Related Applications [0001] This application claims benefit of U.S. Provisional Application No.
60/496,886, entitled "Sputtered Contamination Shielding for an Ion Source" and
filed August 20, 2003, incorporated herein by reference for all that it discloses and
teaches.
Technical Field [0002] The invention relates generally to ion sources, and more particularly
to shielding for an ion source.
Background [0003] Generally, an ion source is a device that ionizes gas molecules and
focuses, accelerates, and emits the ionized gas molecules and/or atoms in a beam
for a variety of technical and industrial applications. For example, ion sources
may be used as thrusters on space craft. Ion sources are also used in
semiconductor material and device processing, optical filter processing, and
metrology, among other applications. Common uses of ion sources include
without limitation cleaning, assisting deposition (by chemically or physically
activating), polishing, etching and/or depositing of thin- film coatings. Typically, a
substrate is passed through an ion beam (e.g., an etching beam) for such
processing.
[0004] An anode layer source (ALS) typically refers to a Hall-current type
ion source having a grounded cathode and a DC-biased anode. The working gas is
fed into an ionization region in the vicinity of the anode and the cathode, where
the combination of electric and magnetic fields in this region ionizes the molecules
of the working gas and accelerates each ion away from the ionization region
toward a target. The ionization region generally forms a closed-loop (e.g., a race
track shape) in the face of the ion source. The shape of this closed-loop "race
track" may be round, oval, linear with rounded ends, or many other closed shapes.
[0005] One benefit to an ALS is that an ALS does not require a hot cathode
electron source (e.g., filament cathode, hollow cathode, or RF neutralizer) with a
separate power supply to sustain the plasma. ALS cathodes are passive, cold
cathodes, typically made of steel. The cathodes also function as pole pieces for
the ALS magnetic circuit. The cold cathodes do not actively emit electrons, but
ions bombarding the cathodes release secondary electrons that help to sustain the
discharge.
[0006] One problem with an ALS, however, is that the ions striking the
cathodes can also sputter material from the cathodes. The sputtered cathode
material may enter the process as a contaminant. Such cathodes are typically steel
or magnetic stainless steel, so the primary contaminant is iron, although other
contaminants may also exist. The sputtered material tends to emit across a wide
range of angles. As a result, the sputtered material tends to impinge the substrate
surface outside the envelope of the etching beam as well as inside the envelope of
the etching beam. Depending on the type of ion source, the operating regime, and
the application, there may be other ion source electrodes or adjacent components
that also sputter in a similar matter and contribute to substrate contamination.
[0007] Most contaminants impinging the substrate surface prior to and
during the passing of the substrate through the etching beam are etched away by
the beam. However, the contaminants that impinge the surface of the substrate
after the substrate has passed through the etching beam remain as contaminants.
In other words, a substrate tends to acquire a new layer of contaminants after
exiting the envelope of the ion beam. Therefore, for example, etching a substrate
using an ALS may yield an etched substrate having an unacceptable concentration
of iron contaminants sputtered from the ALS itself.
Summary [0008] Implementations described and claimed herein solve the discussed
problems by providing shielding associated with an ion source, such as an ALS.
The shield configuration allows the etching ions to pass to the substrate and
effectively blocks sputtered contaminants from impinging the target substrate
outside the envelope of the etching beam.
[0009] Such shielding associated with an ion source reduces the number of
sputtered contaminants impinging and remaining on the surface of a target
substrate. While passing the ion beam through to the target substrate, shielding
can reduce the total number of sputtered contaminants impinging the substrate
before, during, and/or after passage of the substrate through the envelope of the
etching beam. Particularly, a shield configuration that blocks the contaminants
from impinging the substrate after the substrate passes through the etching beam
(i.e., outside of the envelope of the etching beam) yields a higher quality substrate
(i.e., with lower contamination levels).
[0010] In one implementation, an ion source system for processing a
substrate along a substrate location path is provided. An ion source generates an
ion beam. A shield is positioned between the ion source and the substrate location
to pass the ion beam to the substrate while blocking sputtered contaminants from
impinging the substrate.
