnaesite concentrate used in the production of abrasives and industrial water contain calcium components in the form of alkaline earth metal salts, etc., and calcium ions derived from these components are polished. Although it may inevitably remain in the suspension of the material slurry, it has been found that it is preferable that calcium ions remain as much as possible, since it may reduce the accuracy of the polished surface.
- the abrasive of Example 15 (calcium element contained in rare earth oxide)
- the proportion of calcium element exceeds 0% by mass and is less than 2% by mass (especially 0.5% by mass or more).
- the polishing surface accuracy has been improved.
- the ratio of the calcium element was in the range of 2% by weight or more, stable and excellent polished surface accuracy was obtained.
- the ratio of calcium element is more preferably 0.5% by mass or more, and more preferably 2% by mass or more. However, considering the above-mentioned abrasive flaws, the ratio is preferably 10.7% by mass or less, more preferably 7.15% by mass or less.
- This embodiment relates to a so-called high-grade cerium-based abrasive having a high cerium oxide content.
- Example 6-9 At the time of production of the abrasive, the mixing ratio of the cerium nitrate aqueous solution, the lanthanum nitrate aqueous solution, the praseodymium nitrate aqueous solution, and the calcium nitrate aqueous solution to be mixed when preparing the mixture is different from that of the first embodiment.
- the ratio of the mass of each rare earth element and calcium element in terms of oxide in the mixed solution of each example is as shown in Table 2. Other conditions were the same as those in Example 1 of the first embodiment.
- Comparative Example 9-112 In this comparative example, unlike the above-mentioned Example 69, the calcium component was not added to the raw material, and the material was applied without difficulty. In Comparative Examples 9-112, the ratio of the oxide-converted mass of the rare earth element in the abrasive was determined so as to correspond to the mass ratio in Example 69. Other conditions were the same as in Examples 6-9.
- the present embodiment relates to a cerium-based abrasive made of an oxide solid solution in which zirconium oxide, which is not only calcium oxide, is also dissolved in a rare earth oxide.
- a 200 g / L cerium nitrate aqueous solution, a lanthanum nitrate aqueous solution, a praseodymium nitrate aqueous solution, and a calcium nitrate aqueous solution were prepared. Then, in addition to these, zirconyl nitrate (zirconium nitrate oxide) dihydrate is dissolved in pure water to remove foreign substances by filtration, and then pure water is added to add acid.
- a 200 g / L aqueous solution of zirconyl nitrate was prepared in terms of the weight of the compound.
- step 1 The steps after step 1 were the same as in the first embodiment. As a result, an abrasive having an average particle size of 3.9 ⁇ m was obtained.
- Examples 11 to 14 These examples differ from Example 10 in the mixing ratio of each aqueous solution such as an aqueous cerium nitrate solution.
- the mixing ratio in each example is as shown in Table 3. Other conditions were the same as in Example 10.
- Example 15 In this example, two plastic containers (each having a capacity of 100 ml) were prepared, and in each plastic container, 20 g of the abrasive obtained from the abrasive obtained in Example 10 was added. When a zirconate two Abby 360g particle size 0. 8 mm, 1 mass 0/0 of crystalline cellulose (product name: Avicel, Asahi Kasei Corporation) and an aqueous solution 10ml, and Kisametarin aqueous sodium 10ml to the 1 wt% pure water 20 ml each was added, and the abrasive was wet-milled for 3 hours using a paint shaker.
- Examples 16 to 19 These examples are different from Example 15 in the abrasive to be put in the two prepared plastic containers.
- Example 16 the abrasive obtained in Example 11 was used, in Example 17, the abrasive obtained in Example 12 was used, and in Example 18, the abrasive obtained in Example 13 was used.
- Example 19 the abrasive obtained in Example 14 was used.
- the conditions other than the type of abrasive used were the same as in Example 15.
- the average particle size of the obtained abrasive is as shown in Table 3.
