WO2005061978A1 - Procede de production d'un gaz naturel liquefie appauvri en azote - Google Patents

Procede de production d'un gaz naturel liquefie appauvri en azote Download PDF

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Publication number
WO2005061978A1
WO2005061978A1 PCT/GB2004/004834 GB2004004834W WO2005061978A1 WO 2005061978 A1 WO2005061978 A1 WO 2005061978A1 GB 2004004834 W GB2004004834 W GB 2004004834W WO 2005061978 A1 WO2005061978 A1 WO 2005061978A1
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WIPO (PCT)
Prior art keywords
stream
separation vessel
vapour
separation
pressure
Prior art date
Application number
PCT/GB2004/004834
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English (en)
Inventor
Martin Josten
Andrea Redford
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Bp Exploration Operating Company Limited
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Publication date
Application filed by Bp Exploration Operating Company Limited filed Critical Bp Exploration Operating Company Limited
Publication of WO2005061978A1 publication Critical patent/WO2005061978A1/fr

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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0204—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
    • F25J3/0209—Natural gas or substitute natural gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0022—Hydrocarbons, e.g. natural gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/0042—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by liquid expansion with extraction of work
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0228—Coupling of the liquefaction unit to other units or processes, so-called integrated processes
    • F25J1/0229—Integration with a unit for using hydrocarbons, e.g. consuming hydrocarbons as feed stock
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0257—Construction and layout of liquefaction equipments, e.g. valves, machines
    • F25J1/0274—Retrofitting or revamping of an existing liquefaction unit
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0233—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 1 carbon atom or more
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0257—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of nitrogen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/028—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of noble gases
    • F25J3/029—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of noble gases of helium
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/06—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
    • F25J3/0605—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the feed stream
    • F25J3/061—Natural gas or substitute natural gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/06—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
    • F25J3/063—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream
    • F25J3/0635—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream separation of CnHm with 1 carbon atom or more
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/06—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
    • F25J3/063—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream
    • F25J3/066—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream separation of nitrogen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/06—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
    • F25J3/063—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream
    • F25J3/0685—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream separation of noble gases
    • F25J3/069—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream separation of noble gases of helium
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00—Processes or apparatus using separation by rectification
    • F25J2200/04—Processes or apparatus using separation by rectification in a dual pressure main column system
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00—Processes or apparatus using separation by rectification
    • F25J2200/08—Processes or apparatus using separation by rectification in a triple pressure main column system
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00—Processes or apparatus using separation by rectification
    • F25J2200/70—Refluxing the column with a condensed part of the feed stream, i.e. fractionator top is stripped or self-rectified
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2215/00—Processes characterised by the type or other details of the product stream
    • F25J2215/04—Recovery of liquid products
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2220/00—Processes or apparatus involving steps for the removal of impurities
    • F25J2220/60—Separating impurities from natural gas, e.g. mercury, cyclic hydrocarbons
    • F25J2220/62—Separating low boiling components, e.g. He, H2, N2, Air
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2240/00—Processes or apparatus involving steps for expanding of process streams
    • F25J2240/30—Dynamic liquid or hydraulic expansion with extraction of work, e.g. single phase or two-phase turbine
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2260/00—Coupling of processes or apparatus to other units; Integrated schemes
    • F25J2260/60—Integration in an installation using hydrocarbons, e.g. for fuel purposes
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00—Refrigeration techniques used
    • F25J2270/90—External refrigeration, e.g. conventional closed-loop mechanical refrigeration unit using Freon or NH3, unspecified external refrigeration
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2290/00—Other details not covered by groups F25J2200/00 - F25J2280/00
    • F25J2290/80—Retrofitting, revamping or debottlenecking of existing plant

