WO2005000916A1 - Polymerization process for preparing (co)polymers - Google Patents
Polymerization process for preparing (co)polymers Download PDFInfo
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- WO2005000916A1 WO2005000916A1 PCT/EP2004/006601 EP2004006601W WO2005000916A1 WO 2005000916 A1 WO2005000916 A1 WO 2005000916A1 EP 2004006601 W EP2004006601 W EP 2004006601W WO 2005000916 A1 WO2005000916 A1 WO 2005000916A1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
- C08F4/32—Organic compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
Definitions
- the present invention relates to an aqueous dispersion polymerization process for preparing a (co)polymer wherein one or more organic peroxides are used as initiator (as a source of free radicals) in conjunction with an effective amount of one or more controlling agents.
- the invention also relates to formulations comprising organic peroxide(s) and an effective amount of said controlling agent(s) suitable for use in said aqueous dispersion polymerization process.
- the invention finally relates to (co)polymers obtainable by the dispersion polymerization process.
- US 5,155,192 discloses storageable and/or transportable compositions containing peroxydicarbonate to which an organic peroxide has been added to retard the decomposition of said peroxydicarbonate.
- the compositions of US 5,155,192 are suitable for use in the conventional mass, suspension, or emulsion (co)polymerization of ethylenically unsaturated monomers.
- no further specifications of the peroxydicarbonates to be used are given, such as their solubility or their half life.
- US 2002/0123591 discloses the emulsion or suspension polymerization of vinyl chloride monomers, using an organic peroxide that is dosed at least partly to the polymerization mixture at the reaction temperature and wherein essentially all the peroxide has a half life of from 0.05 to 1.0 hour at the polymerization temperature. It is said that a low fish eye level is acquired using this polymerization process.
- (co)polymers with a further reduced level of fish eyes are obtained in an aqueous dispersion polymerization process wherein one or more organic peroxides to be used as initiator are selected from the group consisting of diacyl peroxides, peroxyesters, specific peroxydicarbonates, and mixtures thereof, in conjunction with an effective amount of one or more suitable controlling agents selected from the group consisting of organic hydroperoxides, ethylenically unsaturated organic compounds that preferably cannot homo- polymerize (i.e. form polymers obtained by self-polymerization), compounds with labile carbon-hydrogen bonds, oximes, and mixtures thereof. More preferably, it is an aqueous suspension or emulsion polymerization process. Most preferably, it is an aqueous suspension polymerization process.
- controlling agent is used to describe compounds and mixtures thereof that have a beneficial effect on the polymerization process wherein one or more organic peroxides are used as initiator, as a result of which a final polymer material having a reduced level of fish eyes is obtained.
- the effect of the controlling agent can be explained at least partly by the fact that the controlling agent traps radicals initially formed by the initiator. In consequence, the remaining initiator has more time to distribute homogeneously in the polymerization reaction mixture, which eventually is beneficial to the reduction of the level of fish eyes.
- the polymerization process is a conventional aqueous dispersion polymerization process or an aqueous dispersion polymerization process wherein at least part of the one or more organic peroxides used as initiator is dosed to the reaction mixture at the polymerization temperature, wherein the one or more organic peroxides are selected from the group consisting of diacyl peroxides, peroxyesters, peroxydicarbonates, and mixtures thereof, in conjunction with an effective amount of one or more controlling agents selected from the group consisting of organic hydroperoxides, ethylenically unsaturated organic compounds that preferably cannot homo- polymerize, compounds with labile carbon-hydrogen bonds, oximes, and mixtures thereof, with the proviso that the solubility of the peroxydicarbonate(s) in water at 0°C is at least 5 ppm, as determined by the test described herein.
- the one or more organic peroxides are selected from the group consisting of diacyl peroxides, peroxyesters, and mixtures thereof .
- the one or more organic peroxides are selected from the group consisting of organic peroxides having a half-life of at least 0.0001 hour and at most 1.0 hour at the polymerization temperature .
- the solubility of the peroxyester and/or diacylperoxide in water at 0°C also is at least 5 ppm, as determined by the test described herein.
- the present invention relates to a formulation suitable for use in an aqueous dispersion polymerization process of the present invention, said formulation comprising one or more organic peroxides selected from the group consisting of diacyl peroxides, peroxyesters, peroxydicarbonates, and mixtures thereof, and an effective amount of one or more controlling agents selected from the group consisting of organic hydroperoxides, ethylenically unsaturated organic compounds that preferably cannot homopolymerize, compounds with labile carbon-hydrogen bonds, oximes, and mixtures thereof, with the proviso that the solubility of the peroxydicarbonate(s) in water at 0°C is at least 5 ppm, as determined by the test as described herein.
- organic peroxides selected from the group consisting of diacyl peroxides, peroxyesters, peroxydicarbonates, and mixtures thereof
- one or more controlling agents selected from the group consisting of organic hydroperoxides, ethylenically unsatur
- the solubility of the peroxyester and/or diacylperoxide in water at 0°C also is at least 5 ppm, as determined by the test described herein.
- the present invention relates to a formulation suitable for use in an aqueous dispersion polymerization process of the present invention, wherein the formulation comprises one or more organic peroxides selected from the group consisting of organic peroxides having a half-life of at least 0.0001 hour and at most 1 .0 hour at the polymerization temperature.