[0011] In another implementation, a shielding system positionable between
an ion source and a substrate location is provided. The shielding system passes an
ion beam from an ion source to impinge a substrate on the substrate location while
blocking sputtered contaminants from impinging the substrate.
[0012] In yet another implementation, a method of processing a substrate is
provided. An ion beam is generated and sputters ions from an ion source having a
cathode, the ion beam defining an envelope. The substrate passes through the
envelope. Sputtered contaminants are sputtered from the cathode by the sputtering
ions. The sputtered contaminants are blocked from impinging the substrate
outside of the envelope of the ion beam.
[0013] In yet another embodiment, an ion source system includes an ion
source; and means for passing an ion beam from the ion source to impinge a
substrate while blocking sputtered contaminants from impinging the substrate.
Brief Description of the Drawings [0014] FIG. 1 illustrates a cross-sectional schematic view of an ion source
with exemplary emitter shields.
[0015] FIG. 2 illustrates a more detailed cross-sectional schematic view of
an ion source with exemplary emitter shields.
[0016] FIG. 3 illustrates a cross-sectional schematic view of an ion source
with exemplary substrate shields.
[0017] FIG. 4 illustrates a more detailed cross-sectional schematic view of
an ion source with exemplary substrate shields.
[0018] FIG. 5 illustrates a face of an ion source with exemplary emitter
shields.
[0019] FIG. 6 illustrates a perspective view of the ion source of FIG. 5 with
exemplary emitter shields.
[0020] FIG. 7 illustrates a face of another ion source with exemplary emitter
shields.
[0021] FIG. 8 illustrates a perspective view of the ion source of FIG. 7 with
exemplary emitter shields.
Detailed Description of the Invention [0022] Using shielding in association with an ion source can reduce the total
number of sputtered contaminants striking and remaining on the surface of a target
substrate. A shield configuration can block the sputtered contaminants from
impinging the substrate outside the envelope of the ion beam. Many, but not all,
contaminants that impinge the substrate during (and prior to) the passage of the
substrate through the envelope of the etching beam are etched away from the
substrate by the beam. In one implementation, blocking such contaminants from
impinging the substrate surface after the substrate passes through the etching beam
(i.e., outside of the envelope of the etching beam) significantly reduced
contamination of the substrate surface, although generally reducing the number of
sputtered contaminants reaching the surface of the substrate improves substrate
quality as well (e.g., resulting in about a 50% reduction in substrate
contamination).
[0023] FIG. 1 illustrates a cross-sectional schematic view of an ion source
with exemplary emitter shields, which are adjacent to the ion source. An ion
source processing system 100 includes an ion source 102, and emitter shields 104,
106, and 108. The target of the processing is a substrate 110, which is positioned
or passed at some distance from the emission face 101 of the ion source 102. The
ion source 102 produces an ion beam on an ion beam axis 114, where an ion beam
envelope is defined by arrows 112 and the ion beam axis 114 is substantially
perpendicular to the emission face 101. The substrate 110 is passed through the
ion beam envelope 112, substantially perpendicular to the ion beam axis 114,
although geometries with non-peφendicular ion beam emission and/or
impingement are also contemplated. In addition, ion beam emission intensity and
direction may be different for different portions or sides of the ionization region.
In a typical configuration, multiple substrates are passed sequentially through the
ion beam for processing along this perpendicular path, although other
configurations may involve one or more stationary substrates.
[0024] In one exemplary type of ALS, called a linear ALS, the ion beam is
linear (e.g., long and narrow) as defined by a closed oval ionization region or
channel with long, straight sides (see, for example, FIGs. 5 and 6). Typical
applications of linear ALS systems include processing large flat substrates with
substrate motion generally perpendicular to the longitudinal axis of the beam (i.e.,
perpendicular to the straight section of the ionization channel). Linear ALS
systems, other types of ALS systems, and other types of ion beam sources may
benefit from the described technology.
