WO2003044112A1 - Coating, bag or molded article coated with the coating and coating method - Google Patents

Coating, bag or molded article coated with the coating and coating method Download PDF

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Publication number
WO2003044112A1
WO2003044112A1 PCT/JP2002/010686 JP0210686W WO03044112A1 WO 2003044112 A1 WO2003044112 A1 WO 2003044112A1 JP 0210686 W JP0210686 W JP 0210686W WO 03044112 A1 WO03044112 A1 WO 03044112A1
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WO
WIPO (PCT)
Prior art keywords
coating
coating agent
functional substance
sheet
bag
Prior art date
Application number
PCT/JP2002/010686
Other languages
French (fr)
Japanese (ja)
Inventor
Shinji Yokota
Original Assignee
Shinji Yokota
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shinji Yokota filed Critical Shinji Yokota
Priority to AU2002344082A priority Critical patent/AU2002344082A1/en
Priority to JP2003545741A priority patent/JPWO2003044112A1/en
Publication of WO2003044112A1 publication Critical patent/WO2003044112A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D31/00Bags or like containers made of paper and having structural provision for thickness of contents
    • B65D31/02Bags or like containers made of paper and having structural provision for thickness of contents with laminated walls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B31MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31BMAKING CONTAINERS OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31B50/00Making rigid or semi-rigid containers, e.g. boxes or cartons
    • B31B50/74Auxiliary operations
    • B31B50/742Coating; Impregnating; Waterproofing; Decoating

Definitions

  • the present invention relates to a coating agent, a bag or molded article coated with the coating agent, and a coating method.
  • a functional material having a special function such as titanium oxide having a disinfecting function and deodorizing function, activated carbon having a deodorizing function, etc. has been used on the surface of a molded body by using a resin such as polyester as a binder. Some were applied.
  • polyester resin used as a binder does not have air permeability, so that the surface of the functional material itself is covered with the non-air permeable polyester resin II, and the functional material and air ⁇ ⁇ 'width: It is not possible to keep the function of the object.
  • the present invention provides special functions such as antibacterial, antibacterial, sanitizing, deodorizing, deodorizing, antifungal, fragrance, and phosphorescence for a water-dispersible resin which is a resin having air permeability after being cured by being cured in an amorphous state.
  • the present invention relates to a coating agent obtained by mixing a functional substance having the following. Then, the coating agent is coated on the surface of the rectangular sheet, and then the sheet is bent with the coated surface as the inner surface, and the edges of the inner surface are connected to each other.
  • the present invention relates to a bag characterized in that the bag is adhered using the adhesive force of a ting agent.
  • the present invention relates to a bag characterized in that edges are adhered to each other using the adhesive force of the coating agent.
  • the present invention also relates to a molded article characterized in that the coating agent is attached to a surface.
  • the molding leave has air permeability.
  • the present invention relates to a coating method, which comprises forming a viscous coating film on the surface after applying the coating agent on the surface.
  • a viscous coating film a mucus having a body surface of a terrestrial conch belonging to the slugs and the slugs is used.
  • FIG. 1 is an explanatory diagram showing a method for forming a bag.
  • FIG. 2 is an explanatory view showing a bag forming method as another embodiment.
  • FIG. 3 is a perspective view showing a honeycomb core.
  • FIG. 4 is a perspective view showing the panel.
  • FIG. 5 is a sectional view of the same.
  • the coating agent according to the present invention when cured in a non-crystalline state, can be applied to a water-dispersible resin which is a resin having air permeability after curing, such as antibacterial, sterilization, deodorization, deodorization, antifungal, '
  • a functional material having the above function is mixed.
  • the functional substances mentioned here include antibacterial and antibacterial properties, titanium oxide with deodorizing function, charcoal with deodorizing function (activated carbon, etc.), honey with antifungal function, catechin, and various fragrances.
  • substances having a special function such as a phosphorescent material that performs photometry after absorbing light.
  • fat examples include water-dispersible polyester nucleus (Vainar (registered trademark) manufactured by Toyobo, Elitel (registered trademark) manufactured by Unitika, and Janal (registered trademark) manufactured by Mitsubishi Rayon).
  • resins that have air permeability (respirability) after curing by curing in the non-crystalline state.
  • the coating agent according to the present invention is antibacterial, disinfecting, deodorizing, deodorizing, antifungal, fragrance, and the like to water-dispersible resin, which is a resin having air permeability after curing by being cured in an amorphous state. Even if the water-dispersible resin is cured after coating on a sheet or bag, the cured water-dispersible resin has a mortality property, It can continuously and effectively exert various special functions of the substance over a long period of time.
  • the water-dispersed resin itself has air permeability, so that the surface of the functional substance itself is covered with the air-permeable resin, and the By utilizing the air permeability of the resin, the functional material and the air can be brought into good contact with each other, and the function of the functional material can be exerted continuously and effectively over a long period of time.
  • the water-dispersible resin when cured, it has a light-transmitting property, so that it can transmit ultraviolet light and visible light, and these ultraviolet light and visible light enter the functional material.
  • the functional substance W can perform its function.
  • the coating agent is adhered to the surface of air-permeable components.
  • the molded body referred to here may be any type of material having various forms, and its material may be various materials such as metal, wood, paper, and clay, and is not particularly limited.
  • the molded article having air permeability may be a molded article having air permeability formed by perforating holes in the molded article itself, or a molded article formed of a gas permeable material.
  • the air-permeable substance include air-permeable substances such as paper, wood, fiber, non-woven fabric, clay, and sponge.
  • a method for applying a coating agent to the surface of the molded body a method of applying a functional substance to the surface of the molded body using a water-dispersed resin as a binder, a method of applying a functional substance to a gas-permeable substance, For example, a method of shaping after mixing with a water-dispersible resin, or immersing a molded body in a solution containing a functional material and a water-dispersible resin as main raw materials There is a way to do that.
  • the molded article according to the present invention uses a water-dispersible resin as a binder with a functional substance having a special function on the surface of a molded article obtained by molding a gas-permeable substance having air permeability. Due to the attachment, various special functions of the functional substance can be continuously and effectively exerted over a long period of time.
  • the binder since the water-dispersible resin is used as the binder, the binder has a light-transmitting property when the binder is hardened, whereby ultraviolet and visible light can pass through the binder. Ultraviolet light or visible light can enter the functional substance, and the functional substance can perform its function. Moreover, even after the binder is cured, the binder itself has air permeability, so that the surface of the functional substance itself is covered with the air-permeable resin, and the air permeability of the resin is utilized. Thus, the functional substance and the air can be brought into good contact with each other. Therefore, the function of the functional material will be exerted continuously and effectively over a long period of time.
  • the functional substance when the raw material of the molded article itself has air permeability, the functional substance can be brought into good contact with air by utilizing the air permeability of the molded article itself. However, the function of the functional substance will be exerted continuously and effectively over a long period of time.
  • the function of the functional substance attached to the surface of the molded body can be exhibited over a long period of time, the added value of the molded body can be further improved.
  • the functional material l when the functional material l is applied to the surface of the molded body using a water-dispersible resin as a binder, the functional material should be surely applied to the surface of the molded body that comes into contact with air. According to this, the function of the functional substance can be continuously and effectively exerted over a long period of time, and the added value of the molded article can be further improved.
  • the functional substance in the case where the functional substance is mixed with the air-permeable substance by using a water-dispersible resin as a binder, and then molded, the functional substance can be contained even in the air-permeable molded body, Since a large amount of the functional substance can be contained in the molded body, the function of the functional substance can be continuously and effectively exerted over a long period of time, and thus the molded body can be formed. Can further increase the added value of It can be.
  • the functional substance when the molded article is immersed in a solution containing a functional material and a water-dispersible resin as main raw materials, the functional substance can be contained even in the air-permeable molded article. In this way, a large amount of functional material can be contained, so that the function of the functional material can be continuously and effectively exerted over a long period of time, and the added value of the molded article can be increased. It can be further improved.
  • by forming a plurality of through-holes in the molded body using a needle or the like it is possible to further improve the air permeability, thereby further improving the contact between the functional substance and the air. Can be.
  • coloring is performed by mixing a medium into the solution.
  • the resin and the water-dispersible resin can be uniformly blended, and the connection between the colorant and the water-dispersible resin can be strengthened, especially when printing on glass-based materials.
  • silica By mixing silica into the solution, the adhesiveness to the glass-based material surface can be improved.
  • the present invention is applicable only to a molded article in which a functional substance having a special function is adhered to the surface by using a water-dispersible resin as a binder, and may be used for posters, various kinds of tickets, paintings, and envelopes.
  • Moldings made of paper such as paper, packaging bags, outer bags for medicine, wallpaper, cardboard, various trays, etc., moldings made of wood such as pillars, walls, boxes, etc., and molding leaves made of clay such as pottery and porcelain. It may be a molding leave or a functional substance such as activated carbon or catechin.
  • the functional material when the material of the sheet or the bag itself has air permeability, the functional material can be brought into good contact with air by utilizing the air permeability of the material itself. In other words, the function of the functional substance will be exerted continuously and effectively over a long period of time.
  • the coating material penetrates to the back of the material when the surface of the material is coated with the coating agent, the coating agent spreads on both sides of the material, and the function of the functional material From both sides of the material Can be volatilized.
  • the contact between the functional substance and air can be further improved.
  • the added value of the molded article can be further improved by allowing the function of the functional substance attached to the surface of the sheet or bag to be exhibited over a long period of time.
  • a medium should be mixed in the coating agent.
  • the colorant and the water-dispersible resin can be blended uniformly, and the connection between the colorant and the water-dispersible resin can be strengthened, especially when printing on glass-based materials.
  • silica By mixing silica in the solution, the adhesiveness to the glass-based material surface can be improved.
  • the coating agent according to the present invention is obtained by mixing the functional substance into the water-dispersed resin, the various special functions of the functional substance are continuously provided for a long period of time. It can be used effectively.
