WO2003062196A3 - Gas-phase process and catalyst for the preparation of propylene oxide - Google Patents

Gas-phase process and catalyst for the preparation of propylene oxide Download PDF

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Publication number
WO2003062196A3
WO2003062196A3 PCT/US2003/001873 US0301873W WO03062196A3 WO 2003062196 A3 WO2003062196 A3 WO 2003062196A3 US 0301873 W US0301873 W US 0301873W WO 03062196 A3 WO03062196 A3 WO 03062196A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
preparation
gas
propylene oxide
phase process
Prior art date
Application number
PCT/US2003/001873
Other languages
French (fr)
Other versions
WO2003062196A2 (en
Inventor
Michiel Makkee
Aalbert Zwijnenburg
Jacob Adriaan Moulijn
Original Assignee
Huntsman Int Llc
Michiel Makkee
Aalbert Zwijnenburg
Jacob Adriaan Moulijn
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huntsman Int Llc, Michiel Makkee, Aalbert Zwijnenburg, Jacob Adriaan Moulijn filed Critical Huntsman Int Llc
Priority to AU2003209327A priority Critical patent/AU2003209327A1/en
Publication of WO2003062196A2 publication Critical patent/WO2003062196A2/en
Publication of WO2003062196A3 publication Critical patent/WO2003062196A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)

Abstract

Gas-phase process for the preparation of propylene oxide comprising contacting propylene with oxygen and hydrogen in the presence of a catalyst comprising a bimetallic compound supported on a titanium containing support, the bimetallic compound comprising gold and a metal M selected from the group consisting of platinum, tin, and rhodium. The invention also provides for the catalyst.
PCT/US2003/001873 2002-01-23 2003-01-22 Gas-phase process and catalyst for the preparation of propylene oxide WO2003062196A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2003209327A AU2003209327A1 (en) 2002-01-23 2003-01-22 Gas-phase process and catalyst for the preparation of propylene oxide

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US35111102P 2002-01-23 2002-01-23
US60/351,111 2002-01-23

Publications (2)

Publication Number Publication Date
WO2003062196A2 WO2003062196A2 (en) 2003-07-31
WO2003062196A3 true WO2003062196A3 (en) 2004-03-18

Family

ID=27613461

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2003/001873 WO2003062196A2 (en) 2002-01-23 2003-01-22 Gas-phase process and catalyst for the preparation of propylene oxide

Country Status (2)

Country Link
AU (1) AU2003209327A1 (en)
WO (1) WO2003062196A2 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE527057T1 (en) 2006-11-17 2011-10-15 Dow Global Technologies Llc HYDROXIDATION PROCESS USING A CATALYST FROM A GOLD CLUSTER COMPLEX
DE602008002836D1 (en) 2007-04-05 2010-11-11 Dow Global Technologies Inc INTEGRATED HYDROOXIDATION PROCESS WITH SEPARATION OF AN OLEFINOXIDE PRODUCT CIRCULATION
EP3134208A1 (en) 2014-04-22 2017-03-01 SABIC Global Technologies B.V. Method for the synthesis of supported gold (au) nanoparticles for epoxidation reactions
US11203183B2 (en) 2016-09-27 2021-12-21 Vaon, Llc Single and multi-layer, flat glass-sensor structures
US11243192B2 (en) 2016-09-27 2022-02-08 Vaon, Llc 3-D glass printable hand-held gas chromatograph for biomedical and environmental applications
WO2018160650A1 (en) * 2017-02-28 2018-09-07 Vaon, Llc Bimetal doped-metal oxide-based chemical sensors
CN113912570B (en) * 2020-07-10 2023-09-29 中国石油化工股份有限公司 Method for preparing propylene oxide by direct epoxidation of propylene with the aim of reducing dilution gas
CN113912568B (en) * 2020-07-10 2023-12-29 中国石油化工股份有限公司 Method for preparing propylene oxide capable of increasing limiting oxygen content
CN113912573B (en) * 2020-07-10 2023-07-04 中国石油化工股份有限公司 Method for preparing epoxypropane by directly epoxidation of propylene

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5821394A (en) * 1994-11-24 1998-10-13 Solvay Process for converting a chlorinated alkane into a less chlorinated alkene

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5821394A (en) * 1994-11-24 1998-10-13 Solvay Process for converting a chlorinated alkane into a less chlorinated alkene

Also Published As

Publication number Publication date
WO2003062196A2 (en) 2003-07-31
AU2003209327A1 (en) 2003-09-02

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