[0025] Some generated ions (i.e., sputtering ions) impinge the cathodes 116
and 117, causing cathode material to sputter (shown by arrows 118) from the
cathodes 116 and 117. The sputtered material can enter the process as a
contaminant on the surface of the substrate 110. For example, absent the shields
104, 106, and 108, when the substrate 110 is in positions 122 and 124, sputtered
material from the cathodes 116 and 117 may impinge the substrate 110, thereby
contaminating the surface of the substrate 110. In addition, regardless of the
presence of the shields 104, 106, and 108, sputtered material from the
cathodes 1 16 and 117 may impinge the substrate 110 while passing through the
width 120 of the ion beam on the substrate path. The ion beam width is dependent
upon the envelope defined by edges of the ion beam and the distance between the
ionization region of the ion source and the substrate path.
[0026] A substantial amount of the sputtered contaminants impinging the
surface of the substrate 110 before (e.g., at position 122) and during passage of the
substrate 110 through the ion beam is etched away by the beam. Some such
contaminants remain. Therefore, reducing the total amount of contaminants
impinging the surface of the substrate can improve the quality of the substrate.
Furthermore, any contaminants impinging the surface of the substrate 110 after
passage through the far edge of the ion beam envelope 112 (e.g., see general
location referenced by arrow 113) remain on the surface because none are etched
away. Therefore, reducing the amount of contaminants impinging the surface of
the substrate after passage through the ion beam can reduce substrate
contamination.
[0027] By positioning shields 104, 106, and 108 to block sputtered
contaminants that are directed outside of the envelope of the ion beam, the
sputtered contaminant count is dramatically reduced on the surface of the substrate
110. The outside shield 104 extends upright (i.e., at a greater than 0° angle to a
90° angle) from the face of the ion source 102 and is positioned outside and along
one of the long channels of the ionization region of the ion source. The outside
shield 104 blocks sputtered contaminants emitted to the left in FIG. 1 from the
cathodes 116 of the ion source 102. The end point 126 of the outside shield 104 is
positioned to pass a substantial amount of the ion beam while blocking sputtered
contaminants emitted outside the ion beam envelope.
[0028] The inside shield 106 blocks sputtered contaminants emitted to the
right in FIG. 1 from the cathodes 116 of the ion source 102 and to the left in FIG.
1 from the cathodes 117 of the ion source 102. The inside shield 106 extends
upright (e.g., at a greater than 0° angle to a 90° angle) from the emission face 101
of the ion source 102 and is positioned between the long channels of the ionization
region of the ion source. The end point 128 of the inside shield 106 is positioned
to pass a substantial amount of the ion beam while blocking sputtered
contaminants emitted outside the inside edge portions of the envelope of the ion
beam emitted from cathodes 116 and 117.
[0029] The outside shield 108 blocks sputtered contaminants emitted to the
right in FIG. 1 from the cathodes 117 of the ion source 102. The outside shield
108 extends upright (e.g., at a greater than 0° angle to a 90° angle) from the
emission face 101 of the ion source 102 and is positioned outside and along the
other long channel of the ionization region of the ion source. The end point 130 of
the outside shield 108 is positioned to pass a substantial amount of the ion beam
while blocking sputtered contaminants emitted outside the ion beam envelope.
[0030] In addition, end shields (not shown in FIG. 1 , but examples may be
seen in FIGs. 5-8) may also be employed to block sputtered material emitted from
the ends of an ALS (e.g., the curved end portions of the ionization channels 502
and 702 of ion sources 500 and 700, respectively, in FIGs. 5-8). It should be
understood that the inside shields, the outside shields, and the end shields may or
may not be physically attached to the ion source itself.
[0031] In some operating conditions, the shields may be sputtered the by
ion beam (e.g., depending upon the height, shape, location, and composition of the
shields and the shape and intensity of the ion beam). As such, shields may be
fabricated out of materials that are not process contaminants, such as titanium in a
titanium-oxide deposition process, and/or that have a very low sputter yield
(collectively "process-compatible" materials). In addition to shield materials
being sputtered into the process, some of the cathode or anode materials may be
initially sputtered from the ion source to impinge the shield and then be "re-
sputtered" from the shield into the process. As such, shields may be positioned
with an inward tilt, provided with a louvered design, or manufactured with a
honeycomb or similar structured material to trap sputtered contaminants to reduce
forward sputtering of contaminant material.