  • the surface of the bag is not limited to the outer surface of the bag, but also includes the inner surface of the bag. In some cases, only the outer surface or only the inner surface is coated.
  • a coating agent is coated on the surface of a square sheet, and then the sheet is bent using the coating as an inner side, and the inner part is adhered to each other to form a bag.
  • the edges are thermally welded using the thermosetting property of the coating agent. In this case, the step of applying an adhesive to the edge can be omitted, and the production can be further facilitated, and the production cost can be reduced.
  • a coating agent is coated on the entire surface of one half of the surface of the square sheet and the edge of the other half, and then the sheet is bent with the coated surface as the inner surface, and the edge of the inner surface is formed. If the bag is formed by bonding the parts to each other, even if the outer surface of the bag is printed using a printing device that heats the outer surface of the bag, such as a heat-sublimating printer, the inner surface of the bag can be used. Since they do not adhere to each other, good usability can be achieved.
  • a viscous coating film is formed on the surface after the coating agent is applied to the surface.
  • a viscous coating a mucus covering the body surface of terrestrial snails belonging to the slugs and the slugs is used.
  • the coating surface is covered with a viscous coating film in this way, it is possible to prevent shellfish, barnacles, dust, etc. from adhering to the surface, and to coat the coating film with a mucus that covers the surface of living organisms. If formed, even if the coating film is peeled off from the surface, the peeled coating film is naturally decomposed and reduced to the natural ecosystem, resulting in the generation of new dust.
  • a functional substance having a special function may be attached to the surface of a plant using a water-dispersible resin as a binder.
  • the surface of a plant may be the surface of a trunk or a leaf, or may be a cut surface obtained by cutting a trunk.
  • the present invention is not limited to this, and it is possible to form posters, various tickets, paintings, envelopes, outer bags for medicine, paper, such as wallpaper, corrugated cardboard, various trays, and moldings made of wood, such as pillars, walls, and boxes.
  • the molded body may be a molded body made of clay such as a body or clay such as pottery or porcelain, or may be a functional material such as activated carbon or catechin.
  • charcoal such as activated carbon or honey ⁇ catechin or fragrance ⁇ can be used to produce a coating agent.
  • a water-dispersible polyester resin (Vylon (registered trademark) manufactured by Toyobo) is placed in a container, and 7 kg of ethyl acetate is charged as an organic solvent into the container.
  • the powdered titanium oxide was charged, and then thoroughly mixed with a stirrer to produce a liquid coating agent containing a functional substance.
  • charcoal such as activated carbon or honey ⁇ catechin or fragrance ⁇ can be used to produce a coating agent.
  • the same amount of charcoal such as activated carbon, honey, power techin, fragrance and luminous material can be added to produce a coating agent.
  • the phosphorescent material may be a non-oxide material obtained by adding copper to zinc sulfide, or an oxide material obtained by adding a rare earth element to a ceramic material containing aluminum oxide as a main component.
  • a coating agent can be produced by adding about 5 g of charcoal such as titanium oxide / activated carbon, honey, catechin, or a fragrance to the coating agent.
  • a liquid coating containing the above functional substance was applied to the surface of the poster with a brush.
  • Such posters have antibacterial, sterilization, and deodorizing functions by the action of titanium oxide, and can be stretched indoors. Just adding it will add value, such as being able to perform antibacterial, sanitizing, and deodorizing indoors.
  • a coloring agent was added to the liquid coating agent containing the above-mentioned functional substance, and it was printed on the surface of the ticket with a printing machine.
  • a ticket having powdered titanium oxide adhered to the surface can be produced, and such a ticket has an added value such as anti-bacterial / sterilizing / deodorizing function due to the production of titanium oxide ffl. become.
  • the wrapping paper was immersed in a liquid coating agent containing the above functional substance for 10 minutes, and then the wrapping paper was dried.
  • wrapping paper with powdered titanium oxide adhering to the surface.
  • Such wrapping paper has the added value of having antibacterial, antibacterial, and deodorizing functions at the titanium oxide Sakugawa. With something.
  • a liquid coating agent containing the above-mentioned functional substance was applied to the surface of a rectangular paper sheet with a brush and dried (see FIG. 1 (a)).
  • the coating agent is coated on the surface of the sheet 1 to form the coating surface 2.
  • sheet 1 is bent at the center of sheet 1 (folding curve 3 shown by the dotted line in FIG. 1 (a)) so that coating surface 2 is the inner surface (FIG. 1 (b)
  • a bag 6 was manufactured by bonding the left and right sides 4, 5 of the sheet 1 (see FIG. 1 (c)).
  • thermosetting property of the coating agent applied to the edges 4 and 5 was used to apply heat welding without applying an additional adhesive.
  • an adhesive may be separately applied to the edges 4 and 5.
  • a liquid coating agent containing the above-mentioned functional substance was applied to the surface of a rectangular paper sheet with a brush, and then dried (see FIG. 2 (a)).
  • the coating agent is coated on the surface of the sheet 1 to form the coating 2.
  • a coating agent is applied to the left half of the sheet 1 to form a coating surface 2a, while the right half of the sheet 1 is formed. Applies coating agent only to left and right edges 3 and 4 to form coated surface 2b.
  • the sheet 1 is bent at the center of the sheet 1 (the broken line 3 shown by the dotted line in FIG. 2 (a)) so that the coating surface 2 becomes the inner surface (see FIG. 2 (b)). Then the sheet The bag 6 was manufactured by bonding at the left and right edges 4 and 5 of 1 (see FIG. 2 (c)).
  • thermosetting properties of the coating agent applied to the edges 4 and 5 were used to apply heat welding without applying an additional adhesive.
  • an adhesive may be separately applied to the edges 4 and 5.
  • bags with powdered titanium oxide adhered to the inner surface can be manufactured.
  • Such bags have added value such as antibacterial, sterilization and deodorant functions by the action of titanium oxide. Become.
  • a tray for transporting fresh fish having powdered titanium oxide adhered to the surface can be manufactured, and such a tray for transporting fresh fish has a function of removing bacteria and eliminating odors by the action of titanium oxide. It will be value-added.
  • the sponge for fresh flowers was immersed in the liquid resin containing the above functional substance for 10 minutes to allow the resin to penetrate into the sponge for fresh flowers, and then the sponge for fresh flowers was dried.
  • a sponge for fresh flowers having powdered titanium oxide adhered to the surface can be manufactured, and such a sponge has a value-added value that has a sterilizing and deodorizing function by the action of titanium oxide. There will be something.
  • a 10 liter water-dispersible polyester resin (Toyobo (Vylon (registered trademark)) is heated and melted at 70 ° C and placed in a container. Then, lkg of powdered titanium oxide is charged therein, and then sufficiently stirred with a stirrer. By mixing with stirring, a liquid resin containing a functional substance was produced.
  • pulp of 5 O Kg was mixed into the liquid resin containing the above-mentioned functional substance, and the mixture was formed into a honeycomb core 11 shown in FIG. 3 by a pressure molding machine.
  • 16 is a hexagonal column-shaped through hole formed in the honeycomb core 11.
  • a plurality of small-diameter through-holes 15 were formed in the plates 2 and 3 with needles, and a liquid resin containing the above-described functional substance was applied to the surfaces.
  • the functional material is attached to the surface of the core material having the through hole 16, and the functional material is attached to the surface while having the through hole 15 eclectic of the core material.
  • Panel 14 was manufactured by bonding the sheet materials. The panel 14 is in a state of passing through the panel as a whole due to the action of the through holes 15 and 16 and has air permeability even when the panel as a whole is viewed. Therefore, the contact between the functional substance and air is good.
  • the present invention is embodied in the form described above and has the following effects.
  • the coating agent according to the present invention is obtained by mixing a functional substance into a water-dispersed resin, various special functions of the functional substance are continuously and effectively exerted over a long period of time. You can keep it.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Paints Or Removers (AREA)
  • Laminated Bodies (AREA)

Abstract

To allow a functional substance to continuously and efficaciously exhibit its function over a long time, it is intended to provide a coating produced by blending a water-dispersible resin, which is hardened in an amorphous state and thus exhibits air-permeability after hardening, with a functional substance having a specific function (for example, an antibacterial, sterilizing, offensive odor-relieving, deodorizing, mildew-proofing, aromatic or light-preserving substance). A bag is formed by surface-coating a rectangular sheet with the above coating, folding the sheet as the coated face inside and bonding the inner face edges to each other by taking advantage of the adhesive force of the coating.

Description

明 細 書 コーティング剤及び同コーティング剤でコーティングした袋又は成形体並びに コーティング方法 技術分野  Description Coating agent, bag or molded article coated with the coating agent, and coating method
本発明は、 コーティング剤及び同コ一ティング剤でコ一ティングした袋又は成 形体並びにコーティング方法に関するものである。 背景技術  The present invention relates to a coating agent, a bag or molded article coated with the coating agent, and a coating method. Background art
従来より、 各褪トレイ、 便器、 紙や袋等の成形体は日常生活において幅広く使 用されてきており、 近年では成形体が持つ本来の機能に除菌ゃ脱臭等の付加価値 を付け加えることがなされている。  Conventionally, molded products such as fading trays, toilet bowls, paper and bags have been widely used in daily life.In recent years, it has been possible to add added values such as sterilization and deodorization to the original functions of molded products. It has been done.
例えば、 従来より、 除菌ゃ消臭機能を有する酸化チタンや脱臭機能を有する活 性炭等といった特別の機能を有する機能性物質を成形体の表面にバインダ一とし てポリエステル等の樹脂を用いて塗布したものがあった。  For example, conventionally, a functional material having a special function, such as titanium oxide having a disinfecting function and deodorizing function, activated carbon having a deodorizing function, etc. has been used on the surface of a molded body by using a resin such as polyester as a binder. Some were applied.
ところが、 通常のポリエステル樹脂をバインダーとして用いて成形体の表面に 機能性物質を塗布した成形体にあっては、 機能性物質の機能を長期間にわたって ¾揷しつづけることができないものであった。  However, in a molded article obtained by applying a functional substance to the surface of a molded article using a normal polyester resin as a binder, the function of the functional substance cannot be maintained for a long period of time.