Definitions

  • the present invention relates to a process for separating a multi-component stream containing methane and at least one high volatility component having a relative volatility greater than that of methane and for producing liquefied natural gas ("LNG").
  • LNG liquefied natural gas
  • a preliminary gas treatment stage for the removal of water and acidic gases such as carbon dioxide and hydrogen sulphide (2) a natural gas liquids product separation stage using low but non-cryogenic temperatures for the separation and recovery of the propane and heavier hydrocarbon components, (3) a cooling stage wherein the natural gas is at least partially liquefied and (4) a nitrogen separation or rejection stage.
  • the nitrogen rejection stage is generally effected by fractionating the at least partially liquefied natural gas in a separation column to produce a vapour stream and a liquid stream.
  • the vapour stream from the separation column is rich in nitrogen (for example, about 20 mole %) and is generally used as fuel for the gas turbines that provide power to the liquefaction plant.
  • the gaseous products of the separation stages are generally combined to form the fuel gas.
  • a liquefaction plant is located in a -geographical area having elevated summer temperatures
  • the LNG production capacity of the plant is constrained because the performance of the air coolers that are used to reject the process heat to atmosphere is reduced. It has been found that this decrease in capacity of the LNG plant under summer temperature conditions can be significantly mitigated by a combination of increasing the flow rate of the natural gas feed to the liquefaction plant and of running the cooling stage at a slightly increased outlet temperature.
  • a disadvantage of operating the plant in this manner is that an increased amount of vapour is separated in the nitrogen separation or rejection stage.
  • the separated vapour may exceed the amount required as fuel gas for the turbines that provide power to the liquefaction plant.
  • the vapour from the nitrogen separation stage is acceptable for use as fuel gas for the turbines, the excess vapour may not be suitable for use as feed to a domestic gas network as its high nitrogen content reduces its heating value.
  • domestic fuel gas is generally required to have a content of nitrogen and other high- volatility gases of less than 5.5 mole%. Accordingly, there is a need for a method of reducing the nitrogen content of the excess vapour from the nitrogen rejection stage.
  • the present invention relates to a liquefaction process comprising:
  • the present invention is particularly suitable as a process for producing liquefied natural gas.
  • the second liquid stream enriched in methane is liquefied natural gas
  • the first vapour stream is fuel gas
  • the second vapour stream is domestic gas.
  • An advantage of performing the separation of the high-volatility component in two separation vessels is that the first separation vessel is operated at a higher pressure than the-second separation vessel so that a larger proportion of the high-volatility component is separated in the first separation vessel than the second separation vessel. It is preferred that the pressures of the first and second separation vessels are selected such that the second vapour stream from the second separation vessel has a high- volatility component content that meets the specification for domestic gas while the amount of the first vapour stream that is withdrawn from the first separation vessel is not in excess of the amount that can be consumed in the liquefaction plant and/or in a plant that is co-located with or in the vicinity of the liquefaction plant (hereinafter referred to as "co-located plant").
  • the first vapour stream may be consumed as fuel for the gas turbines that power the liquefaction plant, and/or as feed to a gas-fired heater or boiler of the liquefaction plant and/or may be consumed in a co-located chemical plant or electric power generation plant.
  • the liquefaction plant may be of any capacity (small or large scale) provided that the amount of the first vapour stream is not in excess of the amount that can be consumed in the liquefaction plant and/or in a co-located plant.
  • prior art liquefaction processes have a high volatility component separation stage that may employ a single separation vessel to separate a vapour stream that is enriched in the high-volatility component from a liquid stream enriched in methane or may employ more than one separation vessel wherein the vapour streams are combined to form a fuel gas.
  • the LNG production rate is limited by the constraint on the amount of the vapour stream that can be consumed in the liquefaction plant and/or in a co-located plant.
  • the performance of the air coolers that are used to reject heat to atmosphere is reduced. Therefore, the temperature of the feed stream to the single separation vessel may be higher than under winter temperature conditions thereby increasing the amount of flashed vapour.
  • the maximum feed rate to the separation stage must be reduced so that the amount of the vapour stream that is withdrawn from the separation stage is not in excess of the amount that can be consumed in the liquefaction plant and/or in the co-located plant.
  • the LNG production capacity of the prior art liquefaction plant is constrained by the summer temperature conditions.