[0032] FIG. 2 illustrates a more detailed cross-sectional schematic view of
an ion source with exemplary emitter shields. The system 200 includes a closed-
field ion source 202 and emitter shields 204, 206, and 208, which extend outward
from the face of the ion source 202. (An open-field anode layer ion source may be
employed in an alternative implementation. Also, implementations may be
applied to end-Hall ion sources and various other ion sources. Moreover, ion
sources where the edges of the contaminant distribution zone (e.g., 118 in FIG. 1)
is broader than the edges of the ion beam (e.g., beam 112 in FIG. 1) may gain
particular benefit from such described shielding. In addition, such ion source
beam shapes may vary and may include circular shapes, annular shapes, etc.) A
working gas is emitted behind the anode 210 through inlet 211, flows around the
anode 210, and is ionized at an ionization region 212 through interaction of an
electric field generated by the power source 214 and a magnetic field generated by
permanent magnets 215. The anode 210 is made of a non-magnetic material, such
as 300 series stainless steel. A cathode 216 is made of magnetic material, such as
carbon steel or 400 series stainless steel. The combination of the electric field and
the magnetic field creates the ions and accelerates them away from the ionization
region 212, as represented by dashed beam lines 218, toward a target (e.g., a
substrate).
[0033] However, some ions created at the ionization region 212 bombard
the surface of the cathode 216 near the ionization region 212 and, therefore,
sputter cathode material away from the ionization region 212, as represented by
the exemplary directional arrows 220 and 222. The sputtered material can enter
the ion beam process as a contaminant, such as by impinging the surface of the
substrate.
[0034] In some ion source applications, gases that can form some negative
ions as well as the usual positive ions, such as oxygen, may be used. These
negative ions can sputter the anode and result in sputtered anode material entering
the process as a contaminant in a manner similar to that described herein for
cathode sputtering. As such, the shielding described herein may be used to block
anode sputtered contaminants and other contaminants as well.
[0035] As can be seen in FIG. 2, the sputtered material corresponding to
arrows 220 strikes the surfaces of the shields 204, 206, and 208, and is effectively
blocked from impinging the target. In contrast, the sputtered material
corresponding to the arrows 222 bypasses the shields 204, 206, and 208 and may
impinge the target. However, the sputtered material corresponding to the
arrows 222 remains within the envelope of the ion beam 218 and is therefore
substantially etched away from the substrate by the ion beam during processing.
[0036] Accordingly, the heights of the shields 204, 206, and 208 (relative to
the ionization region 212) are set to substantially block sputtered material that is
emitted outside the ion beam envelope 218, while substantially allowing the ion
beam (and sputtered material emitted within the ion beam envelope) to pass to the
target. Likewise, the widths of the shields 204, 206, and 208 (or the distances of
the shields 204, 206, and 208 from adjacent ionization regions) are set with at least
the same constraints.
[0037] FIG. 3 illustrates a cross-sectional schematic view of an ion source
with exemplary substrate shields, which are adjacent to the substrate path. An ion
source processing system 300 includes an ion source 302 and substrate shields 304
and 306. The target of the processing is a substrate 308, which is located or
passed at some distance from the emission face 301. The substrate 308 is passed
through an ion beam (defined by dashed arrows 310). In a typical configuration,
multiple substrates are passed sequentially through the ion beam for processing
along this path parallel to the emission face 301, although non-parallel paths may
also be employed.
[0038] Some generated ions (i.e., sputtering ions) bombard the cathodes 312
and 314, causing cathode material to sputter (shown by solid arrows 316 and 318)
from the cathodes 312 and 314. As mentioned earlier, cathode sputtered
contaminants are just one type of contaminant material that may enter the process.