これは、 バインダーとして用いたポリエステル樹 ·)]旨に通気性が無いために、 機 能性物質自体の表而が通気性のないポリエステル樹 '脂で被 IIされてしまい、 機能 性物質と空気とが接触することができず、 機能件.物' の機能を継続して ί¾ί'巾:させ 続けることができなくなることによるものである。  This is because the polyester resin used as a binder does not have air permeability, so that the surface of the functional material itself is covered with the non-air permeable polyester resin II, and the functional material and airで き 'width: It is not possible to keep the function of the object.
¾明の開示 Disclosure of explanation
本発明は、 非結晶状態で硬化することにより硬化後に通気性を有する樹脂であ る水分散型樹脂に抗菌 ·抗菌 ·除菌 ·消臭 ·脱臭 ·防黴 ·芳香 ·蓄光等の特別の 機能を有する機能性物質を混入してなるコ一ティング剤に関するものである。 そして、 前記コーティング剤を方形状のシートの表面にコーティングし、 その 後、 コーティング面を内側面としてシートを折曲し、 内側面の縁部同士を前記コ 一ティング剤の接着力を用いて接着したことを特徴とする袋に関するものである。 また、 前記コ一ティング剤を方形状のシートの表面の一側半部の全面と他側半 部の緣部にコーティングし、 その後、 コーティング面を内側面としてシートを折 曲し、 内側面の縁部同士を前記コーティング剤の接着力を用いて接着したことを 特徴とする袋に関するものである。 The present invention provides special functions such as antibacterial, antibacterial, sanitizing, deodorizing, deodorizing, antifungal, fragrance, and phosphorescence for a water-dispersible resin which is a resin having air permeability after being cured by being cured in an amorphous state. The present invention relates to a coating agent obtained by mixing a functional substance having the following. Then, the coating agent is coated on the surface of the rectangular sheet, and then the sheet is bent with the coated surface as the inner surface, and the edges of the inner surface are connected to each other. The present invention relates to a bag characterized in that the bag is adhered using the adhesive force of a ting agent. Further, the coating agent is coated on the entire surface of one side half of the surface of the rectangular sheet and on the other part of the other half, and then the sheet is bent with the coated surface as the inner surface, and the inner surface is bent. The present invention relates to a bag characterized in that edges are adhered to each other using the adhesive force of the coating agent.
また、 前記コーティング剤を表面に付着させたことを特徴とする成形体に関す るものである。  The present invention also relates to a molded article characterized in that the coating agent is attached to a surface.
特に、 前記成形休は、 通気性を有するものである。  In particular, the molding leave has air permeability.
また、 本発明は、 前記コーティング剤を表面に塗布した後に、 表面に粘性を有 する塗膜を形成することを特徴とするコ一ティング方法に関するものである。 特に、 前記粘性を有する塗膜として、 ナメクジ科およびコゥラナメクジ科に属 する陸生卷貝の体表を IIう粘液を用いるものである。 図面の簡単な説明  In addition, the present invention relates to a coating method, which comprises forming a viscous coating film on the surface after applying the coating agent on the surface. In particular, as the above-mentioned viscous coating film, a mucus having a body surface of a terrestrial conch belonging to the slugs and the slugs is used. BRIEF DESCRIPTION OF THE FIGURES
図 1は、 袋の形成方法を示す説明図である。 図 2は、 他実施例としての袋の形 成方法を示す説明図である。 図 3は、 ハニカムコアを示す斜视図である。 図 4は、 パネルを示す斜視図である。 図 5は、 同断面図である。 発明を実施するための最良の形態  FIG. 1 is an explanatory diagram showing a method for forming a bag. FIG. 2 is an explanatory view showing a bag forming method as another embodiment. FIG. 3 is a perspective view showing a honeycomb core. FIG. 4 is a perspective view showing the panel. FIG. 5 is a sectional view of the same. BEST MODE FOR CARRYING OUT THE INVENTION
本発明に係るコーティング剤は、 非結晶状態で硬化することにより硬化後に通 気性を有する樹脂である水分散型樹脂に抗菌 ·除菌 ·消臭 ·脱臭 ·防黴 · ' · ^光等の特別の機能を有する機能性物質を混入したものである。  The coating agent according to the present invention, when cured in a non-crystalline state, can be applied to a water-dispersible resin which is a resin having air permeability after curing, such as antibacterial, sterilization, deodorization, deodorization, antifungal, ' A functional material having the above function is mixed.
ここでいう機能性物質としては、 抗菌や除菌ゃ消臭機能を有する酸化チタン、 脱臭機能を有する炭 (活性炭等)、 防黴機能を有する蜂蜜ゃカテキン、 各種の香 りを ¾する芳香剤、 光を吸収後に究光を行う蓄光材料等の特別の機能を有する物 質がある。  The functional substances mentioned here include antibacterial and antibacterial properties, titanium oxide with deodorizing function, charcoal with deodorizing function (activated carbon, etc.), honey with antifungal function, catechin, and various fragrances. There are substances having a special function, such as a phosphorescent material that performs photometry after absorbing light.
また、 水分散型梭: f脂としては、 水分散型ポリエステル核 旨 (東洋紡製のバイ口 ナール (登録商標)、 ュニチカ製のエリーテル (登録商標)、 三菱レイヨン製のダ ィャナール (登録商標) 等) 等の非結晶状態で硬化することによって硬化後に通 気性 (呼吸性) を有する各種の樹脂がある。 なお、 上記した水分散型: ル樹脂は、 単体で用いてもよく、 また、 これらを混合させたものでもよく、 熱圧 着可能なヒートシール機能を有するものでもよい。 Examples of the water-dispersible tofu: fat include water-dispersible polyester nucleus (Vainar (registered trademark) manufactured by Toyobo, Elitel (registered trademark) manufactured by Unitika, and Janal (registered trademark) manufactured by Mitsubishi Rayon). There are various resins that have air permeability (respirability) after curing by curing in the non-crystalline state. The water dispersion type described above: The resin may be used alone, may be a mixture thereof, or may have a heat sealable heat sealing function.
そして、 本発明に係るコーティング剤は、 非結晶状態で硬化することにより硬 化後に通気性を有する樹脂である水分散型樹脂に抗菌 ·除菌 ·消臭 ·脱臭 ·防 黴 -芳香 ·蓄光等の特別の機能を有する機能性物質を混入したものであるため、 シートや袋にコーティングした後に水分散型樹脂が硬化しても、 硬化後の水分散 型 脂が逝気性を有するので、 機能性物質が有する各種の特別な機能を長期間に わたって継続的に有効に発揮させつづけることができるものである。  Further, the coating agent according to the present invention is antibacterial, disinfecting, deodorizing, deodorizing, antifungal, fragrance, and the like to water-dispersible resin, which is a resin having air permeability after curing by being cured in an amorphous state. Even if the water-dispersible resin is cured after coating on a sheet or bag, the cured water-dispersible resin has a mortality property, It can continuously and effectively exert various special functions of the substance over a long period of time.
すなわち、 水分散型樹脂が硬化した後も水分散型樹脂自体が通気性を有してお り、 これにより、 機能性物質自体の表面が通気性を有する樹脂で被覆されること になり、 かかる樹脂の通気性を利用して機能性物質と空気とを良好に接触させる ことができ、 機能性物質の機能が長期間にわたって継続的に有効に発揮されるこ とになるのである。  That is, even after the water-dispersed resin is cured, the water-dispersed resin itself has air permeability, so that the surface of the functional substance itself is covered with the air-permeable resin, and the By utilizing the air permeability of the resin, the functional material and the air can be brought into good contact with each other, and the function of the functional material can be exerted continuously and effectively over a long period of time.
また、 水分散型樹脂が硬化した際に透光性を有しており、 これにより、 紫外線 や可視光線力 ィンダーを透過することができ、 これらの紫外線や可視光線が機 能性物質に入光し、 機能性物 Wが機能を発揮するようにすることができるのであ る。  In addition, when the water-dispersible resin is cured, it has a light-transmitting property, so that it can transmit ultraviolet light and visible light, and these ultraviolet light and visible light enter the functional material. In addition, the functional substance W can perform its function.
また、 本発明では、 通気性を有する成 ^5体の表面に前記コーティング剤を付着 させたものである。  Further, in the present invention, the coating agent is adhered to the surface of air-permeable components.
ここでいう成形体としては、 種々の形態を有する物休であればよく、 その素材 は、 金厲、 木材、 紙、 粘土などの各種の素材でよく、 特に限定されるものではな い。  The molded body referred to here may be any type of material having various forms, and its material may be various materials such as metal, wood, paper, and clay, and is not particularly limited.
また、 通気性を有する成形体とは、 成形体自体に通気孔を-穿設して通気性を持 たせたものでもよく、 また、 通気性を有する通気性物質を成形した物でもよい。 ここで、 通気性物質としては、 紙、 木材、 繊維、 不織布、 粘土、 スポンジ等の通 気性を有する物質がある。  In addition, the molded article having air permeability may be a molded article having air permeability formed by perforating holes in the molded article itself, or a molded article formed of a gas permeable material. Here, examples of the air-permeable substance include air-permeable substances such as paper, wood, fiber, non-woven fabric, clay, and sponge.
そして、 成形体の表面にコーティング剤を付着させる方法としては、 成形体の 表面に機能性物質をバインダ一として水分散型樹脂を用いて塗布する方法や、 通 '気性物質に機能性物質をバインダ一として水分散型樹脂を用いて混入した後に成 形する方法や、 機能性物質と水分散型樹脂とを主原料とする溶液に成形体を浸漬 する方法がある。 As a method for applying a coating agent to the surface of the molded body, a method of applying a functional substance to the surface of the molded body using a water-dispersed resin as a binder, a method of applying a functional substance to a gas-permeable substance, For example, a method of shaping after mixing with a water-dispersible resin, or immersing a molded body in a solution containing a functional material and a water-dispersible resin as main raw materials There is a way to do that.
