WO2004000730A3 - Nanocrystalline inorganic based zeolite and method for making same - Google Patents

Nanocrystalline inorganic based zeolite and method for making same Download PDF

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Publication number
WO2004000730A3
WO2004000730A3 PCT/US2003/002491 US0302491W WO2004000730A3 WO 2004000730 A3 WO2004000730 A3 WO 2004000730A3 US 0302491 W US0302491 W US 0302491W WO 2004000730 A3 WO2004000730 A3 WO 2004000730A3
Authority
WO
WIPO (PCT)
Prior art keywords
zeolite
inorganic oxide
liquid solution
porous inorganic
directing agent
Prior art date
Application number
PCT/US2003/002491
Other languages
French (fr)
Other versions
WO2004000730A2 (en
Inventor
Johannes Hendrik Koegler
Chuen Y Yeh
Philip J Angevine
Original Assignee
Abb Lummus Global Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Abb Lummus Global Inc filed Critical Abb Lummus Global Inc
Priority to AU2003272185A priority Critical patent/AU2003272185A1/en
Priority to JP2004515605A priority patent/JP2005519847A/en
Priority to EP03754357A priority patent/EP1472185A2/en
Publication of WO2004000730A2 publication Critical patent/WO2004000730A2/en
Publication of WO2004000730A3 publication Critical patent/WO2004000730A3/en
Priority to ZA2004/07046A priority patent/ZA200407046B/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/04—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/20—Faujasite type, e.g. type X or Y
    • C01B39/24—Type Y
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/21—Faujasite, e.g. X, Y, CZS-3, ECR-4, Z-14HS, VHP-R

Abstract

A method for making a zeolite includes impregnating a porous inorganic oxide with a liquid solution containing an inorganic micropore-forming directing agent. The amount of liquid solution is no more than about 100% of the pore volume of the porous inorganic oxide, and the concentration of the directing agent in the liquid solution ranges from about 21% to about 60% by weight. The impregnated amorphous inorganic oxide is heated at a synthesis temperature of from about 50 °C to about 150 °C for a duration of time sufficient to form a zeolite-containing product. The method herein is advantageous for the transformation of a mesoporous or macroporous amorphous inorganic material to a composite structure containing the original mesopores or macropores, but wherein at least some of the porous inorganic oxide material is converted to nanocrystalline zeolite, such as zeolite Y. Also, a unique composition of matter is defined having the X-ray diffraction pattern of zeolite Y, a silica to alumina molar ratio of less than (10), preferably less than (6), and a crystal size of no more than about 100 nm.
PCT/US2003/002491 2002-02-05 2003-01-29 Nanocrystalline inorganic based zeolite and method for making same WO2004000730A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
AU2003272185A AU2003272185A1 (en) 2002-02-05 2003-01-29 Nanocrystalline inorganic based zeolite and method for making same
JP2004515605A JP2005519847A (en) 2002-02-05 2003-01-29 Nanocrystalline inorganic base zeolite and method for producing the same
EP03754357A EP1472185A2 (en) 2002-02-05 2003-01-29 Nanocrystalline inorganic based zeolite and method for making same
ZA2004/07046A ZA200407046B (en) 2002-02-05 2004-09-03 Nanocrystalline inorganic based zeolite and method for making same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/067,719 2002-02-05
US10/067,719 US6793911B2 (en) 2002-02-05 2002-02-05 Nanocrystalline inorganic based zeolite and method for making same

Publications (2)

Publication Number Publication Date
WO2004000730A2 WO2004000730A2 (en) 2003-12-31
WO2004000730A3 true WO2004000730A3 (en) 2004-04-08

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2003/002491 WO2004000730A2 (en) 2002-02-05 2003-01-29 Nanocrystalline inorganic based zeolite and method for making same

Country Status (7)

Country Link
US (1) US6793911B2 (en)
EP (1) EP1472185A2 (en)
JP (1) JP2005519847A (en)
CN (1) CN1331747C (en)
AU (1) AU2003272185A1 (en)
WO (1) WO2004000730A2 (en)
ZA (1) ZA200407046B (en)

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Also Published As

Publication number Publication date
CN1331747C (en) 2007-08-15
WO2004000730A2 (en) 2003-12-31
AU2003272185A1 (en) 2004-01-06
US20030147805A1 (en) 2003-08-07
CN1628077A (en) 2005-06-15
JP2005519847A (en) 2005-07-07
US6793911B2 (en) 2004-09-21
ZA200407046B (en) 2005-11-30
AU2003272185A8 (en) 2004-01-06
EP1472185A2 (en) 2004-11-03

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