WO2005020265A2 - Sputtered contamination shielding for an ion source - Google Patents

Sputtered contamination shielding for an ion source Download PDF

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Publication number
WO2005020265A2
WO2005020265A2 PCT/US2004/027189 US2004027189W WO2005020265A2 WO 2005020265 A2 WO2005020265 A2 WO 2005020265A2 US 2004027189 W US2004027189 W US 2004027189W WO 2005020265 A2 WO2005020265 A2 WO 2005020265A2
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WO
WIPO (PCT)
Prior art keywords
ion source
substrate
ion
emission face
ion beam
Prior art date
Application number
PCT/US2004/027189
Other languages
French (fr)
Other versions
WO2005020265A3 (en
Inventor
David Matthew Burtner
Daniel E. Siegfried
Richard Blacker
Valery Alexeyev
John Keem
Vsevolod Zelenkov
Mark Krivoruchko
Original Assignee
Veeco Instruments, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US10/918,265 external-priority patent/US20050035954A1/en
Application filed by Veeco Instruments, Inc. filed Critical Veeco Instruments, Inc.
Publication of WO2005020265A2 publication Critical patent/WO2005020265A2/en
Publication of WO2005020265A3 publication Critical patent/WO2005020265A3/en

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/02Details
    • H01J37/026Means for avoiding or neutralising unwanted electrical charges on tube components
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/02Details
    • H01J37/04Arrangements of electrodes and associated parts for generating or controlling the discharge, e.g. electron-optical arrangement, ion-optical arrangement
    • H01J37/09Diaphragms; Shields associated with electron or ion-optical arrangements; Compensation of disturbing fields