このように、 本発明に係る成形体は、 通気性を有する通気性物質を成形してな る成形体の表面に特別な機能を有する機能性物質をバインダ一として水分散型樹 脂を用いて付着させているため、 機能性物質が有する各種の特別な機能を長期間 にわたって継続的に有効に発揮させつづけることができるものである。  As described above, the molded article according to the present invention uses a water-dispersible resin as a binder with a functional substance having a special function on the surface of a molded article obtained by molding a gas-permeable substance having air permeability. Due to the attachment, various special functions of the functional substance can be continuously and effectively exerted over a long period of time.
すなわち、 バインダ一として水分散型樹脂を用いているため、 バインダ一が硬 化した際に透光性を有しており、 これにより、 紫外線や可視光線がバインダーを 透過することができ、 これらの紫外線や可視光線が機能性物質に入光し、 機能性 物質が機能を発揮するようにすることができる。 しかも、 バインダーが硬化した 後もバインダー自体が通気性を有しており、 これにより、 機能性物質自体の表面 が通気性を有する樹脂で被覆されることになり、 かかる樹脂の通気性を利用して 機能性物質と空気とを良好に接触させることができる。 したがって、 機能性物質 の機能が長期問にわたって継続的に有効に発揮されることになるのである。  That is, since the water-dispersible resin is used as the binder, the binder has a light-transmitting property when the binder is hardened, whereby ultraviolet and visible light can pass through the binder. Ultraviolet light or visible light can enter the functional substance, and the functional substance can perform its function. Moreover, even after the binder is cured, the binder itself has air permeability, so that the surface of the functional substance itself is covered with the air-permeable resin, and the air permeability of the resin is utilized. Thus, the functional substance and the air can be brought into good contact with each other. Therefore, the function of the functional material will be exerted continuously and effectively over a long period of time.
しかも、 成形体の原材料自体が通気性を有している場合には、 成形体自体の通 気性をも利用して機能性物質と空気とを良好に接触させることができるので、 こ れによっても、 機能性物質の機能が長期間にわたって継続的に有効に発揮される ことになるのである。  In addition, when the raw material of the molded article itself has air permeability, the functional substance can be brought into good contact with air by utilizing the air permeability of the molded article itself. However, the function of the functional substance will be exerted continuously and effectively over a long period of time.
そして、 成形体の表面に付着させた機能性物質の機能を長期間にわたって発揮 させることができることによって、 成形体の付加価値をより一層向上させること ができるのである。  In addition, since the function of the functional substance attached to the surface of the molded body can be exhibited over a long period of time, the added value of the molded body can be further improved.
特に、 成形休の表而に機能性物 lをバインダ一として水分散型樹脂を用いて塗 布した場合には、 空気に接触する成形体表而に機能性物質を確実に W着させるこ とができ、 これによつても、 機能性物質が有する機能を長期間にわたって継続的 に有効に発揮させつづけることができて、 成形体の付加価値をより一層向上させ ることができるものである。  In particular, when the functional material l is applied to the surface of the molded body using a water-dispersible resin as a binder, the functional material should be surely applied to the surface of the molded body that comes into contact with air. According to this, the function of the functional substance can be continuously and effectively exerted over a long period of time, and the added value of the molded article can be further improved.
また、 通気性物質に機能性物質をバインダ一として水分散型樹脂を用いて混入 した後に成形した場合には、 通気性を有する成形体の内部にまで機能性物質を含 有させることができ、 成形体に大量の機能性物質を含有させることができるので、 これによつても、 機能性物質が有する機能を長期間にわたつて継続的に有効に発 揮させつづけることができて、 成形体の付加価値をより一層向上させることがで きるものである。 Further, in the case where the functional substance is mixed with the air-permeable substance by using a water-dispersible resin as a binder, and then molded, the functional substance can be contained even in the air-permeable molded body, Since a large amount of the functional substance can be contained in the molded body, the function of the functional substance can be continuously and effectively exerted over a long period of time, and thus the molded body can be formed. Can further increase the added value of It can be.
また、 機能性物質と水分散型樹脂とを主原料とする溶液に成形体を浸漬した場 合には、 通気性を有する成形体の内部にまで機能性物質を含有させることができ、 成形体に大量の機能性物質を含有させることができるので、 これによつても、 機 能性物質が有する機能を長期間にわたって継続的に有効に発揮させつづけること ができて、 成形体の付加価値をより一層向上させることができるものである。 また、 針等を用いて成形体に複数の貫通孔を穿設することによって、 通気性を さらに向上させることができ、 これにより機能性物質と空気との接触をより一層 良好なものとすることができる。  Further, when the molded article is immersed in a solution containing a functional material and a water-dispersible resin as main raw materials, the functional substance can be contained even in the air-permeable molded article. In this way, a large amount of functional material can be contained, so that the function of the functional material can be continuously and effectively exerted over a long period of time, and the added value of the molded article can be increased. It can be further improved. In addition, by forming a plurality of through-holes in the molded body using a needle or the like, it is possible to further improve the air permeability, thereby further improving the contact between the functional substance and the air. Can be.
また、 機能性物質と水分散型樹脂とを主原料とする溶液に着色剤を添加し、 そ れを成形体の表面に印刷により付着させる場合には、 溶液にメジゥムを混入する ことによって、 着色剤と水分散型樹'脂とを均一-になじませることができ、 着色剤 と水分散型樹脂との結びつきを強固なものとすることができ、 特に、 ガラス系の 物質に印刷する場合には、 溶液にシリカを混入することによって、 ガラス系の物 質表面への接着性を向上させることができる。  When a colorant is added to a solution containing a functional material and a water-dispersible resin as main raw materials and the colorant is attached to the surface of a molded article by printing, coloring is performed by mixing a medium into the solution. The resin and the water-dispersible resin can be uniformly blended, and the connection between the colorant and the water-dispersible resin can be strengthened, especially when printing on glass-based materials. By mixing silica into the solution, the adhesiveness to the glass-based material surface can be improved.
そして、 本発明は、 表面に特別な機能を有する機能性物質をバインダーとして 水分散型樹脂を用いて付着させた成形体であればよく、 ポスターや各種チケ'ソ 卜 や絵画や封. ·筒や包装袋や薬剤用外袋や壁紙や段ボールや各種トレイ等の紙からな る成形体や柱や壁や箱等の木材からなる成形体や陶器や磁器等の粘土からなる成 形休等からなる成形休でもよく、 また、 活性炭ゃカテキン等の機能性物質でもよ い。  The present invention is applicable only to a molded article in which a functional substance having a special function is adhered to the surface by using a water-dispersible resin as a binder, and may be used for posters, various kinds of tickets, paintings, and envelopes. Moldings made of paper such as paper, packaging bags, outer bags for medicine, wallpaper, cardboard, various trays, etc., moldings made of wood such as pillars, walls, boxes, etc., and molding leaves made of clay such as pottery and porcelain. It may be a molding leave or a functional substance such as activated carbon or catechin.
また、 その他の応用例としては、 植木鉢や fflカバーや果実用袋、 防虫パネルや 防虫シート、 スリッパ、 筆記具、 グリップ、 ごみ箱、 水浄化剤等、 幅広い範囲の ものがある。  Other applications include a wide range of applications such as flowerpots, ffl covers and fruit bags, insect repellent panels and sheets, slippers, writing instruments, grips, trash cans, water purifiers, and more.
特に、 シートや袋の素材自|体に通気性がある場合には、 素材自体の通気性をも 利用して機能性物質と空気とを良好に接触させることができるので、 これによつ ても、 機能性物質の機能が長期間にわたつて継続的に有効に発揮されることにな るのである。 しかも、 素材自体に通気性がある場合には、 素材の表面をコーティ ング剤でコーティングした際に素材の裏面にまでコーティング剤が浸透し、 素材 の両面にコーティング剤がいきわたり、 機能性物質による機能を素材の両面で発 揮させることができる。 In particular, when the material of the sheet or the bag itself has air permeability, the functional material can be brought into good contact with air by utilizing the air permeability of the material itself. In other words, the function of the functional substance will be exerted continuously and effectively over a long period of time. In addition, if the material itself has air permeability, the coating material penetrates to the back of the material when the surface of the material is coated with the coating agent, the coating agent spreads on both sides of the material, and the function of the functional material From both sides of the material Can be volatilized.
また、 シートや袋に針等を用いて複数の通気孔を穿設することによつても、 機 能性物質と空気との接触をより一層良好なものとすることができる。  Also, by providing a plurality of ventilation holes in the sheet or bag using a needle or the like, the contact between the functional substance and air can be further improved.
そして、 シートや袋の表面に付着させた機能性物質の機能を長期間にわたって 発揮させることができることによって、 成形体の付加価値をより一層向上させる ことができるのである。  The added value of the molded article can be further improved by allowing the function of the functional substance attached to the surface of the sheet or bag to be exhibited over a long period of time.
また、 機能性物質と水分散型樹脂とを主原料とするコーティング剤に着色剤を 添加し、 それをシートや袋の表面に印刷により付着させる場合には、 コーティン グ剤にメジゥムを混入することによって、 着色剤と水分散型樹脂とを均一になじ ませることができ、 着色剤と水分散型樹脂との結びつきを強固なものとすること ができ、 特に、 ガラス系の物質に印刷する場合には、 溶液にシリカを混入するこ とによって、 ガラス系の物質表面への接着性を向上させることができる。  When a coloring agent is added to a coating agent mainly composed of a functional substance and a water-dispersible resin, and the colorant is attached to the surface of a sheet or bag by printing, a medium should be mixed in the coating agent. In this way, the colorant and the water-dispersible resin can be blended uniformly, and the connection between the colorant and the water-dispersible resin can be strengthened, especially when printing on glass-based materials. By mixing silica in the solution, the adhesiveness to the glass-based material surface can be improved.