- the invention relates to a formulation suitable for use in an aqueous dispersion polymerization process of the present invention, said formulation comprising one or more organic peroxides selected from the group consisting of diacyl peroxides of formula I as described below, and an effective amount of dibutyl maleate as controlling agent.
- the invention relates to a formulation suitable for use in an aqueous dispersion polymerization process of the present invention, said formulation comprising one or more organic peroxides selected from the group of diacyl peroxides of formula I as described below, peroxyesters of formula II as described below, and mixtures thereof, and an effective amount of an organic hydroperoxide as controlling agent, provided that it does not relate to a formulation covered by patent application WO 2004/000799.
- the formulation according to this invention is phlegmatizing agent-free, which means that it contains less than 5 wt% on the total composition of the above phlegmatizing agent, preferably less than 4 wt%. more preferably less than 2 wt%, most preferably less than 1 wt%.
- the controlling agent is the controlling agent
- Hydroperoxides that are suitable for use as controlling agents in the present invention are well-known compounds, many of which are commercially available. They are of the general formula ROOH, wherein R represents an organic group, but not a hydrogen atom, more particularly wherein R represents a branched or non-branched, substituted or unsubstituted alkyl group, alkenyl group, alkynyl group, or cycloalkyl group. R generally does not have more than 40 carbon atoms, preferably not more than 20 carbon atoms, and more preferably not more than 12 carbon atoms. As examples of suitable substituents of the R group may be mentioned the hydroperoxy group, the phenyl group, and the hydroxyl group.
- hydroperoxides examples include methyl hydroperoxide, ethyl hydroperoxide, n-propyl hydroperoxide, isopropyl hydroperoxide, sec-butyl hydroperoxide, isobutyl hydroperoxide, 1-phenyl-1- hydroperoxy ethane, benzyl hydroperoxide, methylethyl ketone hydroperoxide, i.e. a mixture of 2,2'-dihydroperoxy-2-2'-di-n-butyl peroxide and 2,2-dihydro- peroxy butane, cyclohexanone hydroperoxide, i.e.
- tertiary hydroperoxides i.e. hydroperoxides having one or more hydroperoxy groups linked to tertiary carbon atoms.
- tertiary hydroperoxides examples include tert-butyl hydroperoxide (TBHP), tert-amyl hydroperoxide (TAHP), 1 ,1 ,3,3- tetramethylbutyl hydroperoxide (TMBH), 2-hydroperoxy-2-methyl pentane, 2- hydroperoxy-2-methyl-3-butene, 2-hydroperoxy-2,4,4-trimethyl pentane, 2,5- dihydroperoxy-2,5-dimethyl hexane, 2,5-dihydroperoxy-2,5-dimethyl-3-hexyn, 2,6-dihydroperoxy-4-hydroxy-2,6-dimethyl heptane, 2-hydroperoxy-4-hydroxy-2- methyl butane, 2-hydroperoxy-4-hydroxy-2-methyl pentane, 2-hydroperoxy-4- hydroxy-2-methyl heptane, 3-ethyl-3-hydroperoxy-5-hydroxy hexane, cumyl
- Examples of ethylenically unsaturated organic compounds that preferably cannot homopolymerize for use in the present invention are selected from the group consisting of dialkyl maleates, dialkyl fumarates, ⁇ -olefins, styrene, ⁇ - methylstyrene, -unsaturated ketones represented by formula (IV):
- R 17 can be selected from hydrogen, alkyl, alkenyl, and aryl
- R 18 can be selected from hydrogen, alkyl, and aryl
- R 19 can be selected from hydrogen and alkyl
- R 20 can be selected from hydrogen, OH, and OR 21
- R 21 can be selected from alkyl and aryl
- R 17 and R 19 can form a cycloalkenyl or oxa-cycloalkenyl moiety, and compounds represented by formula (V):
- R 22 and R 23 are the same or different and are selected from the group consisting of hydrogen, alkyl of 1 to 4 carbons, cycloalkyl of 5 to 10 carbons, aryl of 6 to 10 carbons, aralkyl of 7 to 11 carbons, alkenyl of 2 to 6 carbons, bromo and chloro; and wherein Z is -C ⁇ N or -C ⁇ C-R 24 , wherein R 24 is selected from the group consisting of hydrogen, alkyl of 1 to 4 carbons, cycloalkyl of 5 to 10 carbons, alkenyl of 2 to 6 carbons, aralkyl of 7 to 11 carbons, and aryl of 6 to 10 carbons.
- Preferred compounds are dibutyl maleates
- Examples of compounds with labile carbon-hydrogen bonds that are suitable for use in the present invention are selected from the group consisting of ⁇ - dicarbonyl compounds and cyclic ⁇ -diketone compounds, including diethyl malonate and acetyl acetone, as mentioned in EP-0,810,213-A2, aliphatic aldehydes, and aromatic aldehydes. Preferred are diethyl malonate and acetyl acetone
- Examples of oximes that are suitable for use in the present invention are selected from the group consisting of compounds represented by formula (VI):
- Preferred controlling agents for use in the present invention are hydroperoxides and ethylenically unsaturated organic compounds that preferably cannot homopolymerize. More preferred controlling agents are hydroperoxides and dibutyl maleate. The most preferred controlling agents are hydroperoxides.
- the (effective) amount of controlling agent to be used in the process of the present invention is dependent on the type of controlling agent and the type of organic peroxide used. Typically, the amount of controlling agent used is 0.3-45 wt%, based on the weight of organic peroxide.
