WO2004074549A3 - Aluminium electrowinning cells with metal-based anodes - Google Patents

Aluminium electrowinning cells with metal-based anodes Download PDF

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Publication number
WO2004074549A3
WO2004074549A3 PCT/IB2004/000431 IB2004000431W WO2004074549A3 WO 2004074549 A3 WO2004074549 A3 WO 2004074549A3 IB 2004000431 W IB2004000431 W IB 2004000431W WO 2004074549 A3 WO2004074549 A3 WO 2004074549A3
Authority
WO
WIPO (PCT)
Prior art keywords
weight
anode
fluoride
aluminium
metal
Prior art date
Application number
PCT/IB2004/000431
Other languages
French (fr)
Other versions
WO2004074549A2 (en
Inventor
Nora Vittorio De
Thinh T Nguyen
Jean-Jacques Duruz
Original Assignee
Moltech Invent Sa
Nora Vittorio De
Thinh T Nguyen
Jean-Jacques Duruz
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Moltech Invent Sa, Nora Vittorio De, Thinh T Nguyen, Jean-Jacques Duruz filed Critical Moltech Invent Sa
Priority to EP04712114A priority Critical patent/EP1608798A2/en
Priority to AU2004213650A priority patent/AU2004213650B2/en
Priority to CA2505285A priority patent/CA2505285C/en
Priority to NZ540408A priority patent/NZ540408A/en
Publication of WO2004074549A2 publication Critical patent/WO2004074549A2/en
Publication of WO2004074549A3 publication Critical patent/WO2004074549A3/en
Priority to NO20054308A priority patent/NO20054308L/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
    • C25C3/18—Electrolytes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
    • C25C3/08—Cell construction, e.g. bottoms, walls, cathodes
    • C25C3/12—Anodes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Primary Cells (AREA)

Abstract

A cell for the electrowinning of aluminium comprises a metal-based anode (10) containing at least one of nickel, cobalt and iron. The anode (10) may be covered with an applied or an integral hematite-based layer and/or a cerium oxyfluoride-based outermost coating. The cell contains a fluoride-containing molten electrolyte (5) at a temperature below 950°C, in which the anode (10) is immersed and which consists of: 6.5 to 11 weight% dissolved alumina; 35 to 44 weight% aluminium fluoride; 38 to 46 weight% sodium fluoride; 2 to 15 weight% potassium fluoride; 0 to 5 weight% calcium fluoride; and 0 to 5 weight% in total of one or more further constituents. An anode stem (14b) containing nickel and/or iron can be used to suspend the anode (10) in the electrolyte (5) facing a cathode (21,21A,25) that has an aluminium-wettable surface (20), in particular a drained horizontal or inclined surface.
PCT/IB2004/000431 2003-02-20 2004-02-18 Aluminium electrowinning cells with metal-based anodes WO2004074549A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP04712114A EP1608798A2 (en) 2003-02-20 2004-02-18 Aluminium electrowinning cells with metal-based anodes
AU2004213650A AU2004213650B2 (en) 2003-02-20 2004-02-18 Aluminium electrowinning cells with metal-based anodes
CA2505285A CA2505285C (en) 2003-02-20 2004-02-18 Aluminium electrowinning cells with metal-based anodes
NZ540408A NZ540408A (en) 2003-02-20 2004-02-18 Aluminium electrowinning cells with metal-based anodes and a fluoride-containing molten electrolyte
NO20054308A NO20054308L (en) 2003-02-20 2005-09-19 Aluminum electro recovery cells with metal based anodes

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IB0300662 2003-02-20
IBPCT/IB03/00662 2003-02-20

Publications (2)

Publication Number Publication Date
WO2004074549A2 WO2004074549A2 (en) 2004-09-02
WO2004074549A3 true WO2004074549A3 (en) 2005-05-12

Family

ID=32894011

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2004/000431 WO2004074549A2 (en) 2003-02-20 2004-02-18 Aluminium electrowinning cells with metal-based anodes

Country Status (5)

Country Link
EP (1) EP1608798A2 (en)
CA (1) CA2505285C (en)
NO (1) NO20054308L (en)
NZ (1) NZ540408A (en)
WO (1) WO2004074549A2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007105125A2 (en) * 2006-03-10 2007-09-20 Moltech Invent S.A. Aluminium electrowinning cell with enhanced crust
CN102149853B (en) 2008-09-08 2014-01-08 力拓艾尔坎国际有限公司 Metallic oxygen evolving anode operating at high current density for aluminium reduction cells
RU2567429C1 (en) * 2013-07-09 2015-11-10 Общество с ограниченной ответственностью "Объединенная Компания РУСАЛ Инженерно-технологический центр" Electrolyte for aluminium production by melts electrolysis
CN104451779B (en) * 2014-12-17 2017-01-18 湖南创元铝业有限公司 Aluminum fluoride control method of aluminum electrolytic cell

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5006209A (en) * 1990-02-13 1991-04-09 Electrochemical Technology Corp. Electrolytic reduction of alumina
US5725744A (en) * 1992-03-24 1998-03-10 Moltech Invent S.A. Cell for the electrolysis of alumina at low temperatures
US6379512B1 (en) * 1998-02-11 2002-04-30 Northwest Aluminum Technology Combination for electrolytic reduction of alumina
WO2004035871A1 (en) * 2002-10-18 2004-04-29 Moltech Invent S.A. Aluminium electrowinning cells with metal-based anodes

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5006209A (en) * 1990-02-13 1991-04-09 Electrochemical Technology Corp. Electrolytic reduction of alumina
US5725744A (en) * 1992-03-24 1998-03-10 Moltech Invent S.A. Cell for the electrolysis of alumina at low temperatures
US6379512B1 (en) * 1998-02-11 2002-04-30 Northwest Aluminum Technology Combination for electrolytic reduction of alumina
WO2004035871A1 (en) * 2002-10-18 2004-04-29 Moltech Invent S.A. Aluminium electrowinning cells with metal-based anodes

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
B. PIRIOU ET AL.: "Essais de caractérisation structurale des bains cryolithiques par spectrométrie infrarouge et par hypertrempe", REVUE INTERNATIONALE DES HAUTES TEMPERATURES ET DES REFRACTAIRES, vol. 15, no. 2, 1978, FRANCE, pages 139 - 146, XP009040625 *
DATABASE COMPENDEX [online] ENGINEERING INFORMATION, INC., NEW YORK, NY, US; SEKHAR J A ET AL: "Micropyretically synthesized porous non-consumable anodes in the Ni-Al-Cu-Fe-X system", XP002307620, Database accession no. EIX98154075458 *
LIGHT MET (WARRENDALE PA); LIGHT METALS: PROCEEDINGS OF SESSIONS, TMS ANNUAL MEETING (WARRENDALE, PENNSYLVANIA); LIGHT METALS 1997 MINERALS, METALS & MATERIALS SOC (TMS), WARRENDALE, PA, USA, 1997, pages 347 - 354 *

Also Published As

Publication number Publication date
CA2505285A1 (en) 2004-09-02
EP1608798A2 (en) 2005-12-28
AU2004213650A1 (en) 2004-09-02
WO2004074549A2 (en) 2004-09-02
CA2505285C (en) 2012-07-17
NO20054308L (en) 2005-09-19
NZ540408A (en) 2007-04-27

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