WO2004111098A3 - Process for the production of polypropylene using a ziegler-natta catalyst - Google Patents

Process for the production of polypropylene using a ziegler-natta catalyst Download PDF

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Publication number
WO2004111098A3
WO2004111098A3 PCT/EP2004/006053 EP2004006053W WO2004111098A3 WO 2004111098 A3 WO2004111098 A3 WO 2004111098A3 EP 2004006053 W EP2004006053 W EP 2004006053W WO 2004111098 A3 WO2004111098 A3 WO 2004111098A3
Authority
WO
WIPO (PCT)
Prior art keywords
particles
production
complex
metal
propylene
Prior art date
Application number
PCT/EP2004/006053
Other languages
French (fr)
Other versions
WO2004111098A2 (en
Inventor
Torvald Vestberg
Pirjo Jaeaeskelaeinen
Original Assignee
Borealis Tech Oy
Torvald Vestberg
Pirjo Jaeaeskelaeinen
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=33155178&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2004111098(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority to US10/559,484 priority Critical patent/US7465775B2/en
Priority to AU2004247364A priority patent/AU2004247364A1/en
Priority to EA200501657A priority patent/EA011642B1/en
Priority to ES04736049.0T priority patent/ES2536477T3/en
Priority to CA002526144A priority patent/CA2526144A1/en
Application filed by Borealis Tech Oy, Torvald Vestberg, Pirjo Jaeaeskelaeinen filed Critical Borealis Tech Oy
Priority to JP2006508279A priority patent/JP2006527271A/en
Priority to CN2004800157074A priority patent/CN1802392B/en
Priority to EP04736049.0A priority patent/EP1631601B1/en
Priority to BRPI0411063-3A priority patent/BRPI0411063A/en
Publication of WO2004111098A2 publication Critical patent/WO2004111098A2/en
Publication of WO2004111098A3 publication Critical patent/WO2004111098A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
    • D01F6/06—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins from polypropylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

This invention relates to a process for the production of a polymer film or fibre wherein a polymer composition comprising a propylene homo- or copolymer is formed into a film or fibre, and wherein said propylene homo­ or copolymer is produced in a process which comprises the polymerization of propylene monomers or propylene monomers and one or more types of comonomers in the presence of a high yield Ziegler-Natta olefin polymerization catalyst, which catalyst comprises a component in the form of particles having a predetermined size range which has been produced in a process comprising: a) preparing a solution of a complex of a Group 2 metal and an electron donor by reacting a compound of said material with said electron donor or a precursor thereof in an organic liquid reaction medium, b) reacting said complex in solution with a compound of a transition metal to procedure an emulsion the dispersed phase of which containing more than 50 mol% of the Group 2 metal in said complex, c) maintaining the particles of said dispersed phase within the average size range of 5 to 200 microns by agitation in the presence of an emulsion stabilizer and d) solidifying said particles, and recovering, optionally washing said particles to obtain said catalyst component. The invention further relates to polpropylene products obtainable by this process and to the use of polypropylene products in the production of films and fibres.
PCT/EP2004/006053 2003-06-06 2004-06-04 Process for the production of polypropylene using a ziegler-natta catalyst WO2004111098A2 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
BRPI0411063-3A BRPI0411063A (en) 2003-06-06 2004-06-04 process for the production of polypropylene using high yield ziegler-natta catalysts
AU2004247364A AU2004247364A1 (en) 2003-06-06 2004-06-04 Process for the production of polypropylene using a ziegler-natta catalyst
EA200501657A EA011642B1 (en) 2003-06-06 2004-06-04 Process for the production of polypropylene using a ziegler-natta catalyst
ES04736049.0T ES2536477T3 (en) 2003-06-06 2004-06-04 Process for manufacturing polypropylene using high-performance Ziegler-Natta catalysts
CA002526144A CA2526144A1 (en) 2003-06-06 2004-06-04 Process for the production of polypropylene using a ziegler-natta catalyst
US10/559,484 US7465775B2 (en) 2003-06-06 2004-06-04 Process for the production of polypropylene using high yield Ziegler-Natta catalysts
JP2006508279A JP2006527271A (en) 2003-06-06 2004-06-04 Method for producing polypropylene using high yield Ziegler-Natta catalyst
CN2004800157074A CN1802392B (en) 2003-06-06 2004-06-04 Process for the production of polypropylene using high yield Ziegler-Natta catalysts
EP04736049.0A EP1631601B1 (en) 2003-06-06 2004-06-04 Process for the production of polypropylene using high yield ziegler-natta catalysts

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP03012906A EP1484345A1 (en) 2003-06-06 2003-06-06 Process for the production of polypropylene using a Ziegler-Natta catalyst
EP03012906.8 2003-06-06

Publications (2)

Publication Number Publication Date
WO2004111098A2 WO2004111098A2 (en) 2004-12-23
WO2004111098A3 true WO2004111098A3 (en) 2005-08-04

Family

ID=33155178

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2004/006053 WO2004111098A2 (en) 2003-06-06 2004-06-04 Process for the production of polypropylene using a ziegler-natta catalyst

Country Status (11)

Country Link
US (1) US7465775B2 (en)
EP (2) EP1484345A1 (en)
JP (1) JP2006527271A (en)
KR (1) KR100990923B1 (en)
CN (1) CN1802392B (en)
AU (1) AU2004247364A1 (en)
BR (1) BRPI0411063A (en)
CA (1) CA2526144A1 (en)
EA (1) EA011642B1 (en)
ES (1) ES2536477T3 (en)
WO (1) WO2004111098A2 (en)