- the amount of controlling agent used is 0.3-45 wt%, based on the weight of organic peroxide.
- the amount preferably is 0.3-3 wt%, more preferably 0.5-1.5 wt%, and most preferably 0.7-1.5 wt%.
- an ethylenically unsaturated compound such as dibutyl maleate
- the amount preferably is 4-45 wt%, more preferably 5 to 25 wt%, and most preferably 8-15 wt%, based on the weight of the organic peroxide.
- the amount of TBHP used typically is in the range of 0.3-2 wt%, based on the amount of diisobutyryl peroxide
- the amount of dibutyl maleate used typically is 5-20 wt%, based on the amount of diisobutyryl peroxide.
- controlling agent can be dosed to the reactants forming the polymerization reaction mixture.
- the controlling agent may be added to the polymerization reaction mixture separately or in admixture with one of the other compounds, such as in admixture with the one or more organic peroxides.
- the controlling agent is admixed with the one or more organic peroxides to be used in the polymerization reaction selected from the group consisting of diacyl peroxides, peroxyesters, peroxydicarbonates, and mixtures thereof, prior to use thereof in said reaction. This admixing results in a formulation comprising organic peroxide and controlling agent.
- the formulation can be a solution of organic peroxide and/or controlling agent or it can be a suspension or emulsion of organic peroxide and/or controlling agent.
- Such a formulation has several advantages, such as improved stability of the peroxide formulation, as is described in US 5,155,192. More specifically, in order to comply with the rules relating to storage and/or transportation of organic peroxide compositions, such formulations must be stored and transported at 20°C below the self-accelerating decomposition temperature (SADT) of the organic peroxide.
- SADT self-accelerating decomposition temperature
- the SADT is an internationally accepted parameter from which the maximum temperature at which goods are allowed to be transported can be derived. For practical and economical reasons the maximum storage temperature should not be below approximately -20°C, meaning that the SADT should be at least 0°C.
- said controlling agent can also have a positive effect on the uncontrolled thermal decomposition behaviour of the organic peroxide.
- a so-called mini-HAST test is performed.
- a mini-HAST test typically a Dewar vessel with a volume of 100 ml is charged with 50 g of a sample comprising the organic peroxide to be tested, optionally in the presence of one or more controlling agents.
- a Temperature v. Time profile of the sample is measured in order to determine the stabilizing effect of the respective controlling agent used.
- a blank sample i.e. a sample with no controlling agent present, is also analyzed to serve as a point of reference.
- Preferred organic peroxides that are particularly suitable for the process of the present invention are selected from the group of consisting of: - diacyl peroxides of formula (I)
- R ⁇ R 6 are independently selected from the group consisting of hydrogen, halogens, alkoxy groups, and saturated or unsaturated, linear or branched, substituted or unsubstituted alkyl, alkaryl, and aralkyl moieties, and wherein two of R 1 -R 3 of R 1 C(R 2 )R 3 and/or two of R 4 -R 6 of R 4 C(R 5 )R 6 can be linked to form a cyclic structure which can be saturated or unsaturated and optionally may be substituted with one or more independently chosen groups R 28 , which R 28 is selected from the group consisting of hydrogen, halogens, alkoxy groups, and saturated or unsaturated, linear or branched, substituted or unsubstituted alkyl, alkaryl and aralkyl moieties, with the proviso that at most one of R 1 C(R 2 )R 3 and
- R 4 C(R 5 )R 6 i is CH 3 , peroxyestei rs of formula (II)
- R 7 -R 9 are independently selected from the group consisting of hydrogen, halogens, alkoxy groups, and saturated or unsaturated, linear or branched, substituted or unsubstituted alkyl, alkaryl, and aralkyl moieties, with the proviso that R 7 C(R 8 )R 9 is not CH 3 , wherein two of R 7 -R 9 can be linked to form a cyclic structure which can be saturated or unsaturated and optionally may be substituted with one or more independently chosen groups R 29 , which R 29 is selected from the group consisting of hydrogen, halogens, alkoxy groups, and saturated or unsaturated, linear or branched, substituted or unsubstituted alkyl, alkaryl, and aralkyl moieties, and wherein
- R 10 is selected from the group consisting of saturated or unsaturated, substituted or unsubstituted, linear or branched alkyl, alkaryl, and aralkyl moieties, peroxydicarbonates having a solubility in water at 0°C of at least 5 ppm of formula (III):
- R 11 -R 16 are independently selected from the group consisting of hydrogen, halogens, and saturated or unsaturated, l inear or branched, substituted or unsubstituted alkyl, alkaryl, and aralkyl moieties, and wherein two of R 11 -R 13 of R 11 C(R 12 )R 13 and/or two of R 14 -R 16 can be linked to form a cyclic structure which can be saturated or unsaturated and optionally may be substituted with one or more independently chosen groups R 30 , which R 30 is selected from the group consisting of hydrogen, halogens, alkoxy groups, and saturated or unsaturated, linear or branched, substituted or unsubstituted alkyl, alkaryl, and aralkyl moieties, and - mixtures of diacyl peroxide(s) of formula (I), peroxyester(s) of formula (II), and/or peroxydicarbonate(s) of formula (III).