- Comparative Examples 13 and 14 These comparative examples differ from Example 15 in that each rare earth in a mixed state The ratio of the weight in terms of the oxide of the class element is different. The mixing ratio in each comparative example is as shown in Table 3. Other conditions were the same as in Example 15. The average particle size of the obtained abrasive is as shown in Table 3.
- Comparative Example 15 This comparative example is different from Example 15 in the stirring speed during the synthesis (see step 2 of Example 1). The stirring speed was 150 rpm. Other conditions were the same as in Example 15. As a result, an abrasive having an average particle size of 1.67 zm was obtained.
- an aqueous solution of zirconyl nitrate was prepared, and pure water was added thereto to obtain 0.3 L of an aqueous solution B (step 1).
- the mass of dinoreconium contained in the mixture B was 9 g in terms of oxide.
- 2 L (concentration: 84 g / L) of an aqueous solution of ammonium hydrogen carbonate was prepared, which was 1.2 equivalents to the total amount of the mixed solution A and the aqueous solution B. Then, the whole amount of the mixed solution A obtained above was dropped into the aqueous solution of ammonium hydrogen carbonate in a stirred state while stirring to obtain coprecipitated particles of carbonate (Step 2).
- aqueous solution B was dropped into the aqueous solution of ammonium bicarbonate in which co-precipitated particles of the carbonate were present in the same manner as in the case of the mixed solution A to obtain a suspension containing a precipitate of the dinoreconium component (Step 3).
- Feeding speed for dropping is 5
- Step 4 the suspension containing the coprecipitated particles and the precipitate of the zirconium component was aged for 2 hours at room temperature (Step 4), and the aged suspension was diluted to 20 L with pure water. The diluted suspension was allowed to stand for 3 hours to precipitate coprecipitated particles (Step 5). After standing, decantation was performed until the volume of the precipitated coprecipitated particles reached less than 4 L (Step 6), and then washing was performed using a ceramic washing device (Step 7). In this washing, washing was performed until the nitrate ion concentration in the suspension became 20 ppm or less. After washing, the aqueous solution containing the coprecipitated particles was filtered to obtain a cake of coprecipitated particles (step 8).
- the obtained cake is dried with a hot air drier (hot air temperature 120 ° C, drying time 8 hours) (Step 9), and the obtained dried product is crushed (Step 10).
- the electric furnace (calcination temperature 300 ° C Calcined in a roasting time of 3 hours) (Step 11), crush the calcined product (Step 12), and convert the crushed calcined product into an electric furnace (roasting temperature 900 ° C, roasting time). (3 hours), and the roasted product was crushed (step 14) to obtain a powder of an oxide solid solution (a rare earth element-Ca-Zr composite oxide).
- each of the two prepared plastic containers (capacity: 100 ml each)
- 20 g of the obtained solid solution of the oxide 360 g of dinoreconia beads having a particle diameter of 0.8 mm, and 1 mass% 10 ml of an Avicel aqueous solution, 1 Oml of a 1% by mass aqueous solution of sodium hexametaphosphate, and 20 ml of pure water were added, and the oxide solid solution was wet-mixed and pulverized for 3 hours using a paint shaker (step 15).
- the zirconia beads were removed from the obtained mixture using a 30-mesh (mesh opening 500 ⁇ m) sieve to obtain an abrasive slurry (oxide solid solution slurry) (Step 16). Then, pure water was added to the obtained abrasive slurry to prepare an abrasive slurry in which the proportion of the abrasive in the entire slurry was 10% by mass (step 17). The amount of the abrasive slurry used in the polishing test was 0.1 L as in the other examples. The average particle size of the obtained abrasive was 1.8 / im.
- the abrasives of Examples 10-19 and Comparative Examples 13-16 were subjected to the above-mentioned XRD measurement to evaluate the presence or absence of CaO (see Table 3).
- XRD charts of the abrasives of Example 15, Comparative Example 15 and Comparative Example 16 are shown in FIG.