以上のように、 本発明に係るコーティング剤は、 水分散型樹脂に機能性物質を 混入してなるものであるため、 機能性物質が有する各種の特別な機能を畏期間に わたって継続的に有効に発揮させつづけることができるものである。  As described above, since the coating agent according to the present invention is obtained by mixing the functional substance into the water-dispersed resin, the various special functions of the functional substance are continuously provided for a long period of time. It can be used effectively.
そして、 かかるコーティング剤をシートや袋の表面にコーティングすることに よって、 シートや袋に付加価値をつけることができるものである。 尚、 袋の表面 とは、 袋の外側面に限られず、 袋の内側面も含み、 外側面だけ或いは内側面だけ にコーティングする場合もある。  By coating such a coating agent on the surface of the sheet or bag, it is possible to add value to the sheet or bag. The surface of the bag is not limited to the outer surface of the bag, but also includes the inner surface of the bag. In some cases, only the outer surface or only the inner surface is coated.
特に、 コ一ティング剤を方形状のシートの表面にコ一ティングし、 その後、 コ ーティング而を内側而としてシートを折曲し、 内则而の緣部同士を接着して袋を 形成した場合には、 内側而にコ一ティングした袋を容易に製造することができる しかも、 内側面の縁部同士を接着する際に、 コーティング剤の熱硬化性を利用 して縁部同士を熱溶着した場合には、 縁部に接着剤を塗布する工程を省略するこ とができ、 製造をより一層容易なものとすることができるとともに、 製造 用を 低廉化することができる。  In particular, when a coating agent is coated on the surface of a square sheet, and then the sheet is bent using the coating as an inner side, and the inner part is adhered to each other to form a bag. Can easily manufacture bags coated on the inner side.In addition, when bonding the edges of the inner surface, the edges are thermally welded using the thermosetting property of the coating agent. In this case, the step of applying an adhesive to the edge can be omitted, and the production can be further facilitated, and the production cost can be reduced.
また、 コーティング剤を方形状のシートの表面の一側半部の全面と他側半部の 縁部にコーティングし、 その後、 コーティング面を内側面としてシ一卜を折曲し、 内側面の縁部同士を接着して袋を形成した場合には、 袋の外側面に熱昇華性プリ ン夕等の加熱を伴う印刷装置を用いて袋の外側面に印刷を施しても、 袋の内側面 同士が接着することがなく、 使い勝手を良好なものとすることができる。 Also, a coating agent is coated on the entire surface of one half of the surface of the square sheet and the edge of the other half, and then the sheet is bent with the coated surface as the inner surface, and the edge of the inner surface is formed. If the bag is formed by bonding the parts to each other, even if the outer surface of the bag is printed using a printing device that heats the outer surface of the bag, such as a heat-sublimating printer, the inner surface of the bag can be used. Since they do not adhere to each other, good usability can be achieved.
また、 本発明では、 前記コーティング剤を表面に塗布した後に、 表面に粘性を 有する塗膜を形成するものである。 特に、 粘性を有する塗膜として、 ナメクジ科 およびコゥラナメクジ科に属する陸生巻貝の体表を覆う粘液を用いている。  In the present invention, a viscous coating film is formed on the surface after the coating agent is applied to the surface. In particular, as a viscous coating, a mucus covering the body surface of terrestrial snails belonging to the slugs and the slugs is used.
このように、 コーティング面を粘性を有する塗膜で覆うと、 表面に貝類やふじ つぼや塵などが付着するのを防止することができ、 しかも、 生物の体表を覆う粘 液によって塗膜を形成した場合には、 表面から塗膜が剥離しても、 剥離した塗膜 は自然に分解され自然界の生態系に還元され、 新規な塵の発生とならなレ、効果が める。  When the coating surface is covered with a viscous coating film in this way, it is possible to prevent shellfish, barnacles, dust, etc. from adhering to the surface, and to coat the coating film with a mucus that covers the surface of living organisms. If formed, even if the coating film is peeled off from the surface, the peeled coating film is naturally decomposed and reduced to the natural ecosystem, resulting in the generation of new dust.
さらには、 植物の表面に特別な機能を有する機能性物質をバインダ一として水 分散型樹脂を用いて付着させたものであってもよい。 ここで、 植物の表面とは、 幹や葉の表面でもよく、 また、 幹を切断した切断面であってもよい。  Further, a functional substance having a special function may be attached to the surface of a plant using a water-dispersible resin as a binder. Here, the surface of a plant may be the surface of a trunk or a leaf, or may be a cut surface obtained by cutting a trunk.
このように、 植物の表面に特別な機能を有する機能性物質をバインダ一として 水分散型樹脂を用いて付着させることによって、 機能性物質の作用によって植物 自体の浄化が行えるとともに、 害虫を駆除することができ、 植物を良好に育成す ることができ、 従来の植物育成形態とは異なる新規の植物育成形態を形成するこ とができる。  In this way, by attaching a functional substance having a special function to the surface of the plant as a binder using a water-dispersible resin, the action of the functional substance can purify the plant itself and control pests. Thus, a plant can be satisfactorily grown, and a new plant cultivation mode different from the conventional plant cultivation mode can be formed.
すなわち、 従来より、 植物の育成においては、 植物に農桀を散布したり、 土壌 に肥料をまくことが行われてきた。 しかしながら、 これらの農薬や肥料は有機物 を含んでおり、 人体に有害であり、 しかも、 自然破壊を招くことから、 近年では、 その使用をできるだけ削減するよう努力している。 そこで、 上述したように、 植 物の表而に機能性物質をバインダ一として水分散型樹脂を用いて付着させること によって、 機能性物質の作用によって植物自体の浄化が行えるとともに、 害虫を 駆除することができるので、 農薬や肥料の使用を削減することができるのである 尚、 植物の表面に機能性物質をバインダ一として水分散型樹脂を用いて付着さ せる方法としては、 水分散型樹脂を水又はアルコールで約 100倍程度に希釈した 溶液に酸化チタン等の機能性物質を所定量投入したものを上空から散布したり、 植物の幹を途中で切断し、 その切断面に直接塗布する。  That is, in the past, in the breeding of plants, it has been practiced to sprinkle agricultural jelly on the plants and to apply fertilizer to the soil. However, these pesticides and fertilizers contain organic matter, are harmful to humans, and cause natural destruction. In recent years, efforts have been made to reduce their use as much as possible. Therefore, as described above, by attaching a functional substance to the metaphysis of a plant using a water-dispersible resin as a binder, the plant itself can be purified by the action of the functional substance and the pests are eliminated. It is possible to reduce the use of pesticides and fertilizers by using water-dispersible resin. A predetermined amount of a functional substance such as titanium oxide is added to a solution diluted about 100-fold with water or alcohol, and sprayed from above, or the stem of the plant is cut midway and applied directly to the cut surface.
以下に、 本発明の具体的な実施例について説明する。 尚、 以下の実施例では、 特定の成形体に特定の機能性物質を付着させた場合について説明しているが、 こ れに限られることはなく、 ポスタ一や各種チケッ卜や絵画や封筒や薬剤用外袋や 壁紙や段ボールや各種トレイ等の紙からなる成形体や柱や壁や箱等の木材からな る成形体や陶器や磁器等の粘土からなる成形休等からなる成形体でもよく、 また、 活性炭ゃカテキン等の機能性物質でもよい。 Hereinafter, specific examples of the present invention will be described. In the following examples, a case where a specific functional substance is attached to a specific molded body is described. However, the present invention is not limited to this, and it is possible to form posters, various tickets, paintings, envelopes, outer bags for medicine, paper, such as wallpaper, corrugated cardboard, various trays, and moldings made of wood, such as pillars, walls, and boxes. The molded body may be a molded body made of clay such as a body or clay such as pottery or porcelain, or may be a functional material such as activated carbon or catechin.
(第 1実施例)  (First embodiment)
まず、 1 5 Kg の水分散型ポリエステル樹脂 (東洋紡製のバイロナール (登録 商襟)) を容器内に入れ、 さらにその中に 1 0 0 gの粉末状の酸化チタンを投入 し、 その後、 撹拌機で十分に撹袢混合することによって、 機能性物質を含有した 液状のコーティング剤を製造した。 '  First, 15 kg of a water-dispersible polyester resin (Vylonal (registered trade collar) manufactured by Toyobo) is placed in a container, and 100 g of powdered titanium oxide is further poured into the container. Thus, a liquid coating agent containing a functional substance was produced by sufficiently stirring and mixing. '
尚、 酸化チタンに代えて或いは酸化チタンとともに同量の活性炭等の炭や蜂蜜 ゃカテキンや芳香剤ゃ蓄光材料を投入してコーティング剤を製造することもでき る。  Instead of or together with titanium oxide, the same amount of charcoal such as activated carbon or honey {catechin or fragrance} can be used to produce a coating agent.
(第 2実施例)  (Second embodiment)
まず、 1 5 Kg の水分散型ポリエステル樹脂 (東洋紡製のバイロン (登録商 襟)) を容器内に入れ、 その中に有機溶剤として 7 Kg の酢酸ェチルを投入し、 さ らにその中に 100g の粉末状の酸化チタンを投入し、 その後、 撹拌機で十分に攛 袢混合することによって、 機能性物質を含— した液状のコーティング剤を製造し た。  First, 15 kg of a water-dispersible polyester resin (Vylon (registered trademark) manufactured by Toyobo) is placed in a container, and 7 kg of ethyl acetate is charged as an organic solvent into the container. The powdered titanium oxide was charged, and then thoroughly mixed with a stirrer to produce a liquid coating agent containing a functional substance.
尚、 酸化チタンに代えて或いは酸化チタンとともに同量の活性炭等の炭や蜂蜜 ゃカテキンや芳香剤ゃ蓄光材料を投入してコーティング剤を製造することもでき る。  Instead of or together with titanium oxide, the same amount of charcoal such as activated carbon or honey {catechin or fragrance} can be used to produce a coating agent.