  • the process of the present invention removes the constraint on the amount of vapour that may be flashed in the high- volatility component separation stage so that, the reduction in the LNG production capacity of the liquefaction plant during summer temperature conditions may be mitigated by increasing the flow rate of the natural gas feed to the liquefaction plant.
  • the additional gas that is vaporised in the high- volatility component separation stage during summer temperature conditions provides a conditioned gas stream for the domestic gas market.
  • a further advantage of the process of the present invention is that by increasing the flow rate of the natural gas feed to the liquefaction plant, increased amounts of gas condensate (a high value product) may be separated therefrom.
  • advantages of the process of the present invention include: a) mitigating the decrease in the LNG production capacity of a liquefaction plant under summer temperature conditions; b) producing a conditioned natural gas stream for the domestic gas market; c) increasing the natural gas feed rate to the liquefaction plant thereby increasing the amount of gas condensate that is separated therefrom; d) the ability to debottleneck an existing liquefaction plant by retrofitting an additional high- volatility separation vessel thereto; and e) the nitrogen content of the first vapour stream flowing to plant fuel may be reduced as a result of its dilution in a larger overall vapour off-take. This is beneficial to the operation of any gas turbines on the liquefaction plant which are fuelled with this first vapour stream.
  • the separation of the high- volatility component may be achieved using 3 or more separation vessels arranged in series, for example, 3 or 4 separation vessels arranged in series, with each separation vessel in the series being operated at a lower pressure than the preceding separation vessel.
  • the separation vessels in the series are simple gas liquid separation drums or distillation/fractionation columns.
  • the first liquid stream that is withdrawn from the first separation vessel is fed to the second separation vessel in the series while the second liquid stream from the second separation vessel is fed to the third separation vessel in the series.
  • the vapour stream withdrawn from the third separation vessel should have a high- volatility component content that meets the specification for domestic gas while the vapour streams withdrawn from the .
  • first and second separation vessels may be combined and consumed in the liquefaction plant and/or in a co-located plant. Accordingly, the operating pressures of the 3 separation vessels should be selected such that the combined amount of the first and second vapour streams does not exceed the amount that can be consumed in the liquefaction plant and/or co-located plant.
  • the high- volatility component is nitrogen.
  • the feed stream to the first separation vessel may also comprise trace amounts of other high-volatility components such as helium, for example, less than 0.1 mole% of other high- volatility components.
  • the feed stream to the first separation vessel is a liquefied natural gas feed streamior a mixture of liquefied natural gas and natural gas vapour.
  • the feed stream to the first separation vessel has a nitrogen content of greater than 0.5 mole %.
  • the feed stream to the first separation vessel has a nitrogen content of less than 10 mole %.
  • the feed stream is obtained by cooling natural gas in one or more cooling stages upstream of the first separation vessel.
  • the feed stream exits the cooling stage at a temperature in the range -150 to -100°C, preferably - 145 to -130°C, for example, about -135°C.
  • the feed stream exits the cooling stage at a pressure of above 35 bar absolute.
  • the feed stream to the first separation vessel is expanded by a suitable expansion means, for example, an expansion valve or a turboexpander, to a lower pressure prior to being introduced to the first separation vessel.
  • the feed stream to the first separation vessel is expanded to a pressure in the range 2 to 30 bar absolute, preferably 3 to 15 bar absolute, for example 5 to 10 bar absolute. Expansion of the feed stream to a lower pressure effects further cooling of the feed stream.
  • the first separation vessel produces a first liquid stream that is lean in nitrogen and a first vapour stream that is enriched in nitrogen.
  • the first vapour stream that is enriched in nitrogen has a nitrogen content of at least 10 mole%, preferably in the range 10 to 30 mole%.
  • the mass flow rate of the first vapour stream is 5 to ' 10% of the mass flow rate of the feed stream to the first separation vessel.
  • the first vapour stream that is enriched in nitrogen is employed as fuel gas for the gas turbines that power the liquefaction plant and/or as feed to a gas-fired heater or reboiler.
  • the first vapour stream is preferably pressurized to a pressure of at least 30 bar absolute, preferably, at least 40 bar absolute prior to being fed to the gas turbines. It is also envisaged that the first vapour stream may be consumed in a co-located plant.
  • the first liquid stream that is withdrawn from the first separation vessel is passed to a second separation vessel that is operated at a pressure less than that of the • first separation vessel.