- the abrasives of Examples 10-19 and Comparative Examples 13-16 were subjected to the above-mentioned polishing test to evaluate the polished surface accuracy and the polishing speed. The results are shown in Table 3.
- the method of preparing the abrasive slurry in the abrasive test was the same as that of each example of the first embodiment for the abrasive obtained in Examples 10-14. In Examples 15-19 and Comparative Examples 13-16, the abrasive slurry finally prepared was used as it was in the polishing test.
- the XRD chart of the abrasive of Example 16 has the following values: around 29.7 °, around 34.5 ° and 49.4 ° In the vicinity, a peak that did not appear in the abrasive of the example appeared. These peaks also indicate the presence of zirconium oxide (identified as Ce—Zr composite oxide).
- Gamma - J show that the components such as CaO or Zr0 2 present Shinano force, one has to Kenco material particles not Ca or Zr is added to the raw material.
- the abrasives of Examples 10 to 19 had a complete solid solution of calcium and zirconium elements in the rare earth oxides. There was no detection of lucidum and zirconium oxide.
- the abrasives of Examples 10 to 19 had the same polished surface accuracy and higher polishing speed than the abrasives of the respective examples of the first embodiment.
- a cerium-based abrasive made of an oxide solid solution powder in which a rare earth oxide containing cerium oxide as a main component and a dinoconium element that is a solid solution in addition to the calcium element alone has a high level, a high polished surface precision, and a high level It was found to be excellent, having a high polishing rate.
- the abrasives of Examples 15 and 19 were the same as those of Example 1.
- the average particle size was smaller than that of the abrasive material No. 0-14, and the polishing surface accuracy was excellent.
- the oxide solid solution particles having a smaller average particle diameter had better polishing surface accuracy and were suitable as an abrasive.
- the abrasives of Comparative Examples 13 and 14 had a higher ratio of dinoreconia elements than the abrasives of the above-described examples.
- the accuracy of the polished surface was inferior to that of the abrasive of the example. Although the reason for this is not necessarily clear, if the zirconium element is excessively dissolved in the rare-earth oxide, the crystallinity of the rare-earth oxide crystal is greatly reduced, and the polishing characteristics such as the polishing surface accuracy are reduced.
- Comparative Examples 15 and 16 had incomplete solid solution of the zirconium element.
- the zirconium oxide identified as CaZrO
- Comparative Example 16 another dinoreconium oxide (identified as a Ce—Zr composite oxide) was detected.
- the abrasives of these comparative examples were inferior in both the polished surface accuracy and the polishing speed to the abrasives of the examples.
- the calcium element and the dinoreconium element are completely used as the abrasive. It is solid solution, and the abrasive particles (oxide solid solution particles) Preference is given to those in which calcium oxide or zirconium oxide does not appear on the outside, and the ratio of the mass of the dinoreconium element to the total oxide equivalent mass of the abrasive is preferably 0.01% by mass to 15% by mass. I understood that.
- Oxygen storage / desorption capacity This oxygen storage / desorption capacity was measured by a thermal conductivity detector with a sample amount of 0.025 ⁇ 0.001 Og. The measurement temperature was 400 800 ° C (every 100 ° C), He was used as the carrier gas, and the pulse size was 1.79 mL. The specific measurement procedure was as follows. First, the measurement sample was kept in 200 ccm He at 800 ° C for 10 minutes, and then cooled to the minimum measurement temperature (400 ° C). After each measurement temperature, 4 or more ⁇ pulses, H pulse and
- O pulses Four or more O pulses were alternately introduced. 800 ° C heat treatment is performed only for the first time, ° C force Measurement was performed by sequentially setting the measurement temperature to the higher temperature side.
- OSC oxygen storage desorption capacity
- FIG. 5 is a graph in which the storage and desorption capacity of oxygen at each measurement temperature is plotted. According to FIG. 5, the oxygen storage in the order of Comparative Example 12, Example 9, and Example 20 was performed. It was confirmed that the desorption ability was improved. Therefore, it was found that when Ca or Zr was dissolved in cerium oxide, the oxygen storage / desorption ability was improved.