- More preferred peroxydicarbonate(s) of formula (III) above and mixtures thereof with peroxyester(s) of formula (II) and/or diacylperoxide(s) of formula (I) are those wherein R 11 -R 16 are independently selected from the group consisting of hydrogen, halogens, and saturated or unsaturated alkyl moieties wherein the number of carbon atoms is at most 4, and wherein two of R 11 -R 13 of R 11 C(R 12 )R 13 and/or two of R 14 -R 16 can be linked to form a cyclic structure which can be saturated or unsaturated and optionally may be substituted with one or more independently chosen groups R 30 , which R 30 is selected from the group consisting of hydrogen, halogens, alkoxy groups, and saturated or unsaturated, linear or branched, substituted or unsubstituted alkyl, alkaryl, and aralkyl moieties.
- organic peroxides it is preferred to select one or more organic peroxides from the group of diacyl peroxides or the group of peroxy- esters or the group of peroxydicarbonates, although it is also possible to select one or more organic peroxides from at least two of these groups of diacyl peroxides, peroxyesters, and peroxydicarbonates.
- diacyl peroxides for use in the process of the present invention are selected from the group wherein R 1 -R 6 are independently selected from the group consisting of hydrogen, alkoxy groups, and saturated or unsaturated, linear or branched alkyl, alkaryl, and aralkyl moieties, with the proviso that at most one of R 1 C(R 2 )R 3 and R 4 C(R 5 )R 6 is CH 3 . More preferred are diacyl peroxides wherein R 1 -R 6 are independently selected from the group consisting of linear or branched alkyl moieties.
- R 1 -R 6 may all be independently selected, it is preferred to use a symmetric diacyl peroxide. Most preferred is the use of just one diacyl peroxide, although it is also possible to use a mixture of diacyl peroxides.
- the most preferred diacyl peroxide for use in the process of the present invention is diisobutyryl peroxide, wherein R 1 and R 4 are hydrogen and R 2 , R 3 , R 5 , and R 6 are methyl.
- peroxyesters particularly preferred peroxyesters for use in the process of the present invention are selected from the group wherein R 7 -R 9 are independently selected from the group consisting of hydrogen, alkoxy groups, and saturated or unsaturated, linear or branched alkyl, alkaryl, and aralkyl moieties, with the proviso that R 7 C(R 8 )R 9 is not CH 3 , and wherein R 10 is selected from the group consisting of saturated or unsaturated, substituted or unsubstituted, linear or branched alkyl moieties.
- peroxyesters wherein R 7 -R 9 are independently selected from the group consisting of linear or branched alkyl and alkoxy moieties and wherein R 10 is tert-butyl, tert-amyl, tert-octyl, or 1 ,1-dimethyl-3-hydroxy-butyl. Most preferred is the use of just one peroxyester, although it is also possible to use a mixture of peroxyesters. The most preferred peroxyester for use in the process of the present invention is tert-amyl peroxy methoxy acetate.
- peroxydicarbonates having a solubility in water at 0°C of at least 5 ppm particularly preferred peroxydicarbonates for use in the process of the present invention are selected from the group wherein R 11 -R 16 are independently selected from the group consisting of hydrogen, and saturated or unsaturated, linear or branched alkyl moieties.
- R 11 C(R 12 )R 13 and R 14 C(R 15 )R 16 are preferably identical, the invention is not limited to these symmetrical peroxydicarbonates. Most preferred is the use of just one peroxydicarbonate, although it is also possible to use a mixture of peroxydicarbonates. The most preferred peroxydicarbonates are di-sec-butyl peroxydicarbonate and diethyl peroxydicarbonate.
- one or more organic peroxides selected from the group consisting of peroxyesters, diacyl peroxides, and mixtures thereof with one or more hydroperoxides or dibutyl maleate is preferred.
- One or more organic peroxides selected from the group consisting of peroxyesters, diacyl peroxides, and mixtures thereof with one or more hydroperoxides are more preferred.
- a combination of a diacyl peroxide with a hydroperoxide is particularly preferred. Fish eye levels in (co)polymers are most effectively reduced if diisobutyryl peroxide is used as organic peroxide in combination with TBHP as controlling agent.
- the extremely fast initiators are characterized by very short half-life periods at the polymerization temperature.
- the preferred half-life of the organic peroxide used in the present invention is at least 0.0001 hour and at most 1.0 hour at the polymerization temperature. More preferably, the half-life is at most 0.8 hours, even more preferably the half-life is at most 0.5 hours, and most preferably the half-life of the organic peroxide is at most 0.3 hours at the polymerization temperature.
- Particularly suitable, especially for CD polymerization processes are organic peroxides having a half-life of 0.01-0.2 hours at the polymerization temperature.
- the organic peroxide (initiator) is dosed to a reactor during the polymerization process. Dosing of an extremely fast initiator to a polymerization reaction allows improved control of the polymerization rate, higher polymerization rates leading to an increased space- time yield of polymerization reactors, and results in the process leading to a polymer with very low residual initiator levels. It is to be understood that the word "dosing" is used to describe the step of adding organic peroxide to the polymerization reaction mixture at polymerization conditions.
- the dosing can be done intermittently during the polymerization over a period of time wherein at least 20%, preferably at least 40%, even more preferably at least 60% of all monomer used in the process is polymerized, meaning that at least two portions of initiator are added to the reaction mixture.
- the addition can be continuous (i.e. a continuous dosing polymerization process), eaning that for a certain period of time the initiator is continuously added to the reaction mixture.
- Combinations of these techniques are also possible.
- An example of a combination of such techniques includes, for instance, a process wherein the initiator is first added continuously, then the addition is stopped, and then it is added continuously again.