Definitions

  • the invention relates generally to ion sources, and more particularly
  • an ion source is a device that ionizes gas molecules
  • Ion sources are also used in
  • an ion beam e.g., an etching beam
  • An anode layer source typically refers to a Hall-current type
  • the working gas is
  • the ionization region generally forms a closed-loop (e.g., a race
  • track may be round, oval, linear with rounded ends, or many other closed shapes.
  • One benefit to an ALS is that an ALS does not require a hot cathode
  • electron source e.g., filament cathode, hollow cathode, or RF neutralizer
  • ALS cathodes are passive, cold
  • cathodes typically made of steel.
  • the cathodes also function as pole pieces for
  • the cold cathodes do not actively emit electrons, but
  • cathodes can also sputter material from the cathodes.
  • Such cathodes are typically steel
  • the primary contaminant is iron, although other
  • the sputtered material tends to emit across a wide
  • a substrate tends to acquire a new layer of contaminants after
  • using an ALS may yield an etched substrate having an unacceptable concentration
  • the shield configuration allows the etching ions to pass to the substrate
  • An ion source generates an
  • a shield is positioned between the ion source and the substrate location
  • the shielding system passes an ion source and a substrate location.
  • a method of processing a substrate is
  • An ion beam is generated and sputters ions from an ion source having a
  • the ion beam defining an envelope.
  • the substrate passes through the
  • an ion source system includes an ion
  • FIG. 1 illustrates a cross-sectional schematic view of an ion source
  • FIG. 2 illustrates a more detailed cross-sectional schematic view of
  • FIG. 3 illustrates a cross-sectional schematic view of an ion source
  • FIG. 4 illustrates a more detailed cross-sectional schematic view of
  • FIG. 5 illustrates a face of an ion source with exemplary emitter
  • FIG. 6 illustrates a perspective view of the ion source of FIG. 5 with
  • FIG. 7 illustrates a face of another ion source with exemplary emitter
  • FIG. 8 illustrates a perspective view of the ion source of FIG. 7 with
  • a shield configuration can block the sputtered contaminants from
  • FIG. 1 illustrates a cross-sectional schematic view of an ion source
  • source processing system 100 includes an ion source 102, and emitter shields 104,
  • the target of the processing is a substrate 110, which is positioned
  • ion source 102 produces an ion beam on an ion beam axis 114, where an ion beam
  • the substrate 110 is passed through the ion beam envelope 112, substantially perpendicular to the ion beam axis 114,
  • the direction may be different for different portions or sides of the ionization region.
  • configurations may involve one or more stationary substrates.
  • the ion beam is
  • linear e.g., long and narrow
  • cathode material shown by arrows 118
  • the sputtered material can enter the process as a
  • cathodes 1 16 and 117 may impinge the substrate 110 while passing through the
  • the ion beam width 120 of the ion beam on the substrate path is dependent
  • substrate 110 through the ion beam is etched away by the beam.
  • impinging the surface of the substrate can improve the quality of the substrate.
  • the substrate after passage through the ion beam can reduce substrate
  • the outside shield 104 extends upright (i.e., at a greater than 0 ° angle to a
  • the outside shield 104 blocks sputtered contaminants emitted to the left in FIG. 1 from the
  • the end point 126 of the outside shield 104 is
  • the inside shield 106 blocks sputtered contaminants emitted to the
  • the inside shield 106 extends
  • the end point 128 of the inside shield 106 is positioned
  • the outside shield 108 blocks sputtered contaminants emitted to the
  • emission face 101 of the ion source 102 is positioned outside and along the
  • the outside shield 108 is positioned to pass a substantial amount of the ion beam
  • end shields (not shown in FIG. 1 , but examples may be
  • an ALS e.g., the curved end portions of the ionization channels 502
  • inside shields the outside shields, and the end shields may or
  • the shields may be sputtered the by
  • ion beam (e.g., depending upon the height, shape, location, and composition of the
  • shields and the shape and intensity of the ion beam).
  • shields may be
  • titanium-oxide deposition process and/or that have a very low sputter yield
  • process-compatible materials In addition to shield materials
  • cathode or anode materials may be
  • shields may be positioned
  • honeycomb or similar structured material to trap sputtered contaminants to reduce
  • FIG. 2 illustrates a more detailed cross-sectional schematic view of
  • the system 200 includes a closed-
  • An open-field anode layer ion source may be
  • implementations may be
  • ion sources where the edges of the contaminant distribution zone (e.g., 118 in FIG. 1)
  • the ion beam (e.g., beam 112 in FIG. 1) may gain
  • beam shapes may vary and may include circular shapes, annular shapes, etc.
  • anode 210 is ionized at an ionization region 212 through interaction of an
  • the anode 210 is made of a non-magnetic material, such as
  • a cathode 216 is made of magnetic material, such as
  • a target e.g., a target that is a target that is a target that is a target that is a target.
  • the sputtered material can enter
  • the ion beam process as a contaminant, such as by impinging the surface of the
  • negative ions can sputter the anode and result in sputtered anode material entering the process as a contaminant in a manner similar to that described herein for
  • the shielding described herein may be used to block
  • arrows 220 strikes the surfaces of the shields 204, 206, and 208, and is effectively
  • arrows 222 remains within the envelope of the ion beam 218 and is therefore
  • the ionization region 212) are set to substantially block sputtered material that is
  • the widths of the shields 204, 206, and 208 (or the distances of
  • the shields 204, 206, and 208 from adjacent ionization regions are set with at least
  • FIG. 3 illustrates a cross-sectional schematic view of an ion source
  • source processing system 300 includes an ion source 302 and substrate shields 304
  • the target of the processing is a substrate 308, which is located or
  • the substrate 308 is passed through an ion beam (defined by dashed arrows 310).
  • an ion beam defined by dashed arrows 310.
  • cathode material shown by solid arrows 316 and 3178
  • contaminants are just one type of contaminant material that may enter the process.
  • the sputtered material can enter the process as a contaminant on the
  • the substrate is outside the ion beam envelope, sputtered material from the
  • cathodes 312 and 314 may impinge the substrate 308, thereby contaminating the
  • shields 304 and 306 By positioning shields 304 and 306 to block sputtered contaminants that are directed outside of the ion beam envelope, the sputtered contaminant count
  • ion beam axis near to the substrate location, near to the emission face 301, or at
  • FIG. 4 illustrates a more detailed cross-sectional schematic view of
  • the system 400 includes an open-ended
  • field ion source 402 although a closed-field ion source may be employed in an
  • the system 400 also includes substrate shields 404
  • anode 408 is made of a non-magnetic material, such as 300 series stainless steel.
  • a cathode 414 is made of magnetic material, such as carbon steel or 400 series
  • dashed beam lines 416 toward a target (e.g., a substrate).
  • a target e.g., a substrate.
  • sputtered material enters the ion beam process as a contaminant, such as by
  • the shields (404 and 406) and the ionization regions 410 are set to block sputtered
  • FIG. 5 illustrates a face of an ion source 500 with exemplary emitter
  • FIG. 6 illustrates a perspective view of the ion source 500 of FIG. 5 with
  • An ion source 500 includes an oval ionization region 502 in which a working gas is ionized and from which ions are emitted.
  • the ion source 500 emits ions from the ionization region 502 in the form
  • a substrate (not shown) is passed through the ion beam for
  • processing e.g., at some distance from the face of the ion source.
  • a substrate is transported along a path pe ⁇ endicular to (or
  • pe ⁇ endicular substrate path including increasing power density, reducing
  • Benefits may also be considered dynamically during the emission. Benefits may also be considered dynamically during the emission. Benefits may also be considered dynamically during the emission. Benefits may also be considered dynamically during the emission. Benefits may also be considered dynamically during the emission. Benefits may also be considered dynamically during the emission. Benefits may also be considered dynamically during the emission. Benefits may also be considered dynamically during the emission. Benefits may also be considered
  • ion source housing e.g., electrical isolation/floating and/or active
  • Emitter shields 504, 506, and 508 are positioned between the ion
  • one or two of the shields 504 are disposed in various embodiments. In various embodiments, one or two of the shields 504,
  • one of the shields is maintained on the far edge of the ion source (i.e.,
  • each shield singly or
  • end shields 510 and 512 may be employed to block sputtered
  • Each end shield 510 Each end shield 510
  • and 512 may be configured (e.g. shaped, placed and sized) to block all emitted
  • shields 510 and 512 may be much taller than the emitter shields 504, 506, and 508,
  • the end shields 510 and 512 may be
  • FIG. 7 illustrates a face of another ion source 700 with exemplary
  • FIG. 8 illustrates a perspective view of the ion source 700 of FIG.
  • An ion source 700 includes an oval ionization
  • the ion source 700 In operation, the ion source 700
  • a substrate (not shown) is transported through the ion beam for processing (e.g., at some
  • a distance from the face of the ion source In an exemplary embodiment, a
  • Emitter shields 704, 706, and 708 are positioned between the ion
  • ionization region 702 as discussed with regard to FIGs. 5 and 6. Likewise, in
  • one or two of the shields 504, 506, and 508 may be omitted.
  • the end shields 710 and 712 are shaped to improve the
  • the rounded shape substantially matches the rounded shape of the
  • present invention including without limitation shields having different shapes, sizes, and locations than those shown, as well as systems having one or more

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  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Physical Vapour Deposition (AREA)
  • Cleaning Or Drying Semiconductors (AREA)

Abstract

Shielding (108) associated with an ion source (102), such as an anode layer source, reduces the amount and/or concentration of sputtered contaminants impinging and remaining on the surface of a target substrate (110). While passing the ion beam through to the target substrate (110), shielding (108) can reduce the total amount of sputtered contaminants impinging the substrate (110) before, during, and/or after passage of the substrate (110) through the envelope of the etching beam. Particularly, a shield configuration (108) that blocks the contaminants from impinging the substrate (110) after the substrate (100) passes through the etching beam (i.e., outside of the envelope of the etching beam) yields a higher quality substrate (110) with reduced substrate (110) contamination.