Other contaminant materials may also be sputtered off of other surfaces of the ion
source or enter the process through other means.
[0039] The sputtered material can enter the process as a contaminant on the
surface of the substrate 308. For example, absent the shields 304 and 306, when
the substrate is outside the ion beam envelope, sputtered material from the
cathodes 312 and 314 may impinge the substrate 308, thereby contaminating the
surface of the substrate 308. In addition, regardless of the presence of the
shields 304 and 306, sputtered material from the cathodes 312 and 314 may
impinge the substrate 308 while passing through the ion beam envelope.
However, a substantial amount of the sputtered contaminant impinging the surface
of the substrate 308 before and during passage of the substrate 308 through the ion
beam is etched away by the ion beam. However, any contaminant impinging the
surface of the substrate 308 after passage through the ion beam remains on the
surface. By positioning shields 304 and 306 to block sputtered contaminants that
are directed outside of the ion beam envelope, the sputtered contaminant count
reaching the substrate is dramatically reduced on the surface of the substrate 308.
It should be understood, however, that such shields may be positioned along an
ion beam axis near to the substrate location, near to the emission face 301, or at
some distance in between the substrate location and the emission face 301.
[0040] FIG. 4 illustrates a more detailed cross-sectional schematic view of
an ion source with exemplary substrate shields. The system 400 includes an open-
field ion source 402, although a closed-field ion source may be employed in an
alternative implementation. The system 400 also includes substrate shields 404
and 406, which are positioned substantially parallel to the face of the ion
source 402 (although non-parallel configurations are also contemplated). A
working gas is emitted from the anode 408 and ionized at the ionization
region 410 through the interaction of an electric field generated by the power
source 412 and a magnetic field generated by permanent magnets 424. The
anode 408 is made of a non-magnetic material, such as 300 series stainless steel.
A cathode 414 is made of magnetic material, such as carbon steel or 400 series
steel. The combination of the electric field and the magnetic field creates the ions
and accelerates them away from the ionization region 410, as represented by
dashed beam lines 416, toward a target (e.g., a substrate). For open-field sources,
additional magnets and pole pieces may be used to provide an extended
acceleration zone to enhance low energy operation and stability. Sputtering of
these extended components can also be a source of contamination.
[0041] However, some ions created at the ionization region 410 bombard
the surface of the cathode 414 near the ionization region 410 (as well as other
surfaces) and, therefore, sputter cathode material away from the ionization region
410, as represented by the exemplary directional arrows 418 and 420. The
sputtered material enters the ion beam process as a contaminant, such as by
reaching the surface of a substrate 422.
[0042] As can be seen in FIG. 4, the sputtered material corresponding to
arrows 418 strikes the surfaces of the shields 404 and 406, and is effectively
blocked from reaching the target substrate 422. In contrast, the sputtered material
corresponding to the arrows 420 bypasses the shields 404 and 406 and may
impinge the target substrate 422. However, the sputtered material corresponding
to the arrows 420 remains within the envelope of the ion beam 416 and is
therefore substantially etched away from the target substrate by the ion beam
during processing. Accordingly, the separation between the shields (404 and 406)
and the substrate path and the separation between and relative alignment between
the shields (404 and 406) and the ionization regions 410 are set to block sputtered
material that is emitted outside the ion beam envelope, while allowing the ion
beam (and sputtered material emitted within the ion beam envelope) to pass to the
target.
[0043] FIG. 5 illustrates a face of an ion source 500 with exemplary emitter
shields. FIG. 6 illustrates a perspective view of the ion source 500 of FIG. 5 with
exemplary emitter shields. An ion source 500 includes an oval ionization
region 502 in which a working gas is ionized and from which ions are emitted. In
operation, the ion source 500 emits ions from the ionization region 502 in the form
of an ion beam. A substrate (not shown) is passed through the ion beam for
processing (e.g., at some distance from the face of the ion source). In an
exemplary embodiment, a substrate is transported along a path peφendicular to (or
some other angle relative to) the long axis of the ion source 500, which emits an
ion beam from the ionization region 502 toward the surface of the substrate as it
passes.