(第 3実施例)  (Third embodiment)
まず、 1 0リッ トルの水分散型ポリエステル樹脂 (東洋紡製のバイロナール (登録商標)) を 7 0 °Cに加熱溶融させた状態で容器内に入れ、 さらにその中に l kg の粉末状の酸化チタンを投入し、 その後、 撹袢機で十分に撹桦混合するこ とによって、 機能性物質を含有した液状のコーティング剤を製造した。  First, 10 liters of a water-dispersible polyester resin (Vylon (registered trademark) manufactured by Toyobo Co., Ltd.) was heated and melted at 70 ° C and placed in a container. Titanium was charged, and then sufficiently stirred and mixed with a stirrer to produce a liquid coating agent containing a functional substance.
尚、 酸化チタンに代えて或いは酸化チタンとともに同量の活性炭等の炭や蜂蜜 や力テキンゃ芳香剤ゃ蓄光材料を投入してコ一ティング剤を製造することもでき る。  Instead of titanium oxide or together with titanium oxide, the same amount of charcoal such as activated carbon, honey, power techin, fragrance and luminous material can be added to produce a coating agent.
(第 4実施例) まず、 1 0 0 gの粉末状の蓄光材料を 1 0 0 gの有機溶剤に添加した後に撹拌 することによって蓄光材料を溶かし、 その中に 5 0 0 gの水分散型ポリエステル 樹脂 (柬洋紡製のバイロナール (登録商標)) を投入し、 その後、 撹拌機で十分 に撹拌混合することによって、 機能性物質を含有した液状のコ一ティング剤を製 造した。 (Fourth embodiment) First, 100 g of a powdery phosphorescent material was added to 100 g of an organic solvent and then stirred to dissolve the phosphorescent material, and 500 g of a water-dispersible polyester resin (teiyobo). (Vironal (registered trademark)) was added thereto, and then sufficiently stirred and mixed by a stirrer to produce a liquid coating agent containing a functional substance.
蓄光材料としては、 硫化亜鉛に銅を添加した非酸化物材料でもよく、 また、 酸 化アルミニウムを主成分とするセラミック材料に希土類元素を添加した酸化物材 料でもよい。  The phosphorescent material may be a non-oxide material obtained by adding copper to zinc sulfide, or an oxide material obtained by adding a rare earth element to a ceramic material containing aluminum oxide as a main component.
また、 有機溶剤としては、 トルエン、 酢酸ェチル等を用いた。  In addition, toluene, ethyl acetate and the like were used as the organic solvent.
さらに、 前記コ一ティング剤に 5 g程度の酸化チタンゃ活性炭等の炭や蜂蜜や カテキンや芳香剤等を添加してコーティング剤を製造することもできる。  Furthermore, a coating agent can be produced by adding about 5 g of charcoal such as titanium oxide / activated carbon, honey, catechin, or a fragrance to the coating agent.
(第 5実施例)  (Fifth embodiment)
まず、 前記実施例と同様に 1 0リツトルの水分散型ポリエステル樹脂 (柬洋紡 製のバイロナール (登録商襟)) を 7 0 °Cに加熱溶融させた状態で容器内に入れ、 さらにその中に l kg の粉末状の酸化チタンを投入し、 その後、 撹抻機で十分に 撹拌混合することによって、 機能性物質を含有した液状のコ一ティング剤を製造 した。  First, 10 liters of a water-dispersible polyester resin (Vylonal (registered trademark) manufactured by Toyobo Co., Ltd.) was heated and melted at 70 ° C. in the same manner as in the above example, and then placed in a container. Then, lkg of powdered titanium oxide was added to the mixture, and then sufficiently stirred and mixed with a stirrer to produce a liquid coating agent containing a functional substance.
次に、 上記機能性物質を含有した液状のコーティングを刷毛でポスターの表面 に塗布した。  Next, a liquid coating containing the above functional substance was applied to the surface of the poster with a brush.
これにより、 紙の表面に粉末状の酸化チタンを付着させたポスタ一が製造でき、 かかるポスターは、 酸化チクンの作用で抗菌 ·除菌ゃ消奥機能を有しており、 室 内に張っておくだけで室内の抗菌 ·除菌ゃ消臭を行うことができるといった ί寸加 ίϊΙΐ直のあるものになる。  As a result, posters in which powdered titanium oxide is adhered to the surface of paper can be manufactured. Such posters have an antibacterial / sterilizing / removing function by the action of titanium oxide, and can be stretched indoors. Just put it on and it will be possible to perform antibacterial, sanitizing and deodorizing indoors.
(第 6実施例)  (Sixth embodiment)
まず、 5 Kg の水分散型ポリエステル樹脂 (柬洋紡製のバイロナ一ル (登録商 標)) と 2 O の水溶性 O Pニスを容器内に入れ、 さらにその中に 5 0g の粉末 状の酸化チタンを投入し、 その後、 撹拌機で十分に撹拌混合することによって、 機能性物質を含有した液状のコ一ティング剤を製造した。  First, 5 kg of a water-dispersible polyester resin (Vylonal (registered trademark) manufactured by TEYOBO) and a water-soluble OP varnish of 2 O are placed in a container, and 50 g of powdery oxidized resin is further placed in the container. Titanium was charged, and then sufficiently stirred and mixed with a stirrer to produce a liquid coating agent containing a functional substance.
次に、 上記機能性物質を含有した液状のコーティングを刷毛でポスターの表面 に塗布した。 これにより、 紙の表面に粉来状の酸化チタンを付着させたポスターが製造でき、 かかるポスターは、 酸化チタンの作用で抗菌 ·除菌ゃ消臭機能を有しており、 室 内に張っておくだけで室内の抗菌 ·除菌ゃ消臭を行うことができるといった付加 価値のあるものになる。 Next, a liquid coating containing the above functional substance was applied to the surface of the poster with a brush. This makes it possible to manufacture posters in which powdered titanium oxide is attached to the surface of paper. Such posters have antibacterial, sterilization, and deodorizing functions by the action of titanium oxide, and can be stretched indoors. Just adding it will add value, such as being able to perform antibacterial, sanitizing, and deodorizing indoors.
(第 7実施例)  (Seventh embodiment)
まず、 前記実施例と同様に 1 0リツトルの水分散型ポリエステル樹脂 (東洋紡 製のバイロナ一ル (登録商標)) を 7 0 °Cに加熱溶融させた状態で容器内に入れ、 さらにその中に l kg の粉末状の酸化チタンを投入し、 その後、 撹拌機で十分に 撹拌混合することによって、 機能性物質を含有した液状のコーティング剤を製造 した。  First, 10 liters of a water-dispersible polyester resin (Vylonal (registered trademark) manufactured by Toyobo Co., Ltd.) was heated and melted at 70 ° C. in the same manner as in the above example, and then placed in a container. 1 kg of powdered titanium oxide was charged, and then sufficiently stirred and mixed with a stirrer to produce a liquid coating agent containing a functional substance.
次に、 上記機能性物質を含有した液状のコーティング剤に着色剤を添加し、 そ れを印刷機でチケットの表面に印刷した。  Next, a coloring agent was added to the liquid coating agent containing the above-mentioned functional substance, and it was printed on the surface of the ticket with a printing machine.
これによつても、 表面に粉末状の酸化チタンを付着させたチケッ卜が製造でき、 かかるチケッ トは、 酸化チタンの作 fflで抗菌 ·除菌ゃ消臭機能を有するといった 付加価値のあるものになる。  According to this method, a ticket having powdered titanium oxide adhered to the surface can be produced, and such a ticket has an added value such as anti-bacterial / sterilizing / deodorizing function due to the production of titanium oxide ffl. become.
(第 8実施例)  (Eighth embodiment)
まず、 前記実施例と同様に 1 0リツ トルの水分散型ポリエステル樹脂 (東洋紡 製のバイロナ一ル (登録商標)) を 7 0 °Cに加熱溶融させた状態で容器内に入れ、 さらにその中に l kg の粉末状の酸化チタンを投入し、 その後、 撹拌機で十分に 撹桦混合することによって、 機能性物質を含有した液状のコーティング剤を製造 した。  First, 10 liters of a water-dispersible polyester resin (Vylonal (registered trademark) manufactured by Toyobo Co., Ltd.) was heated and melted at 70 ° C. in a container in the same manner as in the above Example, and further contained therein. Then, 1 kg of powdered titanium oxide was added to the mixture, and then sufficiently stirred and mixed with a stirrer to produce a liquid coating agent containing a functional substance.
次に、 上記機能性物質を含有した液状のコーティング剤に包装紙を 1 0分間浸 漬し、 その後、 その包装紙を乾燥した。  Next, the wrapping paper was immersed in a liquid coating agent containing the above functional substance for 10 minutes, and then the wrapping paper was dried.
これによつても、 表面に粉末状の酸化チ夕ンを付着させた包装紙が製造でき、 かかる包装紙は、 酸化チタンの作川で抗菌 ·除菌ゃ消臭機能を有するといった付 加価値のあるものになる。  This also makes it possible to manufacture wrapping paper with powdered titanium oxide adhering to the surface. Such wrapping paper has the added value of having antibacterial, antibacterial, and deodorizing functions at the titanium oxide Sakugawa. With something.
(第 9実施例)  (Ninth embodiment)
まず、 前記実施例と同様に 1 0リッ トルの水分散型ポリエステル椋: f脂 (東洋紡 製のバイロナール (登録商標)) を 7 0 °Cに加熱溶融させた状態で容器内に入れ、 さらにその中に l kgの粉末状の酸化チタンを投入し、 その後、 撹拌機で十分に 撹拌混合することによって、 機能性物質を含有した液状のコ一ティング剤を製造 した。 First, 10 liters of a water-dispersible polyester Rho: f Fat (Vylon (registered trademark) manufactured by Toyobo Co., Ltd.) was heated and melted at 70 ° C. in the same manner as in the above Example, and then placed in a container. Add l kg of powdered titanium oxide into it, and then use a stirrer By stirring and mixing, a liquid coating agent containing a functional substance was produced.