Description

Related Applications [0001] This application claims benefit of U.S. Provisional Application No.
60/496,886, entitled "Sputtered Contamination Shielding for an Ion Source" and
filed August 20, 2003, incorporated herein by reference for all that it discloses and
teaches.
Technical Field [0002] The invention relates generally to ion sources, and more particularly
to shielding for an ion source.
Background [0003] Generally, an ion source is a device that ionizes gas molecules and
focuses, accelerates, and emits the ionized gas molecules and/or atoms in a beam
for a variety of technical and industrial applications. For example, ion sources
may be used as thrusters on space craft. Ion sources are also used in
semiconductor material and device processing, optical filter processing, and
metrology, among other applications. Common uses of ion sources include
without limitation cleaning, assisting deposition (by chemically or physically
activating), polishing, etching and/or depositing of thin- film coatings. Typically, a
substrate is passed through an ion beam (e.g., an etching beam) for such
processing. [0004] An anode layer source (ALS) typically refers to a Hall-current type
ion source having a grounded cathode and a DC-biased anode. The working gas is
fed into an ionization region in the vicinity of the anode and the cathode, where
the combination of electric and magnetic fields in this region ionizes the molecules
of the working gas and accelerates each ion away from the ionization region
toward a target. The ionization region generally forms a closed-loop (e.g., a race
track shape) in the face of the ion source. The shape of this closed-loop "race
track" may be round, oval, linear with rounded ends, or many other closed shapes.
[0005] One benefit to an ALS is that an ALS does not require a hot cathode
electron source (e.g., filament cathode, hollow cathode, or RF neutralizer) with a
separate power supply to sustain the plasma. ALS cathodes are passive, cold
cathodes, typically made of steel. The cathodes also function as pole pieces for
the ALS magnetic circuit. The cold cathodes do not actively emit electrons, but
ions bombarding the cathodes release secondary electrons that help to sustain the
discharge.
[0006] One problem with an ALS, however, is that the ions striking the
cathodes can also sputter material from the cathodes. The sputtered cathode
material may enter the process as a contaminant. Such cathodes are typically steel
or magnetic stainless steel, so the primary contaminant is iron, although other
contaminants may also exist. The sputtered material tends to emit across a wide
range of angles. As a result, the sputtered material tends to impinge the substrate
surface outside the envelope of the etching beam as well as inside the envelope of the etching beam. Depending on the type of ion source, the operating regime, and
the application, there may be other ion source electrodes or adjacent components
that also sputter in a similar matter and contribute to substrate contamination.
[0007] Most contaminants impinging the substrate surface prior to and
during the passing of the substrate through the etching beam are etched away by
the beam. However, the contaminants that impinge the surface of the substrate
after the substrate has passed through the etching beam remain as contaminants.
In other words, a substrate tends to acquire a new layer of contaminants after
exiting the envelope of the ion beam. Therefore, for example, etching a substrate
using an ALS may yield an etched substrate having an unacceptable concentration
of iron contaminants sputtered from the ALS itself.
Summary [0008] Implementations described and claimed herein solve the discussed
problems by providing shielding associated with an ion source, such as an ALS.
The shield configuration allows the etching ions to pass to the substrate and
effectively blocks sputtered contaminants from impinging the target substrate
outside the envelope of the etching beam.
[0009] Such shielding associated with an ion source reduces the number of
sputtered contaminants impinging and remaining on the surface of a target
substrate. While passing the ion beam through to the target substrate, shielding
can reduce the total number of sputtered contaminants impinging the substrate before, during, and/or after passage of the substrate through the envelope of the
etching beam. Particularly, a shield configuration that blocks the contaminants
from impinging the substrate after the substrate passes through the etching beam
(i.e., outside of the envelope of the etching beam) yields a higher quality substrate
(i.e., with lower contamination levels).
[0010] In one implementation, an ion source system for processing a
substrate along a substrate location path is provided. An ion source generates an
ion beam. A shield is positioned between the ion source and the substrate location
to pass the ion beam to the substrate while blocking sputtered contaminants from
impinging the substrate.
[0011] In another implementation, a shielding system positionable between
an ion source and a substrate location is provided. The shielding system passes an
ion beam from an ion source to impinge a substrate on the substrate location while
blocking sputtered contaminants from impinging the substrate.
[0012] In yet another implementation, a method of processing a substrate is
provided. An ion beam is generated and sputters ions from an ion source having a
cathode, the ion beam defining an envelope. The substrate passes through the
envelope. Sputtered contaminants are sputtered from the cathode by the sputtering
ions. The sputtered contaminants are blocked from impinging the substrate
outside of the envelope of the ion beam. [0013] In yet another embodiment, an ion source system includes an ion
source; and means for passing an ion beam from the ion source to impinge a
substrate while blocking sputtered contaminants from impinging the substrate.
Brief Description of the Drawings [0014] FIG. 1 illustrates a cross-sectional schematic view of an ion source
with exemplary emitter shields.
[0015] FIG. 2 illustrates a more detailed cross-sectional schematic view of
an ion source with exemplary emitter shields.
[0016] FIG. 3 illustrates a cross-sectional schematic view of an ion source
with exemplary substrate shields.
[0017] FIG. 4 illustrates a more detailed cross-sectional schematic view of
an ion source with exemplary substrate shields.
[0018] FIG. 5 illustrates a face of an ion source with exemplary emitter
shields.
[0019] FIG. 6 illustrates a perspective view of the ion source of FIG. 5 with
exemplary emitter shields.
[0020] FIG. 7 illustrates a face of another ion source with exemplary emitter
shields.
[0021] FIG. 8 illustrates a perspective view of the ion source of FIG. 7 with
exemplary emitter shields. Detailed Description of the Invention [0022] Using shielding in association with an ion source can reduce the total
number of sputtered contaminants striking and remaining on the surface of a target
substrate. A shield configuration can block the sputtered contaminants from
impinging the substrate outside the envelope of the ion beam. Many, but not all,