- N ⁇ x adsorbed species ⁇ Adsorption capacity The NOx adsorbed species ⁇ adsorption capacity was measured by a diffuse reflection spectrum detector (DSR) using a sample volume of 0.025 ⁇ 0.001 lg (carrier gas He). . The measurement temperature was 200 ° C and 500 ° C (every 100 ° C), and the diffuse reflection spectrum was detected. First, after holding the measurement sample at 600 ° C and 390 ccm He ( ⁇ 5%) for 10 minutes,
- FIG. 6-9 shows the measurement results of the absorption wavelength and the intensity at each measurement temperature.
- N ⁇ x removal ability This NOx removal ability was measured by a heat conduction detector and a mass spectrometer with a sample volume of 0.025 ⁇ 0.001 (carrier gas He). In the measurement, the sample was kept at 600 ° C for 10 minutes in He flow, and then cooled to the adsorption temperature of 300 ° C. And, after introducing NO / O (5%) ZHe, hold for 30min, then switch to He flow, 10 ° C
- the temperature was raised to 600 ° C at / min, and the desorbed gas was measured.
- Example 12 NOx desorption could not be confirmed.
- Example 9 gas with a mass number of 30 was detected, and desorption of NO gas was confirmed.
- Example 20 gas detection of mass numbers 30 and 32 was recognized, and desorption of NO gas was confirmed.
- the oxide solid solution powder according to the present invention can be used as an abrasive, a catalyst carrier, an ultraviolet absorber, or the like.
- a glass material on a glass substrate can be polished with high polished surface accuracy.
- a catalyst carrier with excellent A / F atmosphere control characteristics and nitrogen oxide removal performance can be used.
- various ultraviolet absorbers such as an ultraviolet absorber contained in cosmetics and coatings, it is possible to provide an ultraviolet absorber having a high level of ultraviolet absorption.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Finish Polishing, Edge Sharpening, And Grinding By Specific Grinding Devices (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Catalysts (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP05703325A EP1707534A1 (en) | 2004-01-21 | 2005-01-06 | Oxide solid solution powder |
JP2005517215A JP4906348B2 (ja) | 2004-01-21 | 2005-01-06 | セリウム系研摩材及びその研摩方法 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004012939 | 2004-01-21 | ||
JP2004-012939 | 2004-01-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2005070832A1 true WO2005070832A1 (ja) | 2005-08-04 |
Family
ID=34805366
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2005/000053 WO2005070832A1 (ja) | 2004-01-21 | 2005-01-06 | 酸化物固溶体粉末 |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP1707534A1 (ja) |
JP (1) | JP4906348B2 (ja) |
KR (1) | KR100706095B1 (ja) |
CN (1) | CN100410176C (ja) |
TW (1) | TWI304791B (ja) |