次に、 図 1に示すように、 上記機能性物質を含有した液状のコーティング剤を 長方形状の紙製のシートの表面に刷毛で塗布した後に乾燥した (図 1 (a)参照)。 これにより、 図 1 (a)に示すように、 シート 1の表面にコーティング剤がコ一テ ィングされてコーティング面 2が形成される。  Next, as shown in FIG. 1, a liquid coating agent containing the above-mentioned functional substance was applied to the surface of a rectangular paper sheet with a brush and dried (see FIG. 1 (a)). As a result, as shown in FIG. 1 (a), the coating agent is coated on the surface of the sheet 1 to form the coating surface 2.
次に、 シート 1の中央部 (図 1 (a)中、 点線で示す折曲線 3 ) にてコ一ティン グ面 2が内側面になるようにシート 1を折曲し (図 1 (b)参照)、 その後、 シート 1の左右両緣部 4, 5にて接着して袋 6を製造した (図 1 (c )参照)。  Next, sheet 1 is bent at the center of sheet 1 (folding curve 3 shown by the dotted line in FIG. 1 (a)) so that coating surface 2 is the inner surface (FIG. 1 (b) Then, a bag 6 was manufactured by bonding the left and right sides 4, 5 of the sheet 1 (see FIG. 1 (c)).
シート 1の左右両縁部 4, 5を接着する際には、 縁部 4,5に塗布されたコーティ ング剤の熱硬化性を利用して、 別途接着剤を塗布することなく、 熱溶着した。 尚、 縁部 4, 5に接着剤を別途塗布してもよい。  When bonding the left and right edges 4 and 5 of the sheet 1, the thermosetting property of the coating agent applied to the edges 4 and 5 was used to apply heat welding without applying an additional adhesive. . Note that an adhesive may be separately applied to the edges 4 and 5.
これによつても、 内側面に粉末状の酸化チタンを付着させた袋が製造でき、 か かる袋は、 酸化チタンの作用で抗菌 ·除菌ゃ消臭機能を有するといった (寸加価値 のあるものになる。  This also makes it possible to manufacture bags with powdered titanium oxide adhered to the inner surface, and such bags have antibacterial, antibacterial, and deodorant functions due to the action of titanium oxide. Become something.
(第 1 0実施例)  (10th embodiment)
まず、 前記実施例と同様に 1 0リツトルの水分散型ポリエステル樹脂 (柬洋紡 製のバイロナール (登録商標)) を 7 0 °Cに加熱溶融させた状態で容器内に入れ、 さらにその中に l kg の粉末状の酸化チタンを投入し、 その後、 撹拌機で十分に 撹袢混合することによって、 機能性物贾を含有した液状のコーティング剤を製造 した。  First, 10 liters of a water-dispersed polyester resin (Vylonal (registered trademark) manufactured by Toyobo Co., Ltd.) was heated and melted at 70 ° C. in a container in the same manner as in the above example, and further contained therein. 1 kg of powdered titanium oxide was charged, and then sufficiently stirred and mixed with a stirrer to produce a liquid coating agent containing the functional substance II.
次に、 図 2に示すように、 上記機能性物質を含有した液状のコ一ティング剤を 長方形状の紙製のシートの表面に刷毛で塗布した後に乾燥した (図 2 (a)参照)。 これにより、 図 2 (a)に示すように、 シート 1の表面にコーティング剤がコーテ ィングされてコ一ティング而 2が形成される。  Next, as shown in FIG. 2, a liquid coating agent containing the above-mentioned functional substance was applied to the surface of a rectangular paper sheet with a brush, and then dried (see FIG. 2 (a)). As a result, as shown in FIG. 2A, the coating agent is coated on the surface of the sheet 1 to form the coating 2.
その際に、 図 2 (a)に示すように、 シート 1の左側半部には全而にコ一ティン グ剤を塗布してコーティング面 2a を形成し、 一方、 シート 1の右側半部には左 右縁部 3,4にのみコーティング剤を塗布してコーティング面 2bを形成する。  At this time, as shown in FIG. 2 (a), a coating agent is applied to the left half of the sheet 1 to form a coating surface 2a, while the right half of the sheet 1 is formed. Applies coating agent only to left and right edges 3 and 4 to form coated surface 2b.
次に、 シート 1の中央部 (図 2 (a)中、 点線で示す折曲線 3 ) にてコーティン グ面 2が内側面になるようにシート 1を折曲し (図 2 (b)参照)、 その後、 シート 1の左右両縁部 4, 5にて接着して袋 6を製造した (図 2 ( c )参照)。 Next, the sheet 1 is bent at the center of the sheet 1 (the broken line 3 shown by the dotted line in FIG. 2 (a)) so that the coating surface 2 becomes the inner surface (see FIG. 2 (b)). Then the sheet The bag 6 was manufactured by bonding at the left and right edges 4 and 5 of 1 (see FIG. 2 (c)).
シート 1の左右両縁部 4, 5を接着する際には、 縁部 4, 5に塗布されたコーティ ング剤の熱硬化性を利用して、 別途接着剤を塗布することなく、 熱溶着した。 尚、 縁部 4, 5に接着剤を別途塗布してもよい。  When bonding the left and right edges 4 and 5 of the sheet 1, the thermosetting properties of the coating agent applied to the edges 4 and 5 were used to apply heat welding without applying an additional adhesive. . Note that an adhesive may be separately applied to the edges 4 and 5.
これによつても、 内側面に粉末状の酸化チタンを付着させた袋が製造でき、 か かる袋は、 酸化チタンの作用で抗菌 ·除菌ゃ消臭機能を有するといった付加価値 のあるものになる。  According to this, bags with powdered titanium oxide adhered to the inner surface can be manufactured. Such bags have added value such as antibacterial, sterilization and deodorant functions by the action of titanium oxide. Become.
(第 1 1実施例)  (Example 11)
まず、 前記実施例と同様に 1 0リツトルの水分散型ポリエステル樹脂 (東洋紡 製のバイロン (登録商標)) を 7 0 °Cに加熱溶融させた状態で容器内に入れ、 さ らにその中に l kg の粉末状の酸化チタンを投入し、 その後、 撹袢機で十分に撹 拌混合することによって、 機能性物質を含有した液状の樹脂を製造した。  First, in the same manner as in the above example, 10 liters of a water-dispersible polyester resin (Vylon (registered trademark) manufactured by Toyobo) was heated and melted at 70 ° C. in a container, and further placed in the container. lkg of powdered titanium oxide was charged, and then sufficiently stirred and mixed with a stirrer to produce a liquid resin containing a functional substance.
次に、 上記機能性物質を含有した液状の樹脂に 5 O Kg のパルプを混入し、 そ れを加圧成形機で鮮魚搬送用トレイに成形した。  Next, 5 O Kg of pulp was mixed with the liquid resin containing the above functional substance, and the mixture was molded into a tray for transporting fresh fish using a pressure molding machine.
これによつても、 表面に粉来状の酸化チタンを付着させた鮮魚搬送用トレイが 製造でき、 かかる鮮魚搬送用卜レイは、 酸化チタンの作用で除菌ゃ消臭機能を有 するといつた付加価値のあるものになる。  According to this method, a tray for transporting fresh fish having powdered titanium oxide adhered to the surface can be manufactured, and such a tray for transporting fresh fish has a function of removing bacteria and eliminating odors by the action of titanium oxide. It will be value-added.
(第 1 2実施例)  (Example 12)
まず、 前記実施例と同様に 1 0リツトルの水分散型ポリエステル樹脂 (東洋紡 製のバイロン (登録商標)) を 7 0 °Cに加熱溶融させた状態で容器内に入れ、 さ らにその中に l kg の粉^状の酸化チタンを投入し、 その後、 撹拌機で十分に悅 袢混合することによって、 機能性物質を含有した液状の樹 U旨を製造した。  First, in the same manner as in the above example, 10 liters of a water-dispersible polyester resin (Vylon (registered trademark) manufactured by Toyobo) was heated and melted at 70 ° C. in a container, and further placed in the container. 1 kg of powdery titanium oxide was charged, and then thoroughly mixed with a stirrer to produce a liquid tree containing a functional substance.
次に、 上記機能性物質を含有した液状の樹脂に生花用スポンジを 1 0分間浸漬 して、 生花用スポンジの内部に樹脂を浸透させ、 その後、 その生花用スポンジを 乾燥した。  Next, the sponge for fresh flowers was immersed in the liquid resin containing the above functional substance for 10 minutes to allow the resin to penetrate into the sponge for fresh flowers, and then the sponge for fresh flowers was dried.
これによつても、 表面に粉末状の酸化チ夕ンを付着させた生花用スポンジが製 造でき、 かかるスポンジは、 酸化チタンの作用で除菌ゃ消臭機能を有するといつ た付加価値のあるものになる。  According to this method, a sponge for fresh flowers having powdered titanium oxide adhered to the surface can be manufactured, and such a sponge has a value-added value that has a sterilizing and deodorizing function by the action of titanium oxide. There will be something.
(第 1 3実施例)  (13th embodiment)
まず、 前記実施例と同様に 1 0リツトルの水分散型ポリエステル樹脂 (東洋紡 製のバイロン (登録商標)) を 7 0 °Cに加熱溶融させた状態で容器内に入れ、 さ らにその中に l kg の粉末状の酸化チタンを投入し、 その後、 撹拌機で十分に撹 袢混合することによって、 機能性物質を含有した液状の樹脂を製造した。 First, a 10 liter water-dispersible polyester resin (Toyobo (Vylon (registered trademark)) is heated and melted at 70 ° C and placed in a container. Then, lkg of powdered titanium oxide is charged therein, and then sufficiently stirred with a stirrer. By mixing with stirring, a liquid resin containing a functional substance was produced.
次に、 上記機能性物質を含有した液状の樹脂に 5 O Kg のパルプを混入し、 そ れを加圧成形機で図 3に示すハニカムコア 1 1に成形した。 図中、 1 6はハニカ ムコア 1 1に形成された六角柱状の貫通孔である。  Next, pulp of 5 O Kg was mixed into the liquid resin containing the above-mentioned functional substance, and the mixture was formed into a honeycomb core 11 shown in FIG. 3 by a pressure molding machine. In the figure, 16 is a hexagonal column-shaped through hole formed in the honeycomb core 11.