[0044] It should be understood that some benefits may result for a non-
peφendicular substrate path, including increasing power density, reducing
overspray on a source longer than the width of the substrate, and smoothing out
small longitudinal beam non-uniformities. There may also be benefits for a non-
peφendicular angle of emission from the ion source and/or a non-peφendicular
angle of ion impingement on the substrate. It should also be noted that the angle
of the beam may be modified dynamically during the emission. Benefits may also
be achieved from operating with the shields at some other electrical potential
relative to the ion source housing (e.g., electrical isolation/floating and/or active
biasing at a positive potential).
[0045] Emitter shields 504, 506, and 508 are positioned between the ion
source 500 and the path of the substrate along the long channel portions of the
ionization region 502. In various embodiments, one or two of the shields 504,
506, and 508 may be omitted. However, to best block sputtered contaminants
from impinging the substrate surface after the substrate has passed through the ion
beam, one of the shields is maintained on the far edge of the ion source (i.e.,
farthest in the direction of substrate motion). Nevertheless, each shield, singly or
in combination with other shields, may decrease the total amount of sputtered
contaminants reaching or remaining on the surface of the substrate, thereby
improving substrate quality.
[0046] In the illustrated implementation, and in addition to emitter shields
504, 506, and 508, end shields 510 and 512 may be employed to block sputtered
contaminants from the rounded ends of the ion source 500. Each end shield 510
and 512 may be configured (e.g. shaped, placed and sized) to block all emitted
ions and sputtered contaminants emanating from the rounded ionization
region 502 region in the ends of the ion source 500. For example, the end
shields 510 and 512 may be much taller than the emitter shields 504, 506, and 508,
which are sized to substantially pass the ion beam and substantially block the
sputtered contaminants. Alternatively, the end shields 510 and 512 may be
positioned, sized, and shaped to pass a portion of the ion beam and to substantially
block the sputtered contaminants.
[0047] FIG. 7 illustrates a face of another ion source 700 with exemplary
emitter shields. FIG. 8 illustrates a perspective view of the ion source 700 of FIG.
7 with exemplary emitter shields. An ion source 700 includes an oval ionization
region 702 in which a working gas is ionized. In operation, the ion source 700
emits ions from the ionization region 702 in the form of an ion beam. A substrate
(not shown) is transported through the ion beam for processing (e.g., at some
distance from the face of the ion source). In an exemplary embodiment, a
substrate is transported along a path peφendicular to the long axis of the ion
source 700, which emits an ion beam from the ionization region 702 toward the
surface of the substrate as it passes.
[0048] Emitter shields 704, 706, and 708 are positioned between the ion
source 700 and the path of the substrate along the long channel portions of the
ionization region 702, as discussed with regard to FIGs. 5 and 6. Likewise, in
various embodiments, one or two of the shields 504, 506, and 508 may be omitted.
[0049] In addition to emitter shields 704, 706, and 708, end shields 710 and
712 may be employed to block sputtered contaminants from the rounded ends of
the ion source 700. The end shields 710 and 712 are shaped to improve the
amount of the ion beam that is passed while substantially blocking the sputtered
contaminants. The rounded shape substantially matches the rounded shape of the
ionization region 702 at the ends of the ion source 700. In this configuration, the
size and positioning of the end shields 710 and 712 are set to substantially pass the
ion beam and to substantially block the sputtered contaminants from reaching the
substrate.
[0050] The above specification, examples and data provide a complete
description of the structure and use of exemplary embodiments of the invention.
However, other implementations are also contemplated within the scope of the
present invention, including without limitation shields having different shapes,
sizes, and locations than those shown, as well as systems having one or more
shields and systems with or without one or more end shields. In addition, while
the description has described exemplary ion sources as ALSs, other ion sources
may be employed within the scope of the invention. Since many implementations
can be made without departing from the spirit and scope of the invention, the
invention resides in the claims hereinafter appended.