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EP1484345A1 (en) 2003-06-06 2004-12-08 Borealis Technology Oy Process for the production of polypropylene using a Ziegler-Natta catalyst
EP1717269A1 (en) 2005-04-28 2006-11-02 Borealis Technology Oy Alpha-olefin homo-or copolymer compositions
EP1803743B1 (en) * 2005-12-30 2016-08-10 Borealis Technology Oy Catalyst particles
EP1847555A1 (en) 2006-04-18 2007-10-24 Borealis Technology Oy Multi-branched Polypropylene
EP1862480B1 (en) * 2006-05-31 2016-07-27 Borealis Technology Oy Process for preparing an olefin polymerisation catalyst component with improved high temperature activity
DE602006004987D1 (en) 2006-07-10 2009-03-12 Borealis Tech Oy Electrical insulating film
EP2208749B1 (en) * 2006-07-10 2015-12-16 Borealis Technology Oy Biaxially oriented polypropylene films
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EP1900764B1 (en) 2006-08-25 2009-04-01 Borealis Technology Oy Polypropylene foam
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EP1939230B1 (en) 2006-12-28 2009-03-04 Borealis Technology Oy Process for the manufacture of branched polypropylene
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EP2147939A1 (en) 2008-07-22 2010-01-27 Borealis AG Polypropylene composition with improved optics for film and moulding applications
KR102080451B1 (en) 2009-11-11 2020-02-21 보레알리스 아게 Crosslinkable polymer composition and cable with advantageous electrical properties
EA022397B1 (en) 2009-11-11 2015-12-30 Бореалис Аг A polymer composition and a power cable comprising the polymer composition and a process for producing the same
IN2012DN03434A (en) 2009-11-11 2015-10-23 Borealis Ag
US9365708B2 (en) 2009-11-11 2016-06-14 Borealis Ag Cable and production process thereof
CA2792990C (en) 2010-03-17 2019-05-14 Borealis Ag Polyethylene polymer composition and power cable with improved electrical properties
KR102094653B1 (en) 2010-03-17 2020-03-30 보레알리스 아게 Polymer composition for w&c application with advantageous electrical properties
ATE552303T1 (en) 2010-04-21 2012-04-15 Borealis Ag PROPYLENE/1-HEXENE COPOLYMER COMPOSITION WITH WIDE PROCESSING WINDOW FOR SEALANTS
EP2439238B1 (en) * 2010-10-06 2012-12-05 Borealis AG Polypropylene with living hinge properties
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EP2705080B1 (en) 2011-05-04 2017-12-20 Borealis AG Polymer composition for electrical devices
JP6255337B2 (en) 2011-05-04 2017-12-27 ボレアリス エージー Polymer compositions for electrical devices
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EP2521137B1 (en) 2011-05-04 2014-12-17 Borealis AG Polymer composition for electrical and communication devices
EP2565221B2 (en) † 2011-08-30 2018-08-08 Borealis AG Process for the manufacture of a capacitor film
EP2610271B1 (en) * 2011-12-30 2019-03-20 Borealis AG Preparation of phthalate free ZN PP catalysts
US10195581B2 (en) 2012-03-26 2019-02-05 Unchained Labs Parallel reactor systems and methods for preparing materials
JP6030947B2 (en) * 2012-12-26 2016-11-24 サン・トックス株式会社 Polyolefin-based unstretched multilayer film
EP2992335B1 (en) 2013-04-30 2018-04-18 Unchained Labs Methods for sampling from non-atmospheric vessels in a parallel reactor system
US11267916B2 (en) 2014-02-07 2022-03-08 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US10723824B2 (en) 2014-02-07 2020-07-28 Eastman Chemical Company Adhesives comprising amorphous propylene-ethylene copolymers
US10647795B2 (en) 2014-02-07 2020-05-12 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US10308740B2 (en) 2014-02-07 2019-06-04 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US9399686B2 (en) 2014-02-07 2016-07-26 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US10696765B2 (en) 2014-02-07 2020-06-30 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer
US9714302B2 (en) 2014-10-10 2017-07-25 W. R. Grace & Co.—Conn. Process for preparing spherical polymerization catalyst components for use in olefin polymerizations
WO2016066619A1 (en) 2014-10-27 2016-05-06 Borealis Ag Polymer composition for cable applications with advantageous electrical properties
RU2716077C2 (en) * 2015-07-30 2020-03-05 Бореалис Аг Polypropylene composition with improved hot-tack force
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Also Published As

Publication number Publication date
EA011642B1 (en) 2009-04-28
CA2526144A1 (en) 2004-12-23
AU2004247364A1 (en) 2004-12-23
BRPI0411063A (en) 2006-08-01
WO2004111098A2 (en) 2004-12-23
CN1802392A (en) 2006-07-12
EP1631601B1 (en) 2015-04-29
KR100990923B1 (en) 2010-11-01
EA200501657A1 (en) 2006-06-30
ES2536477T3 (en) 2015-05-25
CN1802392B (en) 2010-10-13
US20060235172A1 (en) 2006-10-19
EP1631601A2 (en) 2006-03-08
US7465775B2 (en) 2008-12-16
JP2006527271A (en) 2006-11-30
EP1484345A1 (en) 2004-12-08
KR20060028685A (en) 2006-03-31

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