- the organic peroxide is dosed continuously and/or intermittently from the start of the polymerization reaction, preferably after at least 5%, more preferably at least 10%, even more preferably at least 20%o, most preferably at least 30% of the monomer(s) has already been polymerized and wherein during the dosing period at least 2%, preferably at least 5%, more preferably at least 10%, even more preferably at least 20%, even more preferably still at least 30%, and most preferably at least 50% of all monomer(s) used in the process is polymerized.
- the controlling agent is added to the reaction mixture in admixture with the one or more organic peroxides it is added to the reaction mixture in the same preferred way as the organic peroxide. If, however, the controlling agent is added to the reaction mixture separately, it also is preferably added to the polymerization reaction mixture as indicated above for the one or more organic peroxides.
- the initiator used in the polymerization reaction serves as a source of free radicals.
- the formation of a free radical is followed by the radical's reaction with a monomer, which is the actual initiation of the polymerization.
- aqueous dispersion processes such as suspension or emulsion polymerization processes, wherein the reaction mixture typically is a suspension or (micro-)emulsion of monomer in water, since in these processes an aqueous and a non-aqueous phase are present.
- the solubility of the organic peroxide (the initiator) in water should be relatively low.
- the organic peroxide used as initiator for the present polymerization process has a solubility in water of 5- 10,000 ppm at 0°C, more preferably the solubility in water is 15-1 ,500 ppm at 0°C, and most preferably the solubility in water is 20-1 ,000 ppm at 0°C.
- the amount of organic peroxide to be used as initiator in the polymerization process of this invention is within the range used in conventional polymerization processes. Typically, from 0.005-2 wt% of initiator, preferably 0.01-1 wt%, more preferably 0.01-0.5 wt%, based on the weight of ethylenically unsaturated monomer(s) (vide infra) to be polymerized, is used. It is noted that the organic peroxide used as initiator may be used in combination with other (conventional) initiators.
- the organic peroxide(s) is/are liquid or in solution at the polymerization temperature.
- the term "solutio n" here means a homogeneous mixture of the organic peroxide(s) in an (organic) solvent.
- suitable solvents can be used to dissolve and dilute the initiator.
- solvents are easily removed during the steps in which the polymer is worked up after the polymerization process, as is the case for alcohols, or they are of such a nature that it is acceptable to leave them as a residue in the final polymer, as is the case for solvents that are desired plasticizers for the final polymer material.
- the organic peroxide is dosed to the polymerization process as an organic peroxide dispersion, preferably an aqueous organic peroxide dispersion.
- Preferred embodiments of the formulations according to the present invention are formulations of the one or more organic peroxides and the controlling agent in an (organic) solvent, wherein the solvent is a solvent as further specified in the paragraph above.
- polymerization temperature this is the temperature at which the majority of all monomer (i.e. more than 50 wt%, preferably more than 60 wt%, most preferably more than 75 wt% of the monomer to be polymerized) is polymerized. It is known that the polymerization temperature set-point can be varied over time. Known temperature variations for polymerizations of vinyl chloride include an intentionally higher temperature when the polymerization is started and/or a higher temperature upon pressure drop, both used to increase the reactor output. If a variation in the polymerization temperature is applied, then the polymerization temperature is considered to be the average temperature over time. It is noted that also in the process of the present invention, the polymerization temperature set-point during the start-up and pressure drop stages may be higher than the average polymerization temperature set-point.
- the process of the present invention is pre-eminently suited for the (co)polymerization of one or more ethylenically unsaturated monomers, such as (meth)acrylic acid (esters), styrene, vinyl acetate, acrylonitrile, vinyl chloride monomer (VCM), and the like.
- the process according to the invention involves the polymerization of monomer mixtures comprising at least 50 wt% of VCM, based on the weight of all monomer(s).
- preferred comonomers for use are of the conventional type and include vinylidene chloride, vinyl acetate, ethylene, propylene, acrylonitrile, styrene, and (meth)acrylates.
- At least 80 wt% of the monomer(s) being polymerized is made up of VCM, while in the most preferred process the monomer consists essentially of VCM.
- the polymerization temperature of such processes largely determines the molecular weight of the final polymer.
- the polymerization process can be conducted as a mass process wherein the reaction mixture is predominantly monomer, as a suspension process wherein the reaction mixture typically is a suspension of monomer in water, or as an emulsion or micro-emulsion process wherein the monomer typically is emulsified in water.
- the usual additives may have to be used, such as surfactant(s), protective colloid(s), anti-fouling agent(s), pH-buffer(s), and the like.
- the polymerization process of the invention is preferably conducted at a temperature in the range of 30-80°C, more preferably in the range of 40-70°C . For these temperature ranges an organic peroxide is selected that has a half-life of at most 0.8 hours at the process temperature.
- the polymerization reaction time can vary from about 0.5 to about 15 hours, and is preferably from 0.8-10 hours.
- a reduced level of fish eyes according to this invention means that in comparison with the exact same polymerization without the controlling agent, the number of fish eyes is reduced by at least 15%, preferably at least 20%, more preferably at least 25%, most preferably at least 30%.
- a reduced level of fish eyes preferably means a level below 120 fish eyes/10 dm 2 , more preferably the level is below 100 fish eyes/10 dm 2 , even more preferably below 70 fish eyes/10 dm 2 , still more preferably below 50 fish eyes/10 dm 2 , most preferably below 40 fish eyes/10 dm 2 .