WO (1) | WO2005070832A1 (ja) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007222868A (ja) * | 2006-01-27 | 2007-09-06 | Mitsui Mining & Smelting Co Ltd | 脱酸素剤及び脱酸素剤の製造方法 |
WO2008001745A1 (fr) * | 2006-06-29 | 2008-01-03 | Mitsui Mining & Smelting Co., Ltd. | Agent déshumidifiant/désoxydant |
WO2008001732A1 (fr) * | 2006-06-29 | 2008-01-03 | Mitsui Mining & Smelting Co., Ltd. | Procédé de déshumidification/désoxygénation et emballage désoxygénant, film qui présente une fonction de désoxygénation et composition de résine désoxygénante, toutes deux présentant une fonction de déshumidification |
WO2008140004A1 (ja) * | 2007-05-10 | 2008-11-20 | Mitsui Mining & Smelting Co., Ltd. | 脱酸素剤及び脱酸素剤の製造方法 |
JP2012201884A (ja) * | 2012-01-25 | 2012-10-22 | Mie Industry & Enterprise Support Center | ガラス用研磨材 |
JP2013082050A (ja) * | 2011-10-12 | 2013-05-09 | Japan Fine Ceramics Center | 研磨材料、研磨用組成物及び研磨方法 |
JP2013216559A (ja) * | 2012-04-05 | 2013-10-24 | China Steel Corp | 遠赤外線放射性材料及びその製造方法 |
WO2019026401A1 (ja) * | 2017-08-01 | 2019-02-07 | 信越化学工業株式会社 | シリコーンゴム組成物 |
JP2019087571A (ja) * | 2017-11-02 | 2019-06-06 | 花王株式会社 | 複合砥粒 |
CN115724457A (zh) * | 2022-12-05 | 2023-03-03 | 上海华明高纳稀土新材料有限公司 | 一种白色纳米氧化铈及其制备方法 |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101568615B (zh) * | 2006-12-28 | 2013-02-06 | 花王株式会社 | 研磨液组合物 |
WO2010054054A2 (en) * | 2008-11-05 | 2010-05-14 | Wayne State University | Calcium and lanthanum solid base catalysts for transesterification |
WO2010118553A1 (en) | 2009-04-15 | 2010-10-21 | Rhodia (China) Co., Ltd. | A cerium-based particle composition and the preparation thereof |
CN102559064B (zh) * | 2011-12-15 | 2014-01-29 | 上海华明高纳稀土新材料有限公司 | 铈锆镨固溶体及其制备方法 |
CN103923603A (zh) * | 2013-01-15 | 2014-07-16 | 安阳市岷山有色金属有限责任公司 | 一种氧化物固溶体粉末 |
JP2015120844A (ja) * | 2013-12-24 | 2015-07-02 | 旭硝子株式会社 | 研磨剤の製造方法、研磨方法および半導体集積回路装置の製造方法 |
CN105797706A (zh) * | 2014-12-29 | 2016-07-27 | 北京有色金属研究总院 | 柴油车尾气颗粒物净化用铈镧固溶体催化剂及其制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06316416A (ja) * | 1993-02-10 | 1994-11-15 | Rhone Poulenc Chim | ジルコニウム及びセリウムの混合酸化物を基とする組成物の製造方法 |
JPH10154523A (ja) * | 1996-09-27 | 1998-06-09 | Tosoh Corp | 欠陥ホタル石型セリア系固体電解質 |
JP2002155269A (ja) * | 2000-11-24 | 2002-05-28 | Mitsui Mining & Smelting Co Ltd | セリウム系研摩材の製造方法及びセリウム系研摩材 |
JP2003020277A (ja) * | 2001-04-27 | 2003-01-24 | Air Products & Chemicals Inc | セリアにもとづく固体電解質 |
JP2004002870A (ja) * | 2003-06-11 | 2004-01-08 | Seimi Chem Co Ltd | セリウム研磨材製造用の軽希土類原料 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3738454B2 (ja) * | 1993-08-11 | 2006-01-25 | 住友化学株式会社 | 複合金属酸化物粉末およびその製造方法 |
FR2736343B1 (fr) * | 1995-07-03 | 1997-09-19 | Rhone Poulenc Chimie | Composition a base d'oxyde de zirconium et d'oxyde de cerium, procede de preparation et utilisation |
TW528796B (en) * | 2000-12-13 | 2003-04-21 | Mitsui Mining & Amp Smelting C | Cerium-based abrasive and method of evaluating the same |
CN1206028C (zh) * | 2003-04-28 | 2005-06-15 | 华东理工大学 | 一种纳米铈锆基复合氧化物及其制备方法 |