次に、 図 4及び図 5に示すように、 ハニカムコア 1 1の表裏に板 12, 13を接着 してパネル 1 4を製作した。  Next, as shown in FIGS. 4 and 5, panels 12 and 13 were bonded to the front and back of the honeycomb core 11 to produce a panel 14.
板 2,3には、 針で複数の小径の貫通孔 1 5を穿設してあり、 しかも、 表面に上 記機能性物質を含有した液状の樹脂を塗布した。  A plurality of small-diameter through-holes 15 were formed in the plates 2 and 3 with needles, and a liquid resin containing the above-described functional substance was applied to the surfaces.
このように本実施例では、 貫通孔 1 6を有するコア材の表面に機能性物質を付 着させ、 そのコア材の表衷に貫通孔 1 5を有するとともに表面に機能性物質を付 着させた板材を接着することによってパネル 1 4を製作した。 かかるパネル 1 4 は、 貫通孔 15, 16の作用によってパネル全体としても貴 '通した状態となっており、 パネルを全体としてみても通気性を有している。 そのため、 機能性物質と空気と の接触が良好なものとなっている。  As described above, in the present embodiment, the functional material is attached to the surface of the core material having the through hole 16, and the functional material is attached to the surface while having the through hole 15 eclectic of the core material. Panel 14 was manufactured by bonding the sheet materials. The panel 14 is in a state of passing through the panel as a whole due to the action of the through holes 15 and 16 and has air permeability even when the panel as a whole is viewed. Therefore, the contact between the functional substance and air is good.
(第 1 4実施例)  (Example 14)
まず、 5 Kg の水分散型ポリエステル樹脂 (東洋紡製のバイロナ一ル (登録商 標)) と 2 0 Kg の水溶性 0 Pニスを容器内に入れ、 さらにその中に 5 0 g の粉末 状の酸化チタンを投入し、 その後、 撹抻機で十分に撹拌混合することによって、 機能性物質を含有した液状のコーティング剤を製造した。  First, 5 kg of a water-dispersible polyester resin (Vylonal (registered trademark) manufactured by Toyobo) and 20 kg of a water-soluble 0 P varnish are placed in a container, and 50 g of a powdery powder is further placed therein. Titanium oxide was charged, and then sufficiently stirred and mixed with a stirrer to produce a liquid coating agent containing a functional substance.
次に、 上記機能性物質を含有した液状のコ一ティングを強化プラスチック製の 船体の底面の表面に塗布した。  Next, a liquid coating containing the above functional material was applied to the bottom surface of the hull made of reinforced plastic.
その後、 表面に粘性を有する塗膜として、 ナメクジ科およびコゥラナメクジ科 に属する陸生巻貝の体表を覆う粘液を塗布して、 表面に粘性を有する塗膜を形成 した。  Then, as a viscous coating film on the surface, a mucus covering the body surface of the terrestrial snails belonging to the slugs and the slugs was applied to form a viscous coating on the surface.
これにより、 船底表面に粉末状の酸化チタンを付着させたコーティング層とそ の表面を被覆する粘性を有する塗膜を形成することができた。 かかる船底表面は は、 酸化チタンの作用で抗菌 ·除菌ゃ消臭機能を有しており、 しかも、 粘性を有 する塗膜で表面を覆っているため、 表面に貝類やふじつぼや塵などが付着するの を防止する機能を有していた。 さらには、 生物の体表を覆う粘液によって塗膜を 形成しているため、 表面から塗膜が剥離しても、 剥離した塗膜は自然に分解され 自然界の生態系に還元され、 新規な塵の発生とならない。 産業上の利用可能性 As a result, it was possible to form a coating layer in which powdered titanium oxide was adhered to the ship bottom surface and a viscous coating film covering the surface. The hull bottom surface has antibacterial, antibacterial, and deodorant functions due to the action of titanium oxide, and is covered with a viscous coating film. Will stick Had the function of preventing Furthermore, since the coating film is formed by the mucus that covers the body surface of living organisms, even if the coating film peels off from the surface, the peeled coating film is naturally decomposed and reduced to natural ecosystems, creating new dust. Does not occur. Industrial applicability
本発明は、 以上に説明したような形態で実施され、 以下に記載されるような効 果を奏する。  The present invention is embodied in the form described above and has the following effects.
すなわち、 本発明に係るコーティング剤は、 水分散型樹脂に機能性物質を混入 してなるものであるため、 機能性物質が有する各種の特別な機能を長期間にわた つて継続的に有効に発揮させつづけることができる。  That is, since the coating agent according to the present invention is obtained by mixing a functional substance into a water-dispersed resin, various special functions of the functional substance are continuously and effectively exerted over a long period of time. You can keep it.
そして、 かかるコーティング剤を成形体の表面にコ一ティングすることによつ て、 成形体に付加価値をつけることができる。  By applying such a coating agent on the surface of the molded article, it is possible to add value to the molded article.

Claims

請 求 の 範 囲 The scope of the claims
1 . 非結晶状態で硬化することにより硬化後に通気性を有する樹脂である水分散 型樹脂に抗菌 ·抗菌 ·除菌 ·消臭 ·脱臭 ·防黴 ·芳香 ·蓄光等の特別の機能を有 する機能性物質を混入してなるコーティング剤。  1. It has special functions such as antibacterial, antibacterial, sanitizing, deodorizing, deodorizing, antifungal, fragrance, and luminous properties to the water-dispersible resin, which is a resin that has air permeability after curing by curing in an amorphous state. Coating agent mixed with functional substances.
2 . 請求項 1記載のコ一ティング剤を方形状のシートの表面にコ一ティングし、 その後、 コーティング面を内側面としてシー卜を折曲し、 内側面の縁部同士を前 記コーティング剤の接着力を用いて接着したことを特徴とする袋。 2. The coating agent according to claim 1 is coated on the surface of a square sheet, and then the sheet is bent with the coated surface as the inner surface, and the edges of the inner surface are coated with the coating agent. A bag characterized in that the bag is adhered by using the adhesive force.
3 . 請求項 1記載のコーティング剤を方形状のシートの峩面の一側半部の全而と 他側半部の縁部にコーティングし、 その後、 コーティング面を内側面としてシー トを折曲し、 内側面の縁部同士を前記コ一ティング剤の接着力を用いて接着した ことを特徴とする袋。 3. The coating agent according to claim 1 is coated on one side half of the gar surface of the rectangular sheet and on the other side edge, and then the sheet is bent with the coated surface as the inner surface. A bag characterized in that edges of inner surfaces are adhered to each other by using an adhesive force of the coating agent.
4 . 請求項 1記載のコーティング剤を表面に ί寸着させたことを特徴とする成形体 c4. A molded article c characterized by having the coating agent according to claim 1 adhered to the surface thereof by a dimension.
5 . 前記成形体は、 通気性を有することを特徴とする請求項 4記載の成形体。 5. The molded article according to claim 4, wherein the molded article has air permeability.
6 . 請求項 1記載のコーティング剤を表面に塗布した後に、 表面に粘性を有する 塗股を形成することを特徴とするコーティング方法。 6. A coating method characterized by forming a viscous coat on the surface after applying the coating agent according to claim 1 to the surface.
7 . 前記粘性を有する塗膜として、 ナメクジ科およびコゥラナメクジ科に屈する 陸生卷貝の休表を覆う粘液を用いることを特徴とする請求項 6記載のコーティン グ方法。 7. The coating method according to claim 6, wherein as the viscous coating film, a mucus covering a rest of a terrestrial conch which succumbs to the slugs and the slugs is used.
PCT/JP2002/010686 2001-10-12 2002-10-15 Coating, bag or molded article coated with the coating and coating method WO2003044112A1 (en)

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EP1541495A1 (en) * 2003-12-12 2005-06-15 INTERNATIONAL FLAVORS & FRAGRANCES INC. Packaging for eliminating off-odors
WO2009140507A2 (en) * 2008-05-14 2009-11-19 Drayton Miller "green" temperature-controlled mailer
CN104179016A (en) * 2014-07-30 2014-12-03 滁州惠智科技服务有限公司 Anti-bacterial composite paint for fabrics and preparation method of anti-bacterial composite paint
CN106987078A (en) * 2017-04-01 2017-07-28 华南理工大学 A kind of water dispersible property light stabilizer and preparation method thereof
US9738420B2 (en) 2008-05-14 2017-08-22 Drayton Granville MILLER “Green” temperature-controlled mailer

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JPH02227471A (en) * 1989-02-28 1990-09-10 Dainippon Ink & Chem Inc Immobilized enzyme-containing composite resin for antifouling coating and antifouling coating containing same
JP2000095979A (en) * 1998-09-21 2000-04-04 Kansai Paint Co Ltd Room pollution remedy water paint
JP2000095980A (en) * 1998-09-21 2000-04-04 Kansai Paint Co Ltd Room pollution remedy water paint
JP2002012832A (en) * 2000-04-28 2002-01-15 Asahi Kasei Corp Water-based coating material
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1541495A1 (en) * 2003-12-12 2005-06-15 INTERNATIONAL FLAVORS & FRAGRANCES INC. Packaging for eliminating off-odors
WO2009140507A2 (en) * 2008-05-14 2009-11-19 Drayton Miller "green" temperature-controlled mailer
WO2009140507A3 (en) * 2008-05-14 2010-02-25 Drayton Miller "green" temperature-controlled mailer
US9738420B2 (en) 2008-05-14 2017-08-22 Drayton Granville MILLER “Green” temperature-controlled mailer
CN104179016A (en) * 2014-07-30 2014-12-03 滁州惠智科技服务有限公司 Anti-bacterial composite paint for fabrics and preparation method of anti-bacterial composite paint
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CN106987078A (en) * 2017-04-01 2017-07-28 华南理工大学 A kind of water dispersible property light stabilizer and preparation method thereof

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