- the roll-mill is stopped and the roll distance is adjusted to give a sheet of 0.2 mm (for the Agila mill: 0.3 and 0.4 mm) whereafter the amount of fish eyes is counted on a 100 x 100 mm square of the resulting sheet.
- a significantly reduced level of fish eyes is observed if the polymerization process is started with a "hot start".
- hot start is meant here that the peroxide is dosed at or close to the polymerization temperature.
- a significantly reduced level of fish eyes means that in comparison with the exact same polymerization without the controlling agent, the number of fish eyes is reduced by at least 10, preferably at least 20, more preferably at least 50 per 10 dm 2 .
- TMBH 1 ,1 ,3,3-tetrabutyl hydroperoxide was used.
- TMBH 1 ,1 ,3,3-tetrabutyl hydroperoxide was used.
- TBHP tert-butyl hydroperoxide ex Akzo Nobel 80% in organic solvent mixture
- DTBM di(tert-butyl) maleate degussa-Huels (100%)
- the reactor is depressurized for 5 minutes at 75 mbar (while stirred) to remove the air and nitrogen. Subsequently, the reactor is charged with 2,870 g of VCM, followed by heating of the reactor to the desired polymerization temperature of 57°C in 30-60 minutes. After reaching a stable temperature, a peroxide initiator is dosed continuously or stepwise, either via the peroxide injecting point within 1 minute after reaching the polymerization temperature, or through the peroxide feed line during the polymerization process, or by a combination of the two possibilities, whichever is required.
- Dosing of the organic peroxide through the feed line is done in such a way that the maximum rate (33 %/h) is reached in 0.5-0.65 hours.
- the cooling capacity is limited to a value corresponding to a maximum polymerization rate of about 33 %/h (maximum of the reference experiment).
- the polymerization is stopped when a pressure drop of 2 bar is observed, by cooling the reactor and degassing it. After removal of the residual VCM by evacuation, the polymer is obtained by filtration, washing, and drying.
- the intended volume of aqueous dispersion to be dosed has already been subtracted from the amount of demineralized water added to the reactor at the beginning of the polymerization process. This will ensure that the total amount of water present in the polymerization reaction mixture at the end of the process is approximately equal in all cases. After completion of the polymerization process, the amount of fish eyes/10 dm 2 is determined .
- Tx 187-W35 peroxide (solubility of diisobutyryl peroxide in water at 0°C: 35 ppm, half life: 0.1 hr at the polymerization temperature of 57°C) was used in the amounts indicated in Table 2.
- the Tx 187-W35 was continuously dosed in all Examples D, 7-10.
- Example D no controlling agent was used.
- TBHP was used as controlling agent, with all TBHP being added to the reaction mixture prior to the addition of Tx 187-W35 in Example 10, whereas in Example 7 the TBHP controlling agent was added to the peroxide formulation.
- Example 8 TBHP and TMBH were used as controlling agents added to the peroxide formulation.
- Example 9 DTBM was used as the controlling agent which was added to the peroxide formulation.
- Tx EHP (solubility of di(2-ethylhexyl) peroxydicarbonate in water at 0°C: ⁇ 1 ppm, half life: 2.4 hr at the polymerization temperature of 57°C) was used as organic peroxide, which was added in a single shot at the beginning of the polymerization reaction at the polymerization temperature.
- TBHP was used as the controlling agent which was added to the reaction mixture simultaneously with the Tx EHP.
- the solubility of the organic peroxide is determined by mixing equal volumes of water (deuteriated) and deuteriated tetrachloroethane containing 5% (w/w) of the organic peroxide for 10 minutes at 0°C (Table 3). After phase separation, the quantity of peroxide in the water phase is determined by 1 H-NMR. Table 3
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Abstract
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Priority Applications (12)
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AU2004251843A AU2004251843A1 (en) | 2003-06-27 | 2004-06-18 | Polymerization process for preparing (co)polymers |
CA002530124A CA2530124A1 (en) | 2003-06-27 | 2004-06-18 | Polymerization process for preparing (co)polymers |
MXPA05014067A MXPA05014067A (en) | 2003-06-27 | 2004-06-18 | Polymerization process for preparing (co)polymers. |
KR1020057024687A KR101147877B1 (en) | 2003-06-27 | 2004-06-18 | Polymerization process for preparing copolymers |
BRPI0411751-4A BRPI0411751B1 (en) | 2003-06-27 | 2004-06-18 | POLYMERIZATION PROCESS FOR THE PREPARATION OF A (CO) POLYMER OF VINYL CHLORIDE, AND SUITABLE FORMULATION FOR USE IN A WATER DISPERSION POLYMERIZATION PROCESS |