  • the operating pressure of the second separation vessel is at least 2 bar below the operating pressure of the first separation vessel.
  • the first liquid stream that is withdrawn from the first separation vessel has a temperature in the range -130 to -160°C.
  • the first liquid stream is expanded by a suitable expansion means, for example, an expansion valve or turboexpander, to a lower pressure prior to being introduced to the second separation vessel. Expansion of the first liquid stream effects further cooling of the first liquid stream.
  • the first liquid stream is expanded to a pressure in the range 1 to 10 bar absolute, preferably 1 to 5 bar absolute, more preferably 1 to 3 bar absolute, most preferably 1 to 2 bar absolute, for example, 1 to 1.5 bar absolute.
  • the first liquid stream is expanded to at or near atmospheric pressure.
  • the second separation vessel produces a second liquid stream that is leaner in nitrogen than the first liquid stream and a second vapour stream that has a reduced content of nitrogen compared with the first vapour stream.
  • the second vapour stream has a content of nitrogen of less than 5.5 mole %, preferably, less than 4.5 mole %.
  • the second vapour stream meets the specification for a domestic gas distribution network.
  • the second vapour stream is then compressed to a pressure of at least 60 bar absolute, more preferably at least 80 bar absolute and is then fed into a domestic gas distribution network.
  • the second liquid stream that is withdrawn from the second separation vessel is introduced into an LNG storage tank.
  • a further advantage of the process of the present invention is that an increased amount of gas maybe flashed in the separation stage compared with a conventional separation stage that employs a single separation vessel. Accordingly, a greater amount of cooling may be achieved in the separation stage of the present invention resulting in a reduced cooling duty for the cooling stage of the liquefaction plant.
  • the first and second separation vessels may be simple gas liquid separation drums.
  • the first and second separation vessels may be distillation or fractionation columns wherein liquid and vapour phases are concurrently contacted to effect separation of a fluid mixture, as for example, by contacting of the vapour and liquid phases on a series of vertically spaced trays or plates mounted within the column or alternatively on packing elements with which the column is filled.
  • the distillation or fractionation columns are operated with reflux and/or reboil.
  • the feed stream enters the first distillation column at an intermediate level.
  • the first vapour stream is withdrawn from at or near the top of the first distillation column.
  • the first liquid stream is withdrawn from at or near the bottom of the first separation column.
  • a small portion of the first liquid stream may be heated and returned to the first distillation column as a vapour return stream.
  • the first liquid stream enters the second distillation column at an intermediate level.
  • the second vapour stream is withdrawn from at or near the top of the second distillation column.
  • the second liquid stream is withdrawn from at or near the bottom of the second separation column.
  • a small portion of the second liquid stream may be returned to the second distillation column as a vapour return stream.
  • Expansion of the liquefied natural gas feed stream 1 effects further cooling of the feed stream.
  • the liquefied natural gas feed stream enters first separation column 4 at an intermediate level.
  • separation column 4 vapour enriched with nitrogen and liquid enriched with methane are separated.
  • the vapour leaves the column as a first vapour stream 5 and the liquid leaves separation column 4 as a first liquid stream 6.
  • the first vapour fraction is compressed to a pressure of about 40 bar absolute in a fuel gas compressor 7 and is then fed as fuel gas to a power plant of the liquefaction plant to drive at least one gas turbine and/or is used as feed to a gas-fired heater or reboiler of the liquefaction plant.
  • the first liquid stream 6 is passed to a second separation column 8 that is similar to the first separation column 5 but is operated at a lower pressure.
  • the operating pressure of the second separation column is in the range 1 to 10 bar absolute, preferably at or approaching atmospheric pressure.
  • the first liquid stream 6 from the first separation column 4 is expanded by a suitable expansion means (not shown) before being fed into the second separation column 8.
  • the first liquid stream 6 enters the second separation column 8 at an intermediate level.
  • vapour enriched with nitrogen and a liquid enriched with methane are separated.
  • the second vapour leaves the column as a second vapour stream 9 and the liquid leaves the column as a second liquid stream 10.
  • the second vapour stream 9 has a nitrogen content that is substantially less than that of the first vapour stream 5.
  • the second vapour stream 9 has a nitrogen content of less than 5.5 mole%.
  • the second vapour stream 9 is fed to a domestic gas compressor system 11 where it is pressurized to a pressure of about 80 bar absolute before being introduced into a domestic gas network.
  • the second liquid stream 10 is fed to a conventional LNG storage tank (not shown), preferably, a tank that stores the LNG at or near atmospheric pressure.