contaminants that impinge the substrate during (and prior to) the passage of the
substrate through the envelope of the etching beam are etched away from the
substrate by the beam. In one implementation, blocking such contaminants from
impinging the substrate surface after the substrate passes through the etching beam
(i.e., outside of the envelope of the etching beam) significantly reduced
contamination of the substrate surface, although generally reducing the number of
sputtered contaminants reaching the surface of the substrate improves substrate
quality as well (e.g., resulting in about a 50% reduction in substrate
contamination).
[0023] FIG. 1 illustrates a cross-sectional schematic view of an ion source
with exemplary emitter shields, which are adjacent to the ion source. An ion
source processing system 100 includes an ion source 102, and emitter shields 104,
106, and 108. The target of the processing is a substrate 110, which is positioned
or passed at some distance from the emission face 101 of the ion source 102. The
ion source 102 produces an ion beam on an ion beam axis 114, where an ion beam
envelope is defined by arrows 112 and the ion beam axis 114 is substantially
perpendicular to the emission face 101. The substrate 110 is passed through the ion beam envelope 112, substantially perpendicular to the ion beam axis 114,
although geometries with non-peφendicular ion beam emission and/or
impingement are also contemplated. In addition, ion beam emission intensity and
direction may be different for different portions or sides of the ionization region.
In a typical configuration, multiple substrates are passed sequentially through the
ion beam for processing along this perpendicular path, although other
configurations may involve one or more stationary substrates.
[0024] In one exemplary type of ALS, called a linear ALS, the ion beam is
linear (e.g., long and narrow) as defined by a closed oval ionization region or
channel with long, straight sides (see, for example, FIGs. 5 and 6). Typical
applications of linear ALS systems include processing large flat substrates with
substrate motion generally perpendicular to the longitudinal axis of the beam (i.e.,
perpendicular to the straight section of the ionization channel). Linear ALS
systems, other types of ALS systems, and other types of ion beam sources may
benefit from the described technology.
[0025] Some generated ions (i.e., sputtering ions) impinge the cathodes 116
and 117, causing cathode material to sputter (shown by arrows 118) from the
cathodes 116 and 117. The sputtered material can enter the process as a
contaminant on the surface of the substrate 110. For example, absent the shields
104, 106, and 108, when the substrate 110 is in positions 122 and 124, sputtered
material from the cathodes 116 and 117 may impinge the substrate 110, thereby
contaminating the surface of the substrate 110. In addition, regardless of the presence of the shields 104, 106, and 108, sputtered material from the
cathodes 1 16 and 117 may impinge the substrate 110 while passing through the
width 120 of the ion beam on the substrate path. The ion beam width is dependent
upon the envelope defined by edges of the ion beam and the distance between the
ionization region of the ion source and the substrate path.
[0026] A substantial amount of the sputtered contaminants impinging the
surface of the substrate 110 before (e.g., at position 122) and during passage of the
substrate 110 through the ion beam is etched away by the beam. Some such
contaminants remain. Therefore, reducing the total amount of contaminants
impinging the surface of the substrate can improve the quality of the substrate.
Furthermore, any contaminants impinging the surface of the substrate 110 after
passage through the far edge of the ion beam envelope 112 (e.g., see general
location referenced by arrow 113) remain on the surface because none are etched
away. Therefore, reducing the amount of contaminants impinging the surface of
the substrate after passage through the ion beam can reduce substrate
contamination.
[0027] By positioning shields 104, 106, and 108 to block sputtered
contaminants that are directed outside of the envelope of the ion beam, the
sputtered contaminant count is dramatically reduced on the surface of the substrate
110. The outside shield 104 extends upright (i.e., at a greater than 0° angle to a
90° angle) from the face of the ion source 102 and is positioned outside and along
one of the long channels of the ionization region of the ion source. The outside shield 104 blocks sputtered contaminants emitted to the left in FIG. 1 from the
cathodes 116 of the ion source 102. The end point 126 of the outside shield 104 is
positioned to pass a substantial amount of the ion beam while blocking sputtered
contaminants emitted outside the ion beam envelope.
[0028] The inside shield 106 blocks sputtered contaminants emitted to the
right in FIG. 1 from the cathodes 116 of the ion source 102 and to the left in FIG.
1 from the cathodes 117 of the ion source 102. The inside shield 106 extends
upright (e.g., at a greater than 0° angle to a 90° angle) from the emission face 101
of the ion source 102 and is positioned between the long channels of the ionization
region of the ion source. The end point 128 of the inside shield 106 is positioned
to pass a substantial amount of the ion beam while blocking sputtered
contaminants emitted outside the inside edge portions of the envelope of the ion
beam emitted from cathodes 116 and 117.
[0029] The outside shield 108 blocks sputtered contaminants emitted to the
right in FIG. 1 from the cathodes 117 of the ion source 102. The outside shield
108 extends upright (e.g., at a greater than 0° angle to a 90° angle) from the
emission face 101 of the ion source 102 and is positioned outside and along the
other long channel of the ionization region of the ion source. The end point 130 of
the outside shield 108 is positioned to pass a substantial amount of the ion beam
while blocking sputtered contaminants emitted outside the ion beam envelope.
[0030] In addition, end shields (not shown in FIG. 1 , but examples may be
seen in FIGs. 5-8) may also be employed to block sputtered material emitted from the ends of an ALS (e.g., the curved end portions of the ionization channels 502
and 702 of ion sources 500 and 700, respectively, in FIGs. 5-8). It should be
understood that the inside shields, the outside shields, and the end shields may or
may not be physically attached to the ion source itself.
[0031] In some operating conditions, the shields may be sputtered the by
ion beam (e.g., depending upon the height, shape, location, and composition of the
shields and the shape and intensity of the ion beam). As such, shields may be
fabricated out of materials that are not process contaminants, such as titanium in a
titanium-oxide deposition process, and/or that have a very low sputter yield
(collectively "process-compatible" materials). In addition to shield materials
being sputtered into the process, some of the cathode or anode materials may be