ES04740047T ES2379955T5 (en) | 2003-06-27 | 2004-06-18 | Polymerization process to prepare co (polymers) |
PL04740047T PL1639021T3 (en) | 2003-06-27 | 2004-06-18 | Polymerization process for preparing (co)polymers |
AT04740047T ATE542835T1 (en) | 2003-06-27 | 2004-06-18 | POLYMERIZATION PROCESS FOR PRODUCING (CO)POLYMERS |
EP04740047.8A EP1639021B2 (en) | 2003-06-27 | 2004-06-18 | Polymerization process for preparing (co)polymers |
US10/561,165 US7759438B2 (en) | 2003-06-27 | 2004-06-18 | Polymerization process for preparing (co)polymers |
JP2006515991A JP4861170B2 (en) | 2003-06-27 | 2004-06-18 | (Co) Polymerization method for producing polymer |
NO20060413A NO20060413L (en) | 2003-06-27 | 2006-01-25 | Polymerization method for preparing (co) polymers |
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EP (1) | EP1639021B2 (en) |
JP (1) | JP4861170B2 (en) |
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Cited By (4)
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EP2088162A1 (en) | 2008-02-09 | 2009-08-12 | Celanese Emulsions GmbH | Method for manufacturing polymer dispersions, dispersions created thereby and their application |
WO2011015567A2 (en) | 2009-08-06 | 2011-02-10 | Akzo Nobel Chemicals International B.V. | Storage stable and safe peroxide emulsions with a high active oxygen content |
CN106706890A (en) * | 2017-02-24 | 2017-05-24 | 徐工集团工程机械有限公司 | Asphalt foaming effect measuring device and method |
WO2024132693A1 (en) * | 2022-12-20 | 2024-06-27 | Inovyn Europe Limited | Process for the production of pvc in aqueous suspension using a mixture of initiators and an activity control agent |
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CN107075027B (en) * | 2014-11-21 | 2019-11-08 | 日油株式会社 | The preparation method of copolymer |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3778422A (en) * | 1971-05-17 | 1973-12-11 | Tenneco Chem | Process for the production of vinyl halide polymers |
US5155192A (en) * | 1985-10-30 | 1992-10-13 | Akzo N.V. | Stabilized peroxydicarbonate composition |
US6399728B1 (en) * | 2001-02-01 | 2002-06-04 | Atofina Chemicals, Inc. | Stabilized organic peroxydicarbonates compositions |
US20020123591A1 (en) * | 1998-09-21 | 2002-09-05 | Van Swieten Andreas Petrus | Continuous dosing of very fast initiators during polymerization reactions |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US123591A (en) * | 1872-02-13 | Improvement in curtain-fixtures | ||
US2632758A (en) * | 1946-12-11 | 1953-03-24 | Brothman Abraham | Polymerization of methylmethac-rylate with mixture of benzoyl peroxide and tertiary-butyl hydroperoxide |
US3022282A (en) * | 1959-08-25 | 1962-02-20 | Us Rubber Co | Polymerization catalyst for vinyl chloride |
US3451985A (en) † | 1964-03-26 | 1969-06-24 | Monsanto Co | Method of polymerizing vinyl monomers |
US3787527A (en) * | 1971-10-14 | 1974-01-22 | Electrochem Werke Munich Ag | Process for the setting of unsaturated polyester resins |
GB1497541A (en) † | 1974-05-30 | 1978-01-12 | Ici Ltd | Vinyl chloride polymerisation process |
US3979366A (en) † | 1975-06-12 | 1976-09-07 | Continental Oil Company | Vinyl chloride suspension polymerization |
US4131728A (en) † | 1977-01-10 | 1978-12-26 | The Dow Chemical Company | Method for polymerizing olefinically unsaturated monomers employing a catalyst composition comprising (a) shock-sensitive organic peroxide and (b) an olefinic unsaturated non-homopolymerizable monomer |
JPH0778084B2 (en) * | 1989-08-09 | 1995-08-23 | 信越化学工業株式会社 | Method for producing vinyl chloride polymer |
CA2110209A1 (en) † | 1992-11-30 | 1994-05-31 | Tadashi Amano | Process for preparing vinyl chloride polymers |
US5478900A (en) * | 1993-05-07 | 1995-12-26 | Shin-Etsu Chemical Co., Ltd. | Process for preparing vinyl chloride polymer of quality |
US5548046A (en) * | 1994-02-16 | 1996-08-20 | Elf Atochem North America, Inc. | Stabilized dialkyl peroxydicarbonate compositions and their uses |
JP3524594B2 (en) * | 1994-10-07 | 2004-05-10 | 三菱レイヨン株式会社 | Method for producing methacrylic resin |
WO1997032845A1 (en) * | 1996-03-05 | 1997-09-12 | Akzo Nobel N.V. | Reduction of benzene formation in dibenzoyl peroxide formulations |
JP3986123B2 (en) | 1996-05-31 | 2007-10-03 | ケムチュア コーポレイション | Stabilization of organic peroxides using β-dicarbonyl or cyclic α-diketone compounds |
CA2226130A1 (en) * | 1997-01-10 | 1998-07-10 | Witco Corporation | Organic peroxide stabilization with oximes |
US5892090A (en) * | 1998-02-27 | 1999-04-06 | Witco Corporation | Organic peroxide stabilization with oximes |
JP2001151750A (en) * | 1999-11-24 | 2001-06-05 | Nof Corp | Peroxide composition and polymerization initiator containing the same |
EP1216991A1 (en) | 2000-12-22 | 2002-06-26 | Akzo Nobel N.V. | Transportable and safely packaged organic peroxide formulations comprising reactive phlegmatizers |