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Separation By Low-Temperature Treatments (AREA)

Abstract

L'invention concerne un procédé de séparation comportant : (a) l'introduction d'un flux d'entrée (I), contenant du méthane et au moins une composante hautement volatile, dans une première cuve de séparation (4) qui fonctionne à une pression de l'ordre de 2 à 30 bars absolus et le prélèvement de cette première cuve de séparation (4) d'un premier flux de liquide enrichi en méthane (6) et un premier flux de vapeur enrichi de la composante hautement volatile (5); et (b) l'introduction du premier flux de liquide enrichi en méthane (6) dans une deuxième cuve de séparation (8) qui fonctionne à une pression de l'ordre de 1 à 10 bars absolus sous réserve que la deuxième cuve de séparation (8) fonctionne à une pression inférieure à la pression de fonctionnement de la première cuve de séparation (4) et le prélèvement de la deuxième cuve de séparation (8) d'un deuxième flux de liquide davantage enrichi en méthane (10) et d'un deuxième flux de vapeur (9) ayant une teneur en la composante hautement volatile inférieure à celle du premier flux de vapeur (5).
PCT/GB2004/004834 2003-12-22 2004-11-17 Procede de production d'un gaz naturel liquefie appauvri en azote WO2005061978A1 (fr)

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GB0329713A GB0329713D0 (en) 2003-12-22 2003-12-22 Process
GB0329713.2 2003-12-22

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1715267A1 (fr) * 2005-04-22 2006-10-25 Air Products And Chemicals, Inc. Elimination en deux étapes de l'azote présent dans du gaz naturel liquéfié
WO2010003894A1 (fr) * 2008-07-10 2010-01-14 Shell Internationale Research Maatschappij B.V. Procédé destiné à éliminer un contaminant gazeux d'un courant gazeux contaminé
US9528759B2 (en) 2008-05-08 2016-12-27 Conocophillips Company Enhanced nitrogen removal in an LNG facility
CN117889612A (zh) * 2024-03-12 2024-04-16 新疆凯龙清洁能源股份有限公司 含氮甲烷气脱氮液化的方法及***

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3348384A (en) * 1965-02-19 1967-10-24 Conch Int Methane Ltd Process for the partial liquefaction of a gas mixture
US3360944A (en) * 1966-04-05 1968-01-02 American Messer Corp Gas liquefaction with work expansion of major feed portion
US3874184A (en) * 1973-05-24 1975-04-01 Phillips Petroleum Co Removing nitrogen from and subsequently liquefying natural gas stream
US4195979A (en) * 1978-05-12 1980-04-01 Phillips Petroleum Company Liquefaction of high pressure gas
DE19821242A1 (de) * 1998-05-12 1999-11-18 Linde Ag Verfahren und Vorrichtung zum Verflüssigen eines Kohlenwasserstoff-reichen Stromes
US20030136146A1 (en) * 2002-01-18 2003-07-24 Ernesto Fischer-Calderon Integrated processing of natural gas into liquid products

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3348384A (en) * 1965-02-19 1967-10-24 Conch Int Methane Ltd Process for the partial liquefaction of a gas mixture
US3360944A (en) * 1966-04-05 1968-01-02 American Messer Corp Gas liquefaction with work expansion of major feed portion
US3874184A (en) * 1973-05-24 1975-04-01 Phillips Petroleum Co Removing nitrogen from and subsequently liquefying natural gas stream
US4195979A (en) * 1978-05-12 1980-04-01 Phillips Petroleum Company Liquefaction of high pressure gas
DE19821242A1 (de) * 1998-05-12 1999-11-18 Linde Ag Verfahren und Vorrichtung zum Verflüssigen eines Kohlenwasserstoff-reichen Stromes
US20030136146A1 (en) * 2002-01-18 2003-07-24 Ernesto Fischer-Calderon Integrated processing of natural gas into liquid products

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1715267A1 (fr) * 2005-04-22 2006-10-25 Air Products And Chemicals, Inc. Elimination en deux étapes de l'azote présent dans du gaz naturel liquéfié
WO2006111721A1 (fr) 2005-04-22 2006-10-26 Air Products And Chemicals, Inc. Elimination d'azote en deux etapes dans un gaz naturel liquefie
US7520143B2 (en) 2005-04-22 2009-04-21 Air Products And Chemicals, Inc. Dual stage nitrogen rejection from liquefied natural gas
US9528759B2 (en) 2008-05-08 2016-12-27 Conocophillips Company Enhanced nitrogen removal in an LNG facility
WO2010003894A1 (fr) * 2008-07-10 2010-01-14 Shell Internationale Research Maatschappij B.V. Procédé destiné à éliminer un contaminant gazeux d'un courant gazeux contaminé
CN117889612A (zh) * 2024-03-12 2024-04-16 新疆凯龙清洁能源股份有限公司 含氮甲烷气脱氮液化的方法及***
CN117889612B (zh) * 2024-03-12 2024-05-31 新疆凯龙清洁能源股份有限公司 含氮甲烷气脱氮液化的方法及***

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