WO2004063305A2 - Improved drilling fluids - Google Patents
Improved drilling fluids Download PDFInfo
- Publication number
- WO2004063305A2 WO2004063305A2 PCT/US2003/037398 US0337398W WO2004063305A2 WO 2004063305 A2 WO2004063305 A2 WO 2004063305A2 US 0337398 W US0337398 W US 0337398W WO 2004063305 A2 WO2004063305 A2 WO 2004063305A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- drilling fluid
- crumb rubber
- drilling
- particles
- fluid
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/50—Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls
- C09K8/516—Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls characterised by their form or by the form of their components, e.g. encapsulated material
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/02—Well-drilling compositions
- C09K8/03—Specific additives for general use in well-drilling compositions
- C09K8/035—Organic additives
Definitions
- the invention relates to improved drilling fluid additions which comprise fine particles of crosslinked elastomer.
- the elastomer acts as a plugging agent thereby preventing loss of the drilling fluid to a porous formation.
- a method for preventing loss of drilling fluids is also provided.
- Drilling fluids or drilling muds as they are sometimes called, are slurries used in the drilling of wells in the earth for the purpose of recovering hydrocarbons and other fluid materials. Drilling fluids have a number of functions, the most important of which are: lubricating the drilling tool and drill pipe which carries the tool, removing formation cuttings from the well, counterbalancing formation pressures to prevent the inflow of gas, oil or water from permeable rocks which may be encountered at various levels as drilling continues, and holding the cuttings in suspension in the event of a shutdown in the drilling and pumping of the drilling fluid.
- Drilling fluid can leave the borehole through large or small fissures or fractures in the formation or through a highly porous rock matrix surrounding the borehole.
- gunk squeeze Another process that is employed to close off large lost circulation problems is referred to in the art as gunk squeeze.
- a quantity of a powdered bentonite is mixed in diesel oil and pumped down the well bore. Water injection follows the bentonite and diesel oil. If mixed well, the water and bentonite will harden to form a gunky semi- solid mess, which will reduce lost circulation. Problems frequently occur in trying to adequately mix the bentonite and water in the well. The bentonite must also be kept dry until it reaches the desired point in the well. This method is disclosed in U.S. Pat. No. 3,082,823.
- U.S. Pat. No. 2,890,169 discloses a lost circulation fluid made by forming a slurry of bentonite and cement in oil. The slurry is mixed with a surfactant and water to form a composition comprising a water-in-oil emulsion having bentonite and cement dispersed in the continuous oil phase. As this composition is pumped down the well bore, the oil expands and flocculates the bentonite which, under the right conditions, forms a filter cake on the well bore surface in the lost circulation area. Ultimately, the filter cake will break the emulsion causing the emulsified water to react with the cement to form a solid coating on the filter cake. But such a complex process can easily go wrong.
- U.S. Pat. No. 3,448,800 discloses another lost circulation method wherein a water soluble polymer is slurried in a nonaqueous medium and injected into a well. An aqueous slurry of a mineral material such as barite, cement or plaster of paris is subsequently injected into the well to mix with the first slurry to form a cement-like plug in the well bore.
- a water soluble polymer is slurried in a nonaqueous medium and injected into a well.
- An aqueous slurry of a mineral material such as barite, cement or plaster of paris is subsequently injected into the well to mix with the first slurry to form a cement-like plug in the well bore.
- U.S. Pat. No. 4,261,422 describes the use of an expandable clay such as bentonite or montmorillonite which is dispersed in a liquid hydrocarbon for injection into the well. After injection, the bentonite or montmorillonite will expand upon contact with water in the formation. Thus, it is hoped that the expanding clay will close off water producing intervals but not harm oil producing intervals.
- a similar method is disclosed in U.S. Pat. No. 3,078,920 which uses a solution of polymerized methacrylate dissolved in a nonaqueous solvent such as acetic acid, acetic anhydride, propionic acid and liquid aliphatic ketones such as acetone and methyl-ethyl ketone. The methacrylate will expand upon contact with formation water in the water-producing intervals of the well.
- U.S. Pat. Nos. 4,503,170; 4,475,594; 4,445,576; 4,442,241 and 4,391 ,925 teach the use of a water expandable clay dispersed in the oily phase of a water-in-oil emulsion containing a surfactant to stabilize the emulsion and a polymer dispersed in the aqueous phase. When the emulsion is sheared, it breaks and a bentonite paste is formed which hardens into a cement-like plug.