initially sputtered from the ion source to impinge the shield and then be "re-
sputtered" from the shield into the process. As such, shields may be positioned
with an inward tilt, provided with a louvered design, or manufactured with a
honeycomb or similar structured material to trap sputtered contaminants to reduce
forward sputtering of contaminant material.
[0032] FIG. 2 illustrates a more detailed cross-sectional schematic view of
an ion source with exemplary emitter shields. The system 200 includes a closed-
field ion source 202 and emitter shields 204, 206, and 208, which extend outward
from the face of the ion source 202. (An open-field anode layer ion source may be
employed in an alternative implementation. Also, implementations may be
applied to end-Hall ion sources and various other ion sources. Moreover, ion sources where the edges of the contaminant distribution zone (e.g., 118 in FIG. 1)
is broader than the edges of the ion beam (e.g., beam 112 in FIG. 1) may gain
particular benefit from such described shielding. In addition, such ion source
beam shapes may vary and may include circular shapes, annular shapes, etc.) A
working gas is emitted behind the anode 210 through inlet 211, flows around the
anode 210, and is ionized at an ionization region 212 through interaction of an
electric field generated by the power source 214 and a magnetic field generated by
permanent magnets 215. The anode 210 is made of a non-magnetic material, such
as 300 series stainless steel. A cathode 216 is made of magnetic material, such as
carbon steel or 400 series stainless steel. The combination of the electric field and
the magnetic field creates the ions and accelerates them away from the ionization
region 212, as represented by dashed beam lines 218, toward a target (e.g., a
substrate).
[0033] However, some ions created at the ionization region 212 bombard
the surface of the cathode 216 near the ionization region 212 and, therefore,
sputter cathode material away from the ionization region 212, as represented by
the exemplary directional arrows 220 and 222. The sputtered material can enter
the ion beam process as a contaminant, such as by impinging the surface of the
substrate.
[0034] In some ion source applications, gases that can form some negative
ions as well as the usual positive ions, such as oxygen, may be used. These
negative ions can sputter the anode and result in sputtered anode material entering the process as a contaminant in a manner similar to that described herein for
cathode sputtering. As such, the shielding described herein may be used to block
anode sputtered contaminants and other contaminants as well.
[0035] As can be seen in FIG. 2, the sputtered material corresponding to
arrows 220 strikes the surfaces of the shields 204, 206, and 208, and is effectively
blocked from impinging the target. In contrast, the sputtered material
corresponding to the arrows 222 bypasses the shields 204, 206, and 208 and may
impinge the target. However, the sputtered material corresponding to the
arrows 222 remains within the envelope of the ion beam 218 and is therefore
substantially etched away from the substrate by the ion beam during processing.
[0036] Accordingly, the heights of the shields 204, 206, and 208 (relative to
the ionization region 212) are set to substantially block sputtered material that is
emitted outside the ion beam envelope 218, while substantially allowing the ion
beam (and sputtered material emitted within the ion beam envelope) to pass to the
target. Likewise, the widths of the shields 204, 206, and 208 (or the distances of
the shields 204, 206, and 208 from adjacent ionization regions) are set with at least
the same constraints.
[0037] FIG. 3 illustrates a cross-sectional schematic view of an ion source
with exemplary substrate shields, which are adjacent to the substrate path. An ion
source processing system 300 includes an ion source 302 and substrate shields 304
and 306. The target of the processing is a substrate 308, which is located or
passed at some distance from the emission face 301. The substrate 308 is passed through an ion beam (defined by dashed arrows 310). In a typical configuration,
multiple substrates are passed sequentially through the ion beam for processing
along this path parallel to the emission face 301, although non-parallel paths may
also be employed.
[0038] Some generated ions (i.e., sputtering ions) bombard the cathodes 312
and 314, causing cathode material to sputter (shown by solid arrows 316 and 318)
from the cathodes 312 and 314. As mentioned earlier, cathode sputtered
contaminants are just one type of contaminant material that may enter the process.
Other contaminant materials may also be sputtered off of other surfaces of the ion
source or enter the process through other means.
[0039] The sputtered material can enter the process as a contaminant on the
surface of the substrate 308. For example, absent the shields 304 and 306, when
the substrate is outside the ion beam envelope, sputtered material from the
cathodes 312 and 314 may impinge the substrate 308, thereby contaminating the
surface of the substrate 308. In addition, regardless of the presence of the
shields 304 and 306, sputtered material from the cathodes 312 and 314 may
impinge the substrate 308 while passing through the ion beam envelope.
However, a substantial amount of the sputtered contaminant impinging the surface
of the substrate 308 before and during passage of the substrate 308 through the ion
beam is etched away by the ion beam. However, any contaminant impinging the
surface of the substrate 308 after passage through the ion beam remains on the
surface. By positioning shields 304 and 306 to block sputtered contaminants that are directed outside of the ion beam envelope, the sputtered contaminant count
reaching the substrate is dramatically reduced on the surface of the substrate 308.
It should be understood, however, that such shields may be positioned along an
ion beam axis near to the substrate location, near to the emission face 301, or at
some distance in between the substrate location and the emission face 301.
[0040] FIG. 4 illustrates a more detailed cross-sectional schematic view of
an ion source with exemplary substrate shields. The system 400 includes an open-
field ion source 402, although a closed-field ion source may be employed in an
alternative implementation. The system 400 also includes substrate shields 404
and 406, which are positioned substantially parallel to the face of the ion
source 402 (although non-parallel configurations are also contemplated). A
working gas is emitted from the anode 408 and ionized at the ionization
region 410 through the interaction of an electric field generated by the power
source 412 and a magnetic field generated by permanent magnets 424. The
anode 408 is made of a non-magnetic material, such as 300 series stainless steel.
A cathode 414 is made of magnetic material, such as carbon steel or 400 series
steel. The combination of the electric field and the magnetic field creates the ions
and accelerates them away from the ionization region 410, as represented by
dashed beam lines 416, toward a target (e.g., a substrate). For open-field sources,