DE10131147A1 (en) * | 2001-06-28 | 2003-01-16 | Peroxid Chemie Gmbh & Co Kg | Stabilized peroxidicarbonate preparation |
JP2003252920A (en) | 2001-12-27 | 2003-09-10 | Atofina Yoshitomi Ltd | Organic peroxide solution and manufacturing method of vinyl chloride polymer using the same |
RU2005101236A (en) | 2002-06-20 | 2005-06-27 | Акцо Нобель Н.В. (NL) | (STABILIZED) PEROXIDE COMPOSITIONS, FLEGMATIZED BY A SPECIFIC UNSATURATED FLEGMATIZING AGENT |
JP6089052B2 (en) * | 2015-02-23 | 2017-03-01 | 株式会社エヌ・ティ・ティ・データ | Mobile terminal and program |
-
2004
- 2004-06-18 PL PL04740047T patent/PL1639021T3/en unknown
- 2004-06-18 AT AT04740047T patent/ATE542835T1/en active
- 2004-06-18 KR KR1020127002694A patent/KR20120032550A/en not_active Application Discontinuation
- 2004-06-18 EP EP04740047.8A patent/EP1639021B2/en not_active Expired - Lifetime
- 2004-06-18 KR KR1020057024687A patent/KR101147877B1/en active IP Right Grant
- 2004-06-18 CN CNB2004800181976A patent/CN100445304C/en not_active Expired - Lifetime
- 2004-06-18 AU AU2004251843A patent/AU2004251843A1/en not_active Abandoned
- 2004-06-18 BR BRPI0411751-4A patent/BRPI0411751B1/en active IP Right Grant
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- 2004-06-18 MX MXPA05014067A patent/MXPA05014067A/en active IP Right Grant
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- 2004-06-18 US US10/561,165 patent/US7759438B2/en active Active
- 2004-06-18 CA CA002530124A patent/CA2530124A1/en not_active Abandoned
- 2004-06-18 WO PCT/EP2004/006601 patent/WO2005000916A1/en active Application Filing
- 2004-06-25 TW TW093118592A patent/TW200504097A/en unknown
-
2005
- 2005-12-26 CO CO05129972A patent/CO5721014A2/en not_active Application Discontinuation
-
2006
- 2006-01-25 NO NO20060413A patent/NO20060413L/en not_active Application Discontinuation
- 2006-01-26 ZA ZA200600768A patent/ZA200600768B/en unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3778422A (en) * | 1971-05-17 | 1973-12-11 | Tenneco Chem | Process for the production of vinyl halide polymers |
US5155192A (en) * | 1985-10-30 | 1992-10-13 | Akzo N.V. | Stabilized peroxydicarbonate composition |
US20020123591A1 (en) * | 1998-09-21 | 2002-09-05 | Van Swieten Andreas Petrus | Continuous dosing of very fast initiators during polymerization reactions |
US6399728B1 (en) * | 2001-02-01 | 2002-06-04 | Atofina Chemicals, Inc. | Stabilized organic peroxydicarbonates compositions |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2088162A1 (en) | 2008-02-09 | 2009-08-12 | Celanese Emulsions GmbH | Method for manufacturing polymer dispersions, dispersions created thereby and their application |
DE102008008421A1 (en) | 2008-02-09 | 2009-08-13 | Celanese Emulsions Gmbh | Process for the preparation of polymer dispersions, the dispersions containing them and their use |
US8053511B2 (en) | 2008-02-09 | 2011-11-08 | Celanese Emulsions Gmbh | Process for preparing polymer dispersions, the resulting dispersions and their use |
WO2011015567A2 (en) | 2009-08-06 | 2011-02-10 | Akzo Nobel Chemicals International B.V. | Storage stable and safe peroxide emulsions with a high active oxygen content |
US8846832B2 (en) | 2009-08-06 | 2014-09-30 | Akzo Nobel Chemicals International B.V. | Storage stable and safe peroxide emulsions with a high active oxygen content |
CN106706890A (en) * | 2017-02-24 | 2017-05-24 | 徐工集团工程机械有限公司 | Asphalt foaming effect measuring device and method |
CN106706890B (en) * | 2017-02-24 | 2023-07-04 | 江苏徐工工程机械研究院有限公司 | Asphalt foaming effect measuring device and method |
WO2024132693A1 (en) * | 2022-12-20 | 2024-06-27 | Inovyn Europe Limited | Process for the production of pvc in aqueous suspension using a mixture of initiators and an activity control agent |
Also Published As
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PL1639021T3 (en) | 2012-07-31 |
ES2379955T5 (en) | 2020-03-20 |
EP1639021B2 (en) | 2019-07-10 |
TW200504097A (en) | 2005-02-01 |
BRPI0411751A (en) | 2006-08-08 |
KR20120032550A (en) | 2012-04-05 |
ZA200600768B (en) | 2007-05-30 |
ES2379955T3 (en) | 2012-05-07 |
BRPI0411751B1 (en) | 2020-03-17 |
NO20060413L (en) | 2006-01-25 |
KR101147877B1 (en) | 2012-05-25 |
ATE542835T1 (en) | 2012-02-15 |
AU2004251843A1 (en) | 2005-01-06 |
CA2530124A1 (en) | 2005-01-06 |
US20060142513A1 (en) | 2006-06-29 |
MXPA05014067A (en) | 2006-03-02 |
JP4861170B2 (en) | 2012-01-25 |
JP2007538109A (en) | 2007-12-27 |
EP1639021B1 (en) | 2012-01-25 |
CN100445304C (en) | 2008-12-24 |
CN1813004A (en) | 2006-08-02 |
EP1639021A1 (en) | 2006-03-29 |
KR20060033734A (en) | 2006-04-19 |
RU2006102362A (en) | 2006-07-10 |
US7759438B2 (en) | 2010-07-20 |
CO5721014A2 (en) | 2007-01-31 |
RU2358986C2 (en) | 2009-06-20 |
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