- the patent discloses the use of such polymers as polyacrylamide, polyethylene oxide and copolymers of acrylamide and acrylic or methacrylic acid.
- U.S. Pat. No. 4,191,813 discloses lightly crosslinked copolymers containing at least 40% by weight of vinylbenzyl chloride, the balance of monomers, if any, comprising a major portion of aromatic monomers, with the copolymer being crosslinked in a swollen state by a Lewis acid catalyst.
- the preferred comonomers are one or more of styrene, divinylbenzene and acrylonitrile.
- 4,263,407 discloses similar copolymers wherein the copolymer is post-crosslinked in a swollen state in the presence of a Friedel-Crafts catalyst with a crosslinker selected from a polyfunctional alkylating or acylating agent and a sulfur halide.
- Oleophilic polymers for separating oil from water which show significant swelling in volume upon absorption of oil are described in U.S. Pat. No. 4,172,031. These polymers include polymers of styrenes and substituted styrenes, polyvinyl chloride copolymers of vinylchloride such as a copolymer of 60 wt % vinylchlori.de and 40 wt % vinylacetate, polymers and copolymers of vinylidene chloride and acrylonitrile, and acrylic polymers such as polymers of methylmethacrylate and ethylacrylate, styrene and divinylbenzene copolymers and alkyl styrene polymers and copolymers.
- the reference discloses that these polymers show significant swelling in volume upon absorption of oil.
- U.S. Pat. No. 4,633,950 discloses the use of oil swelling polymers to reduce lost circulation in drilling fluids.
- the polymers are introduced in an aqueous solution to prevent absorption of the hydrocarbon fluid until the polymers reach the well head.
- the present invention is directed to a system and method which ⁇ «begin typing here>»
- the invention relates to an improved additive for a drilling fluid which significantly reduces the loss of fluid to the surrounding subterranean structure while maintaining the lubricity of the drilling fluid.
- the novel additive comprises finely ground elastomer particles.
- Loss of drilling fluid occurs when drilling fluid seeps into the subterranean formation through holes, fractures or fissures in the formation.
- the region in the well where this occurs is referred to as the lost circulation zone.
- elastomer particles When elastomer particles are added to a drilling fluid, they form a seal in the lost circulation zone by expanding in size to seal the fractures or fissures. This prevents further loss of drilling fluid into the formation.
- the present system uses fine elastomer particles which are easily pumped into the well but are capable of swelling to about 40%> to about 140%> more than their original size when exposed to hydrocarbon fluids. Their ability to swell makes the elastomer particles extremely effective at preventing loss of drilling fluid into the subterranean formation.
- the elastomer particles are used with hydrocarbon-based drilling fluids or with a hydrocarbon additive, particles gradually expand, allowing the material to be easily pumped before significant expansion of the particles occurs. That most of the swelling occurs after the elastomer particles are in the desired location in the well eliminates the need for protective coatings or an aqueous pill to prevent swelling of the polymer until it has reached the desired region in the well.
- Another advantage of the elastomer particles is their very low density as compared to conventional materials used to prevent fluid loss.
- the low density of the elastomer particles allows them to be used in higher amounts than conventional fluid loss materials.
- the fluid loss prevention system of the invention require no additional additives other than those normally encountered in drilling fluid such as diesel, oil, other hydrocarbon fluid and water.
- the elastomer particles are easily handled and present little if any industrial hazards.
- the preferred source of the fluid loss agents of the invention are prepared from recycled tires, the invention presents a way to effective use the old tire materials rather than allowing them to collect to form hazardous waste sites.
- the invention also relates to a method for reducing drilling fluid loss by adding finely ground elastomer particles to a drilling fluid in an amount sufficient to block the flow of fluid into the subterranean formation.
- the drilling fluid additive of the present invention comprise particles of elastomers which exhibit swelling when contacted with hydrocarbon fluids, yet do not dissolve in hydrocarbon fluids. This can be achieved by using crosslinlced elastomers which swell but do not dissolve in the presence of a hydrocarbon fluid.
- the swelling elastomers are such that little, if any, swelling occurs until the polymer has reached the lost circulation zone in the well to be sealed. This is accomplished without resort to coatings on the polymer or suspending the polymer with aqueous pill.
- the preferred elastomer used in the practice of this invention is crumb rubber.
- Crumb rubber generally comprises rubber derived from recycled tires or scrap material from the manufacture of tires. Crumb rubber particles are generally of about 3/8-inch or less in size, h the practice of the invention, the crumb rubber should have a mixture of particle sizes ranging of from about 1 to about 400 microns, preferably about 20 to about 400 microns. In the preferred embodiment, the material should include particles of varying diameters within the range stated above.