additional magnets and pole pieces may be used to provide an extended
acceleration zone to enhance low energy operation and stability. Sputtering of
these extended components can also be a source of contamination. [0041] However, some ions created at the ionization region 410 bombard
the surface of the cathode 414 near the ionization region 410 (as well as other
surfaces) and, therefore, sputter cathode material away from the ionization region
410, as represented by the exemplary directional arrows 418 and 420. The
sputtered material enters the ion beam process as a contaminant, such as by
reaching the surface of a substrate 422.
[0042] As can be seen in FIG. 4, the sputtered material corresponding to
arrows 418 strikes the surfaces of the shields 404 and 406, and is effectively
blocked from reaching the target substrate 422. In contrast, the sputtered material
corresponding to the arrows 420 bypasses the shields 404 and 406 and may
impinge the target substrate 422. However, the sputtered material corresponding
to the arrows 420 remains within the envelope of the ion beam 416 and is
therefore substantially etched away from the target substrate by the ion beam
during processing. Accordingly, the separation between the shields (404 and 406)
and the substrate path and the separation between and relative alignment between
the shields (404 and 406) and the ionization regions 410 are set to block sputtered
material that is emitted outside the ion beam envelope, while allowing the ion
beam (and sputtered material emitted within the ion beam envelope) to pass to the
target.
[0043] FIG. 5 illustrates a face of an ion source 500 with exemplary emitter
shields. FIG. 6 illustrates a perspective view of the ion source 500 of FIG. 5 with
exemplary emitter shields. An ion source 500 includes an oval ionization region 502 in which a working gas is ionized and from which ions are emitted. In
operation, the ion source 500 emits ions from the ionization region 502 in the form
of an ion beam. A substrate (not shown) is passed through the ion beam for
processing (e.g., at some distance from the face of the ion source). In an
exemplary embodiment, a substrate is transported along a path peφendicular to (or
some other angle relative to) the long axis of the ion source 500, which emits an
ion beam from the ionization region 502 toward the surface of the substrate as it
passes.
[0044] It should be understood that some benefits may result for a non-
peφendicular substrate path, including increasing power density, reducing
overspray on a source longer than the width of the substrate, and smoothing out
small longitudinal beam non-uniformities. There may also be benefits for a non-
peφendicular angle of emission from the ion source and/or a non-peφendicular
angle of ion impingement on the substrate. It should also be noted that the angle
of the beam may be modified dynamically during the emission. Benefits may also
be achieved from operating with the shields at some other electrical potential
relative to the ion source housing (e.g., electrical isolation/floating and/or active
biasing at a positive potential).
[0045] Emitter shields 504, 506, and 508 are positioned between the ion
source 500 and the path of the substrate along the long channel portions of the
ionization region 502. In various embodiments, one or two of the shields 504,
506, and 508 may be omitted. However, to best block sputtered contaminants from impinging the substrate surface after the substrate has passed through the ion
beam, one of the shields is maintained on the far edge of the ion source (i.e.,
farthest in the direction of substrate motion). Nevertheless, each shield, singly or
in combination with other shields, may decrease the total amount of sputtered
contaminants reaching or remaining on the surface of the substrate, thereby
improving substrate quality.
[0046] In the illustrated implementation, and in addition to emitter shields
504, 506, and 508, end shields 510 and 512 may be employed to block sputtered
contaminants from the rounded ends of the ion source 500. Each end shield 510
and 512 may be configured (e.g. shaped, placed and sized) to block all emitted
ions and sputtered contaminants emanating from the rounded ionization
region 502 region in the ends of the ion source 500. For example, the end
shields 510 and 512 may be much taller than the emitter shields 504, 506, and 508,
which are sized to substantially pass the ion beam and substantially block the
sputtered contaminants. Alternatively, the end shields 510 and 512 may be
positioned, sized, and shaped to pass a portion of the ion beam and to substantially
block the sputtered contaminants.
[0047] FIG. 7 illustrates a face of another ion source 700 with exemplary
emitter shields. FIG. 8 illustrates a perspective view of the ion source 700 of FIG.
7 with exemplary emitter shields. An ion source 700 includes an oval ionization
region 702 in which a working gas is ionized. In operation, the ion source 700
emits ions from the ionization region 702 in the form of an ion beam. A substrate (not shown) is transported through the ion beam for processing (e.g., at some
distance from the face of the ion source). In an exemplary embodiment, a
substrate is transported along a path peφendicular to the long axis of the ion
source 700, which emits an ion beam from the ionization region 702 toward the
surface of the substrate as it passes.
[0048] Emitter shields 704, 706, and 708 are positioned between the ion
source 700 and the path of the substrate along the long channel portions of the
ionization region 702, as discussed with regard to FIGs. 5 and 6. Likewise, in
various embodiments, one or two of the shields 504, 506, and 508 may be omitted.
[0049] In addition to emitter shields 704, 706, and 708, end shields 710 and
712 may be employed to block sputtered contaminants from the rounded ends of
the ion source 700. The end shields 710 and 712 are shaped to improve the
amount of the ion beam that is passed while substantially blocking the sputtered
contaminants. The rounded shape substantially matches the rounded shape of the
ionization region 702 at the ends of the ion source 700. In this configuration, the
size and positioning of the end shields 710 and 712 are set to substantially pass the
ion beam and to substantially block the sputtered contaminants from reaching the
substrate.
[0050] The above specification, examples and data provide a complete
description of the structure and use of exemplary embodiments of the invention.
However, other implementations are also contemplated within the scope of the
present invention, including without limitation shields having different shapes, sizes, and locations than those shown, as well as systems having one or more
shields and systems with or without one or more end shields. In addition, while
the description has described exemplary ion sources as ALSs, other ion sources
may be employed within the scope of the invention. Since many implementations
can be made without departing from the spirit and scope of the invention, the
invention resides in the claims hereinafter appended.