-
2005
- 2005-01-06 EP EP05703325A patent/EP1707534A1/en not_active Withdrawn
- 2005-01-06 WO PCT/JP2005/000053 patent/WO2005070832A1/ja active IP Right Grant
- 2005-01-06 KR KR1020057017501A patent/KR100706095B1/ko not_active IP Right Cessation
- 2005-01-06 CN CNB2005800000852A patent/CN100410176C/zh not_active Expired - Fee Related
- 2005-01-06 JP JP2005517215A patent/JP4906348B2/ja not_active Expired - Fee Related
- 2005-01-20 TW TW094101641A patent/TWI304791B/zh not_active IP Right Cessation
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06316416A (ja) * | 1993-02-10 | 1994-11-15 | Rhone Poulenc Chim | ジルコニウム及びセリウムの混合酸化物を基とする組成物の製造方法 |
JPH10154523A (ja) * | 1996-09-27 | 1998-06-09 | Tosoh Corp | 欠陥ホタル石型セリア系固体電解質 |
JP2002155269A (ja) * | 2000-11-24 | 2002-05-28 | Mitsui Mining & Smelting Co Ltd | セリウム系研摩材の製造方法及びセリウム系研摩材 |
JP2003020277A (ja) * | 2001-04-27 | 2003-01-24 | Air Products & Chemicals Inc | セリアにもとづく固体電解質 |
JP2004002870A (ja) * | 2003-06-11 | 2004-01-08 | Seimi Chem Co Ltd | セリウム研磨材製造用の軽希土類原料 |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007222868A (ja) * | 2006-01-27 | 2007-09-06 | Mitsui Mining & Smelting Co Ltd | 脱酸素剤及び脱酸素剤の製造方法 |
US8328915B2 (en) | 2006-06-29 | 2012-12-11 | Mitsui Mining & Smelting Co., Ltd. | Dehumidifying deoxidizer |
JP5405744B2 (ja) * | 2006-06-29 | 2014-02-05 | 三井金属鉱業株式会社 | 除湿・脱酸素剤 |
JP2008238170A (ja) * | 2006-06-29 | 2008-10-09 | Mitsui Mining & Smelting Co Ltd | 除湿・脱酸素方法、除湿機能を備えた脱酸素包装体及び脱酸素機能フィルム又は脱酸素樹脂組成物 |
WO2008001745A1 (fr) * | 2006-06-29 | 2008-01-03 | Mitsui Mining & Smelting Co., Ltd. | Agent déshumidifiant/désoxydant |
WO2008001732A1 (fr) * | 2006-06-29 | 2008-01-03 | Mitsui Mining & Smelting Co., Ltd. | Procédé de déshumidification/désoxygénation et emballage désoxygénant, film qui présente une fonction de désoxygénation et composition de résine désoxygénante, toutes deux présentant une fonction de déshumidification |
WO2008140004A1 (ja) * | 2007-05-10 | 2008-11-20 | Mitsui Mining & Smelting Co., Ltd. | 脱酸素剤及び脱酸素剤の製造方法 |
JP2013082050A (ja) * | 2011-10-12 | 2013-05-09 | Japan Fine Ceramics Center | 研磨材料、研磨用組成物及び研磨方法 |
JP2012201884A (ja) * | 2012-01-25 | 2012-10-22 | Mie Industry & Enterprise Support Center | ガラス用研磨材 |
JP2013216559A (ja) * | 2012-04-05 | 2013-10-24 | China Steel Corp | 遠赤外線放射性材料及びその製造方法 |
WO2019026401A1 (ja) * | 2017-08-01 | 2019-02-07 | 信越化学工業株式会社 | シリコーンゴム組成物 |
JP2019026772A (ja) * | 2017-08-01 | 2019-02-21 | 信越化学工業株式会社 | シリコーンゴム組成物 |
JP2019087571A (ja) * | 2017-11-02 | 2019-06-06 | 花王株式会社 | 複合砥粒 |
JP7019379B2 (ja) | 2017-11-02 | 2022-02-15 | 花王株式会社 | 複合砥粒 |
CN115724457A (zh) * | 2022-12-05 | 2023-03-03 | 上海华明高纳稀土新材料有限公司 | 一种白色纳米氧化铈及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
JP4906348B2 (ja) | 2012-03-28 |
TW200535098A (en) | 2005-11-01 |
JPWO2005070832A1 (ja) | 2007-12-27 |
CN1764601A (zh) | 2006-04-26 |
KR100706095B1 (ko) | 2007-04-12 |