- the elastomer can be slightly larger, in the range of from greater than or about 400 to about 4000 microns.
- the additive can include particles of up to about 2000 microns (10 mesh) and more preferably up to about 1000 (18 mesh) microns. Mixtures of particle sizes within the ranges can also be used.
- the additive can include particles of about 425 microns, (48 mesh), about 1000 microns, (18 mesh) and about 2000 microns (10 mesh).
- Crumb rubber can be prepared several different ways. In the first method, whole tires are cryogenically frozen and then shattered in a hammer mill to break down the tire into the desired particle sizes and to remove the steel and fibers from the tire.
- a second method involves physically tearing the tire apart and removing the unwanted steel and fibers. In this process, the tire is continuously milled until the desired particle sizes are obtained.
- Another source of crumb rubber is the bushings that remain as the tire is manufactured or remanufactured.
- crumb rubber One key feature of crumb rubber that makes it useful in the practice of the invention is its ability to expand up to about 140%> of its original size when exposed to hydrocarbon fluids and temperatures. As shown in the examples below, when the elastomer particles are exposed to hydrocarbon fluids and temperatures typically encountered in a well (200° F to 300° F) the particles expand to over 140% of their original size. The amount of expansion is dependent upon the hydrocarbon used and the temperature in the well.
- Another feature of the present invention is the relatively low density of the elastomer particles, relative to the fluid. This allows a higher additive loading without adversely affecting the properties of the drilling fluid.
- the elastomers of the invention can be used in amounts up to about 100 lbs. per barrel (ppb)whereas conventional fluid loss additives can be used in amounts ranging from about 5 to about 20 lbs. per barrel.
- the ability to use higher additive loadings means that more of the elastomer particles are present in the fluid to fill and plug the openings into the subterranean formation.
- This last feature is particularly important in deepwater operations where the drilling fluids used require a narrow density range.
- the fluids used in these applications have a density of from about 9.5 to about 10.5 pounds per gallon (ppg).
- the elastomer particles of the invention have a density of from about 8.5 to about 10.5 ppg.
- the addition of the additives of the invention do not adversely affect the density drilling muds.
- Illustrative hydrocarbon fluids useful in this invention include crude oil, diesel oil, kerosene, mineral oil, gasoline, naptha, toluene, ethylenedichloride and mixtures thereof.
- synthetic oils such as those derived from olefins, linear ⁇ -olefins, poly ⁇ - olefms, internal esters and ethers maybe used. Because of economics, availability at any drilling site and performance, diesel oil is most preferred. Synthetic oils, however, are preferred where environmental impact is a concern.
- the drilling fluid additives of the present invention can be used in both hydrocarbon based and aqueous or water based drilling fluids. If polymer expansion is needed in an aqueous system, a hydrocarbon fluid must be added to the elastomer particles to achieve the desired expansion. It has been observed, however, that improved fluid loss can be achieved in aqueous drilling fluids without adding a hydrocarbon fluid. The improved fluid loss reduction is achieved by the ability to use higher amounts of particles
- One method for practicing this invention involves the injection of a discrete pill of drilling fluid containing the drilling fluid additives of the invention in a sufficient amount to seal off the lost circulation zone. This pill is then forced down to the lost circulation zone. The elastomer particles then fill the holes and fractures preventing loss of the fluid. Depending upon the polymer and the composition of the drilling fluid, about two to about 250 pounds of polymer per barrel of fluid can be placed in the pill. Methods for introducing the pill containing the drilling fluid additive of the invention are well known to those in the art.
- cellulose fiber from plant matter such as peanut shells, sugar cane husks or bagasse, almond shells, walnut shells, dried tumbleweed and paper, may be added to the pill.
- Bridging materials such as calcium carbonate may also be added. Coarse and fine mica can also be used.
- the polymer of the invention can be continuously added to the drilling fluid. In these cases, the polymer should be added at a rate of 100 to 250 pounds per hour to the drilling fluid.
- test tube was then placed in a Baroid 500 ml static-aging cell which was then pressurized to 300 psi with nitrogen. The cell was then placed in an oven at the . temperatures noted in the tables and static-aged for three days. A duplicate sample was static- aged for seven days.
- test tubes were removed from the test cells and the height of the rubber was measured. The amount of expansion was calculated using the formula ("height after aging / 33) -1.” The results are reported in Tables 1 and 2.