Claims

Claims WHAT IS CLAIMED IS:
1. An ion source system for processing a substrate along a substrate
location, the ion source system comprising: an ion source generating an ion beam; and a shield positioned between the ion source and the substrate location to pass
the ion beam to the substrate while blocking sputtered contaminants emanating
from the ion source from impinging the substrate.
2. The ion source system of claim 1 wherein the ion source includes a
cathode and generates sputtering ions, the sputtering ions sputtering the sputtered
contaminant from the cathode.
3. The ion source system of claim 1 wherein the ion source includes an
anode and generates sputtering ions, the sputtering ions sputtering the sputtered
contaminant from the anode.
4. The ion source system of claim 1 wherein the ion beam defines an
envelope and the shield blocks the sputtered contaminants outside the envelope of
the ion beam.
5. The ion source system of claim 1 wherein the ion beam defines an
envelope and the substrate location is defined for passing the substrate through the
envelope of ion beam.
6. The ion source system of claim 1 wherein the ion source has a face and
an ionization region, and the shield is positioned upright relative to the face of the
ion source between long channels portions of the ionization region.
7. The ion source system of claim 1 wherein the ion source has a face and
the shield is affixed to the ion source and is positioned upright relative to the face
of the ion source between long channel portions of an ionization region of the ion
source.
8. The ion source system of claim 1 wherein the ion source has a face and
the shield is positioned upright relative to the face of the ion source along and
outside a long channel portion of an ionization region of the ion source.
9. The ion source system of claim 1 wherein the ion source has a face and
the shield is affixed to the ion source and is positioned upright relative to the face
of the ion source along and outside a long channel portion of an ionization region
of the ion source.
10. The ion source system of claim 1 wherein the ion beam defines an
envelope, the substrate location is defined for passing the substrate through the
envelope of ion beam, and the shield is positioned adjacent to the substrate location to block the sputtered contaminants from impinging the substrate on at
least a portion of the substrate location outside the envelope of the ion beam.
11. The ion source system of claim 1 wherein the ion source has a face, the
ion beam defines an envelope, the substrate location is defined for passing the
substrate through the envelope of ion beam, and the shield is positioned
substantially parallel to the face of the ion source and adjacent to the substrate
location to block the sputtered contaminants from impinging the substrate on at
least a portion of the substrate location outside the envelope of the ion beam.
12. The ion source system of claim 1 wherein the ion source includes an
ionization region and at least one end section containing an end portion of the
ionization region, the shield blocking sputtered contaminants emanating from the
end portion of the ionization region from impinging the substrate.
13. The ion source system of claim 1 wherein the sputtered contaminants
are sputtered from a surface of the ion source.
14. The ion source system of claim 1 wherein the ion source has an
emission face from which the ion beam is emitted toward the substrate location
and the emission face is parallel to a surface of the substrate.
15. The ion source system of claim 1 wherein the ion source has an
emission face from which the ion beam is emitted in a normal direction from the emission face toward the substrate location and the emission face is parallel to a
surface of the substrate.
16. The ion source system of claim 1 wherein the ion source has an
emission face from which the ion beam is emitted in a non-normal direction from
the emission face toward the substrate location and the emission face is parallel to
a surface of the substrate.
17. The ion source system of claim 1 wherein the ion source has an
emission face from which the ion beam is emitted toward the substrate location
and the emission face is not parallel to a surface of the substrate.
18. The ion source system of claim 1 wherein the ion source has an
emission face from which the ion beam is emitted in a normal direction to the
emission face toward the substrate location and the emission face is not parallel to
a surface of the substrate.
19. The ion source system of claim 1 wherein the ion source has an
emission face from which the ion beam is emitted in a non-normal direction to the
emission face toward the substrate location and the emission face is not parallel to
a surface of the substrate.
20. The ion source system of claim 1 wherein the shield is actively biased.
21. The ion source system of claim 1 wherein the shield is actively biased to
a positive potential.
22. The ion source system of claim 1 wherein the shield is electrically
isolated from the ion source.
23. The ion source system of claim 1 wherein the shield comprises a
process-compatible material.
24. The ion source system of claim 1 wherein the shield comprises a
contaminant-trapping material.
25. A shielding system positionable between an ion source and a
substrate location that passes an ion beam from an ion source to impinge a
substrate on the substrate location while blocking sputtered contaminants
emanating from the ion source from impinging the substrate.
26. The shielding system of claim 25 wherein the ion beam defines an
envelope and the sputtered contaminants are blocked outside the envelope of
the ion beam.
27. The shielding system of claim 25 wherein the sputtered contaminants
are sputtered from a cathode of the ion source.
28. The shielding system of claim 25 wherein the sputtered contaminants
are sputtered from an anode of the ion source.
29. The shielding system of claim 25 wherein the ion beam defines an
envelope and the substrate location is defined for passing the substrate through
the envelope of ion beam.
30. The shielding system of claim 25 wherein the ion source includes a
cathode and an ionization region that generates the ion beam and sputtering
ions, and the sputtering ions sputter the sputtered contaminant from the cathode
toward the substrate location.
31. The shielding system of claim 25 wherein the ion source has a face
and an ionization region, and the shielding system includes a shield positioned upright relative to the face of the ion source between long channels portions of
the ionization region of the ion source.
32. The shielding system of claim 25 wherein the ion source has a face
and an ionization region, and the shielding system includes a shield affixed to
the ion source and being positioned upright relative to the face of the ion source
between long channel portions of an ionization region of the ion source.
33. The shielding system of claim 25 wherein the ion source has a face
and an ionization region, and the shielding system includes a shield positioned
upright relative to the ion source along and outside a long channel portion of an
ionization region of the ion source.
34. The shielding system of claim 25 wherein the ion source has a face
and an ionization region, and the shielding system includes a shield affixed to
the ion source and being positioned upright relative to the ion source along and
outside and along a long channel portion of an ionization region of the ion
source.
35. The shielding system of claim 25 wherein the ion beam defines an
envelope, a substrate location is defined to pass the substrate through the