EP1707534A1 (en) | 2006-10-04 |
TWI304791B (en) | 2009-01-01 |
CN100410176C (zh) | 2008-08-13 |
KR20050109592A (ko) | 2005-11-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2005070832A1 (ja) | 酸化物固溶体粉末 | |
FI76057C (fi) | Foerfarande foer framstaellning av ceriumoxid med en specifik yta av minst 85 + 5 m2/g och ceriumoxid. | |
JP4328529B2 (ja) | 高い酸素貯蔵能力を有する触媒支持体材料およびこれの製造方法 | |
RU2411995C2 (ru) | Композиция на основе нанометрического оксида церия на носителе с повышенной восстановительной способностью, способ ее получения и применение в качестве катализатора | |
JP5564109B2 (ja) | 特有の多孔度を有する酸化セリウムおよび酸化ジルコニウムを含む組成物、この調製方法および触媒作用におけるこの使用 | |
Wu et al. | Co 3 O 4 particles grown over nanocrystalline CeO 2: influence of precipitation agents and calcination temperature on the catalytic activity for methane oxidation | |
WO2022057593A1 (zh) | 一种核壳结构铈锆基复合氧化物及其制备方法 | |
JP5706546B1 (ja) | セリア−ジルコニア系複合酸化物及びその製造方法 | |
JP3595874B2 (ja) | ジルコニウム−セリウム系複合酸化物及びその製造方法 | |
JPWO2003022740A1 (ja) | 酸化第二セリウム及びその製造法並びに排ガス浄化用触媒 | |
EP2794488B1 (en) | Composite oxide, method for producing the same, and catalyst for exhaust gas purification | |
CN110026179B (zh) | 一种高储氧量的铈锆复合氧化物及其制备方法 | |
JP2005170774A (ja) | 複合酸化物及びその製造方法並びに排ガス浄化用触媒 | |
WO2007132829A1 (ja) | 排ガス浄化用触媒及びその製造方法 | |
JP6701581B2 (ja) | 酸素吸放出材 | |
EP3444225A1 (en) | Alumina-based composite oxide and method for producing same | |
CN104254393B (zh) | 复合氧化物,其生产方法,以及用于排气净化的催化剂 | |
EP2781487B1 (en) | Composite oxide | |
WO2016158656A1 (ja) | 排気ガス浄化用触媒 | |
JP4972868B2 (ja) | 表面修飾されたセリア・ジルコニア系水和酸化物、その酸化物及びそれらの製造方法並びに用途 | |
JP2006247635A (ja) | 排ガス浄化触媒用貴金属含有複合金属酸化物及びその製造方法 | |
WO2020063510A1 (en) | Mixed oxide with improved reducibility | |
JP6322218B2 (ja) | 酸素吸蔵材料及びその製造方法 | |
JP2018150207A (ja) | コアシェル型酸化物材料、それを用いた排ガス浄化用触媒、及び排ガス浄化方法 | |
JP2024053568A (ja) | 還元剤、ガスの製造方法および変換効率増加方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NA NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): GM KE LS MW MZ NA SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LT LU MC NL PL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG |
|
WWE | Wipo information: entry into national phase |
Ref document number: 1020057017501 Country of ref document: KR |
|
WWE | Wipo information: entry into national phase |
Ref document number: 20058000852 Country of ref document: CN |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2005517215 Country of ref document: JP |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 2005703325 Country of ref document: EP |
|
WWP | Wipo information: published in national office |
Ref document number: 1020057017501 Country of ref document: KR |
|
WWP | Wipo information: published in national office |
Ref document number: 2005703325 Country of ref document: EP |
|
WWG | Wipo information: grant in national office |
Ref document number: 1020057017501 Country of ref document: KR |