- Example 2 [0042] In this example, a well was experiencing significant loss of drilling fluid. Traditional loss prevention treatments with agents such as calcium carbonate, fiber and graphite materials proved ineffective in reducing or stopping the loss.
- a combination of 30 pound per barrel of crumb rubber with 20 pounds per barrel of fiber were added to the drilling fluid. After the initial loading of crumb rubber and fiber, a maintenance load of 250 pounds of crumb rubber and 150 pounds of fiber per hour of pumping were used . The result was little or no additional loss of drilling fluid during the rest of the drilling process.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Sealing Material Composition (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2003295812A AU2003295812A1 (en) | 2002-11-22 | 2003-11-21 | Improved drilling fluids |
CA002518747A CA2518747A1 (en) | 2002-11-22 | 2003-11-21 | Improved drilling fluids |
EP03787022A EP1646701A2 (en) | 2002-11-22 | 2003-11-21 | Improved drilling fluids |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US42847502P | 2002-11-22 | 2002-11-22 | |
US60/428,475 | 2002-11-22 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2004063305A2 true WO2004063305A2 (en) | 2004-07-29 |
WO2004063305A3 WO2004063305A3 (en) | 2004-12-16 |
Family
ID=32712965
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2003/037398 WO2004063305A2 (en) | 2002-11-22 | 2003-11-21 | Improved drilling fluids |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP1646701A2 (en) |
AU (1) | AU2003295812A1 (en) |
CA (1) | CA2518747A1 (en) |
WO (1) | WO2004063305A2 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009106796A1 (en) * | 2008-02-29 | 2009-09-03 | Halliburton Energy Services, Inc. | Lost circulation material formulation and method of use |
WO2015042296A1 (en) | 2013-09-18 | 2015-03-26 | Innovative Polymer Solutions, Inc. | Pre-swelled ground tire rubber and methods of making and using the same |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2743233A (en) * | 1952-01-03 | 1956-04-24 | Phillips Petroleum Co | Oil-base drilling muds and methods of drilling with same |
US2894906A (en) * | 1953-12-23 | 1959-07-14 | Shell Dev | Drilling fluid composition for porous formations |
US20020010100A1 (en) * | 2000-01-24 | 2002-01-24 | Wood Robert R. | Drilling fluids |
US20020091167A1 (en) * | 1999-06-09 | 2002-07-11 | The Goodyear Tire & Rubber Company | Surface devulcanization of cured rubber crumb |
-
2003
- 2003-11-21 CA CA002518747A patent/CA2518747A1/en not_active Abandoned
- 2003-11-21 AU AU2003295812A patent/AU2003295812A1/en not_active Abandoned
- 2003-11-21 EP EP03787022A patent/EP1646701A2/en not_active Withdrawn
- 2003-11-21 WO PCT/US2003/037398 patent/WO2004063305A2/en not_active Application Discontinuation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2743233A (en) * | 1952-01-03 | 1956-04-24 | Phillips Petroleum Co | Oil-base drilling muds and methods of drilling with same |
US2894906A (en) * | 1953-12-23 | 1959-07-14 | Shell Dev | Drilling fluid composition for porous formations |
US20020091167A1 (en) * | 1999-06-09 | 2002-07-11 | The Goodyear Tire & Rubber Company | Surface devulcanization of cured rubber crumb |
US20020010100A1 (en) * | 2000-01-24 | 2002-01-24 | Wood Robert R. | Drilling fluids |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009106796A1 (en) * | 2008-02-29 | 2009-09-03 | Halliburton Energy Services, Inc. | Lost circulation material formulation and method of use |
US8043997B2 (en) | 2008-02-29 | 2011-10-25 | Halliburton Energy Services Inc. | Lost circulation material formulation and method of use |
WO2015042296A1 (en) | 2013-09-18 | 2015-03-26 | Innovative Polymer Solutions, Inc. | Pre-swelled ground tire rubber and methods of making and using the same |
EP3057809A4 (en) * | 2013-09-18 | 2017-04-26 | Innovative Polymer Solutions Inc. | Pre-swelled ground tire rubber and methods of making and using the same |
Also Published As
Publication number | Publication date |
---|---|
CA2518747A1 (en) | 2004-07-29 |
EP1646701A2 (en) | 2006-04-19 |
AU2003295812A8 (en) | 2004-08-10 |
WO2004063305A3 (en) | 2004-12-16 |
AU2003295812A1 (en) | 2004-08-10 |
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