envelope of ion beam, and the shielding system includes a shield positioned
adjacent to the substrate location to block sputtered contaminants from
impinging the substrate on at least a portion of the substrate location outside an
envelope of the ion beam.
36. The shielding system of claim 25 wherein the ion source includes an
ionization region and at least one end section containing an end portion of the
ionization region, and the shielding system includes an end shield to block
sputtered contaminants emanating from the end portion of the ionization region
from impinging the substrate.
37. The shielding system of claim 25 wherein the sputtered contaminants
are sputtered from a surface of the ion source.
38. The shielding system of claim 25 wherein the ion source has an
emission face from which the ion beam is emitted toward the substrate location
and the emission face is parallel to a surface of the substrate.
39. The shielding system of claim 25 wherein the ion source has an
emission face from which the ion beam is emitted in a normal direction from
the emission face toward the substrate location and the emission face is parallel
to a surface of the substrate.
40. The shielding system of claim 25 wherein the ion source has an
emission face from which the ion beam is emitted in a non-normal direction
from the emission face toward the substrate, location and the emission face is
parallel to a surface of the substrate.
41. The shielding system of claim 25 wherein the ion source has an
emission face from which the ion beam is emitted toward the substrate location
and the emission face is not parallel to a surface of the substrate.
42. The shielding system of claim 25 wherein the ion source has an
emission face from which the ion beam is emitted in a normal direction to the
emission face toward the substrate location and the emission face is not parallel
to a surface of the substrate.
43. The shielding system of claim 25 wherein the ion source has an
emission face from which the ion beam is emitted in a non-normal direction to
the emission face toward the substrate location and the emission face is not
parallel to a surface of the substrate.
44. The shielding system of claim 25 wherein the shielding system is
actively biased.
45. The shielding system of claim 25 wherein the shielding system is
actively biased to a positive potential.
46. The shielding system of claim 25 wherein the shielding system is
electrically isolated from the ion source.
47. The shielding system of claim 25 wherein the shielding system
comprises a process-compatible material.
48. The shielding system of claim 25 wherein the shielding system
comprises a contaminant-trapping material.
49. A method of processing a substrate, the method comprising: generating an ion beam and sputtering ions from a surface of an ion
source, the ion beam defining an envelope; positioning the substrate within the envelope; emitting sputtered contaminants sputtered from the surface of the ion
source by the sputtering ions; and blocking the sputtered contaminants emanating from the ion source from
impinging the substrate outside of the envelope of the ion beam.
50. The method of claim 49 wherein the surface is on a cathode of the
ion source.
51 . The method of claim 49 wherein the surface is on an anode of the ion
source.
52. The method of claim 49 wherein positioning the substrate within the
envelope comprises: passing the substrate through the envelope.
53. The method of claim 49 wherein the ion source has an emission face
from which the ion beam is emitted toward the substrate and the emission face
is parallel to a surface of the substrate.
54. The method of claim 49 wherein the ion source has an emission face
from which the ion beam is emitted in a normal direction from the emission face toward the substrate and the emission face is parallel to a surface of the
substrate.
55. The method of claim 49 wherein the ion source has an emission face
from which the ion beam is emitted in a non-normal direction from the
emission face toward the substrate and the emission face is parallel to a surface
of the substrate.
56. The method of claim 49 wherein the ion source has an emission face
from which the ion beam is emitted toward the substrate and the emission face
is not parallel to a surface of the substrate.
57. The method of claim 49 wherein the ion source has an emission face
from which the ion beam is emitted in a normal direction to the emission face
toward the substrate and the emission face is not parallel to a surface of the
substrate.
58. The method of claim 49 wherein the ion source has an emission face
from which the ion beam is emitted in a non-normal direction to the emission
face toward the substrate and the emission face is not parallel to a surface of
the substrate.
59. The method of claim 49 further comprising: actively biasing a shield blocking the sputtered contaminants.
60. The method of claim 49 further comprising: actively biasing a shield to a positive potential, the shield blocking the
sputtered contaminants.
61. The method of claim 49 further comprising: electrically isolating a shield from the ion source, wherein the shield
blocks the sputtered contaminants.
62. An ion source system comprising: an ion source capable of emitting an ion beam; and means for passing the ion beam from the ion source to impinge a
substrate while blocking sputtered contaminants from impinging the substrate.
63. The ion source system of claim 62 wherein the means for passing the
ion beam is positioned between the ion source and a substrate location defined
for passing the substrate through the ion beam.
64. The ion source system of claim 62 wherein the ion source includes a
cathode and the sputtered contaminants are sputtered from the cathode.
65. The ion source system of claim 62 wherein the ion source includes
an anode and the sputtered contaminants are sputtered from the anode.
66. The ion source system of claim 62 wherein the means for passing is
actively biased.
67. The ion source system of claim 62 wherein the means for passing is
actively biased to a positive potential.
68. The ion source system of claim 62 wherein the means for passing is
electrically isolated from the ion source.
69. The ion source system of claim 62 wherein the means for passing
comprises a process-compatible material.
70. The ion source system of claim 62 wherein the means for passing
comprises a contaminant-trapping material.
PCT/US2004/027189 2003-08-20 2004-08-20 Sputtered contamination shielding for an ion source WO2005020265A2 (en)

Applications Claiming Priority (4)

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US49688603P 2003-08-20 2003-08-20
US60/496,886 2003-08-20
US10/918,265 US20050035954A1 (en) 2003-08-13 2004-08-13 Method and apparatus to facilitate automated transcription of NMR spectra into a textual report using a graphics tablet
US10/918,265 2004-08-18

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4481062A (en) * 1982-09-02 1984-11-06 Kaufman Harold R Electron bombardment ion sources
JPH0611755A (en) * 1992-06-26 1994-01-21 Canon Inc Image pickup device
EP1130623A1 (en) * 1998-10-30 2001-09-05 Applied Materials, Inc. Apparatus for ion implantation
US20020163289A1 (en) * 2001-05-03 2002-11-07 Kaufman Harold R. Hall-current ion source

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4481062A (en) * 1982-09-02 1984-11-06 Kaufman Harold R Electron bombardment ion sources
JPH0611755A (en) * 1992-06-26 1994-01-21 Canon Inc Image pickup device
EP1130623A1 (en) * 1998-10-30 2001-09-05 Applied Materials, Inc. Apparatus for ion implantation
US20020163289A1 (en) * 2001-05-03 2002-11-07 Kaufman Harold R. Hall